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By B. Dyck, C. Rodgers

ABSTRACT Cameco Corporation is revitalizing its Key Lake Operation uranium mill in northern Saskatchewan. The mill currently uses ammonia stripping in solvent extraction (SX) and ammonia yellowcake precipitation. As part of the revitalization, the company considered installing strong acid stripping in solvent extraction (used at its Rabbit Lake Operation), which would lead to using hydrogen peroxide for uranium precipitation. As part of the process evaluation, tests were carried out to study how the drying temperature in indirect fired dryers would affect the uranium peroxide yellowcake precipitate properties. This paper discusses the test work results, including the relationships between drying temperature and product reactivity with water, product colour, product grade, and energy input requirements.

Jan 1, 2012

By A. R. Naji Meidani, A. Cameron, A. Richardson, M. Isac, R. I. L. Guthrie

The supersonic core of shrouded jets remain coherent over longer distances vs conventional supersonic jets. This phenomenon should allow for greater penetration of oxygen into slag/steel reactor systems. As such, they hold the promise for faster slag/metal mixing in BOF type metallurgical reactor systems, possibly creating greater surface area/volume ratios of reacting phases, and thereby faster kinetics, as compared to conventional supersonic jet systems. In order to assess the potential of shrouded supersonic jets versus their conventional counterparts, an experimental investigation of impinging shrouded supersonic jets into a water model of a simplified BOF system was carried out in the MMPC's water modelling laboratory. The experimental results for three different designs of a shrouded supersonic jet nozzle have been compared in terms of greater penetration depths and reduced mixing times. Based on a novel dimensional analysis, the depth of penetration of a gas jet into a liquid bath is shown to depend on the nozzle-bath distance, the liquid's Froude, Reynolds and Weber numbers, reflecting the ratios of gravity, viscous and surface tension forces to the jet's inertial, or momentum, forces. Good agreement between the mathematical model and experiment was obtained in terms of predicted and observed depths of penetration. Further efforts have been made to study jet penetration into liquid metals. The effects of mean liquid density of slag/metal mixtures and a wide range of gas flow rates on the penetration depth were investigated theoretically. The results show that the penetration depth can be increased with increasing gas flow rate and decreased bath density.

Jan 1, 2004

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By F. J. Guevara

A two-dimensional mathematical model for fluid flow and heat transfer in a sixin- line electric smelting furnace was developed to study the effects of temperature on slag viscosity in both the liquid and mushy zones. The model focused on the fluid dynamics of the molten slag and the effects on the formation of a slag freeze layer on the hot face of the furnace wall. Previous experimental and mathematical work, carried out under Ra number of 109 and using a fluid with Pr number of 65, showed that it is possible to mathematically describe the freeze layer formation over a vertical wall using a fixed-grid model. The chemical composition of the slag was taken into account through its effect on the viscous activation energy as well the solidus and liquidus temperatures. The results show that the flow pattern is strongly modified in areas of high viscosity, in front of the cooling system and at the slag-matte and slag-calcine interfaces. The results are discussed in terms of heat flux over the refractories and their effects on cooling system design.

Jan 1, 2007

By A. Ghirian

Once cemented paste backfill (CPB) is transferred and placed into a mine stope, various coupled mechanisms will take place in the CPB material or structure. It will be subjected to strong coupled thermal (T), hydraulic (H), mechanical (M), and chemical (C) processes. Field studies have shown that the in-situ properties and performance of CPB differ from those obtained in the laboratory. This is mainly due to effects of the aforementioned coupled THMC mechanisms or processes. For a reliable and cost-effective design of a CPB structure and barricade, it is crucial to have a proper understanding of the THMC behaviour and evolution of CPB. Also, it is important to consider the effect of coupled THMC factors (e.g., self-weight pressure, drained/undrained and thermal conditions, pore pressure) while curing the CPB specimens. For this purpose, a laboratory setup is developed to investigate the properties of CPB materials. The setup is capable of curing CPB specimens (10 cm in diameter and 20 cm in height) under controlled vertical pressure (curing under stress) and various coupled THMC conditions, while continuously monitoring the evolution of total stress, pore pressure, suction, temperature, water drainage, chemical composition of the pore water and vertical deformation. Once the required curing time is achieved, the specimen can be extracted and then subjected to experimental tests of interest, such as those that determine the Unconfined Compressive Strength (UCS), shear strength parameters, saturated hydraulic conductivity and thermal properties. In this paper, we describe the developed experimental setup and present some results of the THMC behaviour of CPB under various curing stresses and rates of backfilling. The obtained results show that the THMC properties of CPB are strongly coupled due to several mechanisms, such as self-weight pressure, heat of hydration and suction development as a result of self-desiccation. The findings can assist researchers and practitioners to better understand THMC behaviour and thus design more cost-effective CPB structures.

Aug 1, 2013

By C. H. Madsen

THE Hard Rock gold mine is in the Little Long Lac mining area, Thunder Bay district, northwestern Ontario. It is four miles by road from the town of Geraldton, which is on the Canadian National railway, 180 miles northeast of Port Arthur. The original discovery of gold-bearing quartz veins on the property was made in 1931. Shaft sinking began in the fall of 1934 and approximately 7,400 feet of lateral development on four levels was completed. In 1935, further discoveries were made half a mile west of the early workings, and the No. 2 shaft was sunk in this area in a porphyry zone. In January, 1938, a 20C-ton cyanide plant was completed and began drilling ore from the gold-bearing porphyry orebody. The daily feed was increased gradually to 300 tons in the next six months and a recovery of 97.5 per cent was effected. During the summer of the same year, a new and larger orebody was discovered to the north of the porphyry zone. It occurs in a band of iron formation and contains a high percentage of pyrite and arsenopyrite. Extensive tests were rr.ace on this sulphide ore in the Mines Branch ore dressing laboratory at Ottawa, in the laboratory of Canadian Industries, limited, at Toronto, and later at the mine, to find a suitable method of treatrr.ent. As a result of this research, a Potation plant was added to the original cyanide mill and on November 7th, 1938, differential flotation was used to separate the pyrite from the arsenopyrite fraction of the ore. The pyrite concentrate was re-ground and cyanide:l, and the arsenopyrire concentrate was stored for subsequent treatment. Differential flotation was discontinued in April, 1939, in favour of bulk formation of all the sulphides, and the whole cyanide residue was stored. On March 15th, 1939, a 10-ton pilot roaster was completed and rests were conducted on the arsenopyrite concentrate and the bulk concentrate. The results obtained led to the building of two roasters of the same type, large enough to roast all the concentrates. These roasters were put in operation on September 24th, 1939, and the calcines were cyanided in the original circuit.

Jan 1, 1941

By Gregory C. More O'Ferrall

Generally pillars in the Southern African hard rock tabular underground mining environment are designed using either empirical pillar design formulae or numerical modelling (analytical) methods utilizing the Hoek-Brown failure criterion. However, none of the pillar design methodologies employed takes cognizance of weak layers either within the pillar material or in the immediate foundation of the pillar. Over the past few years, the presence of a weak layer either within the pillar material or within the immediate foundation of the pillar has resulted in the closure of one platinum mine (Everest Mine), closure of one chrome mine (Wonderkop Chrome) and large-scale instability in a couple of chrome and platinum mines in South Africa and Zimbabwe. A study has been initiated to better understand the failure mode and strengths of the pillars where pillar failure associated with weak layers occurred. Owing to the infancy of the study into the failed pillar strength and failure mechanism, the purpose of this paper is to highlight the circumstances that led to the collapse of mining sections and a shaft, and the difficulty associated with designing pillars in the Southern African chrome and platinum mining operations.

Jun 1, 2012

By John R. Hayes, Kebbi A. Hughes, John Rowson, Peter E. R. Blanchard, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm

Uranium ore bodies contain elements within mineral phases that need to be disposed of responsibly. Solid waste can be placed in a tailings management facility (TMF) to contain the waste elements and limit interactions with the environment. It is important to understand how the chemistry of the tailings evolves throughout the lifetime of the operations that feed the TMF and after the site has been decommissioned. The objective of our collaboration with Orano Canada was to study how the tailings from the TMF located at McClean Lake, Saskatchewan change over time. This manuscript discusses our use of X-ray absorption spectroscopy (XAS) and X-ray microprobe to study the fate of Mo and Ca in the tailings. Mo is considered an element of concern (EOC) and it is necessary to determine if a stable solid Mo-bearing species forms. Thermodynamic modeling suggested that aqueous Mo would precipitate over time as powellite (CaMoO4). Comparing Mo K-edge XAS spectra from the solid tailings to the aqueous Mo concentration in the pore water showed that powellite did form and that this did result in a decrease in the aqueous Mo concentration over time. Further, it has been proposed that Ca2+(aq) can react with bicarbonate ions in the pore water and precipitate as calcium carbonate (e.g., CaCO3). This reaction would limit the aqueous bicarbonate present in the tailings that could react with uranyl ions to form soluble uranyl-carbonate complexes. We have identified several trace Ca-bearing species, including carbonates, in the tailings using XAS and X-ray microprobe.

Jan 1, 2020

By Z. Y. Ma, H. Y. Yang

The process of microwave-ultrasound assisted leaching of valuable metals from copper anode slime was proposed in this paper. Design of experiments has been used to study the effect of the main leaching parameters, such as microwave power, ultrasound power and reaction time. The central composite design (CCD) was used to predict the maximum leaching efficiency of copper, tellurium and selenium. The experimental data obtained were fitted to a second-order polynomial equation, and they also were analyzed by analysis of variance (ANOVA). The 3-D response surface plots and the contour plots were applied to determine the optimal conditions. The optimum conditions of microwave-ultrasound assisted leaching process were: microwave power 834W, ultrasonic power 638W and reaction time 403s. Under these conditions, the experimental leaching efficiency of copper, tellurium and selenium were 98.88±0.56% 98.96±0.78% and 98.57±0.67%, respectively, which agreed well with the predicted values.

Jan 1, 2014

By S. Amira

The corrosion behavior of high pressure die-cast and thixocast AXJ530 magnesium alloys has been investigated in 0.05M NaC1 solution at pH 6.0 using potentiodynamic polarization tests, electrochemical noise (EN) technique, electro-chemical impedance spectroscopy (EIS) and scanning reference electrode technique (SRET). The behavior of die-cast and thixocast specimens were compared using each of these techniques and the results discussed. Further tests have been carried out with die-cast AZ91D alloy to better compare and interpret the results. Experiments indicate that the thixocast specimens of AXJ530 alloy have a better corrosion resistance than those of die cast alloy in neutral solution.

Jan 1, 2006

By T. C. Murphy, W. Taciuk

In 1966, the Iron Ore Company of Canada commissioned a wet magnetic scavanging plant for the recovery of fine magnetite values p.resent in spiral tailings discharged from a spiral gravity separation process. The plant includes dewatering, grinding, classification, thickening, mini-wedge screening, and primary, secondary and tertiary wet magnetic separation stages. The source of feed varies in quantity and quality, so the original design included variable operational procedures to deal with these conditions.

Jan 1, 1972

By A. H. Duffield

"Forming part of the Prairie Evaporites, the sylvinite layer mined at Alwinsal underlies the Blairmore quicksands and the water-bearing Devonian formations. Production is achieved by a method of trackless, continuous mining of rooms, leaving pillars for natural support. The paper describes the development of the mine, and the equipment and organization employed in the operation and maintenance of the underground facilities."

Jan 1, 1972

By M. Mbonimpa

Field experimental cells were constructed in 2007 to assess the performance of different cover scenarios for the reclamation of the Parc 1 tailings disposal facility at the Westwood-Doyon Mine site (Abitibi, Quebec). Three configurations of cover with capillary barrier effects (CCBEs) with different thicknesses and material types for the moisture retention layer (MRL) were studied. MRL with 80 cm till, 40 cm till, and 40 cm clayey silt were used for cell nos. 2, 3, and 5, respectively. The capillary barrier layer (CBL) and drainage and protection layer (DPL) of the CCBE consisted of 30 cm gravel. A reference cell without cover was also constructed to compare the geochemical performance of the CCBEs. Due to an unexpected flooding in the leachate exit area of the cells in spring 2008, the cell instrumentation for hydrogeotechnical monitoring was postponed to spring 2009. Changes with time in volumetric water content, suction, soil oxygen concentration, and temperature were measured at different depths. This paper presents and discusses preliminary results obtained from spring 2009 to autumn 2010. In all cases, the degree of saturation Sr is lower in the CBL than in the MRL, indicating the presence of capillary barrier effects at the interface of these layers. Cell nos. 2 and 5 showed hydrogeotechnical behavior typical of an effective CCBE, with Sr maintained above 85% in the MRL and lower than 30?50% in the DPL and CBL. Based on the obtained results, and as expected, MRL thickness and the type of construction material used appear to affect the hydrogeotechnical behavior of the CCBE. Oxygen concentration profiles through the CCBEs were used to estimate the oxygen flux, and results indicate that cell nos. 2 and 3 performed better than cell no. 3. CCBE performance is currently being investigated using the geochemical monitoring data.

Aug 1, 2013

By P. Su

Friction stir spot welding of a range of Mg-alloys is investigated (AZ91, AZ31, AM50 and AM60). The peak temperatures during friction stir spot welding of all Mg-alloys are close to their solidus temperatures. Also, the apparent material viscosity of Mg-alloy sheet is lower than that when Al-alloy sheet material is spot welded. This is important since it means that the widths of the stir zones forming during spot welding of Mg-alloy sheet are smaller than those when Al-alloy sheet is welded (when identical welding parameter settings are applied). These lower apparent viscosity values must be taken into account during numerical modeling of the Mg-alloy spot welding process. The efficiency of energy utilization is very low when Mg-alloy sheet is spot welded and is of the same order as that when fabricating Al-alloy sheet. The energy generation contributions of the rotating pin and the tool shoulder are investigated. When the spot welding operation is carried out without the application of a dwell period, the contribution made by the rotating pin vis-à-vis energy generation is around 66%. The contribution made by the tool shoulder increases to about 65% when a dwell period of four seconds is incorporated during the spot welding operation. This increase results from a longer contact time between the tool shoulder and material within the stir zone, The failure load during overlap shear testing increases when the bonded area and the energy input increase during spot welding. Sample failure initiates from unbonded regions and from discontinuities at the edge of the stir zone. The formation tendency of discontinuities is increased when Mg-Alloy sheet is spot welded because of the limited deformation characteristics of the base material at lower temperatures.

Jan 1, 2006

By M. E. Holter

"Limestone-bearing strata are exposed in seven areas of Alberta, each situated adjacent to rail and road facilities. Six of these centers are located along the eastern edge of the Foothills and Front Ranges of the Rocky Mountains in western Alberta. The other is in northeastern Alberta, along the eastern margin of the Alberta Basin. High-grade limestones are present in Middle Cambrian, Upper Devonian and Mississippian strata. Middle Cambrian (Eldon Formation) limestones have been exploited only in the Exshaw area west of Calgary, where they formerly were used for lime production. Limestone beds of the Upper Devonian Palliser Formation are exploited at Exshaw and at Cadomin in west-central Alberta for the manufacture of cement. Reserves of high-grade limestone also are available in the Palliser Formation near Crowsnest Lake in southwestern Alberta and near BrUle, west of Edmonton. Upper Devonian limestones of the Waterways Formation are widespread in the Fort McMurray area of northeastern Alberta, but available data indicate they are of inferior quality to the limestone deposits of the Rocky Mountains regions. The Mississippian Livingstone Formation contains large reserves of high-grade limestone at several localities in the Rocky Mountains and Foothills. Commercial development of the unit is now underway at Crowsnest Lake and at Exshaw for lime production, and future exploitation of these beds is feasible at Blairmore and Nordegg."

Jan 1, 1973

By S. Fahland, P. Vogel

"The Gorleben salt dome has been investigated since 1979 for its suitability as a repository for the disposal of high-level radioactive wastes. The geoscientific surface exploration was followed by underground exploration of the site beginning in 1983: underground excavation work included the sinking of two shafts from 1986 to 1994, the excavation of the infrastructure area and of drifts located in the first exploration area EB1 within the following years. The exploration was interrupted for ten years from 2000 to 2010 as part of a moratorium. After the expiry of the moratorium in March 2010, the geoscientific underground exploration at the Gorleben site was resumed. The investigations were interrupted again in autumn 2012 due to a political decision. The exploration programme included extensive geoscientific investigations: geological exploration, geophysical investigations, mining exploration and mining observation, laboratory tests, in-situ geotechnical measurements, geological modelling and numerical model calculations. To analyse and interpret the results of the in-situ measurements and mining observation geomechanical, thermal and thermo-mechanical model calculations were carried out. One of the main elements of the in-situ geotechnical investigations were high-resolution geothermal measurements performed in boreholes used for geological exploration and geotechnical tests.The geothermal measurements are used to evaluate several geotechnical findings, e. g. drift closure, rock deformation, stress change, and are completed by thermal model calculations to analyse and interpret the results of in-situ measurements and mining observation. The model calculations have been carried out using the special purpose JIFE code. To consider the whole exploration mine with the adjoining host rock as well as the successive excavation of drifts and boreholes in detail a three-dimensional finite-element model was developed. The model calculations are used to analyse the cooling-off of the surrounding rock of the drifts caused by ventilation. The cooling-off of the surrounding rock is an ongoing process affecting the results of further geotechnical measurements in the near field of the drifts. To predict a realistic time and space dependent distribution of the temperature field of the host rock within the exploration area which is influenced by ventilation thermal model calculations are necessary. Comparing the calculated temperature field with the in-situ determined rock mass temperature field within the exploration area EB 1 the results show a sufficient agreement. Furthermore there is very good correspondence, both qualitatively and quantitatively, between the experimental and the calculated findings regarding the temperature profiles including the effects of excavation and ventilation of the drifts."

Jan 1, 2015

By Michel Épiney, COREM, Mario Drapeau, Caroline Olsen, Claude Bolduc, Benoit Levasseur

"Several metal sulfide minerals (such as copper, zinc and iron), generally abundant in precious metal-containing ores, are known to dissolve during the cyanidation process. These unwanted reactions consume a significant amount of cyanide and oxygen, which is required for the extraction of gold and silver. Leaching kinetics of sulfide minerals are very fast in contact with oxygenated cyanide solutions. Therefore, the solution quickly becomes charged with oxidation products that are mostly metal ions, metallo-cyanide complexes, metal oxides and other sulfur species including thiocyanate, sulfides, polysulfides, thiosulfate, sulfites, sulfates, etc. COREM’s Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during pre-oxidation and cyanidation. The effect of pre-treatment under ozone was investigated using an industrial pulp recreated from process water (charged with thiocyanates) and homogenized flotation tailings material from Agnico Eagle's LaRonde mine. In terms of mechanisms, the ozone treatment provides a complete deactivation of the material surface (characterized by EDTA extraction) and the solution (characterized by Ionic chromatography). This resulted in a lower reactivity of sulfide minerals that led to substantial gains in terms of consumption of cyanide and thiocyanate formation during the cyanidation process. The ozone-pre-treatment edges the classical pre-oxidation treatment (such as oxygen, hydrogen peroxides, etc) providing a quicker deactivation of the sulfide matrix and higher reagent savings in subsequent cyanidation process.INTRODUCTIONThe presence of sulfur in the process of gold leaching by cyanidation is a major drawback to optimizing the reagents consumption with suitable operating conditions. The coexistence of sulfide mineral species, such as pyrite, chalcopyrite, pyrrhotite or sphalerite along with the gold-bearing ore have, indeed, a negative impact on the extraction of precious metals by cyanidation (Bayat et al., 2003), (Azizi et al., 2010). These minerals are known to dissolve with cyanide under alkaline conditions and release in the slurry different kinds of sulfide by-products like polysulfides, thiosel, sulfite and sulfate (Seal II & Hammarstrom, 2003) (Breuer et al., 2008a), (Marsden & House, 2006) (Ghasemian Langeroudi et al., 2013). Once these sulfide by-products are released in solution they react with cyanide to form thiocyanate (Marsden & House, 2006) (Breuer et al., 2008b). The consequence of the dissolution of these cyanicides, is a significant increase in cyanide consumtpion as well as a slow-down of gold extraction."

Jan 1, 2016

By M. Rudolph, T. Leißner, TU Bergakademie Freiberg, C. Mämpel, R. Möckel, M. Embrechts, T. Leistner

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until 1991. For long times, gravity separation processes used to be the dominating beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. For fine (< 100 µm) and very fine (< 20 µm) particles these approaches might not represent effective techniques, significant valuable materials could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these tailings disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these tailings disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles. In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods (including conventional froth flotation and oil-assisted flotation). Different size ranges of the material were previously prepared in order to investigate their response to the different techniques. For the study, special emphasis is put on agglomeration flotation, an oil-assisted flotation method. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (including sulphosuccinamates and phosphonic acids) and depressants (including sodium fluorosilicate and oxalic acid) regime, oil dosage, agitation time and pulp density during oil/pulp agitation. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements and zeta potential analysis. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Jan 1, 2016

By E. Brzychczy

Artificial intelligence techniques are ever more frequently implemented in the modern world. One of their numerous uses is supporting enterprise management. Intelligent techniques and intelligent information technology (IT) systems can be implemented in mining-related issues as well. The author of this article concentrates on supporting the process of planning mining operations by intelligent systems and techniques. The author also underlines the importance of knowledge accumulation in a mining enterprise (especially tacit knowledge) as well as its efficient storing and using. Additionally, the author provides a short description of characteristics of intelligent IT systems and indicates their capabilities in planning mining operations. She presents two solutions, namely: an advisory system which supports the process of planning preliminary works and exploitation works in hard coal mines, and a method of modeling and optimizing mining operations. Finally, the author indicates a few possible future development trends of intelligent systems - the intelligent systems of decision support.

Aug 1, 2013

By Du Xinfeng

The resource quantity of the low rank coalbed methane (CBM) accounts for 47% of the total resource quantity of CBM in China. Compared with the exploration and development of the high rank CBM in Qinshui Basin, China and the low rank CBM in Powder River Basin, USA and Albert Basin, Canada, the exploration and development of the low rank CBM are still in the initial test stage. In this paper, on the basis of analyzing the mining geological conditions such as that the Huanglong Jurassic Coalfield is largely situated in the hills and gullies zones, and the coal reservoir has the features such as the low metamorphic degree, large coal seam thickness, simple coal matrix texture, high permeability and small CBM content and so on, it discusses the key technologies such as the development pattern of CBM, well location arrangement, drilling and well completion technology and fracturing technology and so on. It indicates that the underbalanced drilling and the cavity well completion based on the reservoir protection will be the development directions of the CBM development technology in this area.

Aug 1, 2013