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By P. Kolodziejczyk

Mining seismicity can be harmful both under and on the surface. ? Tremors are not totally damaging, but destructive to buildings and infrastructure, especially in highly urbanized regions, such as Upper Silesia in Poland ? Destroy the social appreciation, trust and support for mining industry ? To prevent or reduce these effects, engineers and scientists develop methods allowing prediction of ground shaking intensity near buildings and various losses that can result from it Evaluation and prediction of mining tremor?s damaging influence on buildings is usually solved with two steps: ? Estimation of local ground shaking intensity (based on known attenuation relation) and classification into one of several predefined intensity intervals ? Apply supposed relation between the shaking intensity interval and qualitatively defined damaging effects to express predicted effects This makes a mixed quantitative/qualitative procedure, difficult to analyze or optimize

Aug 1, 2013

By B. Yu, N. Verbaan, A. Mezei

The recent 20 years witnessed a boom and bust in the nickel laterite industry. Most notoriously is the story of the first three Western Australian nickel laterite projects which all suffered major ramp-up issues. Many hard lessons were learned by the industry and it has been widely reported that the major contributing factors included insufficient testing as well as a limited understanding of the materials handling characteristics at the front-end stage of the flowsheet. This paper compares the current "race to production" in the REE industry to the laterite industry 20 years ago and addresses the fundamental question: ‘Have mining and exploration companies with rare earth projects learned from past lessons and are they doing sufficient and appropriate testwork to prevent failure’? The authors will provide the perspective of a commercial metallurgical laboratory that has gone through the laterite cycle and is active in the present REE cycle.

Jan 1, 2014

By Hugo Julien

According to OSHA 29 CFR Part 1910.119 (Process safety management of highly hazardous chemicals), Canadian Provincial Safety Standard Acts or Federal laws, the owner of stationary equipment (Boilers, stacks, piping, pressure vessel, etc.) should follow a complete inspection plan and follow an Integrity Operating Windows (IOW’s) adapted for each of them. Some important variables shall be included in the inspection plan such as specific damage mechanisms versus alloy used in the original design, process conditions, etc. Some North American’s standards exist, like the one listed in ASME PTB-2-2009, to help owner to create such inspection program. The new API RP 584, Integrity Operating Windows (IOW’s) can guide Mining & Metals owners to find out their specific IOW’s. Inspection frequencies are often described in the Jurisdiction Safety Acts such as the British Columbia B.C. Reg. 104/2004, etc. but often left in the owner representative responsibility (Bill C-21, federal Act to amend the Canadian Human Rights Act). Every deficiency should be repaired according to recognized Codes such as ASME PCC-2, etc.. If flaws not conforming to the original Code of construction are found, this article will introduce the Fitness-For- Service assessment principles to be able to accept it without any repairs.

Jan 1, 2014

By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By R. N. Chakravorty, K. K. Feng

"There is growing evidence that modern methods of mining coal increase the risk of spontaneous combustion. Seemingly unimportant at this time, this hazard could prove to be a barrier to growth and development of the coal industry in some areas of Canada. The paper presents bedrock knowledge on spontaneous combustion gathered by scanning and evaluating current technical and research literature. Special efforts have been made to identify significant coal and environmental factors and to establish criteria for susceptibility. In addition to the state-of-the-art knowledge, preliminary results from on-going studies are discussed."

Jan 1, 1973

By K Belanger, J. Mclachlan, F. Stober, G. Norval, B. Snider, A. Munsch, T. Koehler, E. Piantino, J. Carlos Queiroz

The project to rebuild the smelting furnaces at the Anglo American - Barro Alto ferronickel smelter, located in Goias, Brasil, was initiated in September 2013. To optimize the capital cost, while maximizing furnace integrity and robustness, a design basis giving flexibility to ore composition variation was developed in order to ensure sustained nameplate production. The resulting capital efficient, fasttracked project execution was accomplished through the creation of an integrated project team of Anglo American and Hatch through FEL 3 and FEL 4 phases of the project. The integrated team addressed the project challenges through a cooperative and versatile approach, created by access to knowledge, experience and systems in both Anglo American and Hatch. The team could operate at an optimized speed of execution, as demonstrated in the FEL 3 and FEL 4 completion durations, as well as efficiently mitigating any risks of increasing cost or delaying schedule by utilizing lessons learned and team knowledge from Anglo American on the original green-field project and Platinum smelters and Hatch on similar reference ferronickel furnace rebuilds. Other critical drivers of project cost minimization and revenue loss/generation (considering production revenue of each furnace) are scheduled durations for construction, commissioning and ramp-up. The integrated team commenced construction, commission and ramp-up planning almost one year in advance of the shutdown and this paper will discuss the strategies developed to reduce risks and optimize the construction schedule to mitigate revenue loss and optimize ramp-up time to sustained operation at nameplate capacity.

Jan 1, 2015

By N. Behnood

"This paper describes how material selection, quality assurance, and failure investigation play important roles in the efficiency and safety of mining and metallurgical operations.INTRODUCTION Material selection, quality assurance, and failure investigation are all complementary elements of materials engineering in the application of materials technology for failure prevention. Based on commodity price increase of 300% between 2002 to 2013 [1] and increased cost ofcapital projects and operation, equipment failure, which in some cases causes complete shutdown of the operation, becomes a vital importance in mining and metallurgical plants. The following sections present a number of examples from many failure cases experienced by the author during his three decades of work as a materials engineer in the mining industry."

Jan 1, 2015

By Ruy L. Rodrigues

Vale is in the early stages of commissioning its Onça Puma nickel operations. The project is meant for the production of 58,000 tpa of nickel contained in ferro-nickel, substantially contributing to the company?s vision to achieve world leadership in the nickel business. Mineral resources will be exploited from the homonymous deposits in the Midwest of state of Para, Brazil ? some 100 km southwestwards from the company?s Carajás iron ore properties. Resources as of 83 Mt at 1.73 % Ni will sustain a mine life of approximately 40 years. The property was acquired in late 2005 and Vale has since extended the engineering studies and proceeded with the implementation. Nickel will be mined from saprolitic ore at a rate of approximately 10 Mtpa (ore plus waste) in early years ? ramping up to some 15 Mtpa 7 years later ?, to feed the plant at a rate of 2.5 Mtpa. The process uses conventional RKEF (Rotary Kiln Electric Furnace) pyrometalurgical route whereby the ore is homogenized, calcined in rotary kilns, melted in electric furnaces and further refined to ferro-nickel. The plant has been designed and constructed applying the latest available technology, aligned with Vale?s vison to exceed the highest existing standards for environmental control, health and safety and productivity in the industry. Total investments in these operations are anticipated to correspond to USD 2.3 Bi and will materially contribute to the regional development and well being of the nearby communities and other stakeholders.

May 1, 2010

By Brian Hart, Roger St. C. Smart, James Francis, Mark Biesinger

"There are a number of challenges involved with the surface analyses of different mineral phases from process streams in a flotation facility. The first of course is to collect samples that are representative of the process and to ensure that they remain in a pristine condition prior to introduction into the instrument. In mineral processing, sample collection from the different streams is done on site and preservation involves simply removing oxygen from the sample by bubbling nitrogen or argon gas through the sample and snap freezing with dry ice.The second challenge in studying the surface chemistry of specific minerals is to find reliable methods of mineral phase recognition. In surface analysis of mineral particles confident mineral selection can be difficult with many multi-metal minerals (e.g. chalcopyrite, pyrite, sphalerite) and with precipitated, adsorbed, reacted and contaminant species in the outermost molecular layers.In this paper we show that principal components analysis (PCA) of ToF-SIMS data provides improvement in phase recognition, particle selection and associated variations in surface species. We will demonstrate, with specific examples, that this technique can be utilized to differentiate surface chemical factors promoting (hydrophobic species) or inhibiting (hydrophilic species) flotation.Species recognition based on the PCA method in a study of Cu transfer between chalcopyrite, pyrite and sphalerite mineral mixture clearly identified a statistical difference in copper intensities between the sphalerite and pyrite phases. A similar ToF-SIMS/PCA based study applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrated extensive CuOH and NiOH transfer between the chalcocite and heazlewoodite minerals. The statistical analysis has been able to confirm some mechanisms and deny others proposed to control recovery and selectivity giving more focus on the control factors.The ToF-SIMS PCA statistical analysis has elucidated differences in surface chemistries which illustrate the discriminating depressant action of adherent aluminosilicate (gangue) fine particles and adsorbed ions on the surface of sphalerite grains. In the flotation test concentrates, HIC conditioning resulted in the removal of these gangue fines thereby improving surface collector attachment efficiency, promoting a greater recovery of sphalerite."

Jan 1, 2007

By W. P. Campbell

Introduction OWING to the necessity of curtailing the length of this paper, nothing like an exhaustive treatment of the subject will be attempted. Instead, merely a few aspects will be considered, viz., water trouble in wells, sampling of waters, analysis, methods of reporting analysis, and the comparison of a few typical waters. The waters discussed will not be confined to those occurring in areas where oil or gas has already been found, but will include samples from areas in which drilling is being carried on in the hope that oil or gas may be found, i.e., from unproved fields. The Water Problem The problem of dealing with water encountered in oil and gas producing areas has engaged the attention of petroleum engineers from the early days of the industry. Water was not always considered a menace to oil sands; indeed, a certain amount of it was considered beneficial in some areas, but if such exist today they are very exceptional. In some fields, the problem is more acute than in others, and at times has baffled all attempts to solve it satisfactorily. Wells have been brought-in with promise of good production, but after a brief period have 'gone to water'. Whether ?it has always been a case of poor engineering in the form of unsuccessful water shut-off of 'top' or 'bottom' water, or because 'edge' water was present and water and oil were in such close contact it was impossible to remove the one without the other, is hard to say.

Jan 1, 1929

By Z. Xiao, A. R. Laplante

"The recovery of gold by gravity from grinding circuits differs from virtually all other gravity recovery approaches in that stage (or unit) recoveries are low, typically 1 to 5%, but overall recoveries are generally in the 25 to 60% range, because individual gold particles are presented many times to the primary recovery unit. Full-scale recovery is difficult to predict from benchscale tests. Further, maximizing metallurgical recovery is generally not the primary objective, because of the more efficient downstream recovery circuit (flotation or cyanidation). In this paper, a new concept, the gravity recovery effort, is presented to assist in the design and optimization of gold gravity circuits. It is defined as the product of the circulating load treated by the primary gravity unit, the recovery of this unit, and the gold room recovery. Predicted gold recovery is linked to the recovery effort, the size distribution of gravity recoverable gold (GRG), the dimensionless retention time in the mill and the partition curve of GRG. A case study of economic optimization of the gravity recovery effort is presented. INTRODUCTIONPredicting gold gravity recovery from grinding circuits has always been a hit-and-miss exercise. The problem can be traced to the highly variable gravity recoverable gold (GRG) content of ores, high GRG circulating load, fraction of the circulating load treated, and performance of primary gravity recovery and gold room. Typical values, highs and lows are shown in Table 1."

Jan 1, 2001

By L. R. Plitt, A. A. Turak, B. C. Flintoff

"Since the publication of empirical cyclone models by Lynch and Rao in 1975 and by Plitt in 1976, the technical literature on this subject has consisted primarily of reports of applications, with only a few articles discussing basic modifications or enhancements in model form. In fact, most of the modelling eff ort in this period has been concerned with theoretical models based on the hydrodynamics of multiphase flow. (Preliminary resutls have been encouraging, however, it will be some time before this approach reaches the practical application stage.) This paper presents a review of empirical cyclone modelling technology, with an emphasis on developments since the mid 1970s. The topics addressed include homogeneous and heterogeneous ores, parameter estimation techniques, parameter confidence intervals, and the introduction of a new conceptual model of cyclone operation.IntroductionSince their first reported application in the mineral industry by Driessen (1939), cyclones have become a common unit operation in all of the process industries. The widespread use of the cyclone stems from its relative low cost and its versatility. It can be employed to carry out liquid-liquid, solid-liquid and solid-solid separations. It is the area of solid-solid separation which is of greatest interest to a mineral processing engineer. Historically, this area was divided into two application categories: (I) Separation according to density, the cyclone washer, and, (2) Classification according to particle size, the cyclone ciassifier. (When water is the carrier fluid, the cyclone is more often called the hydrocyclone. For the purposes of this paper the two names are used interchangeably). Classification is the principal application in mineral processing circuit s. Within this category, the cyclone is most commonly employed to provide some positive control over the size distribution of product from a grinding circuit. Other uses include sand-slime separation prior to froth flotation and mill tailings treatment, either for dam construction or in backfill preparation."

Jan 1, 1987

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

By Norman O. Lotter, Virginia Lawson, Mika Muinonen, Dominic Fragomeni, Jorge F. Oliveira

Development of metallurgical flowsheets from drill core to production of finished metal involves two main domains: process mineralogy to sample the ore and develop a successful flowsheet producing saleable concentrate; and extractive metallurgy to convert that saleable concentrate to finished metal. Effective flowsheet development for a new or brown-field concentrator and processing facility is essential to project schedule and return on investment. Over the last decade in particular, the integration of geology, mineralogy, sampling, and mineral processing have empowered the development of an improved practice in flowsheet development. The use of geometallurgical units as a basis for best-practice sampling delivers representative study material to the laboratory. Modern automated mineralogy characterises the whole rock assembly and paymetal mineral hosting, to address downstream process implications. Batch scale flotation testing then uses this information to design and perform well-focused strategies. At early stages of the project, the Extractive Metallurgy team is engaged to determine processing constraints or other economic drivers in conversion of the saleable concentrate into finished metal. The team evaluates available technologies, assesses the impurities and key properties of the given concentrate. In many cases, changes to mineral processing flowsheet are required to maximize value per tonne of concentrate. Site conditions, availability of infrastructure, energy and power all play an important role. Modern metallurgical simulation tools such as FactSage™ and METSIM™ can quickly define the appropriate test program for each process. Bench scale testing and appropriate scale of piloting can confirm simulations and provide design criteria. A case study demonstrates how effective use of these tools and a multidisciplinary team can accelerate flowsheet development, while reducing costs and ensuring that the designed processing facilities maximize project value with minimum risk.

Jan 1, 2014

By T. Hadley, E. Catovic

"Northern Minerals Limited’s (ASX: NTU) flagship project is the Browns Range Rare Earth Project (the Project) located in Western Australia, consisting of a number of deposits with high value, heavy rare earth elements, in particular yttrium, terbium, and dysprosium. The deposits are dominated by xenotime mineralisation, which occurs within hydrothermal silicified and hematitic breccias. The Company delivered an initial JORC compliant resource estimate for the Project at the end of 2012 of 10,500 t of contained total rare earth oxides (TREO), which was increased to 28,084t of contained TREO in October 2013 and further enlarged to 47,997 t of contained TREO in February 2014. Concurrent with the growth of the Project resource base, significant progress has been made in developing the metallurgical process for the beneficiation and extraction of rare earth elements (REE’s) from the xenotime mineralisation. Development of the beneficiation circuit evaluated several process options and selected whole-ore flotation and magnetic separation, followed by flotation (hybrid circuit) as the two preferred flowsheets to pilot, following encouraging results on the bench of 83% and 86% recovery to a 20% TREO mineral concentrate respectively. Several downstream hydrometallurgical extraction flowsheets were evaluated. However, the following two preferred process flowsheets were ultimately selected for further detailed investigation during the prefeasibility study: 1. Sulphation bake, water leach, purification, oxalate precipitation, and/or calcination to produce a mixed RE oxide; 2. Sulphation bake, water leach, phosphate precipitation, caustic conversion, HCl leach, and oxalate precipitation to produce a mixed RE oxalate. Excellent heavy rare earth oxide (HREO) extractions (~ 90%) from beneficiation concentrates were achieved on the bench for both circuits, however flowsheet 1 was ultimately selected as the preferred flowsheet to pilot due to lower capital and operating cost. A mixed rare earth oxalate (42% TREO) or oxide (92% TREO) can be produced with low levels of Th and U of 3 ppm and 6 ppm respectively."

Jan 1, 2014

By G. Azimi, K. K. Varanasi1, A. T. Paxson, R. Dhiman, H. -M. Kwon

Hydrophobic materials that are robust to harsh environments are needed in a broad range of applications. Although durable materials such as metals and ceramics, which are generally hydrophilic, can be rendered hydrophobic by polymeric modifiers, these materials deteriorate in harsh environments. Here it is shown that a class of ceramics comprising the entire lanthanide oxide series, ranging from ceria to lutecia, is intrinsically hydrophobic. Their hydrophobicity is attributed to their unique electronic structure, which inhibits hydrogen bonding with interfacial water molecules. In addition, this work demonstrates that these ceramics sustain hydrophobicity even after exposure to high-temperature environment (1000 °C for 2 h in air). It is envisioned that this class of robust hydrophobic materials will have far-reaching technological potential in various industrial applications, where water repellency and dropwise condensation are desirable.

Jan 1, 2014

By B. Lueger, D. Shen, M. Sedighy, R. Rand, R. Saleh, J. Cheung, M. Rifai, I. Khan, W. Sauri, D. Setianto

The world’s first active power demand stabilization system for a 3-electrode electric arc smelting furnace was commissioned at PT Vale Indonesia in December 2012 on Furnace No. 2 using an SPLC (Smart Predictive Line Controller). The SPLC technology in combination with the Furnace No. 2 rebuild and other upgrades has enabled PT Vale to increase the electrical input to the furnace by up to 20% on a stable and sustainable basis by eliminating peak powers that overload and trip out the electrical equipment, and by reducing power unbalances. The SPLC technology maintains smooth arc power using a continuously variable thyristor controlled series reactor. The SPLC compensates variations in the furnace arc with predictive changes in the circuit reactance at a speed of up to 60 times a second. The system started up quickly and has been shown to be easy to operate and maintain by PT Vale. PT Vale’s Operations Team has been testing the new system at set points of up to 90 MW on the newly re-built Furnace No. 2. Over the last 12 months, the throughput of Line 2 has increased by approximately 10% on an annual average; however, debottlenecking in other design areas of the operation is required in order to achieve 90MW operation on a sustainable basis. This outstanding success results from a combination of the furnace and other upgrades, the SPLC active power stabilization, and the skill of PT Vale in quickly adopting new technologies and maximizing the combined benefits of each technology in their operation.

Jan 1, 2014

By A-A. Bogno, Ch. -A. Gandin, A. Maitre, H. Henein

Most metallic materials are produced from their liquid state. In order to control the properties of industrial products, it is very important to understand their solidification path and the resulting microstructures which can be significantly affected by melt undercooling. High undercooling results in rapid solidification and a refined microstructure with minimal microsegregation. This paper reports on the analysis of rapidly solidified Al-Cu droplets obtained by a single fluid atomization process, Impulse Atomization. A quantitative analysis by Rietveld refinement method of the Neutrons Diffraction data was carried out to determine the fraction of the intermetallic Al2Cu. Knowing the fraction of Al2Cu, the eutectic fractions and corresponding dendritic and eutectic undercoolings were estimated using the metastable extensions of solidus and liquidus lines of the Al-Cu system calculated by Thermo-Calc. In addition to this work, a model of microsegregation coupled with ThermoCalc software via TQ (application programming interface of ThermoCalc) and the Wang-Beckerman model for dendritic growth velocities has been developed for binary alloys. This has led to the development of a phenomenological relationship between primary phase undercooling and initial growth velocity. A comparison of estimated primary undercoolings using a coarsening model with the adiabatic undercoolings for each alloy composition has confirmed that solidification occurs under adiabatic conditions during recalescence.

Jan 1, 2014

By M. Y. Solar, W. G. Davenport

Most of the recent growth in nickel demand has been for the production of stainless steels and virtually all of it has been satisfied by new ferronickel and nickel pig iron projects. But "good" laterite resources are more and more difficult to find: Ni grades are decreasing while Fe contents are increasing and SiO2/MgO ratios vary from 1 to 3 and even higher if limonites are included. Predicting the smelting behaviour of such ores requires a more fundamental understanding of the thermodynamics of these systems in commercial operations. One valid question is thus whether these furnaces are at thermodynamic equilibrium or not. The present paper investigates this question, compares calculated and measured O2 partial pressures and mechanical/chemical slag loss ratios and concludes that ferronickel furnaces are not at thermodynamic equilibrium. This departure from expectation is actually to the operators’ advantage: the targeted ferronickel grades can be obtained at lower reduction potentials than calculated from pure thermodynamics.

Jan 1, 2014

By H. Zhu, Y. Sato, O. Takeda, K. Nakano

Recycling of rare earth magnet wastes is essential to insure the stable supply of rare earth resources. For the development of a novel recycling process, the removal of rare earth oxide from an off-spec alloy magnet was investigated by melting the alloy magnet at 1503 K together with fluoride flux, LiF-50 mol% NdF3 and LiF-?25 mol% NdF3-25 mol% DyF3. After melting, the separation of magnet alloy from the fluoride flux was achieved, and neither suspension of alloy in the flux nor suspension of flux in the alloy was observed. Oxygen concentration in the alloy decreased from 5000 mass-ppm to 160 mass-ppm by utilizing 1.5 times of equivalent amount of flux needed to completely dissolve the oxide. The investigated process is suitable for mildly contaminated waste such as a used (end-of-life) magnet because of its simplicity, low energy consumption and small limitation on location for operation.

Jan 1, 2014