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By D. R. Hatton

To obtain sufficient material on which to perform copper-molybdenum separation testwork a variability set of drill hole reject samples amounting to several tons was put together to include the different ore types proportions expected in the copper circuit. The samples were treated in a copper circuit pilot plant and enough mass of bulk concentrate was recovered to conduct copper moly separation tests in the laboratory. Tests consisted of stage flotation reactor (SFR) rougher pilot plant tests, conventional laboratory rougher, cleaner and 4 stage open circuit cleaner tests. The mineralogical liberation analysis of the feed and concentrate was used to model the effect of liberation on the grade-recovery relationship of the different samples. Mineral kinetic parameters for the various samples were determined by calibration to the test data. The copper concentrate results as simulated from previous studies on the same deposit were used to simulate the variability in head grade and throughput expected for the feed to the copper molybdenum separation circuit for each of the first 10 years of production. This variation in feed was then simulated through the separation circuit to obtain optimised molybdenum grade recovery curves to forecast the circuit production for each of the first 10 years. INTRODUCTION Incorporating Geometallurgy into the design for a copper molybdenum separation is especially challenging due to the low mass of final concentrate typically produced during testwork. This is due to the low molybdenum head grades and high overall molybdenum upgrading expected. With molybdenum head grades of around 300 ppm, 1 tonne of copper circuit feed is expected to produce around 300 g of molybdenum concentrate in the plant. In the laboratory however, this may end up only resulting in a few grams. Obtaining sufficient mass for laboratory testing therefore requires starting with a large initial sample and careful testwork planning to maximise the utilisation of this mass. A testwork program was designed to investigate the effect of ore variability on the copper molybdenum separation circuit (here after referred to as the molybdenum circuit). Composite samples were selected to represent the various ore types, copper content, moly content, pyrite content and clay contents expected in the copper circuit feed. These samples were run through a bulk copper pilot plant to create the feed for the molybdenum testwork. The molybdenum testwork consisted of rougher kinetic flotation tests, rougher cleaner kinetic tests, rougher cleaner kinetic tests with regrind, stage flotation reactor (SFR) pilot plant tests, open circuit cleaner tests. These tests were used to calibrate the ore kinetics in the IGS-FLEET model for simulation of the molybdenum circuit performance.

Jan 1, 2019

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019

By G. Beckstead, L. Gormely, R. Zimmer, K. Hanneman, B. Nethery

As part of the EIS and permitting activities for the Pogo Mine in Alaska, a risk assessment study for the water management plan was carried out. The basis for the study was a site water volume and contaminant balance model. Probabilistic modeling was carried out using the @Risk Monte Carlo simulation package to investigate the frequency, quantity, and quality of discharges under varying assumptions. The results were used in discussions with regulatory officials as part of the permitting process for the project. The simulation allows probabilistic modeling of key environmental parameters based on input frequency distributions involving both quality and quantity of flow. When combined with predictions of water treatment plant capacities and removal efficiency, this was very useful for defining the likelihood of important regulatory outcomes. Based on the model, certain project modifications were made. Using the simulation as a basis, ongoing dialog with regulators led to consensus that all potential risks have been considered and mitigated for the Pogo Mine according to their likelihood and severity, and that regulatory requirements would be achieved. The paper describes the model and some of the applications for which it was used.

Jan 1, 2005

By K. MacMaster

"This paper deals with the history, development, present and future of the Employee Assistance Programs in place at the Inco Ltd. operations in Thompson, Manitoba. It should be noted that, although many similar programs exist in various industries and jurisdictions, these programs had to be fine-tuned to meet the needs of Inco employees, having in mind the helping professional resources available in Thompson and its geographic location. IntroductionIn the late 70s, many Canadian industries and the Canadian Labour Congress and their affiliates commenced discussions on the value of the Employee Assistance Program (E .A.P.) philosophy to both management and labour.In the contract signed between Inco Ltd., Manitoba Division and Local 6166, U.S.W .A. in 1981, a commitment was made to establish a joint E.A.P. for the hourly workforce in Thompson, Manitoba. With this background and sequence of events in mind, it is appropriate to explain the methodology and the steps that were taken for the implementation of the hourly program. Development of Hourly ProgramIt was agreed by the company and the union that the committee to develop the program should consist of equal numbers from both sides: three active union members plus an advisor representing the Union and three supervisory personnel plus an advisor representing the Company; in addition, a person familiar with E.A.P.s from the Alcoholism Foundation of Manitoba was to act as a facilitator. The Union appointed a social worker who was working as a counsellor for union members as their advisor , and the company appointed a staff employee who had worked voluntarily in the field of alcohol and drug abuse for many years. The makeup of the committee was extremely important in order to give credibility to the entire process. The makeup of the committee is shown in Table 1.The facilitator selected from the Alcoholism Foundation of Manitoba was well known in the community and highly respected in his profession."

Jan 1, 1989

By M. S. Millman

Close monitoring of performance at each process stage, from raw material through to finished product, is vital for operational consistency and the production of high quality steel. However, many of the integrated iron and steelmaking process route stages operate under such severe conditions of temperature, dust, water, thermal radiation, vibration, pressure, vacuum, extreme dynamic events, high material flows, corrosion, erosion, electrical-noise, electromagnetic-noise, or audio-noise that, in general, it is a very difficult challenge to obtain useful information for control. Thus, state-of-the-art non-contact and remote sensors are applied to help monitor and control specific process operations. Often, these sensor systems have been developed especially for the steel industry and they are based on four principal technologies: Laser, Microwave, Electro-Magnetics and Thermal Imaging with supporting technologies such as: X-ray Fluorescence, Audiometry, Digital Image Processing, Radio Telemetry, GPS and many others. These advanced sensor technologies are reviewed with respect to their application at various stages along the integrated process route.

Jan 1, 2004

By D. F. Hambley

"In designing are passes f or underground mines specific consideration should be given to unimpaired flow of broken rock, the dump point, and typical practices f or overcoming operational difficulties. Design features such as branches, bends, and knuckles should also be considered. This paper pro vides engineering information and various criteria for designing are passes, draw points. feeders, and support systems, together with several illustrative examples.IntroductionOre passes are the primary mean s o f vertical transfer of mined ore to the ore bins and loading pocket from which the o re is hoisted to the surface (Fig. 1) . While the words "" ore"" and ""ore pass"" are used here, such transfer systems ca n be used for any broken rock.The most extensive ore pass systems are found in caving and sublevel stoping mines. Extensive ore pass systems are also found in multilevel mines having steeply dipping orebodies. In more flat-lying orebodies , ore pass systems are sometimes used in conjunction with conveyor systems .Two decades have passed since the principles of the flow of bulk solids were formulated (Jenike, 1961, 1964; Johanson and Colijn, 1964; Kvapil , 1965). However, few published papers are available that discuss the design criteria for ore pass systems. Therefore, the aim of this paper is to provide the information necessary for good o re pass design .Rock Flow in Ore Pass SystemsIf an ore pass system is to fulfill its function, the transfer o f material must occur in an orderly fashion and in such a way that the full size of the opening is employed effectively. Apart from un controlled flow at the drawpoint, or outlet , whose design will be considered later in this paper, two occurrences may impede flow in an ore pass, namely:• Hangups due to interlocking arches.• Hangups due to cohesive arches.Prevention of each of these problems will be discussed in succeeding sections of this paper. A third problem piping, is related to the ratio of the drawpoint size to the o re pass size and will be discussed under drawpoint de sign."

Jan 1, 1987

By Robert B. Parsons

"Next month will mark the anniversary of the release of an important federal study on a mineral policy for Canada. The study, entitled ""Mineral Policy-A Discussion Paper"", provides well-researched coverage of a broad range of issues that are of interest to the mining industry. Unfortunately, there is a real possibility that the discussion paper will wither and die on the vine, unless the federal and provincial governments, and the private sector, collectively ensure that some of the key considerations which are raised by the paper are acted upon.IntroductionAlmost one year ago, on March 8, 1982, Federal Mines Minister July Erola released an important study entitled ""Mineral Policy-A Discussion Paper"". The discussion paper, which presents the government's assessment of the opportunities and constraints facing the Canadian mineral industry in the 1980s, was prepared within the context o f three principal objectives-strengthening the resource base on which the industry rests, ensuring the adequacy of research activities needed to support development of the resource, and furthering the development of markets for the resource It is clear that, in today's economic climate, not even the most generous incentives would turn the industry around: what is needed is a sound base for future development, when this is possible. In this regard, the discussion paper is an excellent stepping stone, in that it reviews a wide range o f fundamental policy issues which touch on all facets o f the mining industry."

Jan 1, 1983

By J. E. Dodge

Tasu, currently an open-pit operation, services the primary crusher from two areas by ore-pass raises. The problems encountered and advantages gained are discussed. Mine equipment and operating practices are covered, together with blasting practices, line drilling and the pre-shearing necessary to stahilize the pit walls.

Jan 1, 1968

By L. G. Smith, C. A. Shook, W. H. W. Husband, W. Schriek

"The flow of slurries in pipelines is governed by many variables, and the study of the influence of each of these variables is difficult, if not impossible, in some cases. Many correlations are available which fit data within a given range. However, no one method is yet available to design a slurry pipeline for all desired conditions without at least some physical measurements on the slurry itself. For this reason, the slurry pipeline facilities at the Saskatchewan Research Council have been developed during the past 12 years and it is hoped that the development will continue until the process is thoroughly understood and test facilities are no longer necessary. This paper outlines methods currently used and under development at the Saskatchewan Research Council for measurement, control and study of the variables governing the flow of slurries."

Jan 1, 1973

By J. Smit, F. Parada, R. Parra, E. Balladares, M. P. Merino

"In this study, a two-step process was developed for recovering copper, molybdenum, zinc and iron (hematite). In the first step, grinded slags (-65 mesh) were sulphated with SO3 at 350-500ºC to form iron, copper and zinc sulphates. In the next step, the formed sulphates were decomposed to hematite, copper and zinc sulphates and oxysulphates at 700-750ºC. The generated SO3 was recirculated back to the sulphation step. The generated calcine in the decomposition step is leached with 25 gpl acid at 50ºC to dissolve the copper, zinc and molybdenum for further conventional separation and recovery. The hematite residue, of intense red color, can be used as pigment, in the ceramic industry or as pellet feed. The fine crystalline silica remains in the hematite residue."

Jan 1, 2014

By J. H. Curran

Agenda ? Challenges of developed world mining ? Software aids for creative and practical engineering ? Rocscience software philosophy ? Rocscience suite of geomechanics programs ? Case study ? design of de-stress slot Mining Challenges of the Developed World ? Dwindling reserves ? Great depths ? Strict operating and environmental regulations ? Competition from lower cost operations in developing countries

Apr 1, 2005

By Alain Tshilombo, Vijay Reddy, Chowdary Meenavilli, Kelvin Buban, Cory Kosinski, Sriraj Meenavilli, Siddhartha Tirumalaraju

The use of artificial intelligence (AI) for process optimization is expected to play an increasingly important role in the future of the mining industry. The objective of AI is to develop a data driven soft (virtual) sensor using historical data that can estimate unmeasurable characteristics of the process and provide appropriate recommendations during operation to optimize the process through continuous learning. The application of AI to a hydrometallurgical process was evaluated by Sherritt Technologies in coordination with NTWIST. Historical operating data obtained from the Ambatovy facility’s High Pressure Acid Leach (HPAL) circuit was used to develop models to predict autoclave discharge parameters based on operating conditions and ore mineralogy. The prediction models were developed in such a way to also allow the user to simulate and test different operating conditions. A second set of models (AI model) were developed based on the prediction models, economic data and operating constraints for a given process unit to identify optimal reagent and steam dosages across the HPAL circuit. The development of these models was significantly complex due to the dynamic and interactive nature of the HPAL process. Despite the complexity of the models, the models were able to predict, with accuracy, the relationship between ore composition, leach autoclaves retention time, acid addition and steam addition with metal extractions as well as levels of impurities in the autoclave discharge slurry. The study showed that AI has the potential to improve the overall operation of a facility through providing tools to assist with training, troubleshooting and process optimization. INTRODUCTION The Ambatovy project, located in Madagascar, is one of the world’s largest nickel and cobalt mining and processing operation, with a design capacity of 60.000 tonnes of nickel and 5,600 tonnes of cobalt per year (Collins et al., 2016). Commissioning and start-up of the Ambatovy mine and plant facilities were completed in 2012, with acid first introduced to the ore leach in March 2012. Commercial production (defined as 70% of design capacity) was achieved in January 2014 and the production level required to achieve financial completion (90% of design capacity for 90 days) was achieved in March 2015 (Valle et al., 2016). Figure 1 shows a simplified flowsheet of the hydrometallurgical pressure acid leach (PAL) process employed by Ambatovy.

Jan 1, 2019

By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

By A. Navarra, Norman Toro, T. Marín, Fernando Ayala

The quantitative techniques to evaluate the enhancement of a particular unit operation should consider the corresponding changes to the adjacent unit operations. For example, the expansion of off gas handling capacity should consider the corresponding changes in converter cycle times, matte grade, and other operational parameters, that can provide the optimal system-wide benefit. In general, the upgrading of smelter equipment is risky due to the size of capital investment, as well as any unforeseen impacts on rest of the operations. However, this risk can be mitigated by applying the principles of Front End Loading (FEL) in the formulation of multiphase re-engineering projects. The initial phases of engineering are relatively inexpensive, and determine whether or not to pursue the subsequent phases that are comparatively more expensive. Each phase of engineering depends on increasingly detailed descriptions regarding the critical phenomena that can effect design decisions; the increasing levels of detail may result from numerical simulations, as well as laboratory and plant trials. The quantitative framework should be sufficiently flexible to accommodate these increasing levels of detail, regardless of the particular phenomena, so that it may evolve throughout the project. The current article describes the combined usage of mass balancing, thermochemistry and multiphysics, in the development of discrete event simulation (DES) and finite differences (FD). The incorporation of finite differences into a DES framework depends on adaptive time-stepping, to determine threshold-crossing times, e.g. when the matte temperature surpasses a critical level that necessitates the addition of cold charge. The hybridization of DES and FD is appropriate for multiphase smelter development projects, as it supports semi-continuous material flows, operational policies and scheduling, as well as unexpected events and trends, in increasing levels of detail. This type of framework will support the installation and tuning of modern control systems, including state-of-the art sensors and machine learning algorithms.

Jan 1, 2019

"Since all gold mills must sooner or later be cleaned up for permanent shutdown it was felt that a record of what was done at one mill might be of some help to those who will have to do the same job in the future,In cleaning up the mill of Delnite Mines Limited, I had an advantage that most mill superintendents will not have in that I started up the mill and was there until it was shut down, It was also known for two years approximately when the shutdown would be and for a year almost the exact time. This, of course, made careful planning possible and enabled me to get advance information that wouldn't have been available had the shutdown come unexpectedly,Early in 1964 calculation of ore reserves and the known number of working places available indicated that the mine would run out of ore sometime in August or September but not later than October, The time of course would vary with the number of competent miners that could be retained until the shutdown. Since the mining method used exclusively on the ore then remaining was cut and fill, it was known that once mining operations ceased it would require at most two days to crush and grind the last of the ore.In March 1 964 I took samples of the concrete floor under the precipitation presses, in the flux room and furnace room of the refinery and from the assays obtained proved that there would be no profit in breaking up the concrete to recover the gold from it, Samples taken from the top half inch of the concrete floors assayed less than 0, 10 oz per ton,"

Jan 1, 1966

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

Magnetic separation of precipitated magnetite as iron resources in copper slag is one of the potential effective ways to recycle the slag. It is preferable to convert molten fayalite slag after copper smelting process to magnetite slag via oxidation. With a TTT (Time-Temperature-Transformation) diagram, the crystal composition of the slag obtained after air isothermal oxidation could be estimated through a designed cooling path. The crystallization behaviors concerned with molten oxidation was studied for better understanding of the trade-off relationship between magnetite and hematite during molten heat treatment. Moreover, a brief consideration was implemented of the reaction mechanism.

Jan 1, 2014

By D. A. Whitley, R. P. Carone

"Shaft sinking by blind shaft drilling offers the mining industry a different approach to shaft construction. Benefits of blind drilling include less construction time and fewer safety problems while being economically competitive with conventional sinking methods under certain conditions in soft water-bearing formations.Technology and equipment are available today to drill blind shafts up to 20 feet in diameter and over 3,000 feet deep. This is an extension of proven techniques developed by private industry. To drill a 20-foot-diameter hole requires a specially manufactured hydraulic drill unit with a rated hoist of 2 million pounds and 500,000 ft/lb of torque.This brief paper will discuss the following aspects of blind shaft drilling:• benefits;• equipment f or drilling;• circulation methods;• circulation rates;• shaft alignment; and• progress rates to be expected.IntroductionShaft sinking by blind shaft drilling offers the mining industry an improved alternative method for shaft construction. The drilling of 20-foot -diameter shafts to depth s in excess of 3,000 feet can be done by utilizing equipment specifically designed and manufactured for this purpose. This equipment is a distant cousin, at best, to standard oil well drilling rigs. The actual configuration of these drilling machines will be discussed in a following section.To most people, the drilling of mine shafts may seem to be a new or at least recent technology. However, as early as the I920s, German and Dutch miners were drilling 24-foot diameter shafts for coal mines. What led ""miners to resort to drilling were ground conditions that still plague conventional shaft sinkers today: soft , water-bearing formations. The major drawback to these early attempts was a low penetration rate due to poor bit cleaning. This, however, was not the end of early shaft drilling activity. From 1936 to 1950, a number of mine shafts were drilled by the calyx or coring method. This method employs a bit with a large bore down the center. As it drills, it cuts a core. When 5 to 10 feet have been drilled, the core is removed. The disadvantages of this method were the time and work involved in breaking the core free, and it was inadequate in soft water-bearing ground."

Jan 1, 1981

By D. W. Smith, J. J. Koskinen, T. A. Enwald, M. E. Ball

"A full-scale demonstration unit of Tampella's LIFAC desulphurization process was tested at SaskPower's Poplar River Power Station Unit No. I. The test program included a series of parametric tests, followed by a 1500 hour operational evaluation. This paper summarizes the results of the test program, and SaskPower's economic evaluation which led to selection of the LlFAC process for SaskPower's 300 MW Shand power station. IntroductionOne of the major influences on the coal mining industry today is public and legislative response to acid rain. When sulphur-bearing fuels such as coal are burned, the sulphur oxidizes to sulphur dioxid e (S00 which, if uncontrolled, enters the atmosphere as one of the by-products of combustion. S02 then combines with water in the air to form an acid and acid rain results. Combustion also produces nitrogen oxides (N0J which can combine with water in the air forming nitrogen based acid , also contributing to acid rain.Acid rain has become a significant international concern. Newspapers have reported on dying forests, dead lakes and crumbling statues. Papers also include articles professing that the physical results of acid rain are vastly overstated. In the United States, a IO-year, Y2-billion dollar study called the National Acid Precipitation Assessment Program (NAPAP) was commissioned to evaluate the effects of acid rain. Even this extensive scientific study did not resolve the controversy. Despite disagreement over the quantitative effects of acid rain, there is no doubt that public concern over the issue is widespread and deeply felt.In response to this concern, legislators throughout the world have reacted with programs that restrict the emission s o f SO, and NO,. To industries involved in the supply and use of coal, the impact of these legislative programs has been extensive. United States power plants will be spending 10 billion dollars in the next decade for flue gas clean-up equipment. Even all this new equipment will not stem the tide of change to low sulphur coals and to “clean “natural gas. The following summarizes legislative actions taken for Canada and the United States."

Jan 1, 1993

By C. Mattich, Å. Holmström, L. Hedström

"The fluidized bed at Division Ministro Hales (DMH) division of Codelco in Calama, Chile is currently the largest operating roaster for partial roasting of arsenic rich copper concentrates. The roaster converts the Mina Ministro Hales (MMH) enargite rich (Cu3AsS4) copper concentrates into calcine with a low arsenic content that is suitable for mixing with other copper concentrates feeding a flash furnace. The plant sets a new standard for the processing of arsenic rich concentrates, both from the quality of the calcine as well as the environmental performances. The process technology and expertise are based on the solid practical experience of treating arsenic rich concentrates from both the Boliden smelter and Outotec.The partial roasting process is located next to the mine and concentrator and includes a sulphuric acid plant with auxiliary equipment. The produced calcine has an arsenic content significantly below target and the residual sulphur meets the requirement of the flash furnace. The plant operates with high efficiency cyclones resulting in a low amount of calcine passing to the hot electrostatic precipitator (HESP). The small flow of HESP calcine dust can be combined with the low arsenic calcine and still meet the flash furnace feed arsenic requirements.SO2 formed during roasting is converted into sulphuric acid, while volatized arsenic is recovered in the wet gas cleaning section of the acid plant along with a large proportion of antimony present in the MMH concentrate. Arsenic is stabilized as calcium arsenate and sent to disposal at a specially prepared site.The present production rate (September/October 2015) is close to or higher than the original maximum design capacity of the plant.INTRODUCTIONMineralogyThe mineralogy of an ore and concentrate is important, since there is a direct link between roasting performance and concentrate mineralogy. The MMH concentrate has a good combination of minerals that makes the roasting process efficient and flexible. The main minerals are pyrite, enargite and chalcocite (Figure 1). The inert content is about 15% and consists mainly of silicate and alumina based minerals. The lead content is very low and this is desirable, since the presence of even a small amount of lead will cause a substantial increase of sintering during roasting."

Jan 1, 2016

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Several studies conducted recently have shown that molybdenite flotation from Cu-Mo ores is adversely impacted in sea water at pH >~ 10.0 irrespective of the pH modifier; under the same conditions Cu sulfide flotation is relatively unaffected. This has been attributed to the presence of Mg2+ ions and their hydrolysis products in the sea water which adsorb and precipitate on molybdenite surfaces as Mg(OH)2. However, why and how Mg(OH)2 impacts only molybdenite flotation in the complex flotation pulps containing a multitude of minerals is not understood. The work presented in this paper probes the interface and interphase regions near the edge and basal planes of natural molybdenite (MoS2) in aqueous solutions and flotation pulps, particularly in the presence of copper ore pulp and added Mg2+. Differences in interaction of metal ions and their hydrolysis products (Mg2+, Mg(OH)+) were measured on the two faces of this anisotropic mineral. How those differences relate to molybdenite floatability and the impact of aqueous solution chemistry are discussed.INTRODUCTIONWater resource management is an important sustainability challenge in mineral processing. In view of the shortage of fresh water in many parts of the world, mineral processing plants are evaluating alternative sources. Seawater flotation has received much attention recently and there have been several important studies reported in the literature, particularly for the processing of Cu-Mo ores (S. Castro, 2012; S. Castro, Rioseco & Laskowski, 2012; S. Castro et al., 2012; Laskowski & Castro, 2012; Ramos, Castro & Laskowski, 2013; S. Castro & Laskowski, 2013; Laskowski, Castro & Ramos, 2013; Nagaraj & Farinato, 2014; S. Castro, Uribe, & Laskowski, 2014; Veki, 2013). The main conclusions from these studies on Cu-Mo ores in seawater at elevated pH were: a) flotation recovery of Cu sulfides is either unaffected or only marginally reduced, b) molybdenite recovery is adversely affected in seawater at pH values necessary for rejecting pyrite (i.e. pH > 10 to 10.8 depending upon particular system), and c) the precipitation of Mg2+ in seawater as Mg(OH)2 is responsible for the adverse effect on Mo flotation. In order to further investigate the individual effects of Mg2+ and Ca2+ on molybdenite depression in Cu-Mo ore flotation, Nagaraj & Farinato (2014) conducted flotation tests wherein individual metal ions were spiked into tap water during grinding of Cu-Mo ores. They showed the strong adverse effect of Mg2+ addition on Mo recovery and, to a lesser extent, on Cu recovery when pH > 9.5. Under similar conditions, Ca2+ had virtually no effect on either Cu or Mo sulfide flotation. Figure 1 below shows the previous results for Cu- Mo ores in tap water and the effect of addition of Ca2+ and Mg2+ ions. Note that in seawater the adverse effect of Mg2+ on Cu recovery was much smaller than that in tap water (Nagaraj & Farinato, 2014; Figure 4a and 4b and Table 4 therein)."

Jan 1, 2016