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By Michael Moser, Brighty Dutta, David Dreisinger

"Molybdenum is widely used in the industries as an alloying element in the manufacture of steels and super alloys. The widespread use of the element encourages a growing need to develop extraction processes for recovery from both primary and secondary sources. The Solvay Group has developed a solvent extraction reagent named CYANEX®600 for the recovery of molybdenum from acidic solutions originating from both low grade (e.g. copper solvent extraction raffinates, smelter dusts and slags) and high grade (molybdenite) molybdenum sources. CYANEX®600 is a purified form of CYANEX®272 with the active component bis(2,4,4- trimethylpentyl)phosphinic acid. The extraction behavior of CYANEX®600 towards molybdenum in sulphuric acid medium was evaluated. The uptake of molybdenum increased with the increase in concentration of CYANEX®600. The approximate stoichiometry of the extracted complex was: Mo: CYANEX®600 = 1:2. Efficient back-extraction could be achieved with 0.1 M disodium EDTA and 0.1 M (NH4)2CO3, thus providing the option of recyclability of the extractant. The detailed back-extraction studies are currently under progress to find out the possible option for complete transfer of Mo(VI) to the aqueous phase so that high purity Mo salts could be precipitated from the molybdate solutions.INTRODUCTION Molybdenum (Mo) is one of the world’s valuable metals and is highly sought after by researchers due to its versatile mechanical, thermal, chemical properties. Swedish scientist Carl Wilhelm Scheele demonstrated molybdenite to be a mineral sulfide in 1778. Peter Hjelm successfully isolated dark metal powder from the mineral sulphide and named it as ‘Molybdenum’ in 1782 (Gupta, 1992). Molybdenum is a refractory metal of silver gray appearance and is an important alloying element used in the manufacture of steels and super alloys. Molybdenum compounds are widely used in formulation of catalysts (Gupta, 1992). Molybdenum occurs in nature only in chemical combination with other elements. Several molybdenum bearing minerals have been identified, but the only one of commercial significance is molybdenite (MoS2). As molybdenum is a strategic metal for the industrial sector, its widespread use acts as a factor for depletion of the natural resources. Hence, there is growing need to develop extraction procedures for its recovery from both primary and secondary sources. United States, China, Chile, Canada, Peru, and Mexico are listed as the main producers by the U.S. Geological Survey, 2016 (U.S. Geological Survey, Mineral Commodity Summaries, January 2016)."

Jan 1, 2017

By C P. Gravenor

In 1953, a deposit of sedimentary oolitic iron ore was discovered in the Clear Hills area of northwestern Alberta. Since that time, detailed drilling has outlined reserves in excess of 200 million tons of ore grading 30 to 35 per cent iron. Attempts to physically beneficiate the ore to meet blast furnace or direct reduction feed specifications have been, in general, unsuccessful. In 1960, Premier Steel Mills Limited and the Research Council of Alberta jointly sponsored a pilot-plant test at the R-N Corporation at Birmingham, Alabama. About 5,000 tons of ore were treated, and briquettes containing 90 per cent Fe were produced, with 83 per cent recovery. At the same time that the R-N tests were being made, the Research Council initiated a program to produce high-purity powders by chemical methods. Several purification techniques were investigated; hydrochloric acid dissolution of reduced ore was finally adopted. Briefly, the steps involved in this acid process are as follow

Jan 1, 1964

By C. R. Fast, G. C. Howard

The loss of fluid to the formation adjacent a fracture governs the areal extent of the fracture and the success of hydraulic fracturing as a production stimulation technique. The three flow mechanisms which control this loss are the result of the viscosity of the fracturing fluid and the permeability of the formation to the fracturing fluid, its wall building properties, and the combined effects of viscosity and compressibility of the reservoir fluid. The effects of these flow mechanisms can be evaluated in terms of a fracturing fluid coefficient, the fundamental concepts of which are developed in the paper. The fracturing fluid coefficient, which may be used in calculating the areal extent of fracturing, affords a direct measure of the effectiveness of fracturing fluids. The area of hydraulically created fractures is in-creased as the coefficient is de-creased. The fifteen-fold variation noted in this coefficient for the commercially available fracturing fluids tested resulted in a six-fold difference m the calculated areal extent of the fracture system.

Jan 1, 1961

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

By F. E. Patton

"IntroductionAT NORANDA, the strength of the ore and wall-rocks per-mitted mining in large open stopes. While some of the orebodies were small and could be mined out in one stope, in most cases their size was such that it was essential that ore pillars be left during the first stage of mining. In these cases, backfilling has been necessary for ground control and to facilitate the later recovery of the ore in these pillars.This paper discusses the development of the •backfill and •its use in pillar recovery.GeologyThe ore bodies at Noranda occur as replacement deposits in a block of rhyolite flows and breccias, bounded on the north by the Horne Creek fault and on the south by the Noranda Andesite fault. Mineralization consists of pyrite, pyrrhotite, magnetite, chalcopyrite, sphalerite, gold, and various tellurides.The main orebody is a massive sulphide deposit designated the 'H' orebody. It is elliptical in plan, measuring roughly 400 feet by 800 feet, and is divided into two zones -Upper H, extending from surface to the 1,500-foot level, and Lower H, from the 1 ,500-foot level to just below the 3,000-foot level.Mining MethodsOpen stope mining in both Upper H and Lower H zones has been fully described in previous publications (1). A brief review only of the mining methods will be given here."

Jan 1, 1952

By J E. McMynn

The development of the Granduc mine presents a number of problems which are peculiar to its location and surrounding terrain. Because the development tunnels portal onto an area which is covered by an extensive glacier, and the mountain-side is subjected to dangerous snow slides, it was decided to construct an underground powerhouse to supply the necessary electric power and compressed air. This paper deals with the special problems inherent in the design and -construction of an underground plant. It involves the installation of diesel-electric generating equipment having an aggregate capacity of 1,050 kw.,and of air compressors with a total capacity of 2,400 cfm. Items dis-cussed include the selection of equipment to meet site conditions, the ventilation and cooling of the underground room, and the protection of personnel and equipment from explosions and fire. A short discussion on the automatic supervisory and alarm installation is also included. THE Granduc mine is located 135 miles north of Prince Rupert and 25 miles north of Stew-art. This seems quite accessible, mileage-wise, but, due to mountains,

Jan 1, 1963

By F. M. Makarinsky

"This paper describes the conversion of conventional froth flotation cells to open-trough type bank cells, with 'buried' vertical metal partitions. These changes have resulted in: total froth removal along the full length of each bank of cells; extended flotation cell retention times; and has extended the life of the metal components, particularly towards the upper flotation cell areas.INTRODUCTIONOver the past twenty years, the flotation cells used at Falconbridge Limited, Sudbury operations concentrators, have gone through major physical changes. The various concentrators generally started with 100 cubic foot Denver Sub 'A' flotation cells. From these units, we progressed to 'converted' DR units, and/or Denver DR units, if purchased new. (Figures 1, 2, 3)In 1980, the Strathcona concentrator started to pay more attention to the 'front end' rougher flotation cells. Initially, the converted DR flotation cells had 'cut-outs' removed (Figure 4) at all upper vertical cell partitions, towards the ff9th lip areas, in order to get additional froth removal."

Jan 1, 1985

By R. Heikkilä

Fluent information exchange between different work phases, software and systems used in infra construction is a key for successful execution of infra construction projects. Open and publicly available information formats with the determined data models aim to facilitate the interoperability between different software and systems developed by competitive vendors. While building and construction industry has developed and used IFC format for years, infrastructure sector has just recently started to target clear efforts on the development of open information formats for infra construction processes. In the paper, a new Inframodel3 extension just developed in Finland and based on the LandXML1.2 international standard is to be introduced. The aim of the Inframodel3 was set to meet the requirements of information transfer needed especially between BIM based design software, measurement systems and 3-D machine control systems used in road, railway and watercourse construction projects. Some test results are reported and evaluated in the paper. In the field of bridge engineering, the IFC format and IFC Bridge extension have been tested and evaluated in Finland. The results from the experiments show and verify as well the applicability of these open formats to the information exchange requirements in bridge engineering. The current limits for open information transfer of these formats are shown. The active co-operation with the International Building SMART Organization has led to the achieved status and position for both the Inframodel3 and IFC Bridge formats and hence the continuing international support provided by Building SMART.

Aug 1, 2013

By T. G. Joseph, M. Bolster, M. Curley

"High tirerim loading on haul trucks operating on rough ground frequently manifests as mechanical separations and rim base cracking caused by cyclic fatigue. This paper provides an understanding of the impact of high loads on rim component life and tire footprint, bulge, and deformation behaviour; and develops a maintenance planning tool to predict strain implications of high g loading for a given rim location. Loading tests and analyses were conducted for a tirerim arrangement under increasing load and internal tire pressure. Graphical models were developed, allowing higher g load extrapolation predictions for specific rim components.KEYWORDS g load, Mining, Model, Prediction, Rim, Strain, Tire bulge, Tire footprint, Ultra-class vehicleRÉSUMÉ L’application d’un chargement élevé sur le système pneu/jante de camions de transport rou¬lant sur des terrains accidentés se manifeste fréquemment par des séparations mécaniques et une fissure à la base de la jante engendrée par une fatigue cyclique. Cet article nous permet de mieux comprendre l’incidence de l’application de charges élevées sur la durée de vie des composantes de la jante ainsi que sur l’empreinte, la hernie et le comportement de déformation des pneus. Il développe également un outil de planification de l’entretien visant à prévoir l’incidence des contraintes en cas d’application d’un chargement g élevé sur un endroit donné de la jante. Des essais et des analyses de la charge ont été effectués pour un agencement pneu/jante soumis à une charge et une pression interne du pneu croissantes. Des modèles graphiques ont été développés, ce qui a permis d’établir des prédictions sur la base d’une extrapolation du chargement g plus élevé appliqué à des composantes spécifiques de la jante.MOTS CLÉS charge g, contrainte, empreinte du pneu, exploitation minière, hernie du pneu, jante, modèle, prédiction, véhicule ultralourdINTRODUCTION The purpose of this paper is to report on a proposed and trialed tire performance test based on data obtained from controlled testing that is used to predict the impact of high g loading on hauler rims and tires with greater accuracy. For example, for many years oil sand mining operations have expressed qualitative beliefs that an impact load of the magnitude experienced by a rim and tire arrangement is not detrimental to a rim as a stiff component; however, mining equipment components are subjected to cyclic loading where failure can result from repeated load/unload activity, truncating the peak region of a stress–strain response and resulting in fatigue failure at a stress value that is less than the peak value. The outcome reported by oil sand haul truck maintenance groups indicates they have realized that most high g impacts—such as those experienced by hauler tires and rims operating on poor ground conditions—can result in failure due to cyclic loading, where higher loads require fewer cycles for failure. This high-level loading and the resulting strain transmitted to the rim is evident in the results of the laboratory testing presented in this paper."

Jan 1, 2019

By A. J. Hyett, N. Hedrick, J. Blackall

The Garford bulb anchor is a modified cable geometry developed and patented by Garford Ply Ltd. of Australia, and which has recently become widely available in Canada. It is produced by deforming the seven wires (including the central kingwire) of a standard cable into a bulb" (Fig. 1). Laboratory cable pull tests indicate that the bond capacity of the 25 mm Garford bulb anchor is comparable to the nutcase cable, in excess of the birdcage cable, and significantly higher than standard 7-wire strand. Its comparative advantage over the latter is most significant for tests at low radial confinement and high water:cement ratio grout, which corresponds to operational conditions of low quality rock (i.e. weak, highly fractured rock masses, foliated hanging walls, failed ground, etc.) and poor installation quality control (perhaps the most common explanation for cable bolt failures). It is under such conditions that cable bolting is often ineffective. The most impressive result is that for a reduction of the effective rock mass modulus by a factor of five, the Garford bulb cable capacity remains virtually unchanged.

Jan 1, 1995

By Eamonn F. Maher

Superconductivity is one of the most remarkable scientific phenomena ever investigated. It is the phenomenon whereby some materials exhibit zero resistance to the passage of an electric current when cooled to low temperatures, and requires a quantum mechanical explanation. Four Nobel prizes in physics have been awarded specifically on the subject of superconductivity, with many more enabled by superconducting technology. For example, particle beams are generated in accelerators and manipulated in ?particle beam lines? in the ?Big Physics? projects around the world eg. at CERN, Geneva, leading to major discoveries in fundamental particle physics. Similarly, at the JET Propulsion laboratory near Oxford, U.K, controlled nuclear fusion has been demonstrated, and magnetic containment of plasmas is key. In the chemical and biological sciences high field NMR spectroscopy has become indispensable for examining organic matter, revealing the mysteries of the workings of cells, genetics, and in the development of new polymers and pharmaceuticals. With all these very advanced uses for superconducting magnets, it is easy to forget that superconductivity is big business, not just a scientific curiosity. MRI (Magnetic Resonance Imaging) superconducting magnets, the key component of high resolution body scanners, use approximately half of the world?s superconducting wire ? the other half being mostly used in accelerator magnets. The MRI market is about 3 billion dollars per annum, and one MRI magnet uses 200km of wire. New applications for superconducting magnets are now appearing including ?Catheter steering?, enabling much shorter timescales for life-saving brain tumour removals and ?Functional MRI?, a whole new area in patient diagnostics. Whilst the use of low temperature superconductors (LTS) is now well established commercially in superconducting magnets and niche electronic applications, the application of LTS in electric power distribution and transport has been very limited to date. It is now more than fifteen years since the so-called High Temperature Superconductor (HTS) materials were discovered: these can be operated at liquid nitrogen temperatures rather than liquid helium temperatures. However, materials processing and scale-up issues have prevented their widespread use, and in particular the required price/performance criteria are only beginning to be reached except in certain niche markets. BSCCO (Bismuth Strontium Calcium Copper Oxide) tapes up to one km long are now readily available, and have been demonstrated in high current cables for power distribution networks, but the general consensus is that 1) it is difficult to reduce the price much further because of the silver matrix required and 2) in applications where coils are required eg. motors, generators, transformers etc the properties of BSCCO are rather poor because of the critical current dependence on magnetic field. Magnetic fields are always associated with coils and windings, and such fields are of course fundamental to the operation of all electrical machines. YBCO (Yttrium Barium Copper Oxide) however, has good characteristics in field and for the last few years there has been intensive research and development costing several tens of millions of dollars worldwide into the scale-up of production of so-called ?coated conductor?. This ?second generation? tape can be produced by any of many different film deposition techniques, with more or less success for short lengths, but as yet it is unavailable in lengths more than a few tens of metres.

Oct 1, 2003

By M. Hall

"SomarioEl circuito de molienda a Selbaie consta de molino semiaut6geno en un circuito cerrado y molino de balas en un circuito cerrado. El amperaje del motor de se usa controlar el tonelaje el molino. Este sistema estabiliza el circuito pero no mejora activamente el rendirniento del circuito. Se desarroll6 auxiliar el rendimiento del circuito un sistema experto en manipular las objetivos de existir control proporcional-integral. Se ejecut6 el sistema con el Comdale /C conjunto del sistema experto y ha side funcional hace tiempo el mayo de 1992. El sistema experto ha resultado en un aumento en tonelaje de 7tph y una disminuci6n de $210,000 en el caste anual de media de molienda. Se describe el desarrollo del sistema y los provechos derivar se presenta.AbstractThe grinding circuit at Selbaie consists of SAG mill and ball mill closed circuit grinding. The SAG mill motor current is used to control throughput. This system stabilizes the circuit but does not actively optimize circuit performance. An expert system was developed to aid the optimization of the circuit by manipulating the set-points of existing PI control loops. The system was implemented with the Comdale /C expert system package and has been on line since May 1992. The expert system has resulted in a net increase in tonnage of 7tph and a decrease in annual grinding media costs of $210,000. The system development is described and the benefits derived are presented."

Jan 1, 1994

By Philip J. Bangerter, Chris Twigge-Molecey

Design for safety is critical to metallurgical plants, due to the inherently dangerous nature of their processes. Two significant areas of concern are: 1. preventing catastrophic process failures that cause damage or injury; and 2. operational safety that directly affects those working in or living near the plant. Process safety involves human behaviour, but the designer can eliminate or control hazards by engineering approaches, and control impacts through the design of the operating procedures. The tools available to guide safe facility design include bowtie analysis, hazard analysis, and hazard and operability studies. Clean plant design principles can guide the design process to address in-plant occupational health and safety issues. Auditing and review is a key part of the overall design process.

Jan 1, 2015

By R. H. Fett

T HE APPROACH to maintenance must always be ?completely positive: there must be no question of putting off difficult problems until it is more convenient to tackle them. By this it is meant that a piece of machinery or equipment which, by experience, is known to be due for a check should not, merely because it appears to be operating satisfactorily, be left until it reaches a critical .condition and breaks down. The mentality of the Maintenance Manager must be completely orderly and methodical and he should, in fact, possess a ledger-book mind, having a debit and credit outlook. The debit side would be that applying to time out of service, cost in wages, material, personnel involved, etc., and the credit side that relating to continuous operational time of the locomotive and therefore to the ultimate benefit of the mine and the personnel who work there. The Maintenance Manager is not concerned with design problems, and although he and the personnel under his jurisdiction are not engaged in productive work, he and his staff do, nevertheless, add greatly to or detract from the overall efficiency of the organization. Provided the machinery placed in his care is good to start with, he must take the best steps he possibly can to keep it running. However, he may, on occasion, be forced to improvise and this is where the ingenuity of a clever man rises to the occasion.

Jan 1, 1956

By J. R. Bradfield

THOSE familiar with the development of the Horne mine can readily appreciate that more and more accommodation bas been required for underground labour as the mine has grown. A permanent fire-proof change house, 30ft. by 75 ft., was built in 1927 to accommodate 194 men. This was extended ro 30 ft. by 92 ft. in 1928 to accommodate 296 men, and to 30ft. by 110 ft. in 1930 to accommodate 398 men. By 1933 this building was again overcrowded and tentative plans for a new change house were drawn up. However, it was realized that future operations would be centred around No. 4 shaft and a proposed new shaft, and the decision as to the location of the new change house had to be deferred until the area which seemed most suitable for the new shaft had been thoroughly explored underground. In the spring of 1934, the basic idea was accepted of drying the wet clothes in open mesh compartments or baskets located between rows of standard steel street-clothes lockers and built so that the covers or lids would serve as seats or benches.

Jan 1, 1935

By P. Hansman

"Place Dome Canada's Detour Lake Mine is a low-grade gold producer located in northeastern Ontario. Production is targeted for 2850 tonnes of ore per day. As reserves and mining areas continued to be found below and far to the west of the shaft (Fig. 1), it became necessary to review and upgrade the materials handling facilities. This paper deals with the selection, design and construction of an underground crusher and conveyor system capable of handling up to 450 tonnes per hour from the lowest existing level in the mine.BackgroundThe Detour Lake mine site is accessed via secondary Highway 652 which runs northeast out of Cochrane, Ontario. The road consists of 200 Ian of hard top followed by 100 Ian of well maintained gravel to the mine site. A 1500 m airstrip is maintained at the mine site for emergency use. Prior to 1991, the workforce was flown to and from the mine site. Crews were now bused to the site from Timmins. Remnants of a winter road exist to the southeast which at one time ended in La Sarre, Quebec. This was the route used to haul bulk items during the construction period and early production years.A town site has not been established at the site for the current operations. Instead, a rotational scheme is being utilized whereby most personnel will work seven days on site followed by seven days off site. For some employees, however, the work week is termed as a four/three schedule where they work 42 hours between Monday at 10:00 a.m. and Thursday at 4:00 p.m. with the following three days off. All surface employees and maintenance employees underground work 12-hour shifts. All underground employees work a lOV2-hour shift. Supervisors work a similar schedule as their crews, however, other staff may overlap their rotation during the week.A five-compartment shaft was sunk in 1984 from surface to the 610 m elevation. Shaft stations were established at the 120 m, 260 m, 360 m, 460 m, and 560 m levels. The cage compartment consists of a single deck, 4O-man cage in balance with a counterweight. The cage hoist is an Ingersoll-Rand 10H and is regulated to travel at 4.1 m/s. Two 9 t skips operate in balance at a travel speed of 7.1 mls. The skip hoist is a 3.05 m drum Nordberg. Both hoists are automated to function without a hoistman during normal skipping and cage service runs."

Jan 1, 1995

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

By Douglas A. Sloan

"Shutdowns and breakdowns that halt the process-flow of mine production are costly. Skilled maintenance tradesmen are scarce and expensive. The cost of maintenance or of production Joss from Jack of maintenance is significant and warrants considerable managerial attention.The most appropriate maintenance policy is dependent on an economic calculation. At one end of the spectrum is the policy of avoiding all breakdowns by replacement and preventive routines before failure, such as the airlines policy. At the other end of the spectrum is the policy of minimal routines and the acceptance of a breakdown as a prelude to a repair.The complexity and cost of maintenance warrants the appointment of a maintenance manager of senior status. Within the origination, there are a number of activities that can be specialized to improve effectiveness. Among these are the inspectors' activity, the establishment of improvement routines, the planning of repair tasks, maintenance engineering research and value analysis.The maintenance system is the mechanical aid to assist the staff in the implementation of the policy. It is designed to facilitate planning to make the best use of the resources. It provides information to identify areas where managerial action is required to make improvements. The job ticket is the basis of most systems."

Jan 1, 1970

By K. Kawagishi, K. Matsumoto, Y Koizumi, H. Harada

A new burner rig for cyclic and hot corrosion testing of Ni-base superalloys and high-temperature coatings has been developed at the National Institute for Materials Science (NIMS) in Japan. The concepts of the rig design include: use of kerosene as fuel, easy operation for materials research and multi-specimen testing capability per test run. The burner rig consists of six blocks including combustion block, corrosion-solution injection block, furnace block, specimen block, controller block and outdoor facility block. During verification testing, it was confirmed that the rig had accurate specimen temperature control within ±1? from 600 to 1100? and automated easy operation. Cyclic testing of several Ni-base superalloys was conducted. The results from 50 cycle testing indicated that a new NIMS alloy developed for 1700? class gas turbine had higher oxidation resistance than CMSX-4. This new burner rig testing capability at NIMS can be very useful for future oxidation, hot corrosion and coating durability studies.

Jan 1, 2010

By O. A. Ojo, E. Anisimov, A. K. Khan

Electro-spark deposition (ESD) has recently generated a great deal of interest in processing aerospace materials. This is due to its potential for joining and repairing difficult-to-weld precipitation strengthened nickel-based superalloys without having problems of welding cracking that often plaque these materials. The short duration of current pulses involved in the process combined with the intermittent contact results in extremely rapid thermal cycle that produces nearly no heat affected zone in the substrate material. The microstructure of electro-spark deposited superalloy was meticulously studied in this work by scanning electron microscopy (SEM) and analytical transmission electron microscopy (TEM). The results show that in contrast to general assumption, the extreme rapid cooling rates involved in the ESD process did not produce partition-less solidification that is devoid of second phase microconstituents in the material. The secondary microconstituents were found formed along the intercellular regions of the solidification microstructure. The nature of these particles and the possible implication of their formation on mechanical properties of ESD processed material are reported and discussed.

Jan 1, 2015