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Roasting of molybdenite concentrate is an important stage in the production of commercial molybdenum trioxide. The oxidation kinetic and mechanism of molybdenum sulfide concentrates from two plants were investigated at temperatures from 444 °C to 640°C. The rate of reaction was determined for thin layer samples in a muffle furnace at controlled temperatures, oxygen excess and removal of sulfur dioxide. For both concentrates the rate of reaction is fairly slow at temperatures below 500°C and remains fairly constant from 540 to 600 °C. It was observed that the concentrate from the first plant presents a tendency for sintering or glazing at temperatures above 620°C, whereas the same phenomena was observed at 20 or 30 °C higher temperature for the second concentrate. A kinetic model of two reactions, involving the formation of Mo02 as intermediate oxide for the production of Mo03 is proposed and activation energies of 23.0 and 20.8 kJ/mol for the first and second reaction were calculated for temperatures between 520 °C to 600 °C. These low values of activation energies indicate that the overall rate of oxidation is controlled by mass transfer, particularly in a porous layer of oxides. Therefore, the renewal of the surface by mixing and motion of the concentrate layer is of great importance. Sublimation of Mo03 becomes significant for temperatures above 650 °C.

Jan 1, 2007

By M. H. Rana

"A survey of our knowledge in the field of rock mechanics is presented from the viewpoint of applications in the mining industry. Aspects of rock mechanics of special interest to the industry are enlarged upon, with emphasis on the avoidance of over-generalization. The relationship between fundamental and practical rock mechanics is discussed, and the need for cooperation between the university and industry to further our knowledge of -useful rock mechanics is emphasized. An attempt has been made to establish the scope of rock mechanics, as applied to problems in the mining industry. This is brought about by projecting rock mechanics as a tool to be intelligently used rather than magic, capable of producing ""miracles."" Continued education is important for individuals engaged in the application 0f rock mechanics in the mining industry. The scope of this education is discussed from a viewpoint of better communication between industry and the education and/or re-search establishments engaged in this work.Finally, the dangers of over-emphasis on rock mechanics are mentioned, but a justification of the in-vestment in rock mechanics programs in mines is also presented."

Jan 1, 1966

By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016

By Fr. -W. Bach

In the past years the enormous weight saving potential of magnesium sheet has been demonstrated by various research projects all over the world. It has been shown magnesium flat products can benefit automotive, aviation, machine tool and consumer electronics industries. Major material problems such as poor formability, corrosion resistance and high production cost still inhibit the application of magnesium sheets in large scale production. The present contribution outlines achievements in casting and rolling technology. The authors developed an adapted strip casting process in which near-net-shape rolling feedstock of several wrought alloys has been produced. During the rolling process, various parameters were varied in order to modify the microstructure and surface quality of sheet. Several temperature cycles, strains, lubricants, roll surface structures and roll coatings have been analyzed. The sheets were examined and tested in deep-drawing experiments. Suitable rolling schedules have been developed for standard and modified wrought alloys. The study concludes with an overview of current industrial solutions and an estimation of the potential cost savings that might result from the adaptation of the process that has been developed.

Jan 1, 2006

By C. R. Whittemore

PROGRESSIVE industrial organizations have recognized the importance of maintaining an adequate reference library of volumes covering all phases of their particular branch of industry, but it has been the experience of the writer that few engineers know how to use to the best advantage this store of extremely -valuable information which has been accumulated for their service. Nor does the average engineer appreciate the fact that it is only through the current technical literature that he can keep abreast of the rapidly developing fields of engineering. The present-day ramifications of the engineering field are of such wide scope that the human mind is not capable of storing away more than a small fraction of the information available on any particular topie; yet, from time ? to time, such information would prove invaluable. An engineer can know intimately only a small part of his own branch of engineering; but he cannot afford to neglect to take the fullest possible advantage of all that is already known in his own particular field. Technical information may be obtained by one or more of the following methods: (1) by enquiring of the individual who knows; (2) by performing the experimental investigations necessary to ascertain the facts; (3) by consulting the technical literature, where a record may be found of the work of others. This last method is the one we wish to examine. Our main consideration is the question of how to use the library, but first it is necessary to give some attention to the kind of enquiries one takes to the library, and to the nature of the sources of information available.

Jan 1, 1938

By Dong-kil Lee

A ventilation improvement index (VII) was developed in an effort to propose an optimal ventilation improvement measure for a designated mine. The index was designed to incorporate both ventilation effectiveness and cost efficiency. To verify the effect of the index, a mine experiencing a ventilation problem was selected, the ventilation assessed and ventilation network analyses were conducted. In the selected mine, four areas with ventilation difficulties were detected and an improvement schemes for each area were proposed. These were simulated through network simulation and evaluated using the ventilation improvement index. As a result, an optimum ventilation improvement scheme was proposed. The improvement scheme with the highest VII value was incorporated in the design.

Aug 1, 2013

By Peter Moon

THE mineral industry of Canada relies heavily upon the talent of its technical men. It is vital to the well-being of the industry that its supply of young, trained men be adequate. At the present time, the industry is acquiring only 200 new graduates a year. The shrinking supply is far below present and future requirements. Other industries and research organizations are competing for engineers and scientists. Dr. J. B. Mawdsley (1), Past-President of the Canadian Institute of Mining and Metallurgy, has recently outlined a program designed to attack the problem. Dr. J'. C. Sproule (2), another former President of the Institute, has stated that: "The need for selection of trainee material is commonly recognized, but little is done about it." The following paper contains a short discussion of occupational interests, and outlines research, using psychological knowledge and measuring techniques, aimed at the identification of desirable recruits for the mineral industry.

Jan 1, 1963

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By Richard S. Allen

"The casual visitor is not apt to think of the Adirondacks as a one-time hive of mining and manufacturing activity. However, where there are mountains there are usually minerals and northern New York State is no exception.The Adirondacks are a rocky shield, a great stone cap pulled down over what is now northern New York. The bedrock consists of layered metamorphic rocks which were once sandstones or limestones on the bottom of a shallow sea that covered the region 1000 million years ago. The highlands are composed for the most part of the igneous rock anorthosite. Ancient earth upheavals at temperatures of at least 750°C mixed molten masses of anorthosite and the minerals it contained with the older metamorphic rock, resulting in deposits of iron-titanium oxide s, red garnet and other valuable minerals. Of these, the most readily recognizable was iron.The first hint of the existence of iron ore in the Adirondack Lake Champlain region of upper New York State seems to have come from a Swedish naturalist, Peter Kalm (1716-1769), who travelled through French Canada and visited the military outpost of Fort St. Frederic in 1749. In July of that year, Kalm wrote:""Among the kinds of sand which are found on the shores of Lake Champlain; one is black and the other garnet-colored... and they sparkle when the sun shines. All the grains of this sand without exception are attracted to the magnet, the uppermost or black sand being about a quarter inch deep...""Concerned primarily with the fur trade, the officers and men who occupied this remote bastion of La Belle France were apparently unaware of the industrial and commercial possibilities beneath their feet. No deposit of iron was then known to exist any closer than the Three River s area in Lower Canada."

Jan 1, 1983

By Helmut Ehnes

Over 330 million accidents at work happen world wide every year, only counting those leading to more than four days absence. More than 350,000 end fatal. Two million people more die every year due to work-related diseases. To sum this up: around 2.4 million people die every year because of work conditions. Among many risky industries, mining stands out. While mining represents just 1% of employees globally, it unfortunately represents 8% of all occupational fatalities. Mining operations go along with a variety of hazards. Not only in large operations, as they first come to mind, but also in the manifold small scale mines, with an estimated 13 million labourers worldwide exposed to substances such as dust, mercury and other chemicals, while also dealing with poor ventilation, inadequate space and overexertion. But is the number of severe accidents and diseases inevitable or can we change this situation? We can make mining sustainably safer, but we need a successful strategy to do so. A high potential lies in Vision Zero. Vision Zero is a prevention strategy for a safe future without fatal or serious occupational diseases, work accidents and traffic accidents. First defined as early as in the 19th century by Eleuthère Irénée du Pont, its very successful elements were adopted by many European countries first aiming at road safety, then extended to safety and health at work. Vision Zero?s holistic elements cover technology, workplaces, rules, and people as fields of action. By focussing on severe and fatal accidents, its application increases the level of safety and health overall.

Aug 1, 2013

By F. Parada, R. Parra

"The neutralization process of SO2 from coal burning plants is a well-defined technology using limestone to form CaSO4 according to the following reaction: CaCO3 + SO2(g) + 1/2O2(g) = CaSO4 This paper presents the results of a study carried out to validate the option of capturing SO2 using gases from a non-ferrous smelter; SO2 content was up to 12% using a three-stage fluidized bed reactor. The difference in SO2 content affects equilibrium conditions and kinetics, rendering a direct extrapolation of the high efficiency achieved for low SO2 content impossible. The R&D program consisted of a laboratory study using a semi-pilot operation of a one-stage fluidized bed reactor and the construction and operation of a three-step reactor prototype. Results show that the reaction proceeds according to the unreacted core model that imposes a compromise between CaCO3 conversion and SO2 capture. For high SO2 capture, the calcine from the reactor contained CaSO4 and CaO. A complete capture of SO2 from gases with 8 vol.% can be achieved with a mean reaction time of two hours at 800°C."

Jan 1, 2007

By A. Koning, P. Lauzon

Pressure hydrometallurgy operations require vessels to be lined with an impermeable membrane for corrosion protection and one or more courses of refractory or ceramic brick. Examples of unit operations that utilize composite lining systems include pressure oxidation autoclaves, sulphide precipitation autoclaves, chloride leach reactors, flash vessels, cyclone separators, and direct contact condensers (heater vessels and quench vessels). The refractory lining must satisfy multiple requirements: it must thermally insulate the membrane from process fluid, be structurally stable, provide erosion resistance, be chemically compatible with process fluid, and provide an economic service life. New hydrometallurgical processes are pushing the pressure, and temperature, with each new generation of plants. A fundamental understanding of all factors affecting the mechanical stability of the lining system is essential as lining designs move further away from the industry's experience base. The impact of irreversible chemical swell, operating factors, design factors, and installation factors are presented based on modifications to the traditional one-dimensional mechanical stress model. A new stability criterion - that the brick lining remain in contact with the steel shell membrane - is presented. This new stability criterion imposes new restrictions on the lining design.The effect of geometry and adding additional degrees of freedom to the analysis is explored using two-dimensional and three-dimensional Finite Element Analysis (FEA). The effect of these additional degrees of freedom on the results of the one-dimensional model are discussed.

Jan 1, 2004

By L. M. Wang, G. P. Jiang, Y. Jiang, Liao. W. S.

ABSTRACT The authors measured porosities and permeabilities for cores from a low-permeability sandstone uranium deposit in Inner Mongolia. Features studied included fine pore structure, mineral composition, cation exchange capacity, granule appearance, and cementing features. In general, grading of the grains was relatively poor, which decreased the radii of the pore channels. The pore throat distribution was significantly heterogeneous. Pore channels ranged from small to large, but the lack of large pore channels led to low permeability. Cementation by calcite and clays, including montmorillonite, chlorite, and kaolinite, resulted in pore channel narrowing, further decreasing the permeability of the formation.

Jan 1, 2014

By William G. Pariseau

"This contribution describes linkage of stress concentration at the face of tabular excavations, for example, longwall coal mine panels, at a meter scale to surface subsidence at a kilometer scale. Joints are considered according to orientation and spacing at an intermediate scale. A new dual-node, dual-mesh technique based on first principles uses a multi-scale technique that allows for computing whole mine surface subsidence while also allowing for computational details of stress, strain and displacement about main entries and pillars, panel entries, and bleeder entries. The technique is implemented in a conventional continuous Galerkin finite element program that has been in use for many years.The advantage of the dual-node, dual-mesh technique is the capability to do a whole mine analysis that takes into account interaction between all sections of a mine where stress transfer over long distances is often the rule rather than the exception while at the same time allowing for details of stress concentration at working faces where caving is initiated and subsidence begins. The technique, outlined recently during ARMA 2014 (Pariseau, 2014), is applied to an underground coal mine in central Utah where mines are developed from outcrops in steep canyon walls. Meshes contain over 10 million, three-dimensional nodes; runtimes are typically overnight, as a practical matter. Results compare favorably with mine subsidence measurements made over a period of several years and show the capability of this new technique to provide useful design guidance for tabular deposits such as underground coal mines. The role of variability or uncertainty in strata properties is illustrated in element safety factor distributions about development, bleeder and main entries and pillars. Such details are new in this contribution. Energy tracking for mine-induced seismicity is also new. Results show a high correlation between number of events and failed elements and suggest a simple index to mine induced seismicity."

Jan 1, 2015

By T. Grammatikopoulos, K. Gibbs, H. De Souza, C. Gunning

The mineralogy of any ore body is a key factor in defining ore zones and predicting minerals/metals behaviour during processing. The determination of forms of gold, defined as the different chemical states in which gold is encountered in ore deposits, is critical. The most commonly known form is that of gold minerals and alloys, while other forms of gold have been collectively described in the literature as submicroscopic gold (i.e., less than 1 µm in diameter). Gold mining operations generally deal with very low-grade ores, in the order of a few g/t, in which gold displays complex mineralogy. These difficulties complicate the mineralogical studies and pose challenges for processing and recovering the gold. A comprehensive understanding of the chemical forms of gold is necessary to define gold mineralization and optimize gold metallurgy. SGS Canada Inc. has been using QEMSCANTM and a Tescan automated SEM that are automated mineralogical techniques that provide vast amounts of data for microscopic Au. The data in conjunction with other physical and chemical methods provide a comprehensive delineation of the ore composition and behaviour.

Jan 1, 2011

By N. J. Contini, R. W. Knopp

"In March 1988, old Denver flotation cells were removed from Dickenson's Arthur w. White Mill, and a new flotation circuit, consisting of four Prochem rougher cells and a Hydrochem agitated cleaner column, was commissioned. The refractory portion of the gold in the ore is associated with arsenopyrite, therefore the flotation circuit is set up to produce a saleable sulphide concentrate. Tailings from the leach circuit are conditioned prior to being pumped as feed to the flotation circuit. The prototype Hydrochem agitated column has been in operation as a single cleaner stage for rougher concentrate. The effect of flotation circuit changes on gold recovery data, as well as cleaner concentrate production, and development work to achieve the target results, have been investigated. Flowsheet modifications and the resulting circuit performance data, along with test results to date, will be presented.INTRODUCTIONThe mill is capable of treating 1000 stpd of ore averaging approximately 0.30 oz/ton Au. The ore is crushed and ground to 75% - 200 mesh. Gravity concentration, cyanidation, and Merrill - Crowe precipitation yields 84% gold recovery. Detailed descriptions of the comminution, gravity separation, and leaching circuits, as well as background information have been presented elsewhere (Suttill, Van Weert et al). The target cleaner concentrate grade is 1.0 oz/ton Au for custom smelting and refining. Historical gold recovery values of the old circuit was approximately 20% of the gold present in the float feed at the target grade. The recovery value objective set for the new circuit during the planning stages was 50% of the gold present in the flotation feed at 1.0 oz/ton Au in cleaner concentrate."

Jan 1, 1989

By C. H. Lau, I. T. Ng

Uniaxial Compressive Strength (UCS) of rocks is an important mechanical parameter for many civil engineering and rock engineering applications such as tunnel excavation, slope stability and foundation design. Macau is one of the world's fastest growing and most densely populated cities, many large and important infrastructures have been being continuously built using pile foundations which are designed to be supported by granitic bedrock. In Macau, the UCS of the granitic bedrock is required almost for every project involving pile foundations and is always measured directly from UCS test in the laboratory. However, direct measurement of UCS requires high quality rock core sample which is not only time-consuming and expensive but also requires high level of operating skill. In view of this fact, estimation of UCS using some empirical correlations will be more practical and efficient because they are relatively fast and economical compared to the direct measurement from UCS test. In the past, some empirical correlations had been established and widely used for estimating UCS of rocks in common engineering practice. However, it has been well recognized that the rock properties are generally varied with sites or geological regions in other words an empirical correlation developed from one region or one country may not be applicable for other regions or countries. Due to the reason that the empirical correlations for predicting UCS for granite are scarce in practice, in this study an extensive experimental program has been performed and a large database containing data such as UCS, Point Load Index (Is50), Schmidt Rebound Hardness (RL), porosity (?), water absorption (S), specific gravity (Gs) and dry density (?d) has been developed. An attempt has been made for developing a new empirical correlation for estimating the UCS of Macau granite. Accordingly, a comprehensive statistical analysis for correlating UCS with Is50, RL, ?, S, Gs and ?d has been performed and a local empirical relationship based on the developed database is proposed for obtaining reliable estimation of UCS for the granite of Macau. Finally, the performance of the proposed correlation is accessed by using another independent testing database developed in this study. It indicates that Is50, RL, ? and S have strong correlation with UCS whereas Gs, ?d have poor correlation with UCS. This study not only proposed a proper predictive empirical correlation for UCS determination for Macau granite but also provides detailed statistical information which is beneficial to engineers for obtaining better characterization of Macau granite.

Jan 1, 2015

By A. Zarei-Hanzaki, S. M. Fatemi-Varzaneh, M. Haghshenas

The microstructure in modified semi-solid ALTHIX (A356) alloy consists of aAl phase with Al/Si eutectic structure. Silicon phase in eutectic structure is coral like with fine fibers. The lack of good ductility in this alloy is related to the presence of silicon fibers. Accordingly many investigations have been recently conducted to modify the Si morphology through Thermomechanical processing on this alloy. In the present work an ALTHIX (A356) alloy was deformed at 450°C, 500°C and 540°C through different strain rates. Consequently the silicon fibers were broken into small particles. The results indicated that the Si particles may coarsen according to Ostwald ripening mechanism at 540°C deformed by rate of0.0005 sec-1 & 0.0001 sec-1-

Jan 1, 2006

By Seher Ata

"Virtual reality, a three-dimensional computer generated environment, has become recognized delivery system for many forms of education. This article describes the application of virtual reality to mineral processing education. An interactive mineral processing visualisation module has been developed at University of New South Wales (UNSW), Australia. The module provides students with an overview of a base metal concentrator, details about each stage of the process, as well as revealing how the mined ore progresses from stage to stage. The module also involves developing a number of instructional based plant layouts and flowsheets in the virtual environment that are intended to assist the user in understanding the essential components of the base metal concentrator.INTRODUCTIONVirtual Reality (VR) is the creation of an artificial environment that is experienced through sights and sounds provided by a computer (Squelch, 2001). The simulated environment is achieved through a host of technologies such as three-dimensional graphics, audio feedback and special peripheral devices to produce interactive environments.VR has been used in diverse fields including medicine (Riener & Harders, 2012), entertainment (Hsu, 2011), military (Manojlovich, Prasithsangaree, Hughes, Chen, & Lewis, 2003), manufacturing (Zimmermann, 2008; Jiang, 2011), and chemical processing (Schofield, Lester, & Wilson 2005; Squires, Andersen, Reklaitis, Jayakumar, & Carmichael, 2014). VR is also becoming recognized delivery system for many forms of education, including engineering education (Bell & Fogler, 1996; Bell & Scott, 1998; Shin, 2002). For example, virtual laboratories have been designed and developed to teach students fundemental features of the heterogeneous catalytic mechanisms and absorption columns (Bell & Fogler, 1995), the multi-phase and multi-component blast furnace iron making process (Babich & Senk, 2009) and to guide students to identify various safety measures while working in real laboratory (Bell & Fogler, 1996)."

Jan 1, 2016

By S. Perez

Core drilling is a fundamental process in the mineral exploration industry. As deep exploration in hard rocks is accelerated due to the depletion of near ground mineral resources, deep-drilling operations need to reduce their reliance in operators experience and begin to implement new technologies in order to increase efficiency and cost-effectiveness of the overall process. Currently, lack of real-time information on the bit/rock interaction is a major problem. Therefore the mechanism behind the acoustic emission, which is a proven technique for remote monitoring, generation in mechanical rock cutting must be understood in order to provide real time information about the rock. This paper aims to identify the influence of mineral composition of granitic rocks on the acoustic emission (AE) during rock abrasivity test with a single contact tool and to evaluate the feasibility of AE as a means to infer Cerchar Abrasivity Index (CAI). Single contact tool will provide precise and accurate description of the source of AE. To provide constant grooving speed Cerchar apparatus was modified to monitor AE during rock/tool interaction. Tests on the modified Cerchar apparatus are carried out under the static load of 70N and cutting speed of 1 mm/s. A Scanning Electron Microscope (SEM) is utilized to visualize the groove in the rock and to identify the mineral composition through Back-Scattered Electrons (BSE) reflected from the rock sample. Based on the microscope images, it was found that biotite shows a larger groove area and plate-like fractures accompanied with burst-type AE signal, whereas plagioclase and quartz, which are characterized by similar hardness and BSE brightness, possess shattered-like fractures and more continuous-type AE signals. In addition, a-value of the Gutenberg-Richter scale has been found to well correlate with Cerchar Abrasivity Index (CAI).

Jan 1, 2015