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By H. P. Greenwald

About mid-December 1936, the safety director of a large coal corporation visited the authors at the Bureau's Experimental coal mine to discuss a rock-dust barrier he had invented primarily for use in trackless entries of coal mines. The rock dust in this device was carried in its original paper containers and means were provided for ripping these open so that the dust might be scattered in the path of an explosion. The inventor termed the device a "bag barrier", and this term has been adopted in the present paper for convenience. At that time the device was in an early stage of development, and the inventor felt that the barrier should be tested to determine whether it had enough promise of being successful to justify further development. The matter was taken under consideration and finally three tests were made during the week of February 15, 1937. It was concluded that while the device did stop an explosion in two of the three tests, it was much loss effective than ordinary rock dusting, and that too few data were obtained to permit direct comparison with tests of other barriers. Apparently, the conditions under which the device could, be successful were somewhat limited, out the limits could not be defined without additional tests.

Jan 1, 1938

By Benjamin Petkof

Production quarry blasts in three rock types were photographed with a high-speed camera. Analysis of the films showed that step increases sometimes occur in the horizontal velocity of the broken rock. These step velocity increases were observed only in the first foot or so of rock movement. This observation indicates that the gaseous products of the explosion do additional work on the rock after it is crushed and cracked by the initial compressive-stress pulse and the reflected tensile-stress pulse. The observed initial fly-rock velocity is compared with the calculated fly-rock velocity for reflection spalling. A mechanism possibly causing the velocity increases is discussed. INTRODUCTION When a small concentrated charge of explosive is detonated at the bottom of a drill hole near a free surface, two modes of rock failure have been observed; both are associated with the stress pulse generated in the rock by the detonating explosive. The first mode of failure is the crushing and radial tensile cracking associated with the initial passage of the compressive-stress pulse as it propagates outward from the explosion. This type of rock failure is usually confined to the immediate vicinity of the charge hole. The second mode of failure is the tangential and radial tensile cracking associated with the tensile-stress pulse that is reflected from the free surface. This mode of failure is commonly called scabbing or spalling and has been shown to be a primary cause of rock failure in crater formation at one free surface. (3).4

Jan 1, 1961

By H. P. Greenwald

About mid-December 1936, the safety director of a large coal corporation visited the authors at the Bureau's Experimental coal mine to discuss a rock-dust barrier he had invented primarily for use in trackless entries of coal mines. The rock dust in this device was carried in its original paper containers and means were provided for ripping these open so that the dust might be scattered in the path of an explosion. The inventor termed the device a "bag barrier", and this term has been adopted in the present paper for convenience. At that time the device was in an early stage of development, and the inventor felt that the barrier should be tested to determine whether it had enough promise of being successful to justify further development. The matter was taken under consideration and finally three tests were made during the week of February 15, 1937. It was concluded that while the device did stop an explosion in two of the three tests, it was much loss effective than ordinary rock dusting, and that too few data were obtained to permit direct comparison with tests of other barriers. Apparently, the conditions under which the device could, be successful 'Were somewhat limited, out the limits could not be defined without additional tests.

Jan 1, 1938

By Ralph L. Brown

The chemical properties of the unsaturated members of the aliphatic series of hydrocarbons are such as to render them " made to order" starting points or basic . materials for the synthesis of hundreds of important organic chemicals . The tremendous quantities of these unsaturated compounds that are being produced daily in the various coal carbonization and oil refining processes , and which at present have little value other than that of fuel , render a survey of the identity and ex- tent of occurrence of these compounds important from the viewpoint of economic utilization and resource conservation The increased need of liquid fuel and the relatively early exhaustion of petroleum resources will eventually require every utilization of liquid fuel products obtainable directly or indirectly from coal . Accordingly , the Bureau of Mines took advantage of an opportunity for examining the gaseous unsaturated hydrocarbons found in the gas obtained when a mixture of water- Collection of the material gas tar and coal is distilled in a gas-making retort . for examination was made possible through the courtesy of the Trent Process Corporation , Washington , D.C. , which was at that time carrying on at the Georgetown Gas Works , distillation of " amal gams " prepared from various coals and oils by the Trent process for cleaning coals . Kanawha gas coal ( 70%) and water gas tar ( 30 % ) from the Washington Gas Light plant were used in the " amal gam" being distilled at that time . The results obtained in this examination are presented here .

Feb 2, 1922

By Jr. Driscoll

The thermoelectric properties of yttrium monoarsenide, yttrium monoanti-monide) and ternary materials from the Y-As-Se and Y-Sb-Te systems were investigated by the Bureau of Mines from room temperature to 1,000° C. The maximum calculated figure of merit for yttrium monoarsenide and yttrium monoantimonide was 2 x 10-5 ° C-1. YAs and YSb were semimetallic conductors with low Seebeck coefficients and electrical resistivities. The values of the Seebeck coefficient and electrical resistivity of the Y-As-Se and Y-Sb-Te materials were between those of the yttrium selenides and tellurides and of YAs and YSb, respectively. The maximum power factor calculated for the Y-As-Se materials was 2 X 10-5 watt/cm ° C2 which yielded an estimated figure of merit of 6 X 10-4 0 C-1. Most of the Y-As-Se compounds had high Seebeck coefficients and moderately low electrical resistivities. The Y-Sb-Te materials were degenerate semiconductors with power factors of 6 X 10-8 watt/cm ° C2.

Jan 1, 1967

By Frank E. Cash, Max S. Petersen

"INTRODUCTION Explosives have been used in ever—increasing amounts since gunpowder was invented. For hundreds of years only low explosives of the deflagrating type were used, and they were fired by means of a flame or hot object. Ben¬jamin Franklin first ignited gunpowder from a distance in 1751 by means of an electrostatic spark. Further efforts to develop a satisfactory electrical method to ignite explosives from greater distances were overshadowed by the invention of safety fuse in 1831, as this offered a relatively simple and inexpensive means of firing explosives.The discovery and introduction of high explosives of the detonating type and the invention of the fulmitate of mercury blasting cap about the middle of the nineteenth century provided the needed impetus for inventors to develop means of firing the cap by electricity. The original high-tension igniter, following Benjamin Franklin's experiment in which the detonating compound was ignited by a spark, was discarded in favor of a low-tension igniter, in which the detonating compound was ignited by a heated wire. The past 2 decades have seen considerable improvement in the design and construction of electric detonators to make them safer and more efficient, yet in spite of the improvement it is estimated that less than 50 percent of the explosives used in industry today are ignited or detonated electrically. The trend, however, is toward the use of electric methods. In recent years numerous-mining companies have introduced electric blasting exclusively at their mines as a means of improving safety and efficiency."

Sep 1, 1946

By E. D. Gardner

The Bureau of nines, in cooperation with the mining companies of the Southwest, is conducting an investigating to ascertain the safest and most economical explosives to use in metal mines, and to ascertain the best methods of blasting under various conditions. A part of this investigation has been a study of drilling and blasting drift rounds in metal mines. This paper covers one phase of work on drift rounds and discusses the methods of loading the individual holes of the rounds. The blasting tests, on which this paper is based, were made at the Copper queen Branch of the Phelps Dodge Corporation at Bisbee, Arizona.

Jan 1, 1927

By G. L. Oldright, Virgil Miller

"ACKN0WLEDGMENTSThe data given in this paper were collected at the Bunker Hill smelter through the courtesy of Stanley A. Easton, the vice-president and general manager, Frank M. Smith, the smelter director, and with the assistance and cooperation of A. F. Beasley, the smelter superintendent, and his staff members.THE BLAST FURNACE AND PLANTThe general lay-out of the recently built (1917) Bunker Hill plant has been given in the technical press in articles that were cited in Report of Investigations 3088. In addition it may be noted that the description of an ideal smelter given by Riddell 5 a year later fits the Bunker Hill smelter very well, with some changes, such as the location of the stack, made necessary by topography. For purposes of this article on the blast furnace it may suffice to state that the plant is one of the ""side hill location"" type. The various successively lower benches may roughly be considered as made for (1) the stack, (2) Cottrells and bag houses, (3) Dwight and Lloyd sintering machines with the equipment or bins for handling or mixing the feed and storing the finished product, sinter, and (4) the blast furnace feed floor with a slightly rising gradient to the bottom of the bins for sinter, feed, and take. The lowest bench (5) might be considered that of the blast furnace tapping floor at which or at appropriately slightly lower elevations are located the units for softening, refining, and treating precious metals, and for casting and loading lead. A very careful study of grades was made in order to be able to handle the products easily. All units were left with at least one end open to permit expansion of the plant, it desired, and each unit was separated from the other, evidently so that the operators on one level would be annoyed as little as posssible with the products made on another."

Apr 1, 1931

By D. G. Kuehn

Studies were conducted by the Bureau of Mines to determine the positive ions and neutral species produced in glow discharges of gas streams containing 1.0 percent NO in helium, 29 percent dry air in helium, and 1.06 percent NO in N2, Mass spectrographic measurements were conducted for gas pressures from 2.3 to 10.0 torr and dc currents from 10 to 20 mAo Ion species observed included NO+, N2 +, O2 +, N+, and 0+ with lesser amounts of He+, He2+, and N02+. Variations in various ionic and neutral species with discharge duration were interpreted to be consistent with an electrically induced dissociation of NO to produce N2 and O2. No nitrogen oxides were observed to form in glow discharges of the helium-air mixture.

Jan 1, 1975

By G. Nuñez, M. A. Pathak, C. F. Stanley

"A 1986 report by the U.S. National Committee on Blomechanlcs (1) describes lung disease as a major national health problem. The report cites three areas that would benefit from a better understanding of the vibratory patterns of the lung. These areas are outlined below.1. In cases of respiratory distress, pressure driven artificial respirators are used. A new technique using high frequency respiration is quite promising, but the pressure distribution in the lung as a function of frequency is not yet known. At these frequencies of 1 to 60 Hz, the lung expands asynchronously (2) and a better understanding of these expansion nonunlformltles could provide valuable Information about the mechanics of high frequency ventilation.2. Listening to the sounds In the lung can yield valuable Information about the state of the lung. To improve the technique, a better understanding of how acoustic waves propagate through the lung is needed.3. The response of the lung as It Is subjected to acoustic excitation, dynamic loading or shock waves is not well understood. A better knowledge of these responees can lead to improved treatment for patients subjected to either explosive pressure waves or car crashes.4. Researchers are measuring the acoustic Impedance of the Iung to detect early states of dysfunction. Sneckenberger and Whitmoyer (3) have reported Impedances obtained at acoustic frequencies up to about 6000 Hz. However, It la not certain which parts of the lung are responding to the acoustic excitation.To Investigate the vibratory characteristics of the lung, excised rat lungs were excited via the trachea with acoustic waves at frequencies up to 6000 Hz. Thie paper describes an Instrumentation system, utlllzlng time-averaged holographic Interferometry, to detect and quantify the response of the lung surface to the acoustic excitation."

Jan 1, 1989

By Maust. E. J., W. R. Crane

"IntroductionIn the study of mine drainage in the red iron ore mines of the Birmingham district of Alabama, an extensive series of measurements were made in order to determine the drainage from the area overlying and adjacent to the mines. Gaging rods were generally used in measuring streams, and weirs in ditches and sometimes as a check on rod work. These tests in turn were checked by current meter tests. In all, 725 separate stream gagings and 97 weir measurements were made. Certain relationships were worked out, particularly between rod and weir tests, which permitted obtaining results that are much more accurate 'under the existing conditions, than any available formula would give. The large number of weir measurements and the period covered by the tests made it impracticable to construct a weir for each observation so portable, adjustable weirs were built. The methods used are described here for the benefit of those interested in measurement of streams in connection with a study of mine drainage or otherwise. The Drainage AreaThe area draining the mining district lies between the crest of Red Mountain and Little Shades Creek, and for convenience was divided into sub-districts adjacent to certain groups of mines. Gaging stations were established on Little Shades Creek at the upper and lower boundaries of each sub-district, also at points on the tributaries near their junction with the creek. The difference between the volumes of water flowing in Little Shades Creek as it entered and left the sub-districts represents the flow from the tributaries on both sides of the creek. Since the flow coming from the sub-districts was measured direct, the inflow from the tributaries on the opposite side of the creek can be computed from the three volumes determined."

Oct 1, 1926

By K. D. Luxbacher

Understanding methane emissions in underground coal mines is critical for a safe and productive mine. In addition to reasonable estimation of initial coalbed reservoir parameters, it is also crucial that changes in effective stress due to mining and pore pressure reduction are taken into account due to their effects on porosity and permeability. Primary parameters for estimation of emissions or modeling of the mining environment for this purpose are porosity and permeability which can change dramatically as a result of stress redistribution associated with mining and gas desorption from a large coal volume. These parameters affect the emission rates and ventilation requirements, as well as water inflow into the working environment. Stopping leakage, on the other hand, is a secondary stress dependent factor in estimation of emissions, as convergence of the roof and floor strata, compromising the integrity of the stopping, may result in leakage, making prediction of ventilation requirements difficult. This paper aims to examine the effects of porosity and permeability changes of the coal seam on methane emissions in an underground continuous miner section. The models were developed and executed in a dynamic fashion to simulate an advancing section. Through this process, the changes of effective stress in coal, particularly their change paths, on porosity and permeability were incorporated into the models and methane emissions, concentrations, air requirements, water inflow and possible leakage from the stoppings were investigated using a conventional coalbed methane reservoir model.

Jan 1, 2009

By O. Q. Leone

Composite diaphragms were used in the investigation of electrowinning Ti from TiC14 in a fused LiCl-KCI-TiC'2 electrolyte. Composite diaphragms tested were of two general classes--those consisting of two or more solid materials, and those which contained, in addition, a loose material. An electrowinning cell using a flat diaphragm is described. The maximum current density for these diaphragms was 300 amp per ft2. Lower currents permitted longer operation times. The composite diaphragms gave electrode efficiencies that averaged approximately 60 percent, and the electrowon titanium was of good quality--some Brinell hardnesses were as low as 68.

Jan 1, 1972

By A. U. Miller

The added hazards to mining incident to oil and gas wells penetrating the coal measures in proximity to mine workings , have long been recognized in those fields where the extraction of oil , gas , and coal , has been in progress for a number of years . The history of these fields is replete with stories of serious mine fires , explosions , and miraculous escapes from both fires and explosions due to either oil or gas finding its way into the mine workings through the strata , or by mining into an unknown or uncharted and abandoned oil or gas well that had not been properly plugged . The Director of the Bureau of Mines , in response to numerous requests from coal operators and oil and gas operators , called a meeting in 1913 to discuss necessary precationary measures to take when drilling oil or gas wells through workable coal beds and to try, if possible . to formulate a set of regulations that might serve as a guide to those persons preparing regulations covering the drilling of oil and gas wells in the various coal producing States . This meeting was attended by representatives of the coal , oil , and gas industries , State geologists , State mine inspectors , and representatives of the Bureau of Mines . A committee was appointed to prepare a set of regulations , which was later published as U.S.Bureau of Mines Technical Paper 53 ; the discussions and results of the meeting werepublished as U. S. Bureau of Mines Bulletin 65 . Later , the American Institute of Mining and Metallurgical Engineers appointed a committee to draft a model law for the use of the legislature of any State concerned . This committee made its report on April 27 , 1928 . Several of the coal mining States now have more or less comprehensive regulations governing the drilling of oil or gas wells through workable coal beds , others have regulations that are inadequate , while some have no regulations . The State of West Virginia recently enacted a law containing reg lations which are the result of a comprehensive and careful study of the problem .

Nov 1, 1929

By A. W. Khair, S. J. Jung

"A fundamental study of fragment size distribution and characteristics of fracture pattern is presented for the dynamic penetration of a conical bit into coal block. In this paper, damaged zones during crater formation and fragment size distribution were studied. Bit with a sharper tip angle and a smooth body configuration performed better penetration. Results suggest that in coal cutting the trend should be toward the face cleat direction using a sharper angled tip bits which consumes less energy for an optimum range of penetration depths, thus attaining maximum cutting efficiency and reducing fine fragments.1. INTRODUCTIONMuch research in the past has been done on energy requirements and mechanism of energy dissipation for ideal rock fragmentation in cutting process. However the mechanisms of energy dissipation or failure criteria for rocks in cutting process in order to evaluate the efficiency of energy requirements in specific rock fragmentation is not well understood. The formation of a crater in rock under the impact blow of a bit has been observed experimentally (Hartman, 1959). It is known that directly beneath the edge of the bit the rock is crushed into fine powder, toward the sides of the crater it chips out into relatively large fragments. (Sikarskie & Cheatham, 1973). Singh et al. (1967) investigated the cratering process under the two different conditions of static and dynamic loading. They found that the amount of energy consumed per unit volume of crater is unequal for the two different loading conditions. A complex network of fractures often extends downward and laterally into the rock below the bit. The surface of the specimens showed that the dynamic loading damaged larger area then the static loading."

Jan 1, 1989

By J. N. Geyer

In coal mining it is essential to maintain the roof over working places and roadways in the safest condition possible. To this end every effort should be made to win the coal with the least injury to the immediate roof strata, as broken strata certainly present a greater hazard than a sound roof. The chief causes of injury to the roof in mining are inherent in the method of development and recovery and the blasting practices followed. The first, which may produce severe stresses in the roof, weakening it over comparatively large areas has been discussed in previous papers3 and will not be treated here. The second cause is local in effect, but with the same general method of blasting being employed throughout a mine having uniform roof conditions, similar effects on the roof may be expected. In the Bureau's investigation of accidents caused by falls of roof and coal it has been necessary to make a careful study of blasting practices and their effect on the immediate roof. The purpose of this paper is to show the effect of the observed methods of blasting on different types of roof and to point out methods that have been proved to be least harmful to the roof strata. The data used in preparing this paper have been compiled from reports made by Bureau engineers engaged in the study of falls of roof and coal, and embrace mines opened in the Pittsburgh coal in Ohio and Pennsylvania and the Pittsburgh and Sewickley coals in West Virginia.

Jan 1, 1933

By Webster S. Anderson

The design, development, and testing of hydraulic props to provide a lightweight, high strength, recoverable unit is described. Modifications in design incorporating threaded components resulted in the development of a lightweight hydraulic prop fabricated from aluminum alloy tubing. This new design facilitates interchange and replacement of component parts, and the physical properties of the material are not changed as they are when welding is required. The new prop is 65,000 pounds and has a maximum load capacity of a lower weight-to-load capacity ratio than the hydraulic props now available.

Jan 1, 1967

By H. H. Hill

"The wide publicity that is given to the discover; of new oil fields has led many people to believe that our supply of crude petroleum is practically in- exhaustible and that in order to keep pace with the demand for petroleum products, it is only necessary to drill a few more wells in some of the south-western states. It is not generally realized that, although many famous fields have been developed in Oklahoma, Kansas, Texas and Louisiana during the past few years, the production of crude oil in 1919 was not sufficient to meet the demand and it was necessary to import approximately 53,000,000 barrels from Mexico.Continued efforts are being made to recover a larger percentage of the oil underground by improvements in methods of drilling and in handling producing properties. Improvements are also being made in methods for handling the oil after it has reached the surface which will result in reducing losses through leakage and through evaporation. These methods for cutting down waste in production and storage, if universally adopted, will no doubt result in appreciable increases in our supply of crude oil."

Nov 1, 1920

By Roger L. King

The Bureau of Mines has developed probes to be used in emergency mine rescue operations by being lowered through a borehole drilled into an underground mine. Various probes can provide two-way voice communication with trapped miners, continuous mine atmosphere monitoring, temperature indication, and television searching capability. At present, an infrared imaging probe is being developed for "seeing" through coal smoke.

Jan 1, 1976

By Alla D. Mah

The energies of combustion of zirconium carbide and hafnium carbide were measured by combustion calorimetry and the heats of combustion and formation. of zirconium carbide and hafnium carbide were derived . The results are-- ZrC AH298.15 ( combustion) = -308.60 ± 0.55 kcal /mole , AH298.15 ( formation) -47.0 ± 0.6 kcal /mole , AH298.15 = HfC (combustion ) = -306.08 ± 0.20 kcal/mole , AH298.15 ( formation) -52.3 ± 0.4 kcal /mole . = INTRODUCTION This report contains the results of calorimetric measurements to obtain the heats of formation of zirconium carbide ( ZrC) and hafnium carbide ( HfC) . The work was conducted as part of a Bureau of Mines program for determining the heats of formation of oxides , carbides , and nitrides by combustion calorimetry . Combustion calorimetry is one of the most precise calorimetric techniques . The chief obstacle to obtaining accurate heat of formation values for carbides , and the chief reason for the variation in the results of different investigators , is the lack of purity of the carbide samples . Corrections for impurities always involve assumptions which lead to uncertainties . In general , a large impurity correction is accompanied by a large uncertainty in the final result .

Jan 1, 1964