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By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By L. E. Schultze

The Bureau of Mines devised a technique to recover a Zn-Pb concen-trate from a geothermal brine. More than 99 pct of the Zn and Ph was precipitated by treating the brine with H2S and controlling the pH with lime. Recycle of the sulfide precipitates increased crystal size and resulted in easily filterable products. A typical sulfide precipitate contained 53 pct ZnS, 8 pet PbS, 24 pct MnS, and 15 pct FeS. Addition of sulfide as FeS or CaS was not effective in precipitating Zn and Pb, but Zn in the brine was selectively removed with a strongly basic ion-exchange resin. A proposed flowsheet for metals recovery is discussed.

Jan 1, 1985

By K. C. Dean

A semiquantitative test for the presence and identification of cesium and rubidium in rocks, clays, and mineral waters has been developed by the Bureau of Mines. The test can be used in the field, as a guide for the prospector, geologist, or mining engineer engaged in location or development [w]ork. It comprises two simple spot tests of a solution prepared from the [m]ineral sample. Phosphomolybdic acid, added to a drop of the test solution, [d]etects cesium, rubidium, and potassium in quantities as low as 60 parts per [m]illion. Silicomolybdic acid, added to a second drop of test solution, enables the operator to distinguish between cesium and/or rubidium and potassium. Test procedures, equipment requirements, and limitations of the method are described in this report. Cesium and rubidium were discovered in 1860 and 1861 by Bunsen and Kirchhoff with a spectroscope. The elements usually occur together, particularly in granite and granitic pegmatites. Rubidium does not occur as an essential constituent of any known mineral, yet it is found as a minor element in so many minerals that rubidium is 16th in abundance in the earth's crust. Cesium, which ranks as the 37th most abundant element, is the principal component of pollucite and a minor element in a wide variety of minerals.

Jan 1, 1960

By Martin H. Stanezyk

The Bureau of Mines investigated leaching of selected copper sulfide minerals and a composite of impure flotation concentrates at elevated temperatures and pressures with ammoniacal solutions. Copper 1 (tractions of 96 percent were obtained by leaching chalcopyrite at 75° C under oxidizing conditions for 60 minutes. An extraction of 99 percent of the copper contained in the composite concentrate was obtained by leaching the product for 90 minutes at 75° C. In tests of bornite, chalcocite, and covellite, 90 to 97 percent of the copper was extracted at 20° C provided an 8-hour reaction period was used. At 75° C essentially complete dissolution of the copper from these three minerals was accomplished in 60 minutes. Additions of ammonium sulfate to the leach solutions were required to obtain high-percentage extractions of the copper from bornite, chalcocite, and covellite. Although ammonium sulfate was not required when digesting chalcopyrite, copper extraction was enhanced and less free ammonia was required when ammonium sulfate was added to the leach pulps. The chemistry of leaching copper minerals was studied. It was C, termined that chalcocite altered to covellite as one step in the dissolution When leaching iron-bearing copper sulfides, hydrated iron oxide formed on the mineral surfaces, indicating that a diffusion process prevailed. No evidence of covellite was detected.

Jan 1, 1966

By David S. Yantek

A-weighted sound levels around vibrating screens in coal preparation plants often exceed 90 dB(A). The National Institute for Occupational Safety and Health (NIOSH) is actively developing noise controls to reduce noise generated by horizontal vibrating screens. A 121-microphone, 3.5-meter-diameter array was used to perform beamforming to determine locations of significant noise radiation on the screen. Below about 1 kHz, the screen body was found to be the most significant noise source. The beamforming contour maps showed several key locations on the sides of the screen and the feedbox are the most significant contributors. Operating deflection shape (ODS) analysis was used to examine the screen behavior under actual operating conditions. This information is helpful in determining how to modify the screen body to reduce the noise radiated by the screen below 1 kHz. The analysis showed modal vibration patterns on the sides and feed box were the main contributors to noise. The results show several areas on the screen sides and feedbox that can be modified to reduce noise.

Jan 1, 2009

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973

By Roberta L. Hudak, Ellsworth R. Spencer, Eric R. Bauer, Adam K. Smith

The National Institute for Occupational Safety and Health (NIOSH) is conducting research with the objective of preventing hearing loss in the mining industry. Longwall mining is one sector that has received considerable attention. Studies involving the monitoring of worker noise exposures, characterizing equipment sound levels and dominant noise sources, evaluating engineering noise controls, analyzing hearing protection device (HPD) effectiveness, and testing of improved sound level monitoring techniques specifically for longwall mining systems, are being conducted. The research efforts revealed that stageloader operators are the most exposed longwall workers, with the discharge end being the noisiest location along the stageloader. In addition, the studies have shown that using stationary dosimeters, coupled with observational data of the cutting cycle and worker habits, has the potential for improved monitoring of the effectiveness of engineering noise controls. To address the ineffective use of soft foam earplugs, a simplified 3-step method was developed for inserting soft foam earplugs. Results indicate a 9 dB greater attenuation after training subjects on the 3-step method. Finally, muff type HPDs are being evaluated for effects of speech intelligibility in noise. The combined results of these studies illustrates that much can and has been done to prevent noise-induced hearing loss (NIHL) in the mining industry, especially with respect to longwall mining workers. This paper presents an overview of ongoing studies, a progress report of results, and the implications for reducing worker noise exposures and preventing NIHL in longwall mining workers.

By Sean Gallagher, William S. Marras, Alan S. Litsky, Deborah Burr

Background. There is currently little information regarding factors associated with specific modes of motion segment failure using a fatigue failure model. Methods. Thirty-six human lumbar motion segments were fatigue tested using spinal compressive and shear loads that simulated lifting a 9 kg weight in three torso flexion angles (0, 22.5, and 45). Twenty-five segments failed via fatigue prior to the 10,000 cycle maximum. These specimens were visually inspected and dissected so that the mode(s) of failure could be determined.Failure modes included endplate fractures (classified into nine varieties), vertebral body fractures, and/or zygapophysial joint disruption. Logistic regression analyses were performed to determine whether certain morphometric variables, amount of motion segment flexion, disk degeneration scores, and/or loading characteristics were associated with the occurrence of specific failure modes. Findings. Results indicated that stellate endplate fractures were associated with increased posterior shear forces (P < 0.05) and less degenerated discs (P < 0.01). Fractures running laterally across the endplate were associated with motion segments having larger volumes (P < 0.01). Endplate depression was more common in smaller specimens (P < 0.01), as well as those experiencing increased posterior shear force (P < 0.05). Zygapophysial joint damage was more likely to occur in a neutral posture (P < 0.01).Interpretation. These results suggest that prediction of failure modes (e.g., specific endplate fracture patterns) may be possible (atleast for older specimens)

By W. M. Myers

The U. S. Bureau of Mines conducted an investigation to determine the cause of the deterioration of Portland cement during storage and transportation , and to discover a means of preventing it . All available printed sources of information on this subject have been examined and a bibliography has been compiled . The subject has also been discussed with the leaders in the cement industry ; the present report is the result of their cooperation , and is based principally on information thus obtained . Deterioration of Portland cement during storage over any considerable period of time has long been noted ; closely related to it is deterioration of cement during transportation, which involves not only the time factor of storage but also exposure to varied climatic conditions . Deterioration in both cases is due to hydration of the cement by absorption of moisture from a humid atmosphere , or by exposure to actual rain-fall . After hydration cement possesses no cohesive power ; the degree of deterioration is directly proportional to the degree of hydration . The amount of deterioration of Portland cement during storage has been accurately determined in an investigation by the Structural Materials Research Laboratory , in cooperation with the Portland Cement Association . Cement stored in a shed in cloth sacks retained 80 per cent of its original strength after three months storage ; 71 per cent after six months ; 61 per cent after one year ; and 40 per cent after two years . The deterioration of Portland cement during storage and transportation was noted particularly in France during the World War . Information concerning cement used by the American Expeditionary Forces was furnished by Lt. Col. H. S. Spackman and Major E. C. Eckel , U. S. R. , who had charge of practically all matters concerning cement used by the A. E. F. The cement used by the A. E. F. came from the following sources : 42,000 tons was French , Swiss , and Spanish cements ; 120,000 tons was English cement ; 55,000 tons made in plants operated by the A.E.F .; 500 tons ( Not over) from America . Deterioration was most marked in cement from the first source .

Jun 1, 1922

By J. F. Barkley

The following questions and answers were prepared principally to supply information in answer to general inquiries received by the Bureau from those contemplating the use of propane and butane fuels . Primary or basic information only is covered; this usually gives enough guidance for most inquirers . To those who wish information of the treatise type , the handbook , Butane- Propane Gases , published by the Jenkins Publications , Inc. , 1709 West 8th Street , Los Angeles 14, Calif . , is suggested .

May 1, 1949

By N. A. Caspero, W. E. Eckard, W. T. Wertman

A thermal oil-recovery experiment was conducted in the Venango First sand, Goodwill Hill oilfield, Warren County, Pa., about 10 miles northeast of Titusville. The Quaker State Oil Refining Corp., Bradford, Pa., performed the experiment with assistance from Sinclair Research, Inc., Tulsa, Okla., and the Federal Bureau of Mines. The Goodwill Hill field was discovered in 1885. Primary-production oper- ations continued until 1930 when an air-gas injection project, which is still in operation, was started. At the location of the combustion experiment, the reservoir is 400 feet deep and 30 feet thick, with wide permeability and porosity variations. The crude oil is typical Pennsylvania Grade paraffin- base oil with a gravity of 43.9° API and a viscosity of 4.55 cp at 60° F. The well pattern for the experiment consisted of 5 producing wells, enclosing an area of 1.28 acres, and a central ignition-injection well. An air-natural gas mixture was ignited in the ignition well on July 29, 1961. Ignition was followed by injection of air and natural gas at various rates. The experiment was suspended January 5, 1962, when it became evident that economic oil production could not be achieved. There was no conclusive evidence that self-sustained combustion was achieved or that combustion increased oil and water production. A slight increase in liquid production was attributed to stripping action caused by the air-injection rates, which were higher than those normally used during air-gas injection.

Dec 1, 1963

By C. P. Bowie

"It is well known by all who are familiar with the oil industry in America that the oil pipe line is as fundamentally a part of this industry as the railroad is of most other American industries. The oil pipe line was first introduced about 56 years ago, and since that time has so demonstrated its superiority as a means of carrying crude oil froze the well to the refinery, that this method of transportation has largely superseded all others. This has made possible the building of refineries in or near the large consuming centers, rather than at the wells, which are usually remote from the centers of population.The pipes for conveying the oil are laid on the surface of the ground, or at a depth varying from 18 inches to 3 feet beneath the surface, and the main lines are generally eight inches in diameter. The oil is forced through the pipes by means of pumps operated either by steam or by internal combustion engines. The pump stations are located from 1 1/2 to 90 miles apart, varying with the condition of the country through which the pipe lines extend, and the viscosity of the oil to be handled.Some of the larger pipe-line systems and hundreds of miles in length. It is estimated by the U. S. Geological Survey that the total mileage of oil trunk lines in the United States today is approximately 34,000, and that the gathering systems, which are a fundamental part of the trunk systems, aggregate about 11,500 miles in length, making a total of 45,500 miles.Using those figures as a basis, some general conclusions as to the investment represented will be made. At the time most of the lines were constructed, the average cost per mile based on eight-inch pipe was about $6,500. The cost of the average pump station at that time varied from $130,000 to $250,000. The cost at the present time, on account of the increase in price of labor and materials, would be much in excess of these figures. The fixed investment in pipe lines is, therefore, very extensive. It corresponds closely with the actual cost of the property, and is estimated to be approximately $500,000,000."

Sep 1, 1920

By E. D. Gardner, Edmund Stein

"IntroductionMassive sulphides occurring in metal mines are inflammable and furnish the fuel for many mine fires. Actual sampling has shown that dangerous amounts of sulphur dioxide and hydrogen sulphide may occur in mine atmospheres after blasting in massive sulphides. Probably some .of the finer sulphide in the material being blasted burns while it is in contact with the flame from the explosion. It’s also possible that oxygen of the explosive enters into the reaction.That sulphide dusts are explosive under some conditions has long been suspected, but the theory has not been generally accepted as having been proved. Evidence now at hand appears to be conclusive that such explosions do occasionally occur in mine workings in massive sulphides. Information from several mines working in heavy sulphides shows that occasionally, sulphur dioxide in larger amounts than could be expected from the blasting alone are occasionally thrown out into the mine atmosphere during blasting. Accidents have occurred and lives have been lost by men being caught in such gases. Also it appears in a few cases that damage done to timber in stopes by concussions has been greater than could 112.ve been expected from the regular blasts. In most of these cases the unusually large amounts of Sulphur dioxide could only be accounted for by an explosion or by an ignition of sulphide dusts. When this occurs it is probable that the settled dust is stirred up by the first shot of a round, then the dust cloud is ignited by this or a succeeding shot.In one instance, the senior author, while wearing breathing apparatus, returned to a station to take a gas sample immediately after a raise round had been blasted, and encountered a heavy white fume or smoke that was corrosive to the skin and which forced a retreat. The sample, which was taken farther back in a greatly diluted atmosphere, showed a high percentage (0.18) of sulphur dioxide. The station and the raise which was just being started were very dry and the walls and floor of the station contained settled sulphide dust which apparently was ignited by the blast."

Mar 1, 1928

By Phillip W. Holland

The U.S. Bureau of Mines has developed a mass spectrometer method for determining helium in the parts-per-million to 10% range to an accuracy of ± 1%. The method employs a mass spectrometer, an inlet system utilizing a chromatographic gas-sampling valve, and an activated coconut charcoal trap cooled with liquid nitrogen. Gravimetrically prepared standards of helium in nitrogen were used to demonstrate the linearity of the method over the concentration range of 10 ppm to 10.66% helium.

Jan 1, 2010

By R. V. Higgins

Many contributions to methods of forecasting the performance of waterfloods of a five-spot pattern have been made by investigators. In most of these forecasting methods, a previously selected sweep efficiency is used, and other simplifying assumptions are employed to obtain the objective. In this paper the calculated oil recoveries from several five-spot single- and multiple-layer stratified reservoirs were made with a minimum of assumptions, and because of the techniques used, no previously selected sweep efficiency was required. As a result, the accuracy of the forecast is increased. Permeability curves and continuously changing saturation gradients are used in every section of the pattern. By means of a potentiometric model, the flood pattern is divided into channels, the centers of which are the streamlines. The channels are divided into cells. As flood water enters, the permeability and saturation of each cell change with time. In this study the production from multiple-sand layers of different absolute permeability but with the same relative permeability-saturation relations are combined. The results are shown for a single- and 10-layer reservoir with a permeability variation of 0.60. The oil rate, water-oil ratio, and recovery are shown as functions of time for a 2- and 20-centipoise oil starting in primary phase and after fill-up.

Jan 1, 1962

By J. A. HUFF, V. V. BAKER

This circular contains a statement of the statutory provisions of the several States regarding the appointment , qualifications , and remuneration of State mine inspectors . States have been omitted where no specific provision has been made by the State law for mine inspectors .

Jul 1, 1931

By Allan F. Smith

The Bureau of Mines studied toxic products produced by burning eight fire-resistant mines conveyor belts, a brattice cloth, and an electrical cable insulation obtained from laboratory-scale burning experiments under various air-flow conditions. Generally, CO product concentrations for most materials were noticeably higher then the NO2 and HC1 levels that were measured; also, no phosgene was detected. However, several of the fire-resistant belt samples yielded HC1 concentrations that were above the reported lethal level for 1/2 to 1-hour exposures, although these data were limited to flow conditions where air dilution effects were small; the belt materials that showed this behavior included samples of polyvinyl chloride, styrene butadiene, styrene butadiene blends, and a British neoprene which yielded the greatest amount of toxic vapor. In addition, some results are presented on the phosphoric acid concentrations that may be produced from the decomposition of ammonium dihydrogen phosphate when dispersed on a burning coalbed.

Jan 1, 1973

By Howard E. Parkinson

In 1969, new coal mine health and safety legislation was enacted in the United States. As a result of this legislation, the Department of Interior, Bureau of Mines has carried out communications research aimed at developing whole mine communications for increased safety and efficient operation. The research has advanced and many promising results are now being demonstrated to the mining industry. However, there remains a challenge to further improve wireless communications within the mine workings, and through the overburden above the workings. The objectives for future research and development will be discussed, together with the physical and operational constraints that new mine communication systems must face.

Jan 1, 1973

By R. L. Grayson, W. E. Wallace, J. W. Stephens, M. D. Attfield, P. S. Brower, V. Vallyathan, M. J. Keane, J. C. Harrison

Pure respirable quartz is a known pathogenic agent for lung disease. However, for mixed dusts, neither mineralogical nor in vitro cytotoxicity assays unequivocally predict the contribution of quartz to their pathogenic potential.First, although Coal Workers' Pneumoconiosis (CWP) and Progressive Massive Fibrosis (PMF) prevalence have been found to correlate with total respirable coal mine dust exposure, and with coal rank (Attfield and Morring, 1992), epidemiological studies generally have not found the quartz component of coal mine dust as measured by X-ray diffraction or infrared spectroscopy (each of which essentially measures the mass-percent quartz in a bulk sample) to be clear predictors of CWP prevalence or incidence (Walton et al., 1971). Second, the properties which distinguish the extreme fibrogenic potential of quartz are not revealed by conventional in vitro bioassay comparison with other silicate mineral dusts. As an example, quartz and kaolin (aluminosilicate) clay in vitro cytotoxicities are comparable for lavaged primary pulmonary macrophages.The studies discussed here address these two anomalies from a general hypothesis that the pathogenic activity of respired quartz particles is associated with properties of, and interactions with, the particle surfaces. One factor in the expression of toxic activity by a particle surface is the biological availability of that surface. Anomalous lack of correlation of disease prevalence with mass percent quartz in exposures to some mixed composition respirable-sized dusts suggests that individual particle surface features, invisible by bulk sample mass analysis, may alter the biological availability of a fraction of quartz particles in a dust. For pure-surfaced mineral particles, the comparably strong prompt membranolytic activities of quartz and kaolin in vitro suggest that upon deposition of such particles in the lung there must be other interactions with particle surfaces which distinguish quartz. This might be due to toxic surface-associated sites specific to silica, or to interactions of other sites on other mineral particles which affect the biological availability of their toxic functional groups. For example, alurninol groups on clays affect the availability or activity of adjacent silanol groups. Surface activities which distinguish quartz pathogenici ty might be manifest in one or more of the sequential interactions upon deposition in the lung; first with the pulmonary surfactant system, then with extracellular and phagolysosomal enzymatic digestive processes, or with subsequent cytotoxic processes.

Dec 1, 1995

By Guy A. Johnson

Despite the use of warning alarms to alert miners to the backward movement of large mining equipment, miners still are injured too frequently in backup accidents. Currently approved backup alarm technology consists of continuous sounding alarm systems. New technology has developed a warning system that initiates an alarm only if there is an object close behind the vehicle. This advancement eliminates constant exposure to the alarm because a warning is given only in case of a potential collision. Adoption of this development can improve safety and reduce damage, especially for front-end loaders (FEL&apos;s). It will also eliminate a source of nuisance noise in urban and residential areas. This Bureau of Mines report describes the general characteristics of infrared (IR) light, ultrasonic wave, and Doppler radar technology as used for backup alarms, and reviews the testing of the most promising detection devices.

Jan 1, 1986