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By K. M. Ed

AN explosive is a solid or liquid substance which, when fired by some means, changes into a gaseous product occupying a volume very much greater than its original volume. The great speed at which this change takes place causes the explosive to exert a sudden blow on adjacent material. It is this action which is effective in blasting operations when the explosive, confined in a shot-hole, is fired. All explosives are similar in one respect, in that the change into the gaseous state is accompanied by the production of hot gases or flame. This results from the rapid combustion of the solid or liquid ingredients. Ex-plosives differ greatly, however, in the speed at which the reaction takes place. Black blasting powder, for instance, reacts comparatively slowly, hence the flame persists for an appreciable length of time. High explosives, on the other hand, react much more quickly; consequently, the flame is of much shorter duration. In 'closed-light' or 'gaseous' coal mines, the use of ordinary explosives is generally prohibited, due to their inherent ability to ignite gas or coal-dust by reason of the flame which they produce when fired. For instance, black blasting powder, which produces a flame of long duration, is not ordinarily considered safe to use in such mines; neither are ordinary dynamites, as their flames, while shorter than that of black blasting powder are, nevertheless, of sufficient temperature and duration to cause ignition of fire-damp or coal-dust. For this reason, specially formulated high explosives, called 'permitted' explosives, should invariably be used in such mines.

Jan 1, 1940

By Elizabeth Edwards, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg, Kurtis Judd

Mineralogical characterization of the tailings showed the deportment of Ni to be similar in the Vale and Glencore tailings, with 60% of the total Ni locked in pyrrhotite, and the balance 40% associated with pentlandite. The overall Ni dissolution was correlated with the individual dissolution extents of pyrrhotite and pentlandite as functions of four leaching regimes: ‘anoxic acid’ (with and without pH control), ‘oxic acid’ (oxygen sparging), ‘oxic acid’ (air sparging), and ‘oxic ferric’ (air sparging). The results showed that the maximum Ni dissolution was obtained during the pH controlled oxic acid leach with oxygen sparging at pH 1.5, while the anoxic acid leach at pH 1.5 resulted in minimum Ni dissolution (10–15%) from pyrrhotite. An overall Ni mass balance showed that pyrrhotite and pentlandite dissolve simultaneously in the presence of Fe(III) and oxygen, in contrast to the preferential dissolution of pyrrhotite in the absence of Fe(III). Sulphur mass balances revealed that the yield of elemental sulphur is maximized (65%) during the oxic Fe(III) leach at pH 0.6. Furthermore, the kinetics of Ni leaching and elemental sulphur formation from pyrrhotite tailings leached with ferric sulphate between 55–80°C was investigated at constant oxidation-reduction potential. Elemental sulphur yield increased with increasing temperature, but no observable trend could be linked to ferric or ferrous ion concentration.

Jan 1, 2017

By V. Pouyafar

In recent years semi-solid processing of steel alloys has gain more attention among researchers. Production of high quality complex steel parts with higher mechanical properties is the final goal for all these researches. A thorough understanding of the flow behavior of the metal under investigation is the key for a successful process design. The material used in this research is M2 tool steel. The experiments were performed using a Searl-type concentric cylindrical rheometer which is specially designed for high temperature rheological measurements up to 1500 ºC. The rheological techniques were consisted of continuous cooling experiments and isothermal holding and also shear rate step change experiments for different solid fractions. Based on the rheological data a single phase thixotropic model has been derived and adopted to the measured data. The state of the microstructure has been applied through a structural parameter. The model fits well with the experiments.

Oct 1, 2011

By Z. D. Hora

Air hough diatomite is known in many parrs of British Columbia, deposirs of mineable size have only been found in the area between Kam/oops and Quesnel in the sourh-cenrral parr of rhe province. Ar Quesnel, commercial producrion has continued since 1950 from diatomite lenses up ro 35m rhick. OCCURRENCES of diatomite are reported from many parts of British Columbia, but deposits of mineable size are known only from the area between Kamloops and Quesnel. Only Quesnel deposits have yet reached the production stage. Commercial production dates back to 1950, and up until 1979 approximately 22,700 tonnes of diatomite had been produced. Most extracted diatomite was processed until 1980 by Crownite Industrial Minerals Limited in Quesnel to produce an oil absorbent and animal bedding. Smaller shipments are used to make insulating bricks on the lower mainland. Deposits near Quesnel extend 40 km along the western bank of the Fraser River from Quesnel to Alexandria; most production has come from Lots o. 6132 and 906. Di atomite is present as discontinuous lenses up to 35 m thick. Diatomite beds Industrial Minerals in Canada are of Upper Miocene age and are overlain by plateau basalts. Diatomite consists almost exclusively of Melosira granulara diatoms that are usually very small and mixed with variable amounts of clay, ilt and volcanic ash. In recent years, extensive beds of diatomite were identified near the confluence of the Chilcotin and Fraser rivers. Diatomite in this locale is a part o f the Upper Miocene to Pliocene Chilcotin Group of sedimentary rocks that are overlain by olivine basalt and related luffs. A deposit near Red Lake is situated 50 km northwest of Kamloops. Diatomite beds occur in the Tranquille Series of Eocene age and are similar in composition to those in the Quesnel area. The Red Lake deposit is abo ut 4 m thick but its areal extent is only a few tens of hectares.

Jan 1, 1984

By Joseph Bradley

THROUGHOUT this article, minerals used in the paint industry are designated 'pigments'. They may be classified in two groups: (1) Pigments which are used in the state in which they occur in nature, requiring only mechanical preparation. (2) Pigments which require heating or chemical treatment before use, in order to obtain from them a product of the desired quality or shade of colour. They may be further classified according to colour, as follows: White Pigments .-These include calcium carbonate (chalk, marble), gypsum and alabaster, kaolin-or china-clay, and magnesia. However, the white pigments most extensively used are compounds prepared chemically from minerals containing lead, zinc, titanium, and antimony. The white pigments are of particular importance because, not only are they used by themselves, but they also serve as adjuncts to other colours for the production of special shades. Yellow Pigments.-These are mainly naturally occurring ferric hydroxides, as limonite and bog iron ore, or similar. compounds prepared artificially. Brown Pigments .-Pigments of this group are distinguished for their beauty and depth of colour, and many of them are used in the finest of paintings. Familiar names are sienna, umber, and Vandyke brown. They are for the most part ferric hydroxides, containing varying amounts of water; but the group also includes a manganese brown, which consists chiefly of a mixture of oxide and hydroxide of manganese. Red Pigments.-Chief among this group is ferric oxide, known under various trade-names, such as Canadian red, Persian red, etc., and also the much prized and somewhat rare vermilion. The pigment used is either naturally occurring hematite, de-hydrated limonite, or artificially produced red ferric oxide.

Jan 1, 1937

By X. Z. Yuan

Contamination introduced by the impurities from the feed stream can impact the PEM fuel cell performance dramatically. The presence of these unwanted trace species such as CO, H2S, NH3, can adversely affect the fuel cell functioning. It has been reported that the major impact of CO and H2S contamination on the fuel cell performance is kinetic while the effect of NH3 contamination is speculated as membrane conductivity reduction only. In this paper, a model regarding the NH3 contamination is described and the mechanism of the NH3 contamination is illuminated by the model calculations.

Jan 1, 2005

By H. Tokuichi, H. Ohta, K. Sato

A physical separation technique of tantalum capacitors from waste print circuit boards is in a development phase in Japan. A tantalum capacitor consists of an exterior coating of resin (epoxy resin) mixed with silica fillers and a sintered tantalum compact, the latter of which is impregnated with manganese dioxide (MnO2). In this study, we developed a process to recover tantalum oxide from tantalum capacitors by roasting, fluidized-bed separation, and hydrometallurgical treatments. Our aim was to recover tantalum oxide with high purity from waste tantalum capacitors. In this process, the exterior resin was selectively decomposed by roasting without oxidation and pulverization of the sintered tantalum compact at a proper temperature. Furthermore, the decomposed resin with silica filler on the surface of the sintered tantalum compact was mostly removed by fluidized-bed separation. The surface of the sintered tantalum compact was cleaned by ultrasonic irradiation in an acid solution to remove the MnO2 paste as well as residual Ag paste and silica filler. The impregnated MnO2 in the sintered tantalum compact was leached as Mn(II) ions using acid solutions via the reducing effect of tantalum metal to recover purified tantalum oxide.

Jan 1, 2014

By I. Filzwieser, S. Konetschnik, A. Filzwieser, A. Anzinger

Production in copper electrorefining tankhouses mainly depend on two factors: The deposition area, which is a result of the amount of installed cells and cathodes, as well as the current density - the amperage per square meter of deposition area. The present paper shows, that the most economical way of achieving a certain production is to maximize current density by using the METTOP-BRX-Technology - as building and infrastructure can be kept more compact. This industrial proven technology applies a parallel electrolyte flow in each electrolysis cell. In 2011, the first fully industrial applications started up: At the secondary smelter Montanwerke Brixlegg AG, 156 cells are equipped with the METTOP-BRX-Technology; this allows a current density of 390 A/m². Xiangguang Copper Co., Ltd. - a primary smelter and refinery - operates its new tankhouse (720 cells) at 420 A/m²; this stands for an production increase of 50% compared to the same sized ISA tankhouse which is limited to 280 A/m². The first part of the present paper gives a cost comparison between a conventional copper electrorefining tankhouse and a high current density tankhouse when assuming a Greenfield project. The second part describes the cost savings when installing the METTOP-BRXTechnology in an already operating tankhouse.

Jan 1, 2014

By J. W. Smith, J. Van Dusen, A. Papachristodoulou

"As part of a study to evaluate factors affecting tankroom air quality, the mechanism of aerosol generation from bursting bubbles in electrowinning operations has been investigated. Typically 2 to 3 mg/m2.s are produced in zinc tankrooms. Analysis shows that the rate of production of film drops (geometric mean diameter - 2 urn] increases with decreasing bubble size, and that jet droplets (geometric mean diameter - 20 um) are not produced with gas bubble larger than - 4 mm. Both mechanisms of drop formation and current efficiency are affected by surface active agents, with an over-all reduction in emission of up to 60% to 70% being achievable. A source control system which does not adversely affect electrolyte properties is always preferred, and coalescence of all gas bubbles in to a continuous stream of gas at a single point on the electrolyte surface would eliminate aerosol emissions. This objective was the basis for design of a coalescence device which, in laboratory tests, reduced the emission rate by over 95%.The control device fit s over the electrodes in the electrowinning cell and is partially immersed in the electrolyte. A number of changes in the design which resulted in significant improvement in the performance of the device are reported.Field tests have shown that only about 75% of the aerosol below 10 um can be eliminated by coalescence. The remainder (up to 95% of the total) is controlled by coalescence of droplets, by impaction on the exposed collector surface and gravitational settling.The device does not interfere with operation of the tankroom, handles the effect of surges in power during harvesting, and is simple and inexpensive to maintain. IntroductionDuring the electrowinning of metals (such as zinc and copper) gases are evolved along the electrode surface forming small bubbles. The bubbles travel upwards and burst on the electrolyte free surface generating, in this way, small droplets. Because the electrolyte is often highly acidic or contains toxic materials, the whole process can result in the formation of an aerosol in the atmosphere above the electrowinning cells which poses a serious health hazard to workers in the area, and corrodes equipment."

Jan 1, 1988

By Masafumi Maeda

Metal recycling and waste treatment have become common issues in various metal industries, notably, the iron and steelmaking industry and the nonferrous industry. The former tends to treat mass wastes such as municipal wastes or plastics. However, volatile compounds are condensed in dusts of their incineration processes and they should also be treated, likely by the nonferrous industry. Those "end-of-life" products contain heavy metals that might be harmful to mankind and should be handled by the non-ferrous industry. Not only revenue derived from regeneration of metals from the secondary materials but also the revenue generated from the treatment charges is a strong attraction for nonferrous industry to process secondary materials. The present study presents some statistical data of the Japanese corporations in the iron and steelmaking industry as well as the nonferrous industry on their revenues generated from processing of secondary materials. Some of the companies are now concentrating their business resources on new areas of the market. Although the quantity of waste or recyclable material is still small at present, the quantity will increase in the near future, and it is anticipated that international collaboration is required to handle the greater variety and the larger quantity of secondary materials.

Jan 1, 2004

By John Oxenford

There are currently two operators producing oil from the surface-mineable portions of Alberta?s oil sands (Syncrude Canada Ltd. and Suncor Inc.) and two other companies are proposing to enter the industry (Albian Sands in 2002 and True North in 2004). Tailings from the two current oil sands plants contain approximately 220 000 tonnes per year of recoverable TiO2 and approximately 80 000 tonnes per year of recoverable zircon. This represents approximately 6% of the world?s TiO 2 consumption and approximately 9% of the world?s zircon production. With the commissioning of plants by Albian Sands and True North, and the announced expansion of plants by Syncrude and Suncor, it is expected that these tonnages could quadruple in the next ten years. All of these operators have at least 50 years of reserves even at these expanded production rates. The occurrence of heavy minerals in Alberta?s oil sands has long been known and is well documented in the literature. There have been a number of attempts to produce market-grade products from this resource and the results of this work have been quite mixed. Typically, researchers have used the normal mineral dressing techniques of the industry and have found the mineral assemblage does not respond to these techniques all that well. This has led to the widelyheld suspicion that there must be some difficult metallurgical problems associated with this resource. There are three main problem areas that have created difficulties for previous researchers: 1) The bitumen coating on the sand grains; 2) Secondary mineralization such as pyrite, siderite and calcite 3) A high proportion of aluminosilicates (approximately 25%) that have the same gravity, electrostatic and magnetic properties as other minerals in the heavy mineral suite. Recent work by Lakefield Research shows that these problems can be largely overcome with some novel approaches. The bitumen can be removed by washing with a solvent in the presence of a demulsifier. The pyrite can be removed by flotation. And the titanium and zircon minerals can be separated by selective flotation followed by conventional electrostatic and magnetic separation.

May 1, 2001

By J. P. Sims

Abstract - Ultramafic to mafic igneous intrusions of the Las Aguilas district form part of a belt of generally mafic plutonic bodies within medium- and high-grade early Paleozoic metamorphic rocks in the southern Sierras Pampeanas region, Province of San Luis. The intrusions host the largest known nickel sulfide resource in Argentina and contain significant Cu, Co and PGE mineralization (2.2 Mt at 0.5% Ni, 0.5% Cu, 0.035% Co). Sulfides at Las Aguilas Este, one of two principal mineralized zones, are hosted by a body comprising subvertically dipping units of predominantly orthopyroxenite and melanorite cumulate, with lesser dunite, harzburgite, norite, leuconorite, and amphibolite. The units are zoned horizontally from ultramafic to mafic compositions, representing primary magmatic zonation away from an original base or side of the intrusion. Intercumulus nettextured and disseminated aggregates of pyrrhotite-chalcopyrite-pentlandite are concentrated in the peridotitic zones and extend into melanorite. Whole rock major and trace element compositions, and olivine chemistry, indicate that the parent magma was gabbroic/basaltic with 100 (Mg/Mg+Fe) near 59, and resembles tholeiitic magmas generated in subduction-related arc, or back-arc settings. Unusually aluminous Cr-bearing spinel is compositionally similar to those in some synorogenic mafic/ultramafic plutons in magmatic arc settings. Relatively Ni-depleted olivines and low Cu/Pd ratios are indicative of magmatic sulfide segregation early in the crystallization of the magma. Early orthopyroxene saturation and virtual lack of clinopyroxene, in conjunction with sulfur isotope values up to +6.6 ‰, spinel compositions, and presence of graphite, phlogopite and magmatic hornblende, all attest to probable crustal contamination of the parent magma. Assimilation of crustal sulfur may have been crucial in the early attainment of sulfide saturation and resultant formation of magmatic Ni-Cu sulfide mineralization. Fabrics, textures and mineralogy of the intrusions and country rocks and U-Pb zircon dating indicate syntectonic-synmetamorphic emplacement at 478±6 Ma during the Famatinian (Ordovician) orogeny. Minor to locally significant recrystallization and deformation of mafic-ultramafic rocks and redistribution of sulfides and PGE occurred during and following the Famatinian orogeny. The Las Aguilas intrusion is one of several tholeiitic mafic-ultramafic intrusive complexes within an Ordovician arc - back-arc system in the Sierras Pampeanas. Aeromagnetic datasets and regional mapping suggest there is further potential for intrusion-hosted Ni-Cu mineralization along this eroded magmatic arc.

Jan 1, 1999

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By J. C. O'Rourke

"Gibraltar Mines Ltd. has been operating its open pit copper mine for fifteen years. In that time over 140 million tons of waste and low grade material has been placed on the mine waste dumps. Laboratory and in-situ testing indicated that enough leachable copper was recoverable from the dumps to justify a leaching operation which would include the construction of a solvent extraction-electrowinning plant. The plant, which was commissioned in October, 1984 was designed to process 3,000 usgpm of dilute copper solution to produce 5,000 tons per year of high quality cathode copper.This paper deals with the start up and initial year of operation of Gibraltar's SX-EW plant. The three areas: leaching solvent extraction and electrowinning are presented with emphasis on the innovations which were made to help overcome the problems unique to die Gibraltar operation.THE LEACHING CIRCUITThe mines waste dumps are leached to produce a pregnant copper solution as feed to the SX-EW plant. To achieve this the dumps are sprinkled with a mildly acidic solution which percolates through the dump. In travelling through the dumps the solution contacts the surfaces of the liberated copper minerals and disolves the soluble copper into the form of copper sulphate. The leaching reaction is achieved by a combination of bacterial action to oxidize the suphides and solublization of the copper into the acid solution.For the bacterial action to occur the dumps must be at or near the ideal pH of 1.9 - 2.1 and the necessary elements of the reaction must be present. Because a bacterial reaction is involved there is a lag time between the time when the conditions for bacterial growth are achieved and when the bacteria are in their active growth phase. Laboratory tests with Gibraltar ore indicated that bacterial action takes two to three months to reach its maximum rate. See figure 1.The expected lag time for the planned rate of bacterial leaching prompted Gibraltar to start irrigating the dumps in late June 1986 for a plant start up in early fall. The lag time proved to be longer than expected and the dumps took until November to start producing copper at the expected rate. See figure 2."

Jan 1, 1988

By A. J. Hargraves

"It is difficult to quantify comparatively the gassiness of a property. The most common index to gassiness, cubic feet of gas per ton of coal mined, is very arbitrary and does not take into account the geological setting nor the mining operation. The gassiness of a virgin coal in situ can be assessed, but no method is precise and the most accurate methods involve prolonged field and laboratory experiments. In general, gassiness increases with depth. Whereas 'gas' normally implies methane, other gases such as nitrogen, carbon dioxide, etc. may be present in seam gas also. The inflammability of methane is a problem, particularly the explosibility of a methane-air mixture; also oxygen dilution is involved in high gas concentrations and some gases are poisonous even in low concentrations. Cross measuring into a virgin seam is usually not as troublesome as development in the seam, where narrow openings may require strong ventilation to dilute gases exuding from the face and sides. Total extraction presents problems of gas from the working seam, or from adjacent seams, particularly at the return side, or of gas-laden air from the goaf streaming out or sometimes surging out intermittently, again on the return side. In pillar extraction or longwall retreating special roadways may be required to allow the side-to-side and end-to-end flushing of the goaf which is somewhat inherent in longwall advancing. Layering may occur, particularly where ventilation conditions are not brisk. Outbursts of gas from adjoining seams may be induced by sudden rupture of roof or floor in caving workings. Outbursts of coal and gas from the working seam may occur, mostly in development work, under special environmental circumstances. Gas problems may be reduced or eliminated by predrainage of gas ....:. rarely successful from the working seam - usually undertaken from adjoining seams prior to escape of gas released by caving. The ideal solution - general predrainage of gas to the surface from measures prior to mining - has yet to be accomplished. • In the planning of gassy mines it is possible to make an assessment of gas contained in the seams and to estimate what proportion will be released into the mine air, but emission of gas into mine workings is never steady and at present there is no better planning criterion than experience at the mine next door!"

Jan 1, 1973

By O. E. Humeniuk, A. I. A. Salama, M. W. Mikhail

"The Western Research Centre (WRC) of CANMET operate a unique pilot plant facility where ongoing R&D on coal preparation and mineral processing is conducted. The pilot plant carries out two functions: coal preparation processing using state-of-the art technology and coal-liquid mixture preparation with intensive cleaning circuits that can also be used for mineral processing. In total, the pilot plant includes more than 30 different flowsheet options. The facility is dedicated to small and fine coal, and designed to be flexible and versatile.This paper describes the use of a pilot-scale facility as a research tool for process control development, fine coal beneficiation, development of coal-liquid fuels technologies, development of process models and testing and evaluation of new developments. The pilot plant is used to assist in resource development by evaluating and optimizing flowsheet selection, and producing sufficient samples for utilization tests. The facility is also an important tool for evaluating and testing samples from troublesome circuits of operating plants to find means to optimize and improve recovery, particularly of fines circuits.Detailed examples are given to demonstrate the role of a pilot scale facility in coal preparation R&D, coal industry development and optimization of coal processing operations. These examples include the development of heavy-medium cyclone computer control system, detailed evaluation of beneficiation of a coal deposit with high clay content, development of column flotation, and its role in fine cleaning circuits and treatment of ultra-fines in relation to intensive cleaning, the importance of testing coals in different processes, and cleaning processes influence on coking quality and other utilization applications. The potential of the facility for helping the mineral industry is also described."

Jan 1, 1992

By V. G. Papangelakis, G. P. Demopoulos

"Recovery of gold from refractory ores and concentrates presently constitutes one of the most important, challenging, and exciting areas of R&D activity in the gold processing industry. New technologies are being tested for the treatment of refractory gold materials, some of which have been advanced to the level of commercial operation. In this paper, some recent technological developments in the hydrometallurgical processing of pyritic matrix-refractory gold ores are highlighted. Key operational steps of each of the alternate hydrometallurgical technologies are analyzed and potential advantages and drawbacks are identified. The processes which are reviewed are: hydro chemical oxidation, biochemical oxidation and pressure oxidation. INTRODUCTIONOver the years the term ""refractory"" has been applied in gold ore processing to denote situations in which straightforward cyanidation failed to yield high gold recoveries. A number of mineralogical and chemical factors may be responsible for this ""refractoriness"" problem. A systematic classification of the different options for their treatment has been discussed in a recent review paper. In this paper, the pretreatment of the submicroscopic gold encapsulated within the matrix of pyrite and arsenopyrite minerals is considered. This type of gold is the ultimate refractory material because complete breakdown by reaction of the host mineral structure is required.The method which has been traditionally applied for the treatment of pyritic-type refractory gold ores is an oxidation roast (single stage or double stage depending on the As content) of a flotation concentrate to produce a porous calcine, the latter being more amenable to cyanidation. Despite its established practice, oxidation roasting is not considered particularly attractive with today's standards for high product recovery and clean environment. Roasting is known to be very sensitive to heating parameters and feed composition and deviation from optimum conditions can result in reduction in permeability which is translated to incomplete gold liberation."

Jan 1, 1989

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016