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By Brian L. Beninger

This paper discusses the application of the computer to coal preparation process predictions. In broad terms, the computer is used to perform two main functions. Firstly, the given float-sink analysis is interpolated and extrapolated to cover the entire actual range of raw coal specific gravity. Assumptions based on historical data must be made at times. Secondly, the partition curve, which, from historical data, defines the efficiency of a specific coal washing process, is applied to the washability data in order to determine the expected clean coal yield and quality. The vast amount of numerical work which is required to make a prediction of this type exhibits the need for computer methods in this area.

Jan 1, 1979

By Descarreaux. Jean

"The Abitibi volcanic belt was sampled along a cross section extending from Matagami to a point east of Rouyn. A few samples were also collected in Louvicourt township, Quebec. The major elements were determined for 344 samples, and rock names were defined using normative minerals. The analytical data were studied by means of variation diagrams. The Abitibi volcanic belt is characterized by rocks belonging to both the tholeiitic and calc-alkaline magmatic series, but they show some differences as compared to some typical reference series, particularly those from Japan. Basalt is the predominant rock type and accounts for 44 per cent of the sampled outcrops. The volcanic rocks are relatively poor in K2O and TiO2. Regionally, the volcanogenic copper-zinc mineralization is associated with the calc-alkaline volcanic sequences. Locally, within such sequences, some types of abnormal deviations from the averages are recognized only in association with the copper-zinc mineralization. The anomalies are ascribed to hydrothermal alteration consisting of the introduction of MgO and removal of N a20; enrichment in K20 is also observed where zinc mineralization predominates. Examples of such anomalous zones show that, in places, this alteration phenomenon can be quite extensive. Petrochemical characteristics can be used as geochemical ore guides in exploration programs."

Jan 1, 1973

By A. Eslami

When producing high grade mattes in smelter plants, copper losses in the slag are inevitable. Hence, the recovery of copper from slag has been the focus of many research projects, copper flotation being a widely used process. In the Khatoonabad converter, 200 t/d of slag are presently produced with a grade of 2.3% Cu. Assuming a 85% recovery by flotation, about 3.9 t/d copper could be produced, which is of prime importance economically. In the present work, a sample of this slag was crushed and ground in the laboratory to liberate the copper-bearing minerals. Following mineralogical studies, optimum laboratory flotation parameters were obtained, resulting in 90.27 % recovery and 9.42% of copper grade for the rougher stage. At pilot scale, a pulp of 28% solids was floated at ph 10.5 using 40 git of Z6, 25 git of R407 and 20 git of MIBC and A65. A recovery of 83.52% was obtained for a concentrate grade of 28.36% Cu. In the rougher cells, the feed consisted of particles 94% finer than 74 microns whereas in the cleaning stage, particles were 95% finer than 44 microns. Based on the obtained results, the Sarcheshmeh Khatoonabad converter slag is presently being fed to the Chargonbad flotation plant, where a concentrate of 32% copper at 86% recovery is being produced.

Jan 1, 2007

By Wei Sun, Xiangsong Meng, Xiaodong Li, Weisheng Huang, Yuehua Hu, Chonggao Cao, Haisheng Han, Wensheng Chen, Runqing Liu, Central South University

"The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work revealed the effect of water glass on the flotation of scheelite by FTIR and the wettability change of the usual cleavage plane, and proved that water glass inevitably influenced the flotation of tungsten minerals to a large extend in traditional fatty acid flotation process. A new collector, benzohydroxamic acid complexes, was found to be selective for the separation of scheelite and calcium minerals with little water glass. Hence a novel flotation process was developed for the recovery of tungsten minerals in shizhuyuan mine in China. Normal temperature flotation of tungsten minerals was developed to instead of the classical “Petrov's process” for scheelite-calcite-fluorite type ores. Compared with the traditional process, the recovery was improved by 10% and the grade of scheelite concentrate was above 55%. The disappearance or decreasing of water glass contributed to improving the recovery of tungsten and fluorite and the circulation of water and reagents.INTRODUCTIONChina is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves (Cai Gaipin et al., 2009). However the wolframite has been dried up and the scheelite resource has become the main resource of the tungsten metal. Scheelite deposits were classified to scheelite-silicate type and scheelite-calcite-fluorite type based on the associated gangue minerals. Scheelite was easy to separate from the silicate minerals. Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physicochemical characteristics such as solubility, hardness, specific gravity, PZC (point of zero charge) etc.(Arnold & Warren, 1974; Yongxin & Changgen, 1983; Ozcan & Bulutcu, 1993a; Deng et al., 2015, 2016;). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives ( Yongxin & Changgen, 1983; Oliveira & Sampaio, 1988; Sivamohan, 1988; Shi et al., 2014; Bo et al., 2015). It is difficult to separate scheelite especially from calcite with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan & Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is not adequate for a low-grade calcitic scheelite ore. Unfortunately, the reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Yongxin and Changgen, 1983; Schubert et al., 1990; Shi et al., 2014; Bo et al., 2015) used for calcite depression also depress scheelite to a large extent."

Jan 1, 2016

By Warren A. Sheaffer

THE chief uses for copper are as a conductor of electricity and as the chief component in brasses and bronzes. For such uses, the copper must be of very high purity. H the impurities are zinc, iron, lead, arsenic, or antimony, they can be removed to a great extent by fire-refining. H, however, gold, silver, nickel, or cobalt are present, electrolytic refining is necessary. Electrolytic refining must be preceded by fire-refining and hence all impure copper must be fire-refined. The electrolytic refining of copper is most efficiently carried on when the impurities in the anodes are at a minimum. Some of the impurities tend to deposit with the copper at the cathode, while others remain in solution, decreasing the conductivity of the electrolyte and thus increasing the voltage necessary for refining. Since these dissolved impurities must be removed by continuous purifications, the amount of impurity in the anode copper should be reduced by furnace refining to some predetermined limit. Anode furnace operation aims to reduce these impurities to a minimum beyond which the cost of further furnace refining would exceed that of removing the remaining small amounts of impurities from the electrolyte. The anodes should have a fine-grain internal structure because any pieces of metal becoming detached from the anode during the electrolytic refining are inconvenient to remove from the cells and may cause short-circuits. Impurities tend to disrupt such a structure and thus form zones of weakness during corrosion. When the impurities are reduced to a satisfactory mini-mum, the anode, due to having a fine-grain structure, will corrode uniformly over the entire surface area exposed to the electrolyte. Oxides of the impurities may be volatile, in which case they pass off as flue gases, or they may form viscous slags having a lower specific gravity than molten copper, thus permitting their removal by skimming. Some impurities can be oxidized by introducing air into the bath. Due to the large solubility of oxygen in molten copper, oxygen is distributed uniformly throughout the bath and thus comes into intimate contact with all impurities. The oxides which are insoluble in molten. copper are removed either as flue gases or as slag.

Jan 1, 1942

By K. Liu

"In the present work, two-step heat treatments with preheating treatments at different temperatures (175, 250 and 330°C) as the first step followed by the peak precipitation treatment (375°C/48h) as the second step have been performed in Al-Mn-Mg 3004 alloys to study their effects on the formation of dispersoids and evolution of elevated-temperature strength and creep resistance. During the two-step heat treatments, the microhardness is gradually increasing with increasing time until to a plateau after 24 hours when first-treated at 250°C and 330°C while there is a minor decrease with time at 175°C. Results show that both the yield strength and creep resistance at 300°C reach the peak values after the two-step treatment of 250°C/24h+375°C/48h. The formation of dispersoids is greatly related to the type and size of pre-existing Mg2Si precipitated during the preheating treatments, in which that coarsened rod-like ß’-Mg2Si strongly promotes the nucleation of dispersoids while finer needle-like ß’’-Mg2Si has less influence. Under optimized two-step heat treatments and modified alloying elements, the yield strength at 300°C can reach as high as 97 MPa with the minimum creep rate of 2.2×10-9 s-1 at 300°C in Al-Mn-Mg 3004 alloys, enabling them as one promising candidate in lightweight aluminum alloys for elevated-temperature applications.INTRODUCTION Due to the rapid demand from weight-sensitive automotive and aerospace industrials for the light alloys, such as aluminum alloy on the elevated-temperature applications, Al-Mn 3xxx alloys has been developed to obtain the good properties at both room temperature (RT) and elevated temperature, in which the dispersoid-strengthening mechanism plays a significant role (Li & Arnberg, 2003; Li, Muggerud, Olsen & Furu, 2012; Liu & Chen, 2015, 2015). In our previous works (Liu & Chen, 2015, 2015; Liu, Ma & Chen, 2017), the yield strength and creep resistance at 300°C of Al-Mn-Mg 3004 alloy were further improved by modifying the alloying elements, such as Fe and Mo, to optimize the characters of dispersoids, including the size, distribution and the dispersoids free zone (DFZ). For instance, Mo was introduced in aluminum alloy to further improve the volume fraction of dispersoids and reduce the area of DFZ, leading to increasing on both the strength and creep resistance at 300°C (Liu, Ma & Chen, 2017). On the other hand, the mechanical properties became worse at higher Fe content due to its consumption more Mn to form Al6(MnFe) intermetallics, resulting in less available soluted Mn for the precipitation of dispersoids (Liu & Chen, 2015). Therefore, optimizing the characters of dispersoids is always the key to improve the elevated-temperature properties of dispersoid-strengthened aluminum alloys for elevated-temperature applications."

Jan 1, 2017

"In many gold deposits, a reasonable amount of the gold that remains in the cyanide leach tailing is associated with pyrite. Some gold plants have found it economical to incorporate gravity circuits on the cyanide leach tailing to recover the gold bearing pyrite before subjecting it to fine grinding, then recycling the ground pyrite back to the cyanide leach circuit. For low grade gold deposits the loss of gold bearing pyrite is exacerbated as the broader process economics normally favour a coarse grind (> 150 ?m). An option that has received attention over the last decade is to recover the gold bearing sulphides in the milling circuit by gravity, similar to the widely-practiced gravity recovery of free liberated gold. The modelling and simulation of a gravity gold circuit in a milling flowsheet is relatively simple compared with a gold bearing pyrite circuit, as the recycle advantages and breakage functions for gold and pyrite are quite different. This current work represents an attempt to simulate the gravity recovery of gold bearing sulphides in a milling circuit that also incorporates fine grinding, using relatively simple simulation models. The simulation results are further explored with reference to the economics of this type of circuit.INTRODUCTION It is well known that gold is associated with pyrite in most sulphide gold deposits and that the amount of gold associated with pyrite will vary from deposit to deposit. Most of the gold associated with pyrite is liberated in the grinding circuit during the processing of a gold ore. However, some gold remains occluded in the pyrite and is lost in the final leach tailings. Little information is available in the literature on methods to enhance gold liberation from pyrite by specifically removing pyrite, either in the grinding circuit or from the final tailings stream, and grinding it finer. One of the earliest record of this approach is described by King (King, 1949) where pyrite present in Witwatersrand gold ores was recovered by circular jigs and Johnson barrels followed by fine grinding of the concentrate prior to cyanide leaching. Dominy et al., 1970, provides information on the use of Yuba jigs to recover pyrite from the discharge end of ball mills. Again, the jig concentrate was ground to a fine particle size before cyanide leaching to recover the liberated gold. Unfortunately, no information is provided in these articles on the additional gold recovery from implementing these circuits in a flowsheet. Martins et al., 1993, provides details of a gravity circuit using Reichert cones and spirals to recover gold bearing pyrite from a cyanide leach tailings followed by fine grinding of the pyrite concentrate in a Tower mill. The ground concentrate returned to the front end of the already installed leach circuit. Overall recoveries were increased by some 2% to 4% depending on the amount of gold and pyrite in the plant feed."

Jan 1, 2017

By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By A. Deneys

This paper reviews industrial gases used in primary copper production. Copper smelting industrial gas demand has steadily increased since the first commercial oxygenconcentrate smelting in 1952 [1]. In copper production oxygen for smelting is the dominant industrial gas use followed by oxygen for converting. Nitrogen is finding increased use in copper smelters. Nitrogen is used for porous plugs for copper converting and anode refining [2-5]. Nitrogen can be used for concentrate drying [6,7] and is also used in some Ni-Cu smelters as a coolant in Peirce-Smith converting [8,9]. Industrial gas supply options of cryogenic or adsorbent based on-site plant or cryogenic liquid delivery are detailed.

Jan 1, 2007

By J. A. Drozdiak

In this paper we examine, through pilot-scale testing, the possibility of operating a circuit comprised of two stages of HPGR comminution, followed by grinding through a horizontal stirred mill. In order to assess whether the novel circuit design could achieve the reduced energy requirements indicated in the literature, two more-established circuits, a cone crusher / ball mill and an HPGR / ball mill, were examined using a combination of testing and flowsheet simulation. The results showed that, based solely on the specific energy requirements for comminution, the HPGR / stirred mill circuit achieved a reduction of 9.2% and 16.7% over the HPGR / ball mill and cone crusher / ball mill circuits, respectively.

Jan 1, 2012

By Janice Zinck, Maziar E. Sauber

"To counter the recent uncertainty in the rare earths market, diversify the supply source, and help meet the future demand in this sector Canada initiated development of several new rare earth deposits. In the past few years, a number of various studies on rare earths plant design have taken place mainly covering process development, process selection, and flowsheet design. The purpose of this paper is to provide an overview of known domestic and potential resources and reserves of rare earths and their status quo with a focus on the metallurgical processes using the information available in the public domain. Plant designs currently under consideration in Canada are reviewed and evaluated. An outline of the areas of opportunity for selective innovation and technology development in the rare earths flowsheet development and the associated risks and rewards is provided.INTRODUCTIONThe rare earth elements (REE) have a very small annual market, but they are categorized as very strategic metals vital to global economic growth due to their indispensability to the development of modern defence system, green technologies and electronic applications. The International Union of Applied and Pure Chemistry (IUPAC) defines the REE as the 15 elements on the lanthanide series on periodic table of elements, plus yttrium and scandium. REE are classified as light rare earth elements (LREE; La to Gd), and heavy rare earth elements (HREE; Tb to Lu). Physical properties and chemical reactivity of yttrium is similar to those of HREE, thus it is categorized as such. Properties of scandium are not similar enough to classify it as either a LREE or HREE (Weng et al., 2015; Sappin & Beaudoin, 2015). However, the mining industry does not always abide to this definitive classification of the split between LREE and HREE. Therefore, in a comparative study of projects, there is a need to pay attention to how the elements are classified."

Jan 1, 2016

By Amauri Garcia, Rodrigo Valenzuela Reyes, Noé Cheung, José Eduardo Spinelli, Leonardo Fernandes Gomes, Rafael Kakitani

"The present research work deals with directional solidification (DS) of both Al-15wt.%Si and Al-15wt.%Si-1.5wt.%Mg alloys and further characterization of the related microstructures. The growth of refined primary Si and refined eutectic is well-known as positive in order to improve mechanical properties of the Al-Si based alloys. Alloying is also an effective method to strengthen the Al-Si based alloys, in which Mg is considered an important alloying element. However, lack of investigation regarding the effects of Mg on microstructure of these alloys is noted. So, in the present research work emphasis is given on both dendritic and eutectic growth being affected by solidification kinetics (V-growth rate and G-thermal gradient) during transient directional solidification. Experimental evolutions of microstructural spacing of both alloys have been determined which becomes possible to understand the effects of Mg coupled with the effects of growth rate on the final microstructural arrangements. A direct comparison of the tensile mechanical properties obtained for the alloys is also performed. It is shown by these correlations that the addition of Mg generally improves the tensile mechanical resistance with a minor decrease in ductility. Furthermore, the Scheil solidification path of the ternary Al-Si-Mg alloy was determined using the computational thermodynamics software Thermo-Calc, resulting in the following sequence of precipitation: Liquid-Si-a (Al)+Si- a(Al)+Si+Mg2Si. This sequence is compared with the experimental microstructure findings.INTRODUCTION Al-Si alloys containing from 4wt.% to 22wt.% Si comprise more than 90% of all Al-based castings. Parts manufactured with these alloys have a wide range of industrial applications due to their excellent castability, crack resistance, good corrosion resistance, good weldability, low density and high strength (Bray, 1976; Zolotorevsky, 2007; Reyes, 2017). Hypereutectic Al-Si alloys are widely used and researched in the automotive and aerospace sectors due to the low coefficient of thermal expansion, resistance at high temperatures, good wear resistance and high strength (Reyes, 2017; Tebib, 2013). Above the equilibrium eutectic composition (~12.5wt.%Si) the amount of primary Si particles becomes significant (Lasa, 2003). In the place of conventional hypoeutectic Al–Si, there is growing interest in hypereutectic Al–Si alloys as a candidate material for the high-quality engines because a higher volume fraction of silicon may bring about superior properties (Matsuura, 2003)"

Jan 1, 2017

By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By T. G. Ewart

INTRODUCTION FOR THE purpose of this paper, western bituminous coal is defined as steam coal produced in Alberta and southeastern British Columbia for sale primarily to railways and industries. Before examining present and future markets of this industry, it is proper to review briefly financial and operating conditions within the industry. The report of the Royal Commission on Coal, 1946, supplies financial data from which some conclusions may be drawn. In 1944, the industry as defined above had share capital of $24,886,696. In the fifteen years 1930 to 1944, inclusive, the industry produced: 44,364,211 tons of coal. The profit on this tonnage amounted to $4,678,382.58, which represented 10.6 cents per ton of production. Miscellaneous earnings increased the amount available for dividends to shareholders to a total of $8,487,952.41, which is equal to, 19.1 cents per ton of production. Dividends actually paid in this fifteen-year period amounted to $12,332,040.64, which represented an annual average rate of 3.40 per cent on share capital. It is worthy of note that, in 1944, the net current position of the industry, including investments, was $8,753,874.51. The writer believes that the financial position of the industry with respect to capital, current financial position, and net earnings, has not significantly changed from the fifteen-year period out-lined above. The figures quoted indicate the following situation: (1) The western bituminous coal industry is adequately financed. (2) The industry has followed a conservative dividend policy and has accrued funds for contingencies. (3) The industry has sold its production at very reasonable prices as evidenced by its moderate earnings per ton of production.

Jan 1, 1951

By Fathi Habashi

The year 1987 marked the centennial of the beginning of modern hydrometallurgy. On October 19, 1887 British Patent No. 14174 entitled Process of Obtaining Gold and Silver from Ores was issued*. The discovery was made by John Steward MacArthur (Fig. 1), a chemist-metallurgist, supported and assisted by Robert and William Forrest, two brothers practicing medicine in Glasgow. The discovery was made in the basement of their clinic. The process, which became known as the cyanidation process in reference to the alkali cyanide reagent used, immediately received industrial success in New Zealand in 1889 and in South Africa in 1890t. It displaced the chlorination method which had been in use. In 1903 MacArthur was awarded the first Medal of the Institution of Mining and Metallurgy in London1131 - The cyanidation process was responsible for the doubling of gold production in the world in the two decades which followed its first application (Fig. 2). To the modern metallurgist, it may be surprising to think of MacArthur coming across an obscure reagent such as an alkali cyanide as a leaching agent for gold ores. It is the purpose of this paper to discuss the background and the factors that led to this invention, the development of the understanding of the process, and the application of modern technology.

Jan 1, 1999

By J H. Dressel, J. E. Williams

This paper presents a brief review of what coal gasification is, procedures that are available today and processes that may be available in the future. Examples are given as to how the process might be used in power plant applications, the effect on pollution level and power costs, and some thoughts on the added burden that might be placed on mining and coal preparation.

Jan 1, 1973

By G. K. Quainoo

In the automotive industry, the awareness to meet Corporate Average Fuel Efficiency (CAFE) standards has evolved the need to reduce vehicular weight in new automobile designs, with the overall goal of reducing gas emissions into the atmosphere (Kyoto protocol), One efficient method has been to use lighter materials such as aluminum in outer body panels, Heat treatable AA6111 is one of the materials employed due to its unique combination of formability, paint bake strengthening and superior corrosion resistance characteristics, Researchers have applied various thermo-mechanical processes on 6000 series aluminum alloys and have found an improvement in the mechanical properties of these alloys, For a formed and painted automobile panel, the final mechanical properties involve a combination of strength components arising from cold work, strain aging and precipitation minus recovery. In this study, the evolution of microstructure resulting from the interaction of cold work and precipitation in AA6111 has been studied by means of transmission electron microscopy (TEM) after subjecting samples to various heat treatments, tensile testing and differential scanning calorimetry (DSC), This has been done to understand the evolution of microstructure and its influence on the properties of the alloy, The results show a considerable improvement in strength with a corresponding increase in strengthening precipitates with increasing level of cold work in the alloy. DSC results following the application of various levels of cold work also show acceleration in the precipitate phase formation, as precipitates are observed to form at lower temperatures, with increasing level of cold work/

Jan 1, 2005

By H. W. Parsons

Several low-temperature, dry chlorination processes for the treatment of sulphide minerals are reviewed, in a chronological order. These processes include the following: the Swinburne-Ashcroft, Baker-Burwell, Maim, Comstock-Wescott (Aldermac) and the Mitterburg Mining Process. Dry chlorination investigations at the Canadian Mines Branch (now CANMET) and the U.S. Bureau of Mines are discussed, as is a proposed process by the South Africa National Institute for Metallurgy. The techniques used in the process are discussed, as are the shortcomings, problems and failures of the methods.

Jan 1, 1978

By Dao Dac Tao

The Vietnam coal industry in recent years has achieved the rapid growth. However, in the process of industrialization and modernization of the country, the demand for coal for energy is constantly increasing. This paper presents the Vietnam coal industry in the last stage: the opportunities and challenges facing the coal industry as it strives to become modern, highly effective and capable of meeting the demands of national energy security, all in harmony with socio-economic and environmental needs.

Aug 1, 2013

By C. A. Jeffrey, K. Pearson

Abstract - The Croft diorite in central England belongs to a suite of Caledonian igneous rocks collectively known as the South Leicestershire diorite complex. Although the intrusions occupy separate outcrops, they are linked at depth to form a single pluton, buried beneath a cover of Triassic sediments (Le Bas, 1972; 1982, Allsop and Arthur, 1983). Both the Caledonian diorites and the overlying sub-Triassic unconformity have been affected by a complex history of alteration and mineralization which can be subdivided into four stages: (1) deuteric effects, caused by the release of volatiles during magmatic cooling; (2) albitization through sodic enrichment; (3) formation of lowtemperature laumontite, analcime and calcite veins with associated wall-rock alteration to prehnite and pumpellyite; and (4) sub-Triassic unconformity-hosted base metal, manganese and palygorskite mineralization. Zeolite mineralization occured some 200 Ma later than the intrusion itself, during post-Triassic times, as indicated by the presence of a single vein of laumontite and microcrystalline calcite which cross-cuts the sub-Triassic unconformity surface and enters the overlying Triassic sediments. Evidence from fluid inclusion work indicates that two fluids were involved in the deposition of the zeolite veins. One fluid was initially of relatively high temperature (~100°C to 320°C) and low salinity (~0.2 to 5.9 wt% NaCl equiv.), and was probably meteoric in origin, whereas the other was of relatively low temperature (~41°C to 165°C) and high salinity (~0.4 to 16.72 wt% NaCl equiv.), and is interpreted to represent a basinal brine. During Triassic rifting, thinning and fracturing of the crust, with the possible rise of associated magmas (Halliday and Mitchell, 1984), could have increased permeability and heat flow, initiating the circulation of hydrothermal fluids. Triassic unconformity-hosted base-metal mineralization in Central England is similar to other Triassic-Jurassic mineralization in Europe (Mitchell and Halliday, 1976).

Jan 1, 1997