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By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By M. G. Beukes

"In South Africa most of the large gold mines operate between 1500m and 4500m below surface where reef is accessed initially through a vertical shaft system then via a network of tunnels and mined in either a longwall, sequential grid or scattered mining configuration. Due to the complexity of the ventilation networks used to ventilate these mines and the potential disastrous consequences associated with underground fires, it is of utmost importance that these mines are managed in such a way that underground fires are prevented. However, if they do occur the fires are managed to firstly prevent the loss of life and secondly protect the infrastructure and viability of the mine. The aim of this paper will be to: • Discuss current SA mining legislation regarding underground fire prevention and control. • Examine these fires from a risk management perspective by means of a bowtie assessment. • List and discuss the major Threats and Consequences as determined by the bowtie assessment. • Discuss the various prevention and consequence controls for deep level underground fires. • Examine how to effectively run an emergency control room. From this, a practical way of designing, implementing and managing an underground fire management system is explored. Lastly, the paper identifies new technology and ways of thinking and how these can be used to combat underground fires. INTRODUCTION The orebodies of South African gold mines are generally narrow tabular structures that vary in thickness between 0.8m and 1.2m with an inclination of between 200 and 700. This, coupled with depths of between 1500m and 4500m, as well as the unpredictable geology, creates unique challenges and significantly impacts on mine designs and mining methods. In general, gold bearing reefs are accessed initially through a vertical shaft system then via a network of tunnels and mined in either a longwall, sequential grid or scattered mining configuration (Figure 1). Mining is very labour intensive with very limited mechanisation opportunities and this increases the risk to human life if an underground fire occurs. On 16 September 1986, one of the worst mining disasters in SA mining history took place when 177 mineworkers were killed at Kinross Mine. An acetylene tank sparked flames that swept through the mining tunnel igniting plastic covering on the wiring and the flames also set fire to polyurethane foam. The burning plastic combined with polyurethane and the toxic fumes that filled the shafts caused the miners death. This incident was a stark reminder of the serious consequence that underground fires can have on human life as well as the crippling financial and asset impact for the mining companies. Over the past thirty years, the SA mining industry reduced the number of mine fires significantly by replacing normal timber support with fire retardant treated timber, alternative support systems such as backfill and elongate support and many other fire prevention initiatives. Although the number of fire incidents and number of fatalities due to fires does not show a direct correlation because of various factors, the controls put in place against fires has had an impact on the number of fire and explosion fatalities (Figure 2)."

Jan 1, 2019

By B. Huffman

This paper examines several new trends in the design and application of linings for copper melting shaft furnaces including the use of large shapes, monolithic back-up linings and improved refractory engineering to significantly reduce refractory installation time, diamond saw blade costs, fuel and down-time. The net results are shown to be dramatically increased refractory service life, reusable safety linings, elimination of hot spots and lower refractory disposal costs.

Jan 1, 2007

By J. Marks

The measurement of greenhouse gas (GHG) emissions from primary aluminium production and inventory of these emissions of carbon dioxide and PF Cs have become an important issue for primary aluminium producers. Most global producers have either voluntary emission goals or emissions limits established through national regulatory requirements. International good practices for inventory of these emissions for national governments are established through the Intergovernmental Panel on Climate Change (IPCC). The current good practices, last updated in 2000, are being revised and are expected to be adopted by governments in the spring of 2006. There are a number of changes expected in the guidance that will impact how facilities account for their GHG emissions. This paper describes the changes to the guidance and the implications of these changes for aluminium producers.

Jan 1, 2006

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

By Jason A. McLennan

Conditional bias is an infamous problem with estimation methods including kriging. Changing estimation parameters will mitigate, but not remove, conditional bias. The conditional bias of kriging is well understood; however, there is widespread confusion in the literature and among practicing geostatisticians regarding the conditional bias of geostatistical simulation. There is no conditional bias of simulation when the simulation results are used correctly. The correct use of simulation for recoverable reserves estimation is to (1) generate multiple realizations conditional to all available data at a small scale, (2) linearly average all realizations to the chosen block size and (3) calculate the probability of each block being ore and the ore grade of each block. The ?probability of ore? and the ?ore grade? are conditionally nonbiased.

May 1, 2002

By R. C. Reed, A. Akhtar

Oxidation of the third generation cast single crystal, nickel-base superalloy CMSX-10 is examined using isothermal tests at 900°C and 1000°C for times ranging from 20 hours to 100 hours. X-ray diffraction, scanning electron microscopy and energy dispersive secondary X-ray analysis were used to characterize the microstructure. It was found that the external scale formed at 1000°C is made up of (Ni,Co)O and the spinel NiCo2O4. The (? + ? ') microstructure of the superalloy transforms into the intermetallic (3 phase prior to the onset of internal oxidation. Internal oxidation results in the formation of (Ni,Co)Ta2O6 and (Ni,Co)WO4. No evidence was found for the formation of alumina (Al203), and the spinels NiCr2O4 and NiAl2O4 in this third generation superalloy. Results of the laboratory investigation are compared with those of an aero-engine turbine blade removed from service and examined earlier.

Jan 1, 2004

By A. Dahi Taleghani, A. Shojaei

Continuum damage mechanics (CDM) of rocks is studied together with their elastic and plastic behaviors to develop simulation tools for hydraulic fracturing jobs in naturally fractured formations. The model is constituted based upon pressure sensitive inelastic deformation of porous rocks and their damage mechanisms in the cases of drained and undrained conditions. The CDM model is formulated within Fracture mechanics framework. The performance of the developed elastoplastic and CDM models are compared with the available test data of a specific shale play. The hydraulic fractures growth in the reservoir scale is then simulated; in which the effect of fluid viscosity, natural fractures characteristics and differential stresses on induced fracture network is studied. The simulation results are compared with the available solutions in the literature. The developed CDM model outperforms the traditional fracture mechanics approaches by removing stress singularities at the fracture tips and simulation of progressive fractures without any essential need for remeshing.

Jan 1, 2015

By Huan-Qiang Zhang, Gang-Hai Huang, Yu-Yong Jiao, Fei Zheng, Zhang. Xiu-Li

An efficient and accurate three-dimensional (3-D) contact detection algorithm is of vital importance in large-scale computing of discontinuous deformation analysis. The contact detection algorithm takes up a large proportion of the whole calculation time because of the increasing calculation number in three-dimensional case. For block systems which consist of convex polyhedrons, the efficiency and accuracy of the contact detection algorithm is a great challenge. The presented contact detection algorithm in discontinuous deformation analysis (DDA) method is carried out in three phases: the global neighbour searching, the local contact type searching and the contact transferring. A contact detection algorithm for 3-D DDA is presented with some improvements on the three phases. A grid-based global neighbour searching algorithm is used to eliminate unnecessary neighbour blocks to the exact number. The local contact type searching includes two steps. In the first step, the common plane method is used to determine the contact type between convex polyhedrons. In the second step, the contact pairs detected by the common plane method are divided into four basic types. In the third phase, the four contact types are transferred into two basic contact types, vertex-to-face contact type and edge-to-edge contact type, which are managed in a uniform procedure. Three verification examples are calculated, the results show that the proposed algorithm based on the three contact detection phases is robust and efficient.

Jan 1, 2015

By Si Qin

Unknown goafs and roadways of abandoned coalmines can be a great water inrush hazard for coalmine workers. Consequently, advance detection of such hazards is of great importance. By detonating seismic charges in underground coal seams, we can collect seismic data using a surface survey line, which is located across the ground projection of the underground shot point. This experiment was conducted in a coalmine in Shaanxi Province, China. After surface elevation compensation and travel time adjustments, we accurately determined the position of the goaf boundary along the survey line based on the wave velocity anomaly on the seismic record. Then we used a scattered wave imaging technique to enhance the energy of the scattered waves that are generated when the coal seam roof slide wave (refracted wave when the incident angle bigger than the critical angle) hits the roadway, thus confirming location of a geological discontinuity (roadway). This experiment shows that the coalmine ground seismic method, employing an underground explosive charge and a surface seismic array, has the ability to detect an abandoned roadway and goaf in advance of coal mining, thus can improve worker safety.

Aug 1, 2013

By Q. Han, W. Dai

Al-Ti-B type master alloys have been widely used in the grain refinement of aluminum since 1940s. The introduction of Al3Ti and TiB2(AlB2) particles reduces the grain sizes down to about 200 micrometer level and makes cold work possible. However, the mechanism for the grain refinement is still not clear, though it is believed that TiB2 in the presence of Al3Ti nucleate a-Al grains in solidification. This paper presents our finding on the formation of (Ti,Al)B2 solid solution, which leads to a proposed theory on grain refinement by Al-Ti-B type master alloys that upon addition into aluminum melt stable TiB2 particles react with aluminum slowly and release titanium into the melt. The titanium thus released in combination with titanium in the melt through dissolution of Al3Ti maintains a transient titanium-rich layer on the surface of (Ti,Al)B2. This layer offers a low crystal mismatch with a- Al and promotes the nucleation of aluminum grains.

Jan 1, 2014

By Stephan Day

Comments on Robust M3 to Protect Water Quality ?Regulatory and philosophical thinking have tended to evolve at decade scale since 1970s. ?Mines typically last more than a decade. ?Robustness is defined by the ability to adapt to new realities. Managing Water Quality in BC ?1973 ?BC Pollution Control Objectives ?1977 ?Federal Metal Mine Liquid Effluent Regulation (Fisheries Act) ?Late 1980s ?Philosophy of ?Designing for Closure? ?1990s ?Designing for Acid Rock Drainage Management ?2000s ?Awareness of need for water quality management in general, regardless of acidity

May 1, 2010

By H. Lee

Recently, the effects of global climate changes have become top concerns for governments? decision making regarding infrastructure investments. Extreme weather events that exceed the capacity of existing systems have considerably increased in frequency, and the potential effects of changing trends in temperature and rainfall on infrastructure are difficult to ignore. It is essential for governments to estimate the costs and benefits of adaptation to climate change to properly assess the financial feasibility of infrastructure adaptation strategies. This paper proposes a framework for estimating the economic aspects of infrastructure adaptation to climate change. The framework is composed of three steps of implementation: establishment of alternatives for infrastructure adaptation, performance prediction of infrastructure using future climate scenarios, and asset valuation based on costs and benefits. The first step specifies target assets, their adaptability to climate change, and applicable adaptation technologies. The second step evaluates the effects of climate change on the performance of infrastructure. The last step determines the optimal adaptation strategies among various alternatives based on their net benefits. The framework reasonably incorporates future climate scenarios into the estimation processes for climate change effects and provides a basis for budget allocation for governmental infrastructure investments. The framework is expected to assist government decision makers in establishing adaptation strategies in a rational manner under uncertain future climate change.

Aug 1, 2013

By G. T. Lapidus, J. Trejo-Gallardo

A phenomenological model is presented for leaching silver from silver sulfide contained in mineral particles with ammoniacal thiosulfate solutions of copper in stirred reactors. Experimental results were used to adjust the kinetic parameters of the model, such as the reaction order and velocity. The incorporation of the cuprous sulfide-silver sulfide equilibrium at the reaction interface allowed the prediction of the conversion limits for different reagent concentrations. The information obtained from the reactor model was later integrated into a heap leaching simulation, whose results adequately describe tendencies observed in column tests, with respect to variations in copper and thiosulfate concentrations. Comp

Jan 1, 2005

By T. Kawai

Japan Oil, Gas and Metals National Corporation (JOGMEC) has started an exploration program for Seafloor Massive Sulfides (SMS) in the EEZ of Japan, and launched an investigation program for mining, processing and environmental impact on SMS development. With regard to the mining aspect, the mining system consists of three units: a mining unit on the sea floor, an ore lift-up unit to surface, and a mining support vessel unit which has an ore unloading system that unloads onto a shuttle ship. Regarding the mining unit, JOGMEC and certain Japanese mining and machinery companies developed two types of state of the art mining testing tools. Excavation tests on the actual SMS site in the Okinawa Trough, south-west of Japan, were conducted in 2012. In these tests, the functions of the testing tools, such as cutting ore, moving on the seafloor and climbing up slopes having steeper than a 25 degree gradient, were confirmed. The physical characteristics of the ore, which are key parameters for establishing a mining system, are yet to be fully understood as the exploration program has been undertaken simultaneously. Hence, those examinations have been carried out by ground cutting experiments, analysis of drilling core data, and the like. This paper describes the outline of a proposed mining system, mining testing tools and results of the on-site mining testing.

Aug 1, 2013

By N. A. McPherson, P. C. Stevens, A. J. Rigby

"There has been a consistent move in recent years to continuously cast small billets while utilizing ceramic stream protection between tundish and mould. The need to have ceramic stream protection has developed from a need to improve billet surface quality by submerged pouring. The need to protect the ladle to tundish stream in conjunction with tundish to mould protection is explained.The continuous casting of thin slabs is at the development state and will require a great deal of ceramic development to ensure the economic viability of the project. An insight is given to the main problems.IntroductionDuring the early development period o f the continuous casting of steel in the late 1940s and 1950s, much of the work was carried out on small cross section products. For example, the continuous casting of 50 mm square billets was carried out on a production scale in the United Kingdom at Barrow. Slab casting was initiated on a production basis on 100 mm thick stainless steel slabs at Atlas Steel, Weiland, Ontario. In the case of slab casting the thickness increased gradually until it was similar to Slabbing Mill feedstock , i.e. in the range 200 mm to 250 mm , although stainless steel continued to be lower at around 185 mm thick.For billets , a significant proportion of steel is now cast at around 100 mm square which creates specific difficulties when casting with a submerged pour - mould powder practice. The move back to smaller cross sections is further emphasized by the current interest in "" Near Net Shape Casting"" . If this move continues, then significant development will be required to create the refractories used between tundish and mould in the continuous casting process.Two specific areas which will receive attention are; (I) the casting of small cross section billet s; and (2) the casting of thin slab."

Jan 1, 1990

By V. Songmene, R. Khettabi, J. Masounave, R. D. Njoya

L'augmentation régulière des règlements environnementaux et de la sécurité au travail deviennent de plus en plus strictes. L'usinage fait partie des opérations industrielles qui peuvent causer des problèmes de santé au travail et sur l'environnement. La plupart des particules de poussières produites pendant toutes les opérations d'usinage à sec ou lubrifie causent des nuisances environnementales graves. Le travail propose étudie l’influence des paramètres de coupe, des alliages et des états des matériaux sur la formation des copeaux et sur la génération de poussière lors de l'usinage à sec. Deux modes d'usinage (le fraisage et le perçage) sont abordés. Une loi reliant la ténacité des matériaux aux émissions de poussières est proposée. Les effets des matériaux et de leurs conditions, ainsi que des procédés d'usinage sur la génération des poussières ont été mis en évidence. Des mécanismes de formation de poussières sont identifiés et reliés à la formation des copeaux.

Jan 1, 2006

By G. R. Guillet

"Bricks made from local Paleozoic shales, and floor and wall tiles made from imported clays, both established record production volumes in 1985 and are the strongest segments of Ontario's clay products industries. However, renewed interest in traditional materials also supports a good market for clay flower pots and flu e liners, and innovative processing studies are showing promise for possible new production of clay roofing tiles. This paper reviews the highlights of a comprehensive study of Ontario's clay products industries, completed in 1986. IntroductionFor some years now, Ontario's clay products industries have been unspectacular in their attempt to cope with the recent recession and the impact of alternative materials. But a strong demand for bricks in recent years has done much to dispel the gloom. Bricks, drainage tiles, sewer pipes, flue liners, structural and partition tiles, and flower pots have been commonly referred to as ""heavy"" clay products, and they have been based largely on local clays and shales. To this list might be added expanded aggregate and mineral wool. Clay refractories, sanitary ware, electrical porcelain, art pottery, and floor and wall tiles are not considered heavy clay products, and are commonly made from a variety of ceramic materials, many of which are imported.Production facilities for heavy clay products often began in Ontario as small family enterprises, using whatever clay was available locally to supply the local market with building bricks and other clay products needed for construction. Improved road systems increased the market range for these plant s, and new technology and industry standards resulted in gradual upgrading and consolidation of them as traced in Table I"

Jan 1, 1988

By Stavros A. Argyropoulos, Radhakrishna Valiveti, Bernard Closset

"The use of microprocessors in metallurgy is currently increasing at a very fast rate. A large number of companies are offering systems ""off the shelf"" which are aimed at the data acquisition and process control market. There are two main drawbacks to these systems: first, they are usually quite expensive, and second, they are not completely compatible with the target metallurgical application. An alternative is to develop a microcomputer-based system "" in lab "".A dedicated microcomputer system has proved to be very useful in many metallurgical research applications(1,2)). However, in this system the analog input signals had to be transferred over long distances , and significant noise was introduced despite the use of shielded cables. In order to overcome this problem a network of low pass-filter s was designed and built. The usage of the abovementioned system brought the need to digitize the analog signals in-situ and transfer the digital signals, which are much less susceptible to noise over very long distances. This distinctly different design philosophy has become a reality with the evolution of microprocessor technology over the last few years. This design philosophy is utilized in this development."

Jan 1, 1984

By G. Ladouceur

"Northgate Patino Mines produces a copper concentrate assaying 22% Cu. Moisture content of the product averages 12.5% H20 when dewatering with conventional vacuum disk filters. Recent smelter contracts reflect higher energy costs and increased moisutre penalty charges. This situation forced Northgate to investigate possible alternatives such as rotary dryers and pressure filtration. After laboratory testing, it was found that pressure filtration could economically meet the smelter's requirements. Pilot plant testing was then undertaken and confirmed the laboratory test results. Based on these findings, a model I.S.F. 1500 x 28/22 I.R. Lasta filter press was purchased.This paper describes the Copper Rand dewatering flowsheet the operation of the press and the economics of the process.IntroductionNorthgate Patino Inc. operates 2 und erground copper mines and a 3300 ton per day concentrator located in Chibougamau, Quebec, some 425 miles north of Montreal and 300 miles northeast of Noranda, Quebec.Copper concentrate is produced at a rate of 250 tons per day and trucked to a C.N. siding 10 miles from the mill site and then railed to the Noranda Smelter.Until early 1981, moisture content of the concentrate at 12.5070 was acceptable since smelter penalty charges were relatively low ($0.10 per ton per unit over 10070 moisutre). In January 1981, a new contract was signed in which the penalty was raised to $1.10 per ton per unit over 8070 . This and the increasing truck and rail costs justified the change-over from vacuum to pressure filtration . The Lasta I.S .F. 1500 x 28/22 was then purchased and installed, and operation of the plant started in December 1981."

Jan 1, 1987