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By C. Doyle, J. Brennan, C. Díaz, J. Hrepic, K. Cushnie

"In 1991/1992, INCO undertook a successful R&D program aimed at extending the lining lives of the top blown rotary converters (TBRCs)at its Copper Cliff Nickel Refinery (CCNR) and the electric furnace at INMETCO. At the laboratory scale, this effort was divided into three phases. In the first part, mineralogical work was performed on six refractories that were either currently being used to line these vessels or were considered suitable alternatives. In the second part, this mineralogical knowledge was used to help determine the compositions of slags that would not corrode the bricks at the operating temperature (1600°C) of the above furnaces. Finally, several important properties of the six refractories were measured to complete their evaluation as candidate linings. This paper reports the results of all three phases of the laboratory scale R&D work.The mineralogical work showed that rebonded fused grain magnesite-chrome (RFG-MC) bricks consist principally of periclase with minor amounts of free chromite and trace quantities of silicates monticellite and sometimes olivine. The bricks are principally held together by periclase-periclase direct bonding. Of note, the bulk of the chromite exists as exsolved precipitated blebs within the periclase grains. These likely redissolve at high temperature.Slags on the periclase liquidus coexist stably with these refractories. Examples are presented using CaO-MgO-Al2O3-SiO2 slags at~1600°C.Finally, the two refractories manufactured using close to 100% fused grain material generally outperformed the others in terms of physical properties and certainly were superior in their resistance to slag penetration damage."

Jan 1, 1997

By J. Armitage, J. Erskine

Feed level and thickness measurements are essential in the optimization of an electric arc furnace. A precise measurement of the feed thickness and level gives operators the ability to increase the smelter efficiency and reduce the maintenance cost. Hatch has developed a radar system which is an affordable, low maintenance, and accurate level measurement system. The radar units can be installed across the furnace to measure the feed level and the feed thickness can be calculated with one slag level sounding. The present paper describes the development of radar systems as a process optimizing tool by furnace controls. The authors will discuss the challenges involved in installing eight radar units on the roof of a six-in-line electric furnace.

Jan 1, 2015

"Energy efficiency in mining and minerals processing has attracted considerable public and industry attention because of the significant quantities of energy consumption involved. In this context the question of what are worthwhile targets for energy efficiency improvements ought to be of the highest priority. It is however worth taking a step back to avoid falling in the trap of taking preconceived ideas that have been reiterated repeatedly before as gospel. The aim of this paper is to highlight areas where new or alternative approaches could potentially be the better way forward. Some may come as a surprise to conventional industry thinking. Ultimately any such solutions are attractive to practitioners not just in an environmental but also in an economic sense, and hence should be targeted through applied research and development efforts. This paper highlights key aspects of each group of opportunities and some of the individual approaches to provide an overview of the current status quo.MINING INDUSTRY POWER UTILISATION – WHERE IS THE BIGGEST BANG FOR THE BUCK?The question of where is the biggest bang for the buck when trying to determine worthwhile targets for energy efficiency improvements has not always been reported on broadly enough, typically because industry practitioners operate in specific areas of expertise and comfort zone. Looking beyond the familiar doesn’t always come easy. Any technology or methodology consideration to address energy efficiency needs to take into account the context of alternative opportunities of superior value or risks not achieving desired uptake. The following sub-chapters have been ordered by magnitude of improvement potential as best as is possible, starting with the biggest first, and the smallest last. Some may be a surprise relative to conventional mining industry thinking."

Jan 1, 2016

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By A. H. C. A. Zimmerman

WE have just heard what must be regarded as a thoughtful, constructive and somewhat painful analysis of the financial function of our industry. While thinking about this, it is interesting to reflect on the conditions which have stunted the growth of the financial side of our affairs. Mining must be regarded as a wealthy business. •while immeasurable grub takes and development budgets have been lost, there can be little argument that a productive ore-body nearly always produces the type of wealth that breeds some extravagance. I recognize that this statement can be attacked from many sides, but an historical comparison with a commercial enterprise involving similar investment will demonstrate what I mean. However, these old times are be-ginning to disappear for a variety of reasons. High amongst these are: ( l) Increased costs of exploration. (2) Remoteness of many new finds. (3) Fixed or declining metal prices (particularly when expressed in constant dollars). ( 4) Constant demands for higher wages.

Jan 1, 1962

By DONALD E. BARNETT

Since the days of early settlement ew Brunswick has produced a variety of industrial minerals but it is perhaps only the recent discoveries of significant reserves of potash that have elevated the meaning of industrial minerals in their contribution to the provincial economy. With potash production commencing in July 1983, the role of industrial minerals will increase significantly to the value of mineral production in the province.

Jan 1, 1984

By A. S. Dawson

Introduction The purpose of this paper is to discuss, in a general way, the application of geological principles in the exploration for, and development of, deposits of industrial minerals. Mention of geological factors pertaining co specific minerals will be by way of illustration only. Since many prospectors are little acquainted with the geological setting and mode of occurrence of deposits of these minerals, some prospecting possibilities in the field will be pointed out. Geology is a tried and proven tool in the search for and exploitation of metalliferous deposits and of oil and gas fields, but, so far at least as Canada is concerned, only very rarely has a directed, intensive search been made for deposits of industrial minerals. Examples might be cited, however, where, in other countries, such investigations have yielded rich rewards. Thus, development of the vitally important potash deposits of New Mexico was the result of a deliberately planned programme of geological investigation, first by United States Government agencies, and later by private interests. War or the threat of war, or peace-time industrial expansion, can render concentrated exploration for specific minerals desirable or even essential. Such exploration is, primarily, a geological problem. Admittedly, there is in general less scope for the application of geology in the search for, and development of, deposits of industrial minerals than of metalliferous minerals, oil, etc. Where the latter are concerned; the objective of exploration is to find a material that is valuable, within broad limits, no matter where it is located or how it occurs. The unit value of the material is limited only by the amount of the valuable constituent in the formation- its possible upper limit is tremendously high. On the other hand, many industrial minerals constitute in themselves 90 per cent or more of the formation- their amount cannot increase and their unit value is commonly low. Moreover, for commercial exploitation, the deposit must, in general, be reasonably close to markets or to plant or other facilities for processing the raw material, since, owing to its low value, this cannot be transported any great distance. As a consequence, intensive geological search for and investigation of such deposits has been restricted to industrialized areas. Obviously, however, it is good insurance for any operator to understand the geological background of his deposit, particularly in the case of new developments.

Jan 1, 1949

By Alireza Golabchi

The AEC (Architecture, Engineering, Construction) industry is an information intensive industry and all related processes employed during different phases of a project, including planning, designing, building, manufacturing, occupying, and maintenance, involve vast amounts of data that is used for a wide variety of purposes. Building Information Modeling (BIM) is a powerful shared knowledge resource which stores this data to support decision making about a facility through all these different phases in its life cycle. Nowadays, BIM is mostly used in the design and construction phases while it can also be highly beneficial beyond those stages. For example, in the Operation and Maintenance (O&M) phase, BIM could be used for automated facilities management or robotic inspection to provide semantic knowledge for navigation. For any implementation not related to the original intent of the BIM (design), organizations need to be able to represent their project data in a common interpretable form, which provides the possibility of an accurate exchange of data among different software products and platforms, known as interoperability. This study has investigated the current state of interoperability between software products used as Building Information Modeling tools. The main focus has been on a popularly used format for BIM models, Industry Foundation Classes (IFC), since it has been specifically developed to enable standardized data exchange. The research methodology involved a comprehensive literature review and the gathering of all fragmented prior research related to the field in order to develop a consistent understanding of the current state of knowledge. This was accompanied with a detailed case study that evaluated and compared two dominant pieces of BIM software, Revit and Bentley, and examined their interoperability strengths and weaknesses while using the IFC format.

Aug 1, 2013

By Tyler J. Irving

"In June, 2018 Lalor Mine experienced a catastrophic blade failure of its No. 2 main exhaust fan. Over the following weeks several key changes were made to the auxiliary ventilation system to allow for continued production while the exhaust fans were repaired. Issues encountered during the period of reduced ventilation, and how they were addressed, are analyzed. The suspected causes of the exhaust fan blade failure and how risk was mitigated during the reconstruction are discussed. Key findings and lessons learned are summarized.INTRODUCTIONLalor Mine, owned and operated by Hudbay is an underground zinc, gold, and copper mine located in northern Manitoba. The mine workings extend to a depth of 1090 metres below surface and is ventilated using a push-pull system. The mine exhausts through the main exhaust raise; equipped with two, 2,500 HP fans and upcasts through a portal located at the neighboring mine, Chisel North. Air is supplied to Lalor Mine through four intake fans: The Production Shaft Downcast (two, 250 HP), Lalor Downcast (one, 400 HP), and Chisel Downcast (one, 600 HP) fans (Figure 1). In June 2018, Lalor was scheduled to produce approximately 4,000 tpd.On June 20, 2018 at 2:52 pm Lalor Mine experienced a fault on the Variable Frequency Drive (VFD) for Exhaust Fan No. 1. Time would be needed to complete the necessary repairs. The No. 2 exhaust fan was ramped up from 525 rpm to 800 rpm, 90% of its capacity, in order to maintain underground ventilation. At 4:46 pm, approximately two hours after the rpm was increased, exhaust fan No. 2 experienced a catastrophic blade failure. The forces from the blade failure resulted in the top half of the fan housing being thrown 50 metres from where it was installed; with several large sections of fan blade being thrown further (Figure 2)."

Jan 1, 2019

By E. R. Hughes

Introduction Situated 182 miles east of Vancouver, on the Kettle Valley branch of the Canadian Pacific railway, the Princeton coal field is readily accessible to the Coast markets. The area covers approximately forty square miles and present indications are that the deposits should contain at least 300,000,000 tons of coal. Comparatively little development has yet taken place in this coal field. Since the commencement of recorded output, the collieries operating in this area have produced 1,640,518 tons of coal. The coal field proper includes only the Tertiary deposits adjacent to the town of Princeton and does not include the Coalmont or Nicola deposits. Production has never been on a large scale. The largest annual output from any property was 81, 780 long tons mined at the Granby colliery in 1940. Coal output was first recorded in 1909 and since that time fifteen properties are reported to have either mined coal or to have done prospecting or development work; of these, only two are presently active. However, none of the properties now inactive were closed because their coal resources were exhausted. The accompanying key map shows the extent of the Princeton coal field, and the location of the coal mines and prospects in this field General Geology The Princeton field is underlain by rocks of Oligocene age and is one of the series of more or less isolated Tertiary lake basins in which coal, or lignite, has been found in the interior of British Columbia. Resting on the Nicola group rocks of Triassic age, the Princeton sedimentaries consist of sandstones, conglomerates, shales, bentonite, bentonitic clays, and several seams of coal. Tertiary volcanics occur both above and below the stratified rocks and in places they have been thrust through the overlying measures. In some areas, the coal has been burned to a red ash as the result of vulcanism, while in other parts some of the moisture has been driven from the coal, thus improving the grade. The field can best be described by dividing it into two areas: the Southern area, lying to the south of the town of Princeton, where most of the mining has been done; and the Northern area, to the north of Princeton, where very little development has taken place.

Jan 1, 1947

By Jos. Kalbhenn

MR. G. G. BOWSER: Mr. Kalbhenn's paper is an excellent one and is a concise description of a very interesting piece of work. It is well known that a great deal of preliminary study was given to this job before the final plans were made. It is due to this thorough preparation .chat the work progressed so satisfactorily, smoothly, and safely. The ideas carried out in the construction of the hardwood pack, timbered compartment, inclined raise, loading chute, and steel-boomed room, all contributed to a successful conclusion of the work. The extra care in being certain that the compartment shafts were well timbered was especially necessary on account of the difficult blasting conditions. In other words, the foundations .of this job were well and truly laid. The blasting in this work was very difficult due to the nature of the Strata. Working under an ever precarious roof condition and completing .this job with only two lost-time accidents is a record of which to be proud. The shaft men engaged on this work are also due for praise. I regret I did not visit this work while it was in progress. It was not in lack of interest. This, however, more or less proves that the blasting end .of this job went along with practically no trouble. I have seen the nature of the rock, as I made several visits to the tunnels while they were being put through from the Phalen to the Harbour seam. According to figures in Mr. Kalbhenn's paper, the explosives consumption works out to 1.61 pounds per cubic yard of rock in the solid, or 0.8 pounds per ton. The explosives consumption in the tunnels ran from 2.86 to 3.46 pounds per cubic yard or an average of 1.58 pounds per ton of rock. Of course, the rock in the shaft was blasted in the most economical way possible, as far as powder costs are concerned, as the face advanced at close -wright angles to the strata and gravity was acting with the explosive. The tunnels were driven nearly 'end on' the strata and bottom holes had to be lifted, and I believe there was some re-drilling of ribs left in the floor. I would like to congratulate Mr. Kalbhenn on his very fine paper.

Jan 1, 1944

By R. Flood

"Oil has been discovered off Newfoundland in a number of locations on the Grand Banks, the most notable and exciting being in 1979 when Hibernia was discovered. This discovery has brought new challenges to the province as well as to all of Canada. During the seven years"" since its discovery, both industry and governments have attempted to define its parameters and to find the most efficient and economical way to develop the field.A number of studies have been completed during the interval and in 1985, Mobil Canada Ltd. and partners stated that they would prefer to develop the field by using a concrete Gravity-Based Structure (GBS). IntroductionHibernia is located in an environmental climate much more severe than that of any previously developed oil field. The wind and wave conditions are similar to those of the North Sea, but unlike the North Sea, any structure on the Grand Banks would have to contend with ice floes and icebergs. Decisions had to be made on whether fixed structures could be put in place that would withstand the pressures of the ice and the impact of an iceberg, or whether structures that could be removed when such impacts were imminent would be used.Early studies in 1981, determined that it was possible to build a concrete Gravity-Based Structure which could withstand the impact of the largest icebergs that are anticipated to float in that area of the banks.Additional studies increased the knowledge of icebergs: their patterns and size, and verified the original conclusions that Concrete Gravity-Based platforms would provide a practical solution."

Jan 1, 1988

By T. M. Korzekwa, R. L. Cavanagh

Following considerable experience with the beneficiation of Wabana iron ore by standard methods, a study was made of the benefits to be obtained by semi-reduction. The basis of the laboratory program was an extensive mineralogical and liberation investigation which guided subsequent work. Partial reduction and beneficiation on a laboratory scale was carried out on lump ore and fines. The reduced ore was magnetically concentrated and the concentrated fines were briquetted. Data are presented on reducibility, sizing vs reduction rate, magnetic cobbing and separation, and the elimination of phosphorus. Past work is reviewed briefly and comments are made on the relation of laboratory to pilot-scale tests.

Jan 1, 1967

By Arthur Barnes, Mika Muinonen, M. J. Lavigne

"The carbothermic reduction of chromite ore to produce high carbon ferrochromium is among the most energy intensive metal extraction processes performed, due not only to the highly endothermic nature of the reduction reactions but also the very high operating temperatures required for the smelting operation to separate the chrome-containing alloy from the discard slag.KWG Resources and XPS have collaborated over the last 3 years in developing a patented (Winter) processing alternative to the traditional smelting operation in which all processing takes place in the solid state at temperatures many hundreds of degrees lower than those required for liquid processing. Amongst the attractions of the process are much lower capital costs, as well as reduced operating costs, particularly of energy.A techno-economic study on the new process identifies a reduction in overall energy consumption of 70% against conventional processing and approximately 40% lower than the current best practice. By utilising more natural gas than coal based energy sources, the KWG process is able to show an overall 50% reduction in greenhouse gas emissions compared with the most energy efficient current practice. The impact of the new process on future processing is therefore regarded as highly significant, with global energy reductions equivalent to the effect of completely eliminating energy demand from a country the size of Italy.The study concluded that the potential for this process to completely revolutionise the global ferrochrome industry should not be underestimated. Its impact reaches far beyond exploitation of a regional natural resource."

Jan 1, 2015

By W. H. Moore

It seems necessary, at times, that we should reconsider some of the more obscure causes that lead to explosions of gas and coal-dust in mines, in the hope that a recapitulation will keep before us that old and true saying "eternal vigilance is the price of safety". This explosion, while not extensive (resulting in only two much to be regretted deaths) enlarged our vision as to the possibility and probability of other explosions with more disastrous results. As this is only a partial report I shall have to omit many things that are generally included in describing a mine explosion. The mine was worked exclusively with electric cap-lamps -only firebosses and other officials carried safety-lamps. All shots were examined and fired by firebosses with a small hand-battery. Monobel was used exclusively for blasting, and clay for tamping. The system of haulage iri use was main-rope and winches, horses being employed for gathering. Compressed-air was the motive power for all winches and pumps, excepting the pumps at the shaft-bottom which were steam-driven. The mine was wet with practically no dust anywhere, except what was being made at the coal-face in the getting of the coal. Gas was found occasionally, generally in the brushing, especially where the brushing was carried up to a small seam, 2 to 6 feet above the main seam. The place where the explosion took place was known as Leigh's heading, which was being driven to the rise, immediately inbye of the siding (off No. 1 left, off the new slope) and was about 90 feet up from the level.

Jan 1, 1926

By Xueyuan Nie, Xuezhi Zhang, Henry Hu, Shen Xinwei, Jimi Tjong, Li Fang

With the demand for weight reduction in vehicles and airplanes, researchers have shown great interested in casting wrought aluminum alloy 7075 because of its potential advantages such as high strength-to-density ratio and stress-reduction capabilities. It is therefore essential to conduct a fundamental investigation on solidification behavior and grain microstructure of alloy 7075. In this study, a commercially-available wrought aluminum alloy 7075 was used to study the solidification behavior of alloy 7075. A thermal analysis was performed based on the cooling curve and its corresponding first and second derivative curves. The nucleation of the primary a-Al phase and eutectic phases were analyzed. The comparison between the microstructures of the wrought and cast 7075 alloys shows that coarse microstructure and porosity are present in the cast alloy. The techniques for grain refinement in casting, such as the addition of the nucleating particles and applied pressure, should be employed to reduce the dendrite arm spacing and the porosity.

Jan 1, 2015

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By V. Polotski

Initiated and financed by the Canadian Space Agency, Micro-Rover Platform with Tooling Arm (MRPTA) project has targeted the development of a robotic system with remote control and autonomous navigation capabilities for testing a large variety of analogous planetary missions. Although developed for planetary exploration, the navigation system is highly suitable to such areas of application as construction and in mining. Autonomous navigation system is capable of moving the platform to predefined position(s)/orientation(s) while continuously mapping the terrain, assessing its traversability and choosing most appropriate path to follow. Designed according to the JAUS (Joint Architecture for Unmanned Systems) framework, the system consists of several interconnected components. Following components are of particular importance: Pose Estimator (PE), Terrain Evaluator (TE), Map Manager (MP), and Path Planner (PP). The PE uses a minimal sensor configuration consisting of an azimuth gyroscope, inclinometer and wheel odometry. The PE provides reliable pose estimates in spite of pronounced slippage by employing extensive use of fused data. The TE uses a nodding laser scanner which continuously sweeps the area in front of the platform and constructs a ?traversability grid? (TG) of the surrounding area. Multiple TGs are constantly constructed along the platform motion path are combined into a terrain map maintained by the MP. The PP uses this map to compute a motion path Obtained path is executed by the motion controller and remains current until it is contradicted by the most recent map ? at which point it is re-planned. This paper addresses integration issues, lessons learned and also outlines the possible applications for construction and mining.

Aug 1, 2013

By Richard W. Hutchinson, Robert W. Hodder

"Pyritic massive sulphide deposits lie conformably above submarine volcanic rocks, and beneath siliceous and manganiferous iron formations. The massive bodies are often zoned, with a barren pyritic top grading downward into pyrite with sphalerite, and occasionally galena, and a chalcopyrite-rich base. They are frequently brecciated, like the lavas beneath them, which contain pyrite and chalcopyrite as coatings on joints and fractures and as dispersed grains. The lavas also exhibit propylitic, argillic and silicic alteration. These sulphide deposits appear to have formed on sea bottom from fluids escaping through the lavas during periods of exhalative and sometimes explosive volcanism. The process may be comparable to the present deposition of base metals from hot brines in the Red Sea. Some porphyry copper deposits resemble the altered, sulphide-impregnated lavas which lie beneath bodies of pyritic massive sulphide. In porphyry copper deposits, pyrite and chalcopyrite occur as veinlets and dispersed grains in intensely fractured tuffs, flows, sub-volcanic intrusions or other host rocks, characterized by propylitic, argillic and silicic alteration. Metal zoning is present; sphalerite and galena often occur in manganiferous veins peripheral to a shell of pyritic veinlets which encloses the mineable zone of chalcopyrite-bearing veinlets. This sulphide distribution appears to have formed from hydrothermal fluids escaping, either passively or violently, from solidifying magma. The fluids may be comparable to hot brines encountered by drilling in the Salton Sea area of California.There are also important differences between massive sulphide and porphyry copper deposits. The former usually occur in differentiated, mafic-to-felsic subaqueous volcanic rocks, whereas porphyry copper deposits are often associated with shallow plutons and subaerial volcanic rocks of intermediate to felsic composition. Calcic-sodic metasomatism accompanies the massive sulphides, whereas potassic metasomatism characterizes the porphyry cop.per deposits. Further, ages of massive sulphides range from Archean (Keewatin) to Tertiary, but porphyry coppers are Triassic to Tertiary in age. These similarities and differences suggest that massive sulphide and porphyry copper deposits are related tectonically and metallogenetically. The former were generated during early stages of crustal evolution, particularly in Archean time, and were repeatedly derived during early stages of younger, individual tectonic cycles. In contrast, the porphyry coppers developed during the later stages of crustal evolution - later in terms of both absolute age and relative age within younger individual tectonic cycles. They appear in younger rocks generally, and specifically in rocks involved in events of the middle and late tectonic stages of orogenic belts. The massive sulphide deposits are of early-magmatic eugeosynclinal affiliation, whereas the porphyry deposits formed in late-magmatic, predominantly subvolcanic settings at the edge of continental plates, where contemporaneous exhalative volcanism was mainly a subaerial phenomenon. Transitional types of deposits exist and are found on continental margins with flanking eugeosynclinal sequences."

Jan 1, 1972