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In a previous paper the author showed that silver considerably delayed the recrystallisation of lead after cold work. The effect of antimony on the rate of recrystallisation of distorted lead was studied next, and the experiments performed, and the results obtained, are described in this paper. Electrolytic lead was used as a standard of comparison.It was also used to make the lead antimony alloys.This electrolytic lead contained 0.0005% total impurities.It was prepared from commercial lead by fire refining, followed by electrolysis and finally by vacuum casting. The process was described in the previous paper and the description need not be repeated here. PREPARATION OF LEAD - ANTIMONY ALLOYS.The steps taken to procure pure antimony are outlined in the appendix. To make the lead antimony alloys a mother alloy was prepared thus:-A quantity of the antimony (it was received in the powdered form) was placed in a pyrex glass tube, which was closed at one end. The antimony was washed with hot hydrochloric acid (1: 1), then with more dilute acid, then with distilled water, and finally with absolute alcohol; it was dried by warming and evacu,ating the tube. This should leave the antimony more nearly free from surface oxides.The amount of antimony was determined by weighing quickly; the appropriate amount of vacuum-cast electrolytic *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

By H. Thomasson

THE war, like all destructive agencies, has focused attention on salvage and conservation, and to such an extent that a decade of normal progress has been crowded into a few months. This is particularly true as regards the repair of cutting tools. As a consequence, there has arisen a wide demand for comparable data by those engaged in such work, and for basic information by others who wish to repair tools. These repairs may be grouped in three classes: (1) The repair of broken tools of relatively slender cross-section, such as broaches, reamers, drills, etc., of a type that could be returned to service if a means to join the broken surfaces were available, as fortunately it is in the low-temperature silver solder process; (2) the repair of tools that possess shanks, tangs, and other non-cutting portions that may be broken or damaged to the extent that only the addition of metal will permit their return to service; and (3) the repair of special rotating tools, such as end-mills and milling cutters, that may have portions broken from the cutting edges or have their edges so worn in service as to require building up.

Jan 1, 1943

By I. R. Kramer

I. R. Kramer (Martin Co.)—In a recent paper Nakada and Chalmers24 reported some observations of effects of surface conditions on the stress-strain curves of aluminum and gold single crystals. It is of interest to compare these observations with the results published previously in this journal and to comment on their general conclusions. In brief, Nakada and Chalmers concluded that the removal of the surface layer of a prestrained specimen lowered the stress-strain curve for aluminum but not that for gold. Further, they concluded that the surface work hardening of aluminum is confined to a depth not more than l0-3 cm. In our results25 published previously, it was pointed out that when prestrained specimens of aluminum and gold were polished to reduce the thickness upon reloading the initial flow stress decreased markedly. Further if a sufficient amount of metal was removed, the yield point failed to appear. With continued application of the load the stress-strain curve became coincident with that of the virgin crystal. We have found this behavior in some 100 determinations to hold consistently for gold, aluminum, and copper in both single and poly-crystalline specimens. The amount of strain required before the curves coincided depends upon the amount of metal removed but it is usually less than 0.01. This type of behavior is the same as that reported for metarecovery by other investigators.29 For aluminum specimens which have been prestrained and then heated to temperatures above 50°C we have consistently found that the stress-strain curve was typical of the orthorecovery28 type. In this case the stress-strain curve always lies below that of the virgin specimen. With respect to Ref. 24 the curves for aluminum are always below that of the virgin curves, while those for gold become coincident. This observation indicates at least for aluminum that the specimens must have been heated to a temperature high enough to cause recovery by an alteration of the internal dislocations. In addition, a recovery would be expected because of the removal of the surface work-hardened layer. Nakada27 had reported that, with his particular apparatus in which a perchloric acid polishing solution was used, the temperature of the specimen increased 65°C. The curves presented in Ref. 24 for gold do not permit one to detect the initial flow stress upon reloading after the surface-removal treatment. In fact, contrary to the method used by Nakada and Chalmers, the change in the stress-strain curve produced by a surface-removal treatment cannot be described in terms of a decrease in stress at strains much higher than that at the initial flow stress because of the coincidence of the curves at the higher strain values. With regard to the depth of the work-hardened surface layer, our data show for aluminum single crystals (7.5 by 0.3 by 0.3 cm) that the initial flow stress remained constant after 12 x 10-3 cm had been removed from the thickness. This depth was independent of the prior strain. For gold crystals this depth is somewhere between 10 x 10-3 and 20 x 10-3 cm. Y. Nakada (author's reply)— Kramer states,28 "for aluminum specimens which have been prestrained and then heated to temperatures above 50°C, we have consistently found that the stress-strain curve was typical of the orthorecovery28 type. In this case the stress-strain curve always lies below that of the virgin specimen." However, Cherian et a1.26 discovered that aluminum polycrystals annealed at 32" and 100°C showed the metarecovery behavior. They showed that the orthorecovery behavior did not appear until the crystals were annealed at 150°C. Kramer suggests28 that the drop in the flow stress of aluminum crystals after the surface removal by electropolishing24 may be due to the recovery caused by the temperature rise which may occur during the electropolishing.27 However, as indirectly stated in Ref. 24, the current density used in these electro -polishing experiments was 0.15 amp per sq cm. According to ref. 27, this current density should cause a temperature rise of only 40°C. This may cause the metarecovery but not the orthorecovery. Furthermore, as stated explicitly in Ref. 24, the surface removal was accomplished by chemical etching as well as by electropolishing. The results were the same for both electropolishing and etching. During the etching, the specimen temperature did not rise above 35°C. Some aluminum crystals were placed in water at 35° C for 30 min. These crystals did not show the decrease in flow stress. Therefore, it is quite clear that the flow-stress drop after the surface removal is not caused by a high-temperature recovery. However, as Kramer points out,28 it is quite possible that the internal dislocation structure may have been altered because of the removal of the highly work-hardened surface layer. However, how much this rearrangement contributes toward the flow-stress decrease is not known at present.

Jan 1, 1965

By T. R. Wildeman

"At the Big Five wetland, which was built to treat drainage from a metal mine, encouraging results have attributed to sulfate reduction. Cu and Zn were reduced to below detection limits of 0.50 mg/L, Fe was reduced by at least 90% to below 3 mg/L, and the pH was raised from below 3 to above 6. The study showed that treatment was primarily through microbial processes within the substrate and that plants were not needed to insure success.Constructed wetlands can be taken through design and proofing stages, and into operations scale in a meaningful time frame for on-line acid drainage remediation. In staged design, laboratory experiments are initiated to determine reasonable substrate materials for remediation of a particular drainage. When a reasonable substrate is found, bench scale experiments are initiated as the next stage in the design. In these studies, removal efficiency, permeability, and flow are analyzed to identify candidate substrate which will support sulfate reduction and be hydraulically reasonable. Using this design method at one site, an acid drainage of pH 2.5 was raised to a pH of above 7. Total heavy metal concentrations in this drainage exceeded 900 mg/L. In the pilot constructed wetland Cu, Zn, and Fe were reduced by 99%.Determining how well these anaerobic cells operate in the winter is done at the pilot plant site in Idaho Springs, CO. It's been found that over the last four winters, those cells that emphasize anaerobic removal within the substrate have operated continuously and effectively the year round. Winter operation is aided by the fact that the water temperature of the acid drainage is always between 14 and 16° C, and the cell can be readily insulated from the cold. Activity of the sulfate reducing bacteria may decrease during the winter. However, it appears that organic complexation of metals helps to maintain low concentrations of metals in the effluent."

Jan 1, 1992

By Yuchen Wu, Jing Mei, GUOZHONG LIU, KE GAO, Songjie Tian, Jianwei Cheng, Yu Wang, Yuhang Wu, Hui Wang

The stability and integrity of protective coal pillars between the longwall working face and development roadways are greatly affected by the mining activities such as the development face advancing or retreat mining. Due to underground strata pressure, the coal pillar cracks could be further developed and then the air leakage passages (mainly cracks) could be produced greatly. The air circulation caused by the atmospheric pressure difference between the two sides of the coal pillar may also provide suitable conditions for the possible spontaneous combustion of the residual coal in the mine gob. In this paper, a typical the protective coal pillar in a Chinese coal mine is studied. The deformation and stress of coal pillars during the mining process of longwall working face are simulated by using FLAC3D. The displacement and strain of coal pillars are analyzed. Two indexes, the linear fracture rate (LFR) and area fracture rate (AFR), are introduced to characterize the development of internal cracks’ development within coal pillars. By using field measurement, the air leakage intensity distribution due to coal pillar cracks is obtained; the equation of air leakage resistance of coal pillar under the influence of mining is derived. Then, the possible location of large air leakage of coal pillar is determined, which can be used as guidelines to study the possibilities of coal spontaneous combustions happening in pillar or mine gob. The research results help to control such potential hazards in advance.

Jun 16, 2022

By III, Peter J. Rogers, J. Gordon Ogden

A study is described which attempts to identify the chemical factors of common concern to environmental and exploration geochemistry as indicated by recent work in both disciplines in Nova Scotia. Cores taken in lake sediments define geochemical baselines for the modern and pre-industrialisation periods. The investigation of lake and stream drainage indicates the presence of numerous chemical and organic factors that can be attributed to man's activities, such as construction and energy consumption. Geochemical surveys of lake and stream sediments are used to locate potentially toxic, high risk areas in Nova Scotia. Rapid change occurs in most surface drainage systems with the possibility of numerous chemical reactions taking place. It is found that spatial and temporal variations in the chemistry of modern and recent sediments are of interest to exploration and environmental surveys.

Jan 4, 1992

By Qingxiang Huang

Shallow seam coal field has the largest coal reserve in China. Mining in shallow depth causes serious problems. One of them is subsurface dewatering. In this paper, the physical simulating model was performed to study overburden movement and aquiclude stability in the shallow seam mining of Yushuwan coal field, China. According to the characteristic of clay aquiclude in the overburden, the proper simulation materials and proportions of mixture for simulating the plastic clay aquiclude layers and brittle bedrock layers were determined by the stress-strain tests. The physical simulating model was carried out to simulate the failure and caving process of the roof and overburden. Based on the simulating tests, it was found that the movement of clay aquiclude follows the movement of the underlying bedrock layers. The basic caving mechanism of the overburden roof strata was also presented. The tests also showed that the best way to control the stability of aquiclude is to reduce the subsiding gradient Ts. This research provides a foundation for further study on mining dewatering and water conservation.

Jan 1, 2006

By W. A. Lang

COAL of sub-bituminous rank underlies much of the plains area of Alberta. This coal is geo-logically young, and occurs in Belly River and Edmonton strata of Up-per Cretaceous age. Generally, the seams are flat-lying, but in some areas they may dip as much as 5 degrees. The overburden, composed mainly of glacial clays and sand-stones, may vary in depth from a few feet to several thousand feet. Recovery of the coal has 'been by drift, slope, and shaft underground mines, and by open-pit stripping operations. Production has been obtained from a large number of mines, most of which have been relatively small and with preparation equipment limited to a loading tipple with screening facilities, and a picking belt where high-ash materials can be removed from the larger sizes. The coal has been sold for domestic and industrial space-heating, for production of process steam, and for power generation. In re-cent years competition from natural gas, propane, and oil has seriously interfered with the production and marketing of sub-bituminous coal, especially with the disposal of the smaller sizes at a realistic price.

Jan 1, 1958

By Jerry Wallace

The goal: At an industrial site, sever a well pipe containing an interior obstruction in a timely, cost effective manner by using a shape-charge to cut through the casing more than 50 meters below ground surface from the outside, doing so while inside a larger pipe, without damaging the larger pipe. The problem: Pumps and retrieval tools stuck nearly 50 meters below ground surface inside a 305 mm diameter by 9.5 mm wall thickness water well casing. The well, depth of 185 meters, had to be inspected for contaminates then properly decommissioned before industrial expansion could take place overhead. The limitations: A 508 mm diameter pipe had been driven around the 305 mm pipe to a depth of 63 meters. The usable internal diameter of the larger pipe was about 480 mm while the smaller pipe had buckled at one point forming a 350 mm wide spot. The charge thickness was limited to less than one-half the difference. Additionally, water that filled the annular space between the two pipes had to be displaced for the charge to work properly. The solution: Enlist the support of the shape-charge manufacturer to design, build and test a charge to work under the conditions present, then make it work in the field.

Jan 1, 2000

By J. M. Dempsey, R. A. Litle

Asarco Incorporated’s Omaha, Nebraska refinery site and the City of Omaha’s downtown redevelopment projects are the perfect example of the marriage of the Brownfield and Sustainable Development strategies. Nebraska’s largest voluntary site remediation project created a focus point for redevelopment and has spurred over $1 billion in economic investment within a 1-mile radius of the site. Asarco was faced with options of very expensive and uncertain facility upgrades or a shutdown. Local leaders, Asarco, and regulators worked together to convert a controversial and complex site to a park-like redevelopment area with numerous long-term benefits to the City and the environment.

Jan 1, 2004

By N. Kumar Kittusamy

ALTHOUGH MANYSTUDIES HAVE SHOWN an association between operating heavy construction equipment and symptoms of musculoskeletal disorders (MSDs), little research has been performed that systematically characterizes the exposure of operating engineers to ergonomic hazards. This study evaluated: 1) vibration at the seat/operator interface;2) transmissibility of vibration in the Z-axis; 3) psychophysical ratings of vibration level and vibration discomfort; and 4) postural requirements of the job. Results indicate that the digging operation had higher levels of total weighted acceleration than high- or low-idling conditions. Transmissibility data showed that the seat amplified vibration, particularly in the lower frequencies. Seats demonstrated that they may not be sufficient in protecting operators from long-term effects of vibration exposure. High positive correlation was found among subjective ratings (vibration discomfort and vibration level), but moderate positive correlation was found between subjective ratings and quantitative vibration levels. Postural evaluations revealed that the operators were required to assume awkward postures of the neck, shoulder and trunk while performing their jobs. Work-related injuries and illnesses pose a continuing threat to the health and well-being of American workers. The construction industry has been historically recognized as having higher rates of fatality, injury and illness than other industries (McVittie285+; BLS). In 1994, an estimated 218,800 lost-work-day injuries were reported in the construction industry (BLS). Construction also had the second-highest incidence rate for sprains and strains. Although the industry has made progress since then, injuries and illnesses, including MSDs, continue to because for concern.

A key driver to the success of a tunnelling project (the project) is the management of hydrogeological risk. The hydrogeological risk, if not managed, may cause significant impacts on the overall performance of the project. Impacts may include groundwater quality impairment due to contaminant transport and acid drainage from disturbed geology to groundwater, and groundwater lowering. The groundwater lowering and quality impairment may cause tunnel failure, with consequences such as injury to humans, as well as reduced property and environmental values, potentially costing millions of dollars to sponsors of the project. Depending on the nature of the contaminants and level of hydraulic connection of bedrock fracture along the length of tunnel, the contaminant transport may reduce structural strength of the tunnel due to corrosive action of contaminants such as acid drainage. The groundwater lowering can lead to varying degrees of ground settlement, posing threat of tunnel collapse. The management of hydrogeological risk includes:detection of potential pathways for contaminants into and around the tunnel,identification of factors responsible for the lowering of groundwater, and development of strategic measures to control groundwater lowering and contaminant transport. The paper presents an in-house hydrogeological risk management model named Vedanta-THRM (tunnel hydrogeological risk management). The model uses Risk Management Standard AS/NZS 4360:2004 (Standards Australia, 2004), Pressure State Response framework developed by Organisation of Economic Cooperation and Development, and Interaction Matrices. The Vedanta-THRM identifies important characteristics, processes and events of potential hydrogeological risk and develops control measures for managing hydrogeological risk throughout the life cycle of the project. The Vedanta-THRM was applied for a project in the early stages of planning and found to be useful in assessing, evaluating and reducing the hydrogeological risk in a managed approach that potentially increased the performance of the project. The application results also provided management options for use by project sponsors and insurance industry, which included tunnel risk financing options and options for equity investors to choose among various returns under different tunnel credit ratings.

Jan 1, 2008

By Patricio Santis, Jacopo Seccatore

Artisanal and Small-scale Mining (ASM) is a prominent activity in the extractive industry: considering only gold, it produces about 20% of world market supply. Despite this fact, ASM is generally associated with negative aspects of its environmental impact, and operational research is generally neglected. This paper emphasizes the peculiarity of the drilling and blasting systems of small underground mines in selected South American Countries. Such Countries, while having large mineral deposits and well recognized large-scale mining activities, at the same time still present on their territory ASM activities that are archaic, highly inefficient and dangerous for the safety of its operators. This paper documents drilling and blasting activities from gold mining in Ecuador and Chile. First, are described the outdated and often non-rational techniques employed by miners, to provide a general framework of the current methods. Then, it is shown what can be improved and how the current methods can be modified. Finally, are shown some field applications and the comparisons of the results obtained. One case shows how blast pull efficiency can be increased of from 82% to 98% by changing non-rational applications of explosive products. Another case shows how, by rationalizing blast designs, drilling and blasting costs can be reduced by 9% per month, the advance by blasting increased by 29% and the blasting efficiency increased from 70% to 90%. Finally, it is concluded that examples of application show how operational improvements are easily applicable on the field, relying only on tools and resources of artisanal mining, but combining solid engineering bases with confidence-gain and respect for the experience of the miners.

By William R. Oakley

In order to best-discuss the met spar industry let me take the liberty to review our involvement, that is, my company's. Our organization has been involved in the fluorspar industry for approximately thirty-five years. We started our activity in Western Kentucky as a mining company and a beneficiator of spar, that is, grinding and grading. After a few short years, the mine became contaminated and rather than invest in a flotation plant, the property was sold and our spar activity was moved, primarily to Mexico. It was decided not to establish ourselves as a Mexican corporation, so, it was necessary to take the position of backer-financier of numerous mining operations. We served in this capacity for quite some time. We also built processing plants on the border in Texas, that is, sizing, grading, etc. in order to market into the steel industry. In 1957, generally speaking, fluorspar for the steel industry was purchased as gravel fluorspar with a maximum of 10% -1/16". The price of this material was $23.50 to $24.00 per ton f.o.b. railcar at the Rio Grande Crossings and about $26.00 or $26.25 f.o.b. barge, Brownsville, Texas. Usually the material was purchased on an effective basis. As you know, 2-1/2 times the silica total, subtracted from the total CaF2 gives the effective calcium fluoride. This was normally the extent of the chemical specifications. Consequently, material was shipped with no regard whatever, to anything other than effective units. The variations in material was absolutely unbelievable. In addition to this, quite frequently, cars were shipped, as they say in the industry, topped. This being, good material placed in the top of cars or barges over bad or low grade. The entire shipment may very well have met the effective unit spec, but the complete imbalance of the sub grade vs. the high grade more or less guaranteed that the consumer was probably using a great deal of low grade and therefore, his usage had to be way higher than it should have been. He came to the conclusion, that because of these conditions and the new technology developing in the steel industry, it was just a matter of time that the entire raw material industry would have to improve. Rather than spend our efforts directed to a substitute flux, we put together a sizing and grading plant in order to ship a controlled crude product, with independent laboratory analysis confirming size and quality. The age of control was started. We began shipping 70 to 72-1/2, 80 and 85 effective with sizing 1/2" by 2", 1" by 3", and 2" by 5" with absolute control on the amount of fines. A material with no fines was a premium product. Incidentally it sold for $24.50 -60 effective up to $28.50, $29.50 for 80 effective.

Jan 1, 1978

Your thoughts on the current status of the global minerals industries? The global economic, technological, social and political changes of the last two decades of the 20th century resulted in the emergence of a restructured minerals industry. This industry is now based on a new cost-cutting philosophy; utilization of modern technology; productivity gains rather than production tonnages; diversification of mineral markets; and globalization of exploration, mining and processing. Quantity and tons used to be the focus. The emphasis today is on remaining competitive in the marketplace by lowering per-unit production costs as much as possible. What factors and trends will impact the minerals industries in this, the 21st century? A number of parameters will impact minerals operations and shape the future sustainability and growth of the minerals industries. Increased demand for minerals will be accompanied by the demand for technical advancements. We will also see a continued emphasis on health and safety, environmental stewardship, and education and training. Let me elaborate.

Jan 1, 2002

By A. L. Engel

In previous reports5/ of ore-testing studies, tests made by established methods on typical ores selected as representative of certain mining districts have been described in considerable detail. In addition to established test procedures, such as screen analysis, chemical analysis, microscopical examination of ores and products, sink-and- float separation, gravity concentration, flotation, ,and magnetic separation with or without roasting, it was sometimes necessary to apply other methods, such as leaching, in instances where physical separations were not feasible.

Jan 1, 1940

By A. L. Engel

In previous reports5/ of ore-testing studies, teats made by established methods on typical ores selected as representative of certain mining districts have been described in considerable detail. In addition to established test procedures, such as screen analysis, Chemical analyses, microscopical examination of ores and products, sink-and-float separation, gravity concentration, floatation, and magnetic separation with or without roasting, it was sometimes necessary to apply other methods, such as leaching, in instances where physical separations were not feasible.

Jan 1, 1940

By Dunlop GA

Pilot Plant confirmatory testing of the treatment route developed in the Metallurgical Laboratory is an essential factor in the development of complex ore bodies. Objectives should be well defined to permit the efficient planning and cost effective operation of the pilot plant project. The primary objective for the pilot plant should be to confirm the viability of the developed flowsheet on a continuous basis, examining only major variables such as ore types, quantum changes in grind, comparison between bulk and sequential flotation circuits, use of flotation columns, evaluation of autogenous grinding and production of samples of concentrates for market evaluation. Secondary objectives may include the collection of engineering design data and the production of a comprehensive report to Bankable Document standards to provide technical support for capital financing. The complexity of the ore body and the scale of the final operating project together with the pilot plant objectives will determine the extent of the pilot plant operations. The level of expenditure associated with a pilot plant can vary, in total cost and as a percentage of the total development capital investment required to take the prospect from exploration to a producing mine. Factors contributing to expenditure are discussed. Associated with cost considerations is the level of confidence mining company investors can have that their capital investment will return dividends.

Jan 1, 1990

By S. Shi, J. Y. Hwang, B. Li

Silver, copper, and zinc are commonly known elements with antibacterial and antifungal capabilities. Attempts have been made to dope silver on minerals, glass, and ceramics and the resulting materials have been investigated for their antibacterial and antifungal properties. Since silver is expensive and very reactive, silver doped materials have been found inappropriate in some applications. Copper-vermiculite is investigated as an alternative. Vermiculite has high cation exchange capacity on the magnesium ion in the crystal structure. Copper ion may have a high tendency to replace magnesium because of similar charge interference and ionic radius. Copper-vermiculite is prepared by reacting vermiculite and copper chloride solution. By impregnating copper ions into the nanometer openings between the layers of vermiculite, it is possible to render the composite with antibacterial functions if the copper ions could be released gradually from the composite. The antibacterial efficiency of Cu-vermiculite against Escherichia coli was studied using the Halo method. The results show that Cu-vermiculite is effective for preventing the reproduction of the bacteria. Heat treatment of Cu-vermiculite at up to 400°C does not show significant changes in antibacterial activities.

Jan 1, 2002

By G. E. Murray

Introduction The development of the method for recovering zinc from lead blast-furnace slags at Trail is interesting and important in the history of both lead and zinc metallurgy. Many efforts have been made in the past, particularly in Germany, to make economic recovery of zinc from slag. The Pape process on Oker slags was successful and is being worked at the present time. More recently the Waelz process has come to the fore. One effort at Cockle Creek, Australia is of special interest in view of subsequent developments. This was re-ported in detail by Guy Courtney in 1920(1). It deserves mention as it shows how, as in many other instances in the metallurgy of lead and zinc, important pioneering work has been done in Australia. These experiments, started over 25 years ago, comprised reduction with coke, powdered coal, and eletrothermically in carbon-lined furnaces. The so-called slag eye furnace, which volatilised the metals from a blast furnace running with a hot top, was also investigated.

Jan 1, 1933