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By M. D. Schlesinger

Experimental data for coal hydrogenation are presented to show that when a vehicle oil produced from coal is present, coal is hydrogenated to the same high conversion whether molybdenum catalyst is impregnated on the coal or intimately mixed with the slurry. Differences in product distribution could be related to the severity of operating conditions. No minimum mixing time was established, but 2 hours was sufficient. Longer periods of mixing, to 14.75 hours, had no effect on the results. The hydrogenation conditions were in the pressure range of 8,500 to 10,000 p,s,i. at 400° to 500° C. Most of the experiments were made in duplicate. The results were obtained with molybdenum concentrations of 0.01, 0.1, and 1 percent. Al the mentioned pressure range and a time at temperature of 15 to 60 minutes, coal conversions higher than 98 percent were obtained.

Jan 1, 1962

By B. Dimitriades

The Bureau of Mines measured the reactivities of 19 hydrocarbons known to be prominently present in automotive exhaust and ambient air in a smog chamber. Results agreed well with those obtained using two other smog chambers. Reactivity scales were developed for hydrocarbons and aldehydes using the results of this work and those of a previous study. Application of the reactivity scales to automotive exhaust samples gave fair agreement between predicted and observed rate-of-N02-formation values; however, predicted and observed ozone yields were neither in agreement nor did they correlate well. This lack of correlation for ozone yield was attributed to the inappropriateness of (1) the individual component reactivity data, (2) the reactivity classification scheme used, and (3) the linear summation method. In seeking to understand this problem and to develop more appropriate reactivity scales, the data were examined from a reaction mechanism standpoint, and further studies were suggested.

Jan 1, 1975

By Charles L. Kimbell

Tables 16 through 19 continue the series of providing the world merchant fleet distribution by type of vessel and the ranking of the major fleets by country of registry. Table 20 this year provides a summary of the world's liquid gas carrier fleet. These vessels are included in the totals given for the world's tanker fleet, but gives a breakdown demonstrating the growth of the importance of natural gas in the world's energy commodity consumption. Panama and Suez Canals Tables 21 and 22 provide the latest available information on the transit of mineral commodities through the Panama Canal, by number of vessels, direction, and the commodities transported. Although the number of vessels transiting the Panama Canal dropped slightly (0.5%) between 1989 and 1990, the total amount of cargo moved rose by 3.6% and the amount of mineral commodities moved rose by 7.2%.

Jan 1, 1993

By W. E. Robinson

Sixty samples, selected from a 2,300-foot core of the Green River Formation in Colorado, were studied to ascertain differences in the structure of the organic material present in the oil shale samples. Emphasis was placed upon relating differences in the aromatic content of the insoluble kerogen and the alkane content of the extractable material obtained from the selected samples. The methods used in determining these differences consisted of fractionation of the soluble material, carbon and hydrogen analysis, volatile material determination, carbon residue determination, oxidation rate determination, and infrared analysis. In general, it was concluded that the organic material in this core does vary in chemical structure and that same of these variations resulted from factors related to depth of burial. Other observed changes in structure of the organic material were not depth-dependent and resulted from other factors such as source material variations, biological alterations, or ecological differences.

Jan 1, 1971

By G. B. Atkinson

Properties of catalysts prepared from intermetallic compound precursors were investigated by the Bureau of Mines as part of its mission to decrease U.S. dependence on foreign sources for scarce catalytic materials, such as nickel, cobalt, and chromium. Methods were developed whereby catalysts with surface areas of 30 to 40 m2/g were prepared from intermetallic compounds. Activity of these catalysts for the methanation reaction and methanol synthesis was deter-mined using a fixed-bed, single-pass, flow-through reactor. Catalysts prepared from rare-earth-nickel intermetallics had specific activity for methanation that was five times greater than that of commercial catalysts and were equal to or better than commercial catalysts with regard to sulfur tolerance. Under identical reaction conditions, catalysts prepared from thorium-copper intermetallics produced more than 10 times as much methanol as a commercial low-pressure catalyst and exhibited a high degree of catalytic stability.

Jan 1, 1982

By A. W. Hall

Cylindrical plastic scintillators were investigated for efficiency in detecting neutron-induced prompt gamma rays. Scintillator performance was compared on the basis of half-resolution and peak-to-trough ratios for gamma spectra obtained from Co-60 (1.17 and 1.33 MeV), Th-228 (2.62 MeV), and PuBe (4.43 MeV). Various sizes of Pilot Chemical scintillators (types B, F, M, and Y) were tested. The best half-resolution, 7.7 percent for PuBe, was achieved with a 5-by 5-inch Pilot Y?scintillator and dual photomultipliers. Comparison with sodium iodide (NaI) scintillators and the use of plastic scintillators for on-stream analysis of sulfur in coal is discussed. Plastics were found to be unsuitable for on-stream analysis of materials having complex prompt gamma ray spectra; however, they could conceivably be used for those yielding Simpler spectra.

Jan 1, 1974

By Stephen A. Hare, O&apos

The melting, casting, and welding of the Raney nickel alloy (42 pct Ni-58 pct A1), a methanation catalyst useful in coal gasification, were investigated. Melting was done in graphite crucibles by heating aluminum and adding nickel using a cryolite slag cover. Casting conditions were found to be optimum when the melt temperature ranged from 1,125° to 1,200° C and the mold temperature ranged from ambient to 250° C. Suitable mold materials were found to be quartz, heat-resistant glassware, olivine, and zircon. Welding of the alloy can be accomplished using tungsten inert gas process. Tensile strength of the alloy, in the as-cast condition, was found to be 2,000 1b/sq in with an impact strength of less than 1 ft-1b. The coefficient of thermal expansion was determined to be 18.4 x 10-6/° C after heat treatment.

Jan 1, 1977

By Raymond L. Carpenter

In connection with its continuing studies of the characteristics of alloys and alloying elements, the Bureau of Mines investigated the crystal structure of fused boron. This report describes how the structure of fused boron was found to be rhombohedral by the powder method for crystal-structure determinations by X-ray diffraction. The determinations of the crystal structure of boron reported in the literature were made on crystals prepared by various methods such as electrolysis, thermal decomposition of a boride, or by hydrogen reduction of boron tribromide. Table 1 summarizes the data found in the literature on the crystal structure of boron. The information shows the following: (1) Three structures have been reported for boron, (2) boron prepared by different processes--or even by varied conditions of a process--produces crystals of different structure, and (3) no information is given on the crystal structure of fused boron.

Jan 1, 1960

Provide mine personnel with a convenient means of determining the optimum installation geometry of roof trusses in bedded roof. Background Mine operators frequently ask the following questions concerning roof truss installations: 1. Where should the bearing plates or brackets be placed or where should the inclined holes be started? 2. At what angle should the holes for the inclined chords or angle holts be drilled? 3. What tension should be put into the inclined chords so as to achieve the most effective results for the effort and expense? Truss hardware manufacturers have responded to these questions with answers based on what seems to work best. While designs based on past experience are frequently reliable, there was a need for a rational approach that could accommodate a variety of conditions. The Bureau has developed a procedure that enables mine operators to optimize roof truss installations in bedded roof.

Jan 1, 1989

By Daniel N. Tallman

To provide technology for achieving more efficient water filtration systems for the mineral industry, the Bureau of Mines performed demon-stration filtration tests at three iron ore mines and one steel mill. A comparison of equivalently sized magnesium oxide (MgO) and sand filters showed that MgO had a higher capacity and could operate at higher fil-tration rates than sand. In demonstration tests when alum (AlK(S04)2) was the coagulant, suspended solids breakthrough occurred even though the pressure across the filter (head loss) was 7 psig or less. Under these circumstances, the MgO demonstrated 20 to 100 pct greater filtra-tion capacity, defined in terms of the volume of water filtered before breakthrough. When an organic floccu1ant was used at one location, head loss was the run-limiting factor; the filters essentially plugged with-out any solids breakthrough.

Jan 1, 1985

Avoid accidents that can occur when applying belt dressing from an aerosol can, particularly when can pressure has dropped or when spraying against wind. Approach Use a garde-type sprayer. How It Works Commercially available garden-type sprayers can be used for applying conveyor belt dressing from 12 feet away, or more. Pressure is easily raised and maintained at about 50 psi. Most sprayers have a hand pump, but a battery-powered cordless model is also available. Garden-type sprayers are available in various sizes from 11/2 to 18 gallons, with the larger models wheel mounted. The 3-gallon model evaluated by the Bureau has a shoulder carrying strap, which gives additional safety advantages. Use of the strap frees both hands for climbing ladders or holding onto catwalk rails. When spraying, one hand can remain on a handhold to lessen the chances of touching a moving belt.

Jan 1, 1980

By G. T. Lineberry, W. J. Wiehagen

This paper discusses a practical method for enhancing the performance of mining work crews. The method, described as the Work Crew Performance Model (WCPM), seeks to define performance variability within similar tasks of an underground work crew. Key components of the WCPM include: (I) job definition through task analyses; (2) the ranking of job elements by perceived cost consequence; (3) observational techniques to establish performance baselines; and (4) cost linkages between adherence to task procedures and measures of consequence for noncompliance. The components of this model emphasize a reliance on learning from a veteran work force and using that information to reinvest in strategies to enhance safety and efficiency. These strategies are not limited to technologic efforts but include consideration of the so-called "soft-skill technologies" aimed at reducing variability in individual performance and at effecting a continuous improvement in overall system effectiveness.

By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

To reduce operator exposure to noise from vibrating screens at coal preparation plants. Background Hearing loss is one of the most common occupational illnesses in the United States. In the U.S. mining industry, hearing loss is 2.5 to 3 times greater than what is expected for the average population that is not exposed to occupational noise. Furthermore, studies by the National Institute for Occupational Safety and Health (NIOSH) showed that by age 50, 90% of coal miners have a hearing impairment versus only 10% of the population that is not exposed to occupational noise. A NIOSH cross-sectional survey of coal preparation plants showed that 43.5% of employees were overexposed to noise. The study also found that vibrating screens were one of the top five loudest types of equipment at these plants?as well as the most numerous?making them a key noise source to address.

Nov 1, 2009

By J. C. Edwards

Fire experiments were conducted in the Safety Research Coal Mine (SRCM) at the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, with coal, diesel-fuel, electrical-cable, conveyor-belt, and metal-cutting fire sources to determine the response of fire sensors to products-of-combustion (POC). Metal oxide semiconductor (MOS) and smoke fire sensors demonstrated an earlier fire detection capability than a CO sensor. This capability was of particular significance for a conveyor-belt fire in which the optical visibility was reduced to 1.52 m with an increase in CO of less than 2 ppm at a distance of 148 m from the fire. Application of a neural-network program to the sensor responses from each type of fire source resulted in correct classifications of coal, diesel-fuel, cable, belt, and metal-cutting combustion with a mean of 96% of the test data correctly classified.

Jan 1, 2000

By E. R. McMillan, M. R. Geer, Joseph Daniels, H. F. Yancey

Investigations of coking properties of Washington coals made before 1939 and studies of coking precesses indicated that PiaTceC:Countyx:oals, particularly those from the Vlilkeson-Carbonado--Fairfax area, yield excellent coke structures. ThE: ash content of the cokes W2S relatively high, sulfur ordinarily.was low, and the phosphorus, although variable, was not excessively high for some purposes. For years the coals had been coked in beehive and standard byproducts ovens and had entered Pacific coast markets for every purpose to which coke is adapted. Certain areas of the Roslyn bed of Kittitas County also were known to possess coals with coking properties. This coal had been employed largely for bench-gas manufacture and occasionally, blended with other coals, in byproduct ovens. Coals from other western Washington areas also had baen utilized for coking in the past but were not of immediate significance.

Aug 1, 1943

By Dennis Cox, Stephen P. Signer, Joanne Johnston

A method to assist in the evaluation and selection of roof bolts using in situ measurements of roof bolt loading has been developed by researchers of the Spokane Research Center, National Institute of Occupational Safety and Health. Both axial and bending forces are measured by strain gauges at many locations along the length of fully grouted bolts during various stages of mining. This information is then used to (1) predict bolt loading for variations in bolt spacing, grade, and diameter, (2) calculate the design changes necessary in zones where bending loads are high, and (3) determine if bolt length is adequate. Results from several case studies of full-column bolt loading in coal mine gate roads are used to illustrate the design method. This knowledge will give design engineers a tool for the selection of roof support systems that will improve underground safety by reducing roof bolt failures.

By E. D. Calvert

As part of its goal to minimize the requirements for critical and strategic minerals, the Bureau of Mines is conducting research to foster the use of domestically abundant materials such as molybdenum. This report describes the development of an investment shell molding technique that can be used to make castings of molybdenum and its alloys. The mold material is cubic Zr02 with a monoclinic Zr02 binder. The shell, formed by standard investment molding techniques described in the text, is prepared for molybdenum casting by firing for 6 hours at 1,550° C (2,822° F) or for 4 hours at 1,650° C (3,002° F). The resulting castings have predictable and reproducible dimensions with good detail. As-cast strength is poorer than the strength of wrought materials below 1,600° F. At and above this temperature, tensile strengths of cast and wrought materials are nearly equal. Aqueous corrosion of the castings in most media is insignificant.

Jan 1, 1982

By J. O. Jones

[Willis Mountain in southeastern Buckingham County is one of several kyanite deposits its central Virginia. It is composed principally of kyanite resulting from metamorphism of siliceous sedimentary beds rich in alumina. The mountain, which trends north-south, is 2 miles long and is topped by a narrow ridge with sleep rugged sides rising to an altitude of 1,160 feet and projecting 500 fast shove the surrounding countryside. Bureau Mines engineers examiner Willis Mountain early in 1949, when bonded concentrations of coarsely crystalline kyanite were observed in the kyanite-quartzite on the northern end of the mountain and in loose boulders on the eastern slope. Commencing in late July 1949, the investigations continued on the Long Mountain segment for 11 months, ended in June 1950. A total of 600 samples from 32 diamond-drill holes, aggregating 3,876 feet of drilling, and from 255 feet of sampling in 3 trenches was assayed for kyanite and ferric oxide.]

Jan 1, 1954

By E. Chin

Bangladesh, whose population probably passed 100 million by yearend, remained one of the poorest countries in the world, with a per capita gross domestic product (GDP) of $126.2 Its only economically significant mineral production was natural gas. A few other minerals or mineral-based commodities were also produced, generally for local consumption. These included cement, clays, nitrogenous fertilizers, limestone, salt, steel, and pilot plant production of ilmenite and rutile. Exploration for oil was a continuing quest, which was hindered by a lack of funding and a hesitancy on the part of foreign petroleum companies to make long-term or expensive exploration commitments. PODUCTION AND TRADE Production of natural gas continued to increase as more use was being made of the abundant gas reserves variously put at between 7 and 16 trillion cubic feet. The main consumers were nitrogenous fertilizer producers and electric powerplants, but other industries were converting to natural gas from imported coal or fuel oil wherever possible.

Jan 1, 1986