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By J. P. Grieco, F. W. Grieco

"Manufacturing of Jaw CrushersOriginIn 1858 Eli Whitney Blake invented the first successful mechanical rock breaker-the Blake-type jaw crusher. Blake adapted a mechanical principal, the powerful toggle linkage system used to transform rotating motion and energy into oscillating mot ion and tremendous compressive forces. Today these same principals apply and the basic Blake-type jaw crusher is one of the leading machines of its class for heavy duty primary crushing service.In 1881 Philetus W. Gates patented a design for a crusher, the forerunner of the modern gyratory crusher which dominated the field from the late 1800s to the early 1900s. In 1910 the largest gyratory crushers built had 48-inch openings. However, about this time the jaw crusher came to life when the Power and Mining Machinery Co. built an even larger sized opening crusher-a giant 84-inch by 60-inch jaw crusher for a trap rock quarry in Pennsylvania. A 24-inch gyratory crusher became the ideal sized secondary machine for this size jaw. From that time on jaw crushers were looked on favourably as primary breakers and lines were brought up to date to parallel the already developed gyratory lines.FunctionMost heavy duty Blake-type jaw crushers work basically the same way. They are ruggedly designed and capable of crushing material in some cases in excess of 80, 000 p.s.i. compressive strength. They are very simple machines with few moving part s and, with the exception of replacement of renewable parts, are relatively maintenance free. It is quite common to have these machines in product ion for 20 to 30 years. The following will de scribe how these machines work. Large-diameter high-inertia flywheels which are connected to the main eccentric shaft, rotate inside a connecting rod type mechanism called a Pitman. It transforms rotating motion into vertical oscillating motion. This vertical motion is in turn transformed into reciprocating mot ion by means of a system of 2 toggles, each connected to the Pitman. The rear toggle is connected to the fixed rear head, and the front toggle is connected to the swing jaw which is hinged at the top of the crusher. With each rotation of the eccentric shaft the swing jaw opens and closes on rock which is fed into the crusher chamber, crushing the rock in a series of bites. These bites, or strokes as the y are called, usually vary between 1/2 inch to 1 1/2 inch at speeds of 120 to 200 strokes per minute. The reduction ratio of feed input to discharge is usually about 8 to I. Output capacities can vary from 100 tons/hour to 1200 tons/hour depending on the size of machine and its discharge opening. Horsepower requirements can vary from 75 hp to 400 hp.The entire crusher chamber is lined with replaceable 14070 manganese steel liner plates. This material is ideally suited for the job since it hardens as it wears during crusher operation. Manganese is also used in the high wear areas at each end of the toggle plates."

Jan 1, 1985

By Sigmund J. Andersen, Eva A. Mørtsell, Jostein Røyset, Randi Holmestad, Oddvin Reiso, Yanjun Li, Øyvind Paulsen, Calin D. Marioara

"With the purpose of increasing the extrudability of lean alloys, we reduce levels of the alloying elements Mg and Si in a 6xxx extrusion alloy. To avoid sacrificing strength, we investigate the compensating effect of smaller amounts of lithium and germanium, alone and in combination. Recent studies by atomically resolved high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) together with density functional theory (DFT) calculations have demonstrated that while Li replaces Mg, Ge substitutes Si in the columns in the hardening ß’’-phase. Several studies have shown that Ge replaces Si in other precipitates as well, and that both Li and Ge promote precipitation and can improve macroscopic properties, like strength and thermal stability. The scope of the current work has been to investigate and document the combined effect of the two alloying elements. Of the investigated alloys, the one containing both elements displayed highest hardness, corresponding with a significant increase in precipitate number density. We used HAADF-STEM to determine the extent of Li and Ge in the precipitate structures.INTRODUCTION The two most important alloying agents, with respect to age hardening of the 6xxx alloy series, are Mg and Si. In general, 6xxx alloys are formed into their final shapes by rolling or extrusion, before being age-hardened at elevated temperatures around 180°C. The hardening effect during this stage is due to the formation of metastable, semi-coherent, precipitate needles along the three < 001>Al directions generally following the precipitation sequence (Marioara, Nordmark, Andersen, & Holmestad, 2006): Supersaturated solid solution ? atomic clusters ? Guinier-Preston-zones (pre-ß”) (Edwards, Stiller, Dunlop, & Couper, 1998) (Marioara, Andersen, Jansen, & Zandbergen, 2001) ? ß” (Andersen, et al., 1998) (Hasting, et al., 2009) ? ß’ (Vissers, Huis, Jansen, & H. W. Zandbergen, 2007), U1 (Andersen, Marioara, Vissers, Frøseth, & Zandbergen, 2007), U2 (Andersen, Marioara, Frøseth, Vissers, & Zandbergen, 2005), B’ (Vissers, Marioara, Andersen, & Holmestad, 2008) ? ß, Si (stable)"

Jan 1, 2018

By J. Mullins

Coal was first banked by the Dominion Coal Company, Limited, in 1898, near No. 2 Colliery, the same site as is presently used for that purpose. Though today there are banks at Glace Bay, Sydney, and Sydney Mines, these notes, except when otherwise desirable, will be confined to describing the practice as developed at the No. 2 Banking Station, Glace Bay, as being typical of methods obtaining at all sites. Storing The manner in which the coal was piled is illustrated diagrammatically in the accompanying sketch. A train of coal was brought on the main trestle, which extended the full length of the banking ground at a height of 22 to 39 feet above the natural surface, and dumped into bins which were integral with the trestle work. Chutes from these bins permitted the coal to be fed into 3-ton cars, which were horse drawn laterally on narrow gauge tracks laid about 10 ft. centres, to a maximum distance of 400ft. from the trestle. These cars were end-dump and as the pile extended laterally the narrow gauge tracks were lengthened by shorter or longer filling pieces, so that their ends were always kept at the brow of the bank. Much coal, however, had to be dumped directly on the tracks and hand trimmed to fill the valleys, and level off, between the tracks.

Jan 1, 1931

By Alastair J. Sinclair, Asger Bentzen

Abstract - A simple linear model for interpreting duplicate analytical data for a range of values is described. The conceptual model can be quantified using a reduced major axis model rather than the inappropriate traditional least squares approach. The reduced major axis parameters (slope, intercept) and associated errors provide a quantitative basis for: (1) defining bias, and (2) comparing results within laboratories, between laboratories and between sampling/analytical methods. Application of the linear model must be preceded by extraction of obvious outliers or small groups of values that have an inordinately large impact on values of the statistical parameters defining the model. In addition, consideration must be directed to the presence of more than one population of sampling error, as in the case of multiple styles of mineralization being sampled.

Jan 1, 1998

By H. B. Gillis

THE following pages c9ntain a brief description of the processes involved in the manufacture of silica brick at the Sydney plant of the Dominion Steel & Coal Corporation. Silica brick manufacture was commenced at Sydney in 1918, for the purpose of supplying the requirements of the steel plant, where about three million silica bricks were used annually. Previous to that date, all silica refractories were brought to Sydney from American sources and were subject to a freight cost of nine dollars per ton, or about twenty-seven dollars per thousand. As a preliminary step to manufacture, a thorough investigation of all possible sources of silica in the vicinity of Sydney was carried on during 1916 and 1917. ?Eighteen separate deposits were examined. Of this number, only four were found suitable for brick making, and the Leitches Creek silica, being the nearest of these four deposits to Sydney, was selected as the raw material for the proposed plant. CRYSTAL MODIFICATIONS OF SILICA A brief review of the silica minerals may serve to indicate why careful investigation of sources of supply is necessary before actual brick-making is attempted. The crystal modifications of silica, i.e., quartz, tridymite, and cristobalite, all possessing alpha and beta phases, play a most important part in determining the suitability or otherwise of the resulting brick. By heat treatment, any one of these forms of silica may be converted to either of the others. The inversion temperatures (after Fenner) in degrees Centigrade are shown on rage 160.

Jan 1, 1938

By Staff

Introduction The Hedley mine, perhaps better known as- the Nickel Plate mine, is one of the outstanding properties of southern British Columbia. Discovered in 1898 by Woollison and Arundell, prospectors, the property was bonded in 1899 to M. K. Rodgers for the Marcus Daly Estate, of Butte, and development was started the same year. From the high grade of the ore outcrop, and its colour, due to oxidation of the arsenopyrite, it was not difficult to open up and trace the showing. The Nickel Plate ore-shoot, which apparently had been easy to follow on surface, was more difficult to trace underground. In 1903, prospecting on an adjoining property, the Sunnyside, showed commercial ore at surface, but it was only after two years&apos; work that the ore-body was defined and shipments started. From this property, $1,200,000 have been taken out. Prospecting was also carried on on the IXL, Climax, Copper Cliff, Mound, Bulldog, Exchange, Silver Plate, Gold Plate, and other properties, all of which had surface showings, but up to date only the Nickel Plate, Iron Duke, Morning, and Sunnyside have produced commercial ore. In 1904, the Bulldog looked like a very promising mine, but it failed to make good. In 1905, the Sunnyside No. 1 was in the limelight, but it also failed to make the grade. In 1906, an outcrop on the Sunnyside No. 3 looked interesting. Subsequent work. on this claim produced $840,000, and at the same time ore which yielded $400,000 was mined from the Sunnyside No. 4. In 1908, the Nickel Plate ore-body entered a lean zone and, as the diamond drill failed to give satisfactory results, the Daly Estate, after making a profit of $1,151,000, sold the property to the Hedley Gold Mining Company, Limited, for $760,000, retaining, however, a large interest.

Jan 1, 1929

By STEPHEN V. FORGERON

The Loch Lamond celestite properties in central Cape Breton Island were mined by Kaiser Celestite Mining Limited from 1970 until 1976. Poor market conditions in J976forced operations to cease. Kaiser holdings included the Lake Enon, MacRae and A mac prospects. A total of about 272,000 tonnes of raw celestite have been mined. Celestite deposits are situated in the Loch Lamond Basin, specifically in Lower Windsor sedimentary rocks. Of the five formations in the Lower Windsor Group, celestite is found in the upper four. Celestite in the Enon Formation occasionally replaces shale that separates stromatolitic dolomite columns; elsewhere in the formation it occurs in association with siltstone and gypsum. Jn the B2 Limestone Formation celestite fills pores or grades between limestone and gypsum. It replaces both limestone and silty limestone conglomerate in the Loch Lamond Formation; this limestone is of unusually high grade (60 to 70% SrSO,J for the area. Evidence indicates that the Uist Formation may hold important celestite reserves. Original celestite mineralization probably resulted from evaporation of seawater on mudflats or 'sabkhas'. Secondary mineralization also may have occurred. Strontium ions could have been leached from pre-existing concentrations and overlying gypsum, moved downdip in groundwater and combined with sulphate rich waters to deposit as celestite in porous B2 limestones.

Jan 1, 1984

By A. F. Laurin, A. L. Dorr

"Because of its wide areal extent, its numerous lithological facies and its high degree of metamorphism, the Quebec portion of the Grenville province has only partly been explored and prospected. Rock types that are economically among the most interesting in the Grenville are those of mafic and ultramafic compositions, because of their great potential for coppernickel and chromium-platinum. The peculiar mode of occurrence and the distribution of these igneous masses in which copper-nickel mineralization is known to occur indicate' two common geological features: (1) aerial photographs and/or topographic maps strongly' suggest close spatial (and possibly temporal and genetic) association of most of these mineralized mafic and ultramafic intrusions with circular structures; (2) when plotted on a large-scale map comprising the Quebec portion of the Grenville, these circular structures fall along two lines which could correspond to major tectonic features. Even though the genetic links among the mineralized mafic-ultramafic masses, the circular structures and the linear features are not yet fully understood, their associations are believed to be empirically valid and should therefore be used as geological tools by those interested in exploring the Grenville for copper-nickel and possibly chromium-platinum deposits. It should be noted that these mafic and ultramafic bodies do not appear to be spatially related to anorthosite complexes."

Jan 1, 1971

By Y. Masuda, Y. Nakamura, K. Haraguchi, A. Taniguchi, K. Arita

Availability of the elements originating from steelmaking slag for various marine phytoplankters including purely cultured strains and natural populations was tested in land and shipboard laboratories. The results obtained demonstrate that, although their solubility was not uniform among different slags, dissolved iron, silicate and phosphate from the slag stimulate phytoplankton growth. No negative effect of the slag addition on their growth was observed at lower dose, e.g. less than 200 mg/l. Since most coastal waters are the hypernitrogenous environment due to anthropogenic load of ammonium, the slag can be an ideal source of silicate and phosphate, which restore the hyper-nitrogenous condition into truly eutrophic condition with balanced Redfield ratio. In so-called HNLC (high-nitrate low-chlorophyll) oceanic areas such as the Southern Ocean and the subarctic North Pacific, where iron is almost only limiting factor of the phytoplankton growth, the slag could also be a source of iron and enhance CO2 fixation by phytoplankton photosynthesis. (Key words: carbon deposition in deep-sea, marine environmental remediation, phytoplankton, slag as a source of iron, phosphate and silicate.)

Jan 1, 2004

By Y. Zedan

Cutting fluids play important roles during machining, including the reduction of friction and temperature. Using a cutting fluid, however, degrades the quality of the environment and increases machining costs. The aim of the present research work is to study the effect of cutting fluids and their interactions with cutting parameters on the quality of holes during the drilling of 6061-T6 aluminum alloys. The lubrication types and modes investigated are dry machining, flood lubricant machining and minimum quantity lubrication machining (MQL), while the part quality criteria include the surface finish, the dimensional accuracy, and burr forms and sizes. A scanning electron microscope (SEM) was used to investigate the formation of built-up edges (BUE) in the drill flutes as well as the surface texture of drilled holes. It was found that dry machining and MQL machining can produce parts having quality levels comparable to those obtained in wet machining, when using the optimal cutting conditions.

Jan 1, 2011

By W. G. Wahl

The Slave Province, a segment of Archean continental crust, migrated west and north from the northern flank of the Superior protoshield shortly after the Kenoran orogeny. The probable cause of migration, the path it followed and the cause of its coming to rest can be inferred from the Bouguer gravity data. The migration caused an indentation in the edge of the Superior protoshield which precluded the development of the Hudsonian orogenic front under Hudson Bay. As the nickel and asbestos deposits of the Thompson Nickel Belt and the New Quebec Nickel Belt are restricted to this orogenic front, no such deposits would occur under Hudson Bay.

Jan 1, 1973

By Ron Davidson

"The Utility Mine in southeast Saskatchewan is owned by Saskatchewan Power Corporation and operated by Mana/ta Coal Ltd. Up to 3.3 million tonnes of lignite is supplied annually to Saskatchewan Power's Boundary Dam Generating Station. The coal occurs in two predominant seams which are covered by up to 37 metres of saturated fine-grained overburden. Overburden is removed by two draglines working in two pits. Coal is hauled to the mine mouth power station. Comprehensive drainage and reclamation programs are integral parts of the operation. IntroductionThe Utility Mine is owned by Saskatchewan Power Corporation and operated by Manalta Coal Ltd. It is located in southeastern Saskatchewan, approximately 200 km southeast of Regina and 8.5 km southwest of Estevan (Fig. 1). The climate of the Estevan area is semi-arid with long, cool winters and short, hot summers. The mean annual precipitation is 42 cm and the mean summer temperature is 20°C; mean winter temperature is -10°C. The Utility Mine supplies coal to the adjacent Boundary Dam Generating Station. Increases in the station's generating capacity during the past decade have resulted in an extensive expansion program for the Utility Mine. This expansion program, the geological conditions present in the area, and the mining/reclamation operations will be highlighted in the following sections<1.2). History The Estevan area has a long history of coal mining. In the early years, coal was mined via entries into coal seam outcrops along the slopes of the Souris River valley. Surface strip mining was introduced in the late 1920s and progressed to the point where it totally replaced underground mining by the 1950s. Surface mining methods are currently used exclusively by all of the Estevan area operators."

Jan 1, 1985

By G. Guiglionda, A. Deschamps, F. De Geuser, M. Langille, B. J. Diak

"Increased demand for light-weighting in passenger vehicles has created a need for strong, light, ductile materials to be used in body-in-white applications. The AA6xxx-series of aluminum alloys are suitable candidates meeting most requirements but can fall short of the formability demands of designers, necessitating an understanding of what controls the formability in this alloy series. This work examines the effect of copper alloying in AA6xxx on the pre-ageing and natural ageing responses of the microstructure and mechanical properties. The changes in microstructure observed by differential scanning calorimetry and hardness testing are related to the work-hardening and strain-rate sensitivity parameters for these alloys measured by tensile testing. An observed asymmetry in the measured strain-rate sensitivity associated with increasing versus decreasing strain rate changes suggests that a different mechanism operates for the two conditions. It is postulated how this asymmetry in strain-rate sensitivity will impact the necking and ductility behaviour of these alloys.INTRODUCTION The widespread use of AA6xxx series alloys in the form of sheets has provided the need for a more thorough understanding of the complex interactions between composition, processing, resulting microstructure and ultimately, the mechanical properties of the alloys. Conventional industrial practices involve the production of rolled AA6xxx sheet (typically 1 mm thick) to be used for body-in-white (BIW) applications for auto body panels (Hirsch, 2004, 2014). The final metallurgical step prior to the shipment of these panels to manufacturers involves a solution heat treatment (SHT) reverting the ageing products of the alloys into solid solution and the product is then shipped to the customer. During this shipping time and while sheets are waiting to be used, the natural ageing (NA) process occurs whereby the strength of the alloys increases resulting in reduced formability. This can result in a product that is unable to meet the formability demands of the automotive manufacturer. As a result, industry has moved towards performing pre-ageing (PA) treatments to prolong the “shelf-life” of the material prior to it having insufficient formability. Once formed into BIW panels, the parts are then painted and subsequently undergo the paint curing heat treatment which consists of a short period of time at medium temperature, typically 20 minutes at 170–190°C. This short artificial ageing (AA) treatment, known as the paint bake (PB), provides additional strength and improved dent resistance for the material, but reduced formability. The PB result is strongly dependent on the PA treatment performed prior to the forming operation. Furthermore, the addition of copper (Cu) to a base Al-Mg-Si composition is known to increase the alloy’s strength. The goal of this work is to study the effect of Cu on strength, strain hardening, and strain-rate sensitivity (SRS) of these alloys, to understand the strength-formability compromise, for two separate heat treatment schedules; one including and one excluding the PA treatment, both followed by NA."

Jan 1, 2018

By Douglas E. Wolfe, Jogender Singh, Robert Miller, Dong-Ming Zhu, Jeff Eldridge

This paper discusses microstructural changes produced by two novel approaches using electron beam physical vapor deposition (EB-PVD) in which periodic strain fields/microporosity was incorporated within the large columnar grains of Zr02- 8wt.%Y2O3 (8YSZ). The traditional columnar microstructure of partially stabilized zirconia has been slightly modified to produce a lower thermal conductive thermal barrier coating (TBC) by periodically interrupting the condensing vapor resulting in microstructural modifications with diffuse or sharp interfaces and morphological changes on the sub-micron scale without changing the composition of the TBC. These microstructural modifications resulted in a 20-30% reduction in the thermal conductivity, 28-56% increase in hemispherical reflectance, improved oxidation cyclic life (over 100%), and better strain tolerance as compared to standard ZrO2-8wt.%Y2O3 deposited on platinum-nickel-aluminide and CoNiCrA1Y bond-coated MAR-M-247 test samples. The TBC with tailored microstructures were examined by various techniques including scanning electron microscopy (SEM), x-ray diffraction (XRD), steady-state laser heat flux technique, and hemispherical reflectance.

Jan 1, 2004

"HPGRs operate in a wide array of applications in mining and minerals. These range from relatively coarse crushing of copper and gold ores at one end of the spectrum to the processing of fine iron ore pellet feed and fine industrial mineral products at the other. Traditionally these circuits involve the treatment of relatively moist materials in pre-grinding circuits; using single stage HPGRs in open circuit or as a closed circuit operation with screening or partial product recycle. More recently, HPGR is increasingly deployed in dry grinding in combination with air classification. The high throughput demonstrated by larger HPGRs has stretched the application towards coarser size reduction duties for a number of new projects. At the same time, the basic principle of inter-particle crushing for generating a product with a high fines proportion gives ground to investigate applying the technology further towards finished product duties. The advantages that HPGR brings are clear. Multi Stage grinding enables energy efficient size reduction across more of the comminution circuit. Primary HPGR serves for a coarse grinding duty, whereas a secondary HPGR is geared towards generating a fine product for downstream processing or even a finished product. This publication summarizes some of the features of staged HPGR circuits and discusses some examples of operating and projected applications.INTRODUCTION In most HPGR applications, the grinding units are used as a single process stage, either in open circuit, such as for pebble crushing [Rose 2002, Westermeyer 2000, Van der Meer 2015] or in closed circuit with classification [Van der Meer 2009, 2012] or product recycling [Van der Meer 2010]. Where a higher plant capacity is required, the HPGRs are commonly installed in multiple lines in a parallel arrangement [Parker 2005, Koski 201, Vanderbeek 2006]. HPGRs can take a wide range of feed size distributions, and grind this down to a product with a high fines content. In general view, there is a limit on the size reduction range that even an HPGR can provide. Grinding down from a very coarse ore (e.g. 70-100 mm) to a very fine product (e.g. 100 microns range) is stretching the ability of a single stage HPGR circuit. Fine grinding generally requires a classification stage that returns the classifier oversize to the head of the HPGR circuit. From one point of view, it can be demonstrated that when recycling a large proportion of fines and middlings back to the HPGR feed results in an effective feed with an overrepresentation of middlings and fines, which will eventually reduce the grinding efficiency and consequently result in an increased recirculation mass flow [Van der Meer 2014]. From another point of view the large recycling mass puts a strain or even a limit on the capacity of present-day conveyor capacity."

Jan 1, 2018

By Guocheng Pan

Geostatistics has been widely accepted as a standard tool for reserve estimation and mine planning. Kriging has been adopted as the best estimator of grade. Although many discussions have been conducted in the use of kriging in the mining industry, insufficient attention has been given to solutions for over-smoothing. This effect has been frequently encountered in many mines. The so-called over-smearing refers to two facts: (1) over-reduction of grade variabilities and (2) over-estimation of low-grade ore tonnages. This study attempts to link over-smoothing effects with several other practical aspects in kriging. These include the weight independence of data values, variogram modeling, and search strategy used in estimation. All solutions recommended here are suited for precious metal deposits (e.g. gold) in open-pit mining.

Jan 1, 1995

By Robert A. Creaser, Iain Mitchell, Robert L. Linnen

Abstract - The Bermuda Zn-Pb showing is hosted by dolomitized Blue Fiord Formation of Devonian age, located east of the Ensorcellement dome on the Grinnell Peninsula of Devon Island. Fluid inclusions in hydrothermal calcite indicate that the mineralization precipitated from low-temperature, highly saline brines. The ?34S compositions of sphalerite, galena, and marcasite range from 16.1‰ to 35.2‰. Consequently, the Bermuda showing is interpreted to be Mississippi Valley-type (MVT) mineralization. The apparent age of mineralization has been determined by the Rb-Sr method from sphalerite separates, and a Late Devonian age of 357 ± 50 Ma (MSWD=65), with an initial 87Sr/86Sr ratio of 0.7083 ± 0.0020 is indicated. This date, within error, is the same as the Polaris deposit. This suggests that the mineralization formed during the Ellesmerian Orogen, although it is also possible that mineralization is associated with extension, related to the opening of the Sverdrup basin. The strontium and sulfur isotopes and fluid inclusion analyses indicate the involvement of a brine that acquired its salinity from interaction with evaporites, lower in the stratigraphic succession. The Polaris mine is the type deposit in the Cornwallis Zn-Pb district and is hosted by the Thumb Mountain Formation. The results of this study are significant because they demonstrate that regional brine movement is more widespread than previously recognized, and that MVT mineralization in the Cornwallis Zn-Pb district is not restricted to the Thumb Mountain Formation.

Jan 1, 2004

By M. S. Ünal

Creation of 3D model of coal seams is a tedious and time consuming operation. Computer aided 3D solid modelling of coal seams can be performed in a fast and detailed manner. However, in case of having tectonically disturbed coal seams where faults may be observed, expert opinion is necessary to decide the geometry of the coal seam. The aim of this study is detection of fault zones with computers by using drill hole data. Firstly, a digital database is generated by using the drill hole data. Surface models of the layers are produced by applying triangulation method on coal seam roof elevations. The generated surface is divided into small squares and consequently dip and dip direction values are calculated for each square. Variograms for dip and dip direction are determined and maps showing the variation of dip and dip direction are generated by using geostatistical methods such as kriging and co-kriging. Examination of disconformities observed on estimation maps created by kriging and co-kriging clearly reveals the extension of faults. The method used in this study is applied to detect fault lines of a known mine field. 3D solid modelling of the coal seam has also been performed by using conventional cross-section method. The results of both methods were in good agreement. Identification of major faults by using the method introduced in this study could certainly simplify 3D solid modelling of coal seams.

Aug 1, 2013

By Yuwang Wang, Yanggeng Tan, Kezhang Qin, Zengqian Hou

Abstract- The large Derni Cu-Co (-Zn) deposit in Qinghai Province exhibits unusual geological features, and its genesis is controversial. Based on previous research and detailed field investigations, petrographic studies of the host volcanic rocks, isotope and trace element geochemistry of the sulfide ore, and comparison with typical ore deposits, this deposit is a VHMS (submarine volcanichosted massive sulfide deposit) type. This argues against previous interpretations of a magmatic or a hydrothermal replacement origin. Systematic rock, mineral and geochemical studies of the host serpentinites of the ore district indicate that the protoliths of several types of serpentinites that are widespread in the ore district are mainly ultramafic volcanic rocks. The mineralization formed within an ultramafic volcanic breccia, or between the breccia and its overlying Mg-rich carbonate rocks and volcanic sedimentary rocks. The ore-forming components were derived mainly from ultramafic rocks and partly from mafic rocks. The ultramafic rocks are MgO-rich, CaO-poor with a high MgO/FeO ratio, and the mafic rocks are rich in Na2O and poor in K2O. The chemical composition of the ultramafic rocks is similar to that of volcanic peridotite, or komatiite. The volcanic rocks that host the Derni deposit are among the most basic host rocks known for VHMS deposits, and the Derni deposit represents the most basic member in the VHMS deposit spectrum.

Jan 1, 2000

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005