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By Ana Paula de Andrade Manfridini

A formação de nitretos na superfície de aços Interstitial Free (IF) nitretados a plasma em função da temperatura de tratamento foi investigada. Amostras de aço IF estabilizados ao Ti, laminado a frio e com shot peening foram nitretadas a plasma nas temperaturas de 450°C, 475°C e 500°C durante 4 horas. A camada nitretada resultante foi caracterizada por microscopia eletrônica de varredura (MEV), difração de raios-X (DRX) e método Rietveld. As imagens de MEV revelaram duas principais regiões na camada nitretada formada nas três temperaturas de tratamento: uma camada de compostos constituída de ?-Fe2-3N e ?’-Fe4N e uma camada de difusão apresentando uma matriz ferrítica com finos precipitados de ?’’-Fe16N2. Através da DRX, foi observada uma variação na proporção das fases ?-Fe2-3N e ?’-Fe4N. A partir de análises Rietveld, foi sugerido que a maior temperatura de nitretação facilitou a formação de nitretos ?-Fe2-3N, uma vez que a quantidade dessa fase aumentou de 475°C para 500°C. A presença deste precipitado com maior teor de nitrogênio sugere uma possível maior aplicabilidade dos aços IF.

Aug 16, 2017

By Chad B. Donovan

There is a strong need in North America and other major steel producing markets where major capital investment in new equipment has been minimal over the past several years to make improvements to existing casting machines. In many cases, very cost effective improvements can be made to existing equipment in order to maximize the efficiency and production of an older designed continuous caster, a classic caster. SMS Group and its predecessor companies have been maintaining continuous casting molds for over forty years. This experience has allowed SMS Group to intimately understand the advantages and disadvantages of each design. The most vital component of the continuous caster is the mold copper design, as it has the most influence over the ability to cast a quality product. Updating to a modern copper design is less complicated than most steel producers think and the benefits are significant. Premium mold coatings such as UniGuard® and NanoGuard® allow casters to guard against exposed copper and wear while producing quality products for record campaign lengths.

Oct 30, 2017

By Andrew Slifka, Pello Uranga, Douglas Glenn Stalheim

Structural steel final mechanical properties of strength and ductility are predominately generated by the final ferrite grain size/packet size and homogeneity of that ferrite grain size/packet size through the cross-sectional area. Forty to seventy percent of the strength components come from how fine the final cross-sectional ferrite grain size/packet size that can be produced.[1] All the ductility properties of structural steels for a given microstructure are predominately driven by how fine AND homogenous the final cross-sectional ferrite grain size/packet size can be refined.[2,3,4] One key ductility property of structural steels used in construction and energy transmission applications is fatigue. Both low and high cycle fatigue can be realized in these end applications, however, low cycle fatigue is typically the predominate mechanism. In construction applications the environment for fatigue is typically air, such as in wind towers or high-rise building construction. In energy applications, there is an interest in high pressure (5.5 – 21 MPa, 800-3000 psi) gaseous hydrogen as an alternative fuel source to fossil fuels. A project to study the effect of the cross-sectional grain size/homogeneity of a relatively pure polygonal ferrite microstructure on the fatigue performance in air and high-pressure gaseous hydrogen has been developed. This paper will discuss the project strategy, microstructure developed for the project and initial test results.

Oct 1, 2019

By Franz Reufer

At Rogesa in Dillingen, Germany, a joint venture company of AG der Dillinger Hüttenwerke and Saarstahl AG and at Salzgitter Flachstahl GmbH in Salzgitter the sinterplants are equipped with the Paul Wurth EFA™ process for the final sinterplant off-gas cleaning. In Dillingen two and in Salzgitter one EFA™ plant are in operation at the respective sinterplants to comply with the very stringent environmental rules prevailing in Germany according to the German Clean Air Act called “TA Luft”. The main target is to eliminate or reduce emissions like dust, sulfur components, dioxins/furans and others in the sinter process off-gas. Since 2006 and 2011 the two EFA™ plant are in operation at Rogesa while the EFA™ plant in Salzgitter was also commissioned in 2011. These installations significantly contribute to the improvement of the emission situation of the Dillingen and Salzgitter Works. The EFA™ technology is the state-of-the-art process for such kind of application in terms of additive and energy consumption, reliability and availability. The report gives an overview of the EFA™ process and the performance results of the Dillingen and Salzgitter plant.

Aug 1, 2018

By Caruline de Souza Carvalho Machado

Tensões residuais podem ser muito prejudiciais ao desempenho de um componente, tornando sua quantificação e avaliação extremamente uteis. A difração de raios-X é um método de análise não destrutivo que permite avaliar as tensões sem comprometer o material. Neste trabalho, tiras de aço duplex UNS S32304 com 1,8mm de espessura foram cortadas nas dimensões 36x72mm e soldadas de modo autógeno através do processo TIG. Produziram-se dois tipos de amostras variando-se o gás de proteção a saber: mistura de argônio 98% e nitrogênio 2% e argônio 99.995%. Utilizou-se um difratômetro com geometria Bragg-Brentano, fonte de radiação CuKa ( = 1,5419Å). A técnica sen2 ? foi empregada para determinar a tensão residual da fase austenita no ângulo 2?=146.22°. Os resultados mostram um estado de tensões residuais trativo nas proximidades da zona fundida, chegando a um estado compressivo em regiões distantes. A análise comparativa dos perfis de tensão residual revela que a amostra soldada apenas com argônio apresenta menor tensão residual trativa na zona fundida.

Aug 8, 2018

By Werner Klein

The utilization of production facilities in an optimum way, with reliable due date fulfillment, reducing raw material and energy consumption, are challenges iron and steel companies are facing in their business every day. By using an APS system such goals can be achieved to increase the competiveness of iron and steel producers. A sophisticated APS supports the overall planning process by applying complex rules based on product and order mix, its production routings with corresponding processing and transport times and resource availability. Specific technological as well as steel grade and energy related constraints are also considered to meet company specific KPIs. A core feature of APS solution is to react online on deviations to plan during the production process. Deviations such as nonconformance of intermediate material attached to an order, sudden production delays, unavailability of important production resources, makes it necessary to update the production plan. In general the task of APS is to support the preferred work-to-order concept, by assigning work-orders to available production facilities along the product specific process route and generate optimized material sequences for critical work centers.

Aug 17, 2017

By Lucas Ribeiro Ramos

Este trabalho investigou as alterações microestruturais e de dureza em amostras da liga eutética Al-11%Si-5%Ni submetidas ao tratamento por refusão superficial a laser (RSL). Nos tratamentos, foram realizadas seis combinações de parâmetros de velocidade de varredura (V) e potência (P) do laser. As seis trilhas resultantes do processo de refusão a laser foram examinadas por microscopia óptica para verificação da mudança das dimensões das trilhas, por microscopia eletrônica de varredura para averiguação do refino microestrutural e por ensaios de microdureza Vickers para verificação do aumento de dureza. Foi estabelecida uma correlação entre espaçamento dendrítico primário (?1) e microdureza envolvendo resultados do presente experimento RSL e outro envolvendo fundição convencional. A RSL foi eficaz no refinamento da microestrutura, formando dendritas de a-Al e região eutética interdendrítica, obtendo ?1 mínimo de 0,86 µm e elevação da microdureza em até 88% se comparada a microestrutura bruta de fundição.

Oct 30, 2017

By Anna Beatriz Almeida Leandro da Costa, Djalma Valério Ribeiro Neto, Flánelson Maciel Monteiro, Mauro Froes Meyer, Bruna Pereira do Nascimento Souza

As argilas são matérias primas fundamentais na confecção dos produtos cerâmicos. Na produção de revestimentos cerâmicos as argilas com baixa quantidade de óxido ferro (Fe2O3), que resultam em peças com coloração branca ou bege, são preferenciais. Esse tipo de argila não é comumente encontrado pela indústria, o que torna seu valor expressivamente mais alto. Portanto, o objetivo deste trabalho é analisar as propriedades tecnológicas de massas cerâmicas produzidas com uma argila caulinítica do município de Boa Saúde-RN para produção de revestimentos. O procedimento experimental teve início com a fabricação das massas cerâmicas usando a argila, quartzo, caulim, feldspato K e dolomita, todos materiais com granulometria de 0,074mm. O processo de compactação das amostras ocorreu em uma prensa hidráulica com pressão de 21 MPa. As peças foram secas em uma estufa e sinterizadas no forno do tipo mufla, sem atmosfera protetora, nas temperaturas de 1000°C e 1100°C, com taxa de aquecimento de 10°C/min e patamar de isoterma de 60 minutos. No total, foram confeccionadas quarenta (40) amostras, sendo vinte (20) por temperatura. As propriedades tecnológicas das amostras foram aferidas através dos ensaios de absorção de água (AA%), retração linear (RL%), perda ao fogo (PF%), porosidade aparente (PA%) e massa específica aparente (MEA). Os resultados dos ensaios apontam que a argila estudada pode ser destinada para o setor de revestimentos do tipo poroso.

Mar 1, 2019

By Johanna Alegría-Ortega

Cr/CrN bilayer coating was deposited on AISI 440C by Cathodic Arc. The composition and structure of the Cr/CrN coating were investigated by scanning Electron Microscope, X-Ray Diffraction and X-ray Photoelectron Spectroscopy. The results show that crystal structure obtained was CrN phase with preferred [220] orientation. The hardness and adhesion of coating also were studied. The evaluation of erosion-corrosion (EC) on 440C bare and coated with Cr/CrN was performed by carrying out wear tests using a slurry jet with impingement angle 90° at 4 and 8 m/s. Corrosion, erosion and synergism wear rate were evaluated following the procedure described in ASTM G-119-09. This study presents that the synergism wear rate exceeds 40% of the total mass loss for coating and 60% of mass loss for the 440C, being the most aggressive wear component. The increase in impact velocity generated a rise in mass loss for both 440C bare and coated. The Cr/CrN coating offers better corrosion and erosion–corrosion resistance under all the tested conditions.

Aug 8, 2018

By Marcela Gotelip Barbosa

Pellets are the main iron input to the blast furnace at ArcelorMittal Lazaro Cardenas iron and steel making facility in Mexico. Pellets are made at this facility using the concentrates generated and shipped from their captive mines viz., Las Truchas, Pena Colorada, Volcan Sonora. The concentrating plants, after grinding the ore to the liberation size, use magnetic separation and flotation to reject the silica, sulphur and phosphorous impurities. At Volcan Sonora Mines, the ore is contaminated with phosphorous minerals, and hence, after magnetic separation, the phosphate minerals are floated using anionic carboxylate collector (sodium oleate). Apart from floating the phosphate minerals, the sodium oleate also has some tendency to smear on the iron bearing mineral surfaces leaving a hydrophobic surface, which is expected to reduce the green pellet strength due to absorption of ultrafine sized air bubbles on these surfaces, and further generate higher levels of dust during the induration process. In order to alleviate this industrial problem, comparative studies were carried out on the concentrates from magnetic separation using reagents from synthetic sarcosinate and carboxylate family collectors. Results have indicated that the sarcosinate family members not only were found as replacement to carboxylate collectors, but also reduce the phosphorous content below the values achieved with oleate, thus have considerable benefits in the downstream steel making process. Based on the results, plant runs are being taken up at Volcan Sonora. In this article, the laboratory results obtained on iron grades and recoveries, and phosphorous rejection using both the reagents are presented.

Aug 1, 2018

By "Andreas Steinwandter

The demand for increasing energy efficiency and CO2 reduction is one of the global megatrends of our time. Although the steel industry suffers from a volatile economic environment, the steel plants are interested to find opportunities for sustainable cost reduction and put efforts into healthy solutions for the environmental. Integrated steel plants are trying to cut electrical power and energy costs as these are among the biggest cost factors that can be influenced and taking all the advantages they can. For the integrated iron and steel making route the interaction of waste energy utilization along with process energy demand, natural and metallurgical gases, steam and heating systems as well as power generation has to be considered. Potential energy sources, such as sinter plant, basic oxygen furnace (BOF) cooling stack or reheating furnaces are considered in order to elaborate an integrated energy concept. Especially electric power generation is an attractive option for steel plant operators since it can easily be connected to the existing power grid of the steel plant. When direct local use of waste heat is limited, the best option is to convert it to mechanical/electrical power with a Rankine Cycle. A stand-alone system, compact design with minimum operational costs in order to fit into the existing steel plant layout, are the main requirements of such units. The objective of this paper is to demonstrate economic feasible opportunities for energy recovery for sinter cooler and basic oxygen furnace with focus on electric power generation via ORC modules taking at the same time advantages of CO2 reduction by utilizing waste heat from the process. Furthermore typical arrangements and layouts of such solutions as well as basic economic calculations will be presented in the paper.

Oct 30, 2017

In today’s competitive steelmaking environment, the optimization and continuous supervision of the blast furnace process is of major importance. Modern probes and process measurement systems can assess the specific operation of the blast furnace. They provide a better and detailed process understanding and control. The benefits are even more important when they are combined with process models and expert systems. Everyday operation, productivity and even the lifetime of a blast furnace can be significantly improved by collecting, interpreting and acting upon such process data correctly. Only a comprehensive knowledge of the various process phenomena together with measurement of process variables inside the blast furnace enables the operators to optimize coke and fuel rates, to run the blast furnace smooth, reliable, and safe, and to make best use of the available raw materials. While the improvement of the blast furnace process with respect to productivity remains the main task, also, the timely identification of abnormalities and the assessment of process variations is an objective. This paper describes the blast furnace measurement systems that are available for everyday automatic use and provides an understanding for the possibilities of modern probes. The different applications are daily blast furnace supervision, charging process optimization, and observation of the internal state. Finally, the paper gives recommendations on probe configurations for different blast furnaces sizes, considering both a technical and an economical point of view.

Aug 2, 2018

By Viviam Serra Marques Pereira

Aços ARBL são utilizados na fabricação de tubos para transporte de gás natural e petróleo e, devido ao ambiente agressivo, rico em H2S, em que são aplicados, devem resistir à fragilização por hidrogênio. No presente trabalho, verificou-se qual a influência do alongamento longitudinal dos grãos de um aço API X65, com baixo Mn, sobre a permeabilidade de hidrogênio. O material foi caracterizado com a utilização dos microscópios óptico e eletrônico de varredura e os ensaios de permeabilidade foram conduzidos com base na norma ASTM G 148-97. A microestrutura do aço era composta por ferrita e perlita, com baixo teor de inclusões arredondadas de Al e Ca e sem bandeamento. Com os resultados obtidos a partir dos ensaios de permeabilidade, calcularam-se os coeficientes de difusão efetiva do hidrogênio nas seções longitudinal e transversal do aço, e o valor do primeiro se mostrou levemente superior ao do segundo. Isto indica que pode haver influência do alongamento longitudinal dos grãos sobre a permeabilidade de hidrogênio.

Aug 16, 2017

By Norbert Asamer, Stefan Purrer

Depending on the product or the material grade, conventional deburring machines, such as e.g. with rotating hammers, are in many cases not capable to reliably or completely remove burrs from the edges of a continuously cast product. Burr, however, is generated at the front and/or tail ends of a slab, bloom or billet as a result from torch cutting. Likewise, traversal grinding of the slab’s rolling surfaces can also cause burr at the long side edges of the slab whereby such burr can even be more difficult to remove. Based on their experience and know-how with abrasive machining processes (abrasive cutting, high-pressure grinding) over a period of more than 50 years up to now, BRAUN has developed a highly flexible deburring grinding machine for applications which are too difficult for conventional deburring techniques. BRAUN’s deburring grinding machines were successfully introduced to the steel industry and have proven their worth under normal production conditions already. The subject paper describes the key features and advantages of BRAUN’s machine design and the operational results from the first already completed projects.

Oct 1, 2019

By Evandro Tolentino

As fibras vêm sendo empregadas nos materiais de construção civil desde o início da humanidade. No começo da década de 50 houve o início da utilização de fibras de aço no reforço de matrizes de cimento. Com isso foram notadas alterações no comportamento do material, sendo detectado o aumento da tenacidade pós-fissuração. Esta é uma pesquisa experimental que teve como objetivo a definição de parâmetros de ensaios para a produção de argamassas de cimento Portland, que utilizem fibras de sisal nas suas composições, tratadas quimicamente por acetilização com intuito de reduzir a absorção de água. O sisal (Agave Sisalana) apresenta boas propriedades físicas e mecânicas. As fibras foram cortadas manualmente nos comprimentos de 20 mm. As diferentes composições de argamassas foram produzidas com 0,2% e 0,4% de fibra de sisal, em relação ao volume total da argamassa. Estudou-se o comportamento mecânico dos compósitos com ensaios de resistência à tração na flexão. Os resultados mostraram uma melhoria na resistência à tração na flexão para argamassas com fibras tratadas quimicamente por acetilização.

Oct 30, 2017

By Antonio Esposito

Saving energy and reducing pollution by minimizing emissions are today great challenges in the coking industry worldwide. In order to achieve satisfying results, equipment as well as technology should be continuously improved and updated. The most modern design tools should be adopted to maximize the coke production rate also ensuring the best coke quality. In this scenario, Paul Wurth is realizing the new coke making plant of CSPecem, Ceara - Brazil. These batteries are based on Paul Wurth “jumbo oven concept”. This solution incorporates all most modern features and design upgrading, in the aim of an easy and long-lasting operation putting a particular attention to environmental performances: the reduced number of ovens and the low number of pushing per day have the main effect of reducing pollution sources. Finally the paper will highlight Paul Wurth SOPRECO® System, which is foreseen to be installed in CSPecem batteries. SOPRECO®, which is capable of controlling the pressure for each individual oven in a coke oven battery, is thus able to reduce volatile emissions through doors, roofs and stand pipes up to 90%. The coke oven gas (COG) produced during the carbonization process is cleaned in a coke oven gas treatment plant to the level stipulated by applying the Best Available Technology (BAT).

Aug 1, 2018

By Paul Riches

Today’s steel producers face the dual challenge of ensuring on-time delivery and ever demanding product requirements, while also running a lean operation. Every day the management of a long rolling plant requires continuous optimization of both operating and business practices. Imagine a long rolling facility, where individual pieces of equipment communicate with each other, where sensor information can be used not only for control purposes but to also monitor the condition of the equipment, where models are used to verify the process is within working limits and the equipment raises alerts to operators when it requires maintenance! Utilizing the ongoing evolution in technology though data collection, communication, internet of things, control techniques and smart sensors, there is now more information available than ever before. The collection and analysis of this information will both advance control and monitoring of plant performance; revolutionizing long rolling mill plants worldwide and optimizing the entire value chain, along with improved and more flexible production.

Oct 30, 2017

By Lorena Cristina Amorim, Iara Patrícia Vieira de Oliveira, Leandro Rocha Lemos, Guilherme Liziero Ruggio da Silva, Erick Mitchell Henrique Braga, Paulo Santos Assis

No atual cenário acirrado de competitividade, umas das linhas para redução do custo da mistura de carvões é o desenvolvimento de matérias-primas alternativas nacionais que minimizem o custo do coque e mitiguem a emissão de CO2. O presente trabalho avaliou a utilização de resíduos de shredder (fluff) como aditivo nas misturas para a produção de coque metalúrgico. A utilização de fluff na mistura de carvões minerais sugere uma rota de destinação ecologicamente correta, a fim de mitigar o impacto causado pelo acúmulo desse resíduo no meio-ambiente, além de uma alternativa para redução de custos de produção do coque metalúrgico. Foram realizados enfornamentos, em escala piloto, com adição de fluff, com objetivo de avaliar o impacto sobre a qualidade do coque, especialmente sobre a Resistência após Reação com CO2 (CSR) e a Resistência Mecânica a Frio (DI150-15). Os resultados mostraram a viabilidade técnica da adição de até 1% em massa do material, mantendo a qualidade metalúrgica do coque produzido.

Oct 1, 2019

By Isabela Costa Mendes Peres

As soldas dissimilares de liga de níquel 182 são utilizadas em usinas nucleares para conectar tubulações de aço inoxidável com componentes fabricados em aço de baixa liga. O procedimento envolvido na soldagem dissimilar pode modificar as propriedades do material, o que afeta diretamente a junta soldada no sentido de aumento da probabilidade de incidência do processo de corrosão. Neste trabalho foi realizado a soldagem dissimilar de corpos de prova dos aços de baixa liga e aço inoxidável austenítico AISI 316L com as ligas de níquel 82 e 182. Estudou-se o comportamento frente à corrosão da junta de solda de liga 182 em ambientes ácidos contendo NaCl e Na2S2O3 empregando-se técnicas eletroquímicas. Ensaios de polarização anódica potenciodinâmica foram utilizados para caracterizar o comportamento de corrosão localizada do material. Os resultados mostraram que o comportamento eletroquímico da junta de solda está relacionado com o aporte térmico e a presença ou não de oxigênio no meio.

Aug 8, 2018

By Wen Xuan

Oolitic iron ores have significant economical importance because of their extensive resources in the world. However, their utilisation is often quite limited due to the high content of phosphorus inside. The phosphorus is often finely disseminated in the oolite structure and generally not liberated in the form of free particles. The iron ore used in this work is a typical oolitic goethitic iron ore with high phosphorus. The process of phosphorus removal from this ore is difficult because the phosphorus is not present as distinct minerals. As a result, no physical beneficiation process is able to separate the phosphorus from the iron bearing phases. The current concentrate contains low iron grade (Fe ~49%) and high phosphorus content (P 0.7~0.8%). The acid leaching is a potential way to dissolve phosphorus. Previous studies have shown that the thermal treatment makes the phosphorus more accessible for the acids and enables more efficient phosphorus dissolution. Some chemical additives are reported to enhance this phenomenon. A series of tests have been carried out using roasting - grinding - magnetic separation - leaching technologies to remove the phosphorus from this current concentrate. In the first stage, several tests were performed at pilot scale under the same conditions as described in some publications. The achieved results were similar to those from previous tests at laboratory scale. In the second stage, new test conditions were investigated in laboratory scale in order to achieve better result and to reduce the operational cost.

Aug 1, 2018