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By M. Cortie, L. Iorio

The amount of nitrogen contained in an austenitic stainless steel affects its properties significantly. The maximum content of nitrogen feasible in a range of experimental low-nickel austenitic stainless steels containing significant additions of copper is evaluated The nitrogen content is calculated based on published interaction coefficients, and by use of the FACT thermodynamic computer program and database. The differences between the two methods of prediction can be attributed to inaccuracies in the published interaction coefficients. The calculated nitrogen contents of some experimental alloys are compared with the actual nitrogen contents obtained when the alloys were produced in an induction furnace. The actual nitrogen contents obtained were higher than those predicted by either method, and this is believed to be due to a super saturation of nitrogen occurring in the melt, which was not relieved during the short period in which the charge was molten. It was evident that the experimental alloys can contain between 0,25 and 0,40 per cent nitrogen (depending on temperature, composition, and nitrogen pressure) when melted in a sealed induction furnace, and this is more than adequate for the purpose of forming and stabilizing the austenite phase.

Jan 1, 1994

The term geostatistics was introduced by Matheron (1960) to cover the development and application of mathematical and statistical models which take specific account of the spatial structure of a 'regionalised' variable. In ore valuation the relative positions of available ore values within an ore body or portion thereof, can only be ignored in the unlikely case where there is no significant pattern of association or correlation between them - that is, if they do not disclose any significant spatial structure. A structure might not be evident in the available data, e.g. where the spacing of the available values is relatively wide such as in surface drilling on a new deep gold mine. However, practical selective mining considerations could dictate the need for eventual underground valuation on a scale much smaller than that represented by this spacing and the possibility of a significant structure on such a smaller scale cannot then be ignored. Some spatial structure must be present wherever the average variability among the values of check ore samples from the same, adjacent or nearby grooves or of borehole cores from the deflections in the same borehole, is lower than the overall variability for ore values within the whole ore body. Another practical check on the presence of a spatial structure is where it is evident that there is or will be a significant variation in the ore grades for individual ore blocks. Any correlation between peripheral and follow-up internal ore block values also provides evidence of a spatial structure, and hence the regression techniques covered in §1.16-1.2 1 can be accepted as the first application of the geostatistical procedures. The spatial structure of a regionalised variable can be studied and measured by the pattern, usually a decreasing function, in the level of correlation or of the covariance between pairs of values as the distance or lag between the values increases, that is, by the correlogram or covariogram (Krige, 1968, 1969, 1976; and Fig. 18). In geostatistics, for various practical and theoretical reasons (Matheron, 1960, 1971), the measure most commonly used is the semivario- gram, which increases as the lag increases. The semivariogram and covariance values are interrelated and for the lognormal- de Wijsian pattern used extensively for gold ore valuation both measures as well as their relationship can be defined on a fairly straightforward basis. Provided the underlying as- sumptions are realistic, the choice of measure - correlogram, covariogram or semivariogram - will be dictated mainly by convenience. Paragraph 2.2 will cover some general geostatistical terms and $2.3-2.12 will deal mainly with the theoretical side of the lognormal-de Wijsian model for spatial structures. Wherever the relevant variable lends itself to normalisation via the 3-parameter lognormal distribution (see 51.9) the de Wijsian semivariogram model is also likely to be suitable and will provide substantial advantages in application. Various practical applications will be covered in Section 3. Although confined to the lognormal-de Wijsian model, much of the theory covered and the general approach is applicable to all spatial structures. [ ]

Jan 1, 1981

By B. Kruger

After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron. The iron-free (less than 1% Fe) converter matte is granulated and sent to the base metals and precious metals refineries for further processing. During the smelting and converting processes two distinct gas-strength gas streams are produced: ?The Peirce Smith converter off-gas contains 4%?9% SO2which is treated in a conventional sulphuric acid plant to produce 94% H2SO4. ?The electric furnace off-gas contains 0.9% SO2which was (until September 2002) vented through a 91- metre high stack to atmosphere. In October 2002 Impala Platinum commissioned a SULFACID® plant at its smelter in Rustenburg, which recovers the SO2from the electric furnace off-gasses into a weak sulphuric acid solution. The SULFACID® technology utilizes wet activated carbon to oxidize the SO2toSO3. The SO3reacts with the water on the catalyst and is washed off the catalyst bed as a sulphuric acid solution with up to 13 wt. H2SO4. The plant operates at 60ºC and at atmospheric pressure. The SULFACID® technology is widely used in the pigment industry. This is, however, the first application of the technology on electric furnace off-gas. Keywords: SO2, sulphuric acid, electric furnace, off-gas, SULFACID®

Jan 1, 2004

By M. Z. Naghadehi, F. F. Nasategay, J. Sattarvand, R. Battulwar, E. E. Gohari

After the recent increase in catastrophic failures of tailings dams such as the Burmadinho, Brazil failure in 2019, the mining industry has actively engaged in the stabilisation of tailings dams. Most of the tailings storage facility (TSF) guidelines suggest a laborious action that can be facilitated through imaging by unmanned aerial vehicles (UAVs). Although UAVs are not unknown to most mining operations, automated rill detection through aerial image processing is a new concept. This study utilises images from sites in the U.S. and employs semantic segmentation with a UNet architecture to detect location and size of these rills. The developed model can be used as a tool for monitoring surface erosion of TSFs.

Sep 1, 2021

By T. Mützea, L. Schützenmeister, G. Kacheb

High-Pressure Grinding Rolls (HPGR) are employed in cement plants worldwide. Although the technology has been mastered in the majority of applications, design-, scale-up- and operationalchallenges still exist today. In addition to modelling throughput, energy requirement and comminution success, the prediction and avoidance of malfunctions is of great importance in current research. The performance of the mill is highly influenced by the roll speed and the fineness of the feed material. Another parameter influencing the composition of mill feed is the circulating load, which is determined by the grinding circuit configuration, the target fineness and the separation efficiency of the classifier. In order to meet this circumstance and simultaneously maintain a reasonable level of material input and testing effort, a complete grinding circuit on a small technical scale was set up in the research centre of Thyssenkrupp Industrial Solutions AG. The present study varied the roll speed (0.5-2 m/s) and the proportion of fines in the feed (0-75 %) in order to investigate the influence of both parameters on the finish grinding of a Portland cement with a target fineness of 4000 cm²/g according to Blain. The experimental results are compared with model concepts and critically examined with regard to their transferability to industrial plants. Keywords: Cement grinding, grinding circuit, HPGR

Jan 1, 2020

By T. Matlou, S. Myendeki, V. Midzi, T. Zulu, H. Mabotja, T. Mulabisana, B. S. Zulu, L. Hlatshwayo, T. Makhateng

The Council for Geoscience (CGS) performed a macroseismic investigation following the occurrence of an earthquake in the Boksburg area on 11 June 2023. The event had a magnitude of ML 4.4 and a focal mechanism that showed the event as having strike-slip motion along a northwest-southeast oriented fault. The event resulted in aftershocks, some of which occurred away from the causative fault in the east in an area without a mapped fault. However, the cluster of past events in that area suggests that there is an active fault. Due to the size of the main earthquake, a macroseismic survey was conducted to determine its impact on the community in the region. Analysis of observed data obtained from questionnaires resulted in the creation of 153 intensity data points. Their distribution showed high intensity values close to the earthquake source area. However, the investigation highlighted a number of anomalies, such as the higher than expected intensity values observed far from the event epicentre. It could be that these anomalies are caused by site conditions, for example, amplification of ground motion due to thick soil layers.

Jan 12, 2025

By G. Song, X. Liu

The global coal industry has changed significantly in recent years. In this paper we analyse the coal production and consumption, imports and exports, and coal prices in China and other major coal-producing countries during the past four decades. The analysis shows that global coal production and consumption have declined over the last three years, in striking contrast to the continuous growth for most of the past 35 years. Australia, Indonesia, and Russia have become the world’s major coal providers, while China, India, and the USA, and Germany are the major coal consumers. The world’s, and China‘s, coal industry can be classified into four stages of development: the stable growth phase, stable phase, rapid growth phase, and high-quality phase. Coal prices rose in the world’s four major coal markets in 2016 after four consecutive years of falling prices. The elimination of overcapacity and production-optimizing operations in China could assist in achieving a demand and supply balance.

Aug 8, 2024

By R. G. Diale, H. R. Chauke, T. M. Ledwaba, P. E. Ngoepe

FeCo alloys play an important role in soft magnetic materials with a wide range of technological applications due to their high saturation magnetization and Curie temperature. However, these alloys have low ductility at room temperature. The ductility can be improved by the ternary addition of elements such as V. A density functional theory supercell approach was used to generate B2 Fe50Co50-xVx (0 ≤ x ≤ 50) structures and the properties were evaluated at different atomic percentage compositions to determine the ductility at room temperature. The structures were fully optimized to obtain better equilibrium ground-state properties such as lattice parameters and thermodynamic properties for both binary and ternary systems. The stability of Fe50Co50- xVx was evaluated from the heats of formation, elastic properties, and phonon dispersion curves. Furthermore, magnetic strength was evaluated from magnetic moments. It was found that all structures are thermodynamically stable due to the negative heats of formation. The calculated Pugh’s ratio and Poisson’s ratio confirm that alloying with V effectively improved the ductility. It was also found that Fe50Co50-xVx showed a positive shear modulus for the entire concentration range investigated, in agreement with phonon dispersion curves. The ternary addition of V to the FeCo system resulted in reduced magnetic strength due to a decrease in magnetic moments. These findings reveal that B2 FeCo-V alloys can be used as components and actuators for the automotive industry.

Jun 10, 2024

By M. Steyn

The coordination compound tetrakis(1,3-diphenyl-1,3-propanediona to)zirconium(IV), [Zr(DBM)4], (DBM = dibenzoyl methane/1,3- diphenyl-1,3-propanedionol) was synthesized and characterized by single-crystal X-ray diffraction. [Zr(DBM)4] crystallizes in the monoclinic space group P21/c (a = 24.769(4) Å, b = 10.216(5) Å, c = 19.314(4) Å, and = 101.541(5)°). The coordination geometry around the zirconium atom, formed by the eight O-donating atoms of the four -diketonates, is found to be a near-perfect square antiprism. Crystal packing is stabilized by C?H... interactions throughout the crystal lattice. This structure is a noteworthy example of the application of ambient condition synthesis of zirconium compounds in N,N'-dimethylformamide (DMF) as reaction and crystallization solvent, highlighting the possibilities of aerobic condition metal purification through chelation.

Jan 1, 2014

By W. E. Stumpf

"SynopsisSouth Africa recently announced a resurgence in its commercial nuclear power programme. The implications for the development of the necessary high-level manpower within South Africa’s tertiary educational system and its national research and development (R&D) capacity in materials science and engineering, as well as in other engineering disciplines, are placed into perspective. An organized national process of developing this manpower by moving away from the previously high-risk and costly ’large programmes’ to rather a selection of ‘small and better’ research projects and a redefinition of what constitutes ‘nuclear materials’ are proposed as parts of this strategy.IntroductionSince 2008, and more particularly in 2014/2015, South Africa has woken up to the fact that significant steps need to be taken to ensure sufficient electricity generating capacity for the future, even beyond the coal-fired stations at Medupi and Kusile currently under construction. It is, therefore, encouraging to see some active large-scale wind farms in the Eastern Cape near Jeffrey’s Bay, in the Couga area, and others in the Western Cape already in operation. In addition, many solar energy projects are also progressing from the small localized scale to larger programmes in the Northern Cape, which may contribute some capacity on a national basis. South Africa needs to tap into its renewable resources of wind and solar much more, but will these projects solve the country’s long-term industrial needs? Unfortunately not. One cannot run mines and trains on solar cells. Industry needs reliable baseload capacity, and with very limited easily accessible hydrocapacity this leaves really only coal, possibly natural gas, and nuclear power as options. South Africa’s current over-reliance of about 90% on coal–fired power, however, places it in an internationally vulnerable position, and diversification into a more equitable energy mix should be a national priority for the medium to long term. South Africa cannot significant climate change confronting the human race, as the IPCC cautioned in 2013, and will have to adjust its future energy reliance to a more balanced combination of sources."

Jan 1, 2015

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

By P. C. Pistorius, D. Kruger, Y. Kacar

Because of its superior properties, stainless steel has been widely used for many applications. Nonmetallic inclusions can influence the quality of stainless steel products. A set of samples was used to track the response of inclusion composition during processing of a heat of titanium-bearing 18% chromium steel, from deoxidation after decarburization, to the solidified slab. The oxide inclusions responded as expected to additions of deoxidizers and calcium treatment, changing from silica to alumina and spinels, and then to calcium aluminates. The samples confirmed that titanium nitride can nucleate on liquid calcium aluminate during steel solidification.

Aug 1, 2021

By C. Gatschlhofer, A. Krammer, H. Raupenstrauch, T. Hochsteiner, A. Holzer, L. Wiszniewski

The rising demand for lithium-ion batteries, coupled with international climate targets, emphasises the need for circular economy and zero-waste recycling approaches. However, so far, no industrial-scaled solutions are available that fulfil global recovery targets. Therefore, a novel pyrometallurgical reactor was developed at the Chair of Thermal Processing Technology at Montanuniversitaet Leoben to avoid lithium slagging and recover volatile elements via the gas phase. Nevertheless, previous results show that several impact factors, including interfering elements or pre-treatment steps, strongly limit the recycling efficiency of black mass. To simulate the black mass and provide feedback on possible influences of pre-treatment steps, cathode material from production with additives of interfering elements was analysed regarding melting behaviour. The results show that formation of a further processable alloy was increased by almost 50% when pretreatment steps were excluded, indicating pre-treatment steps as a major influence to be considered within this specific recycling route.

Jan 1, 2023

By W. K. Brinsden

In August 1965, the late Mr Alan Smith, then Mill Superintendent at Gold Mines of Kalgoorlie (GMK), Australia, asked me to investigate the planting of vegetation on the GMK slimes dams in order to ease the dust problem in urban and industrial areas-a problem that is caused largely by dust from these barren slimes dams. My early sources of information were the comprehensive papers in various issues of the Journal of The South African Institute of Mining and Metallurgy. However, the climate of Johannesburg differs from that of Kalgoorlie. The average Johannesburg rainfall, which falls mostly in summer, is 730 mm, and the average maximum summer temperature is 26°C (top 34°C). The winters are cool, the average maximum being 18°C (low -7°C). Kalgoorlie, on the other hand, receives, on average, 257 mm of sporadic rainfall, has hot dry summers with an average maximum of 35°C (top 45°C), and cool winters with an average maximum of 18°C (low -2°C). My obvious choice was to look at established trees growing on the GMK lease. A number of Athel pines were growing vigorously adjacent to the Oroya mining and geology offices and also on a nearby sand dump. The Athel pine (Tamarix aphylla), which is native to North Africa, Asia, and India, was originally introduced into Australia in 1936 by Mr Essington Lewis, then manager of BHP. His cuttings were planted in Whyalla, where some difficulty had been experienced in finding trees and shrubs that would flourish despite the district's low rainfall. In August 1965, cuttings of approximately 20 cm length and 1 cm diameter were taken from the GMK trees, stripped of leaves, and placed in jars of water in the sun. When the cuttings had sprouted both leaves and roots, they were planted in local soil in tins (about 20 cm high and 10 cm in diameter), and watered daily. In October 1965, when the new shoots were about 8 cm long, the trees were transplanted onto a lower flat section¬approximately 30 m wide, 30 m long, and 2 m high-of the Trafalgar slimes dam. No additional soil or fertilizer was used, and the trees were planted in their tins, the bases of which had been removed (the tin would eventually rust away). A few common varieties of non-prickly cactus and two native salt bush (spp Atriplex) were also planted, but did not survive, probably because of the acidity of the slime. During the summer of 1965/1966, Kalgoorlie's rainfall was 88 per cent above the average, and this probably helped the trees to survive. The moisture content was usually about 2,5 per cent from about 10 cm below the surface, and the pH value of the slime (d80 approximately 75 µm) was about 6. The trees were watered twice a week for the first four months and then left untended. By 1974 they had grown to only about 0,7 m, which indicated that their growth in slime was very slow. Other Athel pines were planted on the wall of the dam, but did not survive beyond 1974, probably because of the steep (about 500) slope and the hardness of the walls, which were initially formed by hand-shovelling of the slime as the height of the dam was raised. Five of the six Athel pines planted in 1965, which probably reached maturity (approximately 5 m in height) in 1981-16 years after being planted-have survived. In the early 1980s, waste rock had to be dumped on the dam, but the management of KMA (now KCGM) took care to ensure that the trees were not buried. Trials are being conducted on other tailings dams so that the performance of cuttings taken from the trees on Trafalgar dam can be compared with that of cuttings taken at various sites in Western Australia. It might also be worth while for an attempt to be made to strike cuttings from Trafalgar dam in pots containing different mixtures of soil and slime.

Jan 1, 1991

By A. F. Silva, R. Dockendorff, J. M. Girao Sotomayor, V. F. Navarro Torres, C. Castro

This paper shows the importance of performing probabilistic analyses in open pits, especially for mine planning, which can lead to more efficient ore extraction and meeting the acceptability criteria for safety in mine slopes. Three-dimensional stability analyses were performed to evaluate the future geometry of a large open pit for iron ore extraction in Brazil. The strength parameters of the lithologies were calibrated using ruptures in the pit walls. After determining the factors of safety (FoSs) from the calibrated parameters, probabilistic analyses were performed using the total range of values of each parameter under different field conditions to verify the reliability of the initial analysis. In this sense, it was possible to plot the probability of failure (PoF) and the FoS on the graph of slope height versus slope interramp angle (IRA) for the future pit in each lithology. IRA recommendations are made for two scenarios: (1) the best scenario: dry without ubiquitous joints and (2) the worst scenario: the water table at 10 m depth with ubiquitous joints in the most unfavourable direction. The results show that probabilistic evaluation is an important tool for establishing alert mechanisms in slopes that can be termed stable.

Jul 2, 2022

By D. F. Malan, R. P. Els

The limit equilibrium model, used in displacement discontinuity codes, is a popular method to simulate pillar failure. This paper investigates the use of physical modelling to calibrate this model. For the experiments, an artificial pillar material was prepared and cubes were poured using the standard 100 mm × 100 mm civil engineering concrete moulds. The friction angle between the cubes and the platens of the testing machine was varied by using soap and sandpaper. Different modes of failure were observed depending on the friction angle. Of interest is that significant loadshedding was recorded for some specimens which visually remained mostly intact. This highlights the difficulty of classifying pillars as failed or intact in underground stopes where spalling is observed. The laboratory models enabled a more precise calibration of the limit equilibrium model compared to previous attempts. Guidelines to assist with calibration of the model are given in the paper. The limit equilibrium model appears to be a useful approximation of the pillar failure as it could simulate the stress-strain behaviour of the laboratory models.

May 3, 2023

By M. R. L. Blackwell

Over the period 1964 to 1969 Conzinc Riotinto of Australia undertook and completed an evaluation of a large low-grade copper orebody on Bougainville Island in the Territory of Papua and New Guinea. From the outset it was clear that the geographic, climatic and topographic characteristics of the area would necessitate a heavy capital outlay on production and support facilities. Both the physical problems and the magnitude of the investment amplified the need for a thorough and rigorous evaluation of the various strategies for exploiting the orebody. In view of the number of independent and inter-related variables and the flow of new data, a computer-based evaluation process extended the scope and depth of the analysis considerably. The system used permitted an iterative assessment and re-assessment of the various strategies with the results becoming increasingly refined with time. This process encompassed the modelling of the orebody, the simulation of alternative operating strategies and the determination of the financial profitability of the project,

Jan 1, 2014

By J. Githiria, D. Wachira

The conventional truck and shovel haulage system has become expensive to operate in most mines due to current strict environmental conditions, increase in depth and size of open-pit mines, increase in labour costs, and fuel costs. These factors have motivated the search for alternative material haulage options in open-pit mines. In-pit crushing and conveying (IPCC) system has been regarded as a plausible alternative in material haulage systems. However, usage of IPCC has been limited to a few mines due to limited knowledge of IPCC performance, and other technical factors of the system. This paper investigates, and evaluates the productivity performance of four types of IPCC systems (fixed, semi-fixed, semi-mobile, and fully mobile IPCCs) using mine productivity index (MPi). Using a model developed by MATLAB, the MPi for the four systems is computed using input variables such as availability, utilisation, performance and number of trucks and shovels in a limestone quarry. The mine productivity index for fixed, semi-fixed, semi-mobile, and fully mobile IPCC is obtained as 67.13%, 69.02%, 70.52%, and 71.52% respectively. In conclusion, the fully mobile in-pit crushing and conveying system is the most appropriate IPCC in the quarry, due to its better productivity performance compared to the other three IPCC systems and the truck and shovel system currently in use.

Sep 1, 2021

By N. Snyders, I. Mwandawande, S. M. Bradshaw, M. Karimi

"Flotation columns are normally operated at optimal superficial gas velocities to maintain bubbly flow conditions. However, with increasing superficial gas velocity, loss of bubbly flow may occur with adverse effects on column performance. It is therefore important to identify the maximum superficial gas velocity above which loss of bubbly flow occurs. The maximum superficial gas velocity is usually obtained from a gas holdup versus superficial gas velocity plot in which the linear portion of the graph represents bubbly flow while deviation from the linear relationship indicates a change from the bubbly flow to the churn-turbulent regime. However, this method is difficult to use when the transition from bubbly flow to churn-turbulent flow is gradual, as happens in the presence of frothers. We present two alternative methods in which the flow regime in the column is distinguished by means of radial gas holdup profiles and gas holdup versus time graphs obtained from CFD simulations. Bubbly flow was characterized by saddle-shaped profiles with three distinct peaks, or saddle-shaped profiles with two near-wall peaks and a central minimum, or flat profiles with intermediate features between saddle and parabolic gas holdup profiles. The transition regime was gradual and characterized by flat to parabolic gas holdup profiles that become steeper with increasing superficial gas velocity. The churn-turbulent flow was distinguished by steep parabolic radial gas holdup profiles. Gas holdup versus time graphs were also used to define flow regimes with a constant gas holdup indicating bubbly flow, while wide gas holdup variations indicate churn-turbulent flow. IntroductionTwo types of flow can be distinguished in gasliquid flows in bubble columns: bubbly flow and churn-turbulent flow. The bubbly flow regime is characterized by uniform flow of bubbles of uniform size. Churn-turbulent flow, on the other hand, is characterized by a wide variation in bubble sizes with large bubbles rising rapidly and causing liquid circulation.Flotation columns are normally operated in the bubbly flow regime, which is the optimal condition for column flotation (Finch and Dobby, 1990; Yianatos and Finch, 1990; Ityokumbul, 1992). However, it has been generally observed that flotation column performance deteriorates when the superficial gas velocity is increased beyond a certain limit where the flow regime changes from bubbly flow to churn-turbulent flow (Xu, Finch, and Uribe-Salas, 1991). The identification of this critical or maximum superficial gas velocity is therefore important for optimal operation of flotation columns."

Feb 1, 2019

By J. Petersen, T. Moyo, D. Maharaj

This study investigates the effect of ammonium thiosulfate on the leaching of gold from the contacts of unpopulated cut electronic printed circuit boards (PCBs). Studies in the literature show ammonium thiosulfate to be a viable option in comparison to the commonly used but hazardous cyanide leaching route. However, the simultaneous dissolution of Cu interferes with the Au leaching reaction, often limiting the extraction to moderate levels. To optimize the system, an ammoniumthiosulfate system containing 0.5M ammonia, 0.5M ammonium thiosulfate, and Cu(II) sulfate at varying concentrations was studied as an alternative hydrometallurgical option for the recovery of gold from PCB. Tests were done with unpopulated standardized model PCBs (cut to 15 x 30mm pieces). Gold extraction of 47.3% was achieved after a 24-hour leaching experiment with a 0.02M copper background concentration. Further experiments focused using different initial background Cu concentrations (0M – 0.1M) to determine its effect on both gold and copper extractions. An initial Cu concentration of 0.045M resulted in the highest gold extraction, with 93.7% extraction after 6 hours of leaching. Further analysis of the data shows that the kinetic rate of gold leaching is correlated in a first-order dependence with the actual copper concentration in the solution, which increases with the concomitant dissolution of copper and gold from the PCBs. A lower threshold of 0.017M and an upper threshold of 0.15M copper in solution were determined, in between which gold extraction shows this first-order rate increase. The upper threshold is potentially linked to the onset of copper precipitation, which blinds the metal surfaces, slowing further leaching. The findings of this study suggest that in an industrial recovery operation of gold from waste PCB using the thiosulfate method, copper concentrations need to be carefully monitored, and the process should preferably operate with uncut or coarsely cut untreated boards to minimize exposure to copper circuits.

Dec 11, 2024