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By John C. Holtz

"INTRODUCTION Information on the gaseous products from the detonation of explosives has been obtained in two ways. In the first, the atmosphere in mines is analyzed after blasting, and in the second, the gases found after detonating an explosive in a testing apparatus are analyzed. The Bureau of Mines, in a cooperative research 3/ that compared data obtained in the field with those obtained in the testing station, showed that the results were not in entire agreement. The production of carbon monoxide was found to be governed chiefly by the oxygen balance of the explosive, but the production of oxides of nitrogen did not change in so simple a manner. Because of the increasing interest in correlations between the composition of the explosive and the production of toxic gases, it seemed desirable to continue the investigation.PURPOSE OF INVESTIGATIONAs field tests are both time consuming and expensive and as field results are affected by factors that are not always under control of or clearly evaluated by the operator, the purpose of this investigation is to develop a testing-station procedure that will reproduce the gaseous products quantitatively under known conditions analogous to those that may be expected in the field. In addition, the factors affecting the formation of toxic gases, particularly oxides of nitrogen, will be studied,"

Apr 1, 1940

By J. H. Maysilles

The Bureau of Mines is conducting research on various technologies to recover alumina from domestic resources for feedstock to existing aluminum smelting capacity as a means to reduce dependence on imported bauxite, which represents 93 pct of U.S. aluminum requirements. One of the more promising technologies being investigated is the hydrochloric acid leaching of kaolinitic clay. In the hydrochloric acid leaching technology, alumina is recovered from iron-free aluminum chloride leach liquor and separated from impurity elements by sparging the liquor with HC1 gas to crystallize aluminum chloride hexahydrate (ACH). A large-scale crystallizer with a 336-gallon usable volume was constructed and operated to obtain engineering and design data for potential scale up and to demonstrate the ability of the technology to produce specification grade alumina. Test campaigns involving about 1,400 hours of operation were completed. ACH meeting all chemical purity requirements could not be produced by a single crystallization, but was produced by recrystallizing the product from the calcined kaolin clay leach liquor. Product crystals with a size distribution of more than 80 pct plus 100 mesh and 65 pct plus 65 mesh were made at a rate of 10 pounds of ACH/(hr)(ft3). The zirconium tube heat exchanger used to maintain constant process temperature operated with an over-all heat transfer coefficient of 420 to 500 BTU/(hr)(ft2)(°F).

Jan 1, 1981

By Stanton L. Tainter

When the disruption of gold mining stopped the usual source of siliceous flux needed by copper smelters , sandstone copper deposits in northern Arizona offered possibilities as a source of the flux during the war emergency . The Federal Geological Survey , while making a comprehensive survey of sandstone copper deposits , investigated the Warm Springs mining district in northcentral Coconino County in August 1943. A month later , J. H. Hedges , chief of the Tucson Division , Mining Branch , Bureau of Mines , examined the operations in connection with an application for an access road . Both investigations concluded that the district , as an emergency source of copper-bearing siliceous flux , had considerable merit , provided high prices for copper continued in effect . Early in 1944 , V. M. Ryan and S. B. Atherley requested assistance from the Bureau in exploring various deposits on their property . The Bureau / drilled 152 holes , aggregating 3,756 feet , on the Petoskey and Mackin groups of claims . This report is based upon churn drilling done under contract from October 7 to November 25 , 1944 .

Feb 1, 1947

By R. E. Green

The Bureau of Mines undertook a bench-scale study of three different types of oxidized taconites3 from the Lake Superior district to improve the dispersion-selective flocculation-desliming process for beneficiating these materials. The response-surface contours of the effects of dissolved ionic species in the water and of three dispersion systems on the selective flocculation process were studied. Results of metallurgical data and chemical analyses of the aqueous phase showed that the water quality affects the performance of the selective flocculation process.

Jan 1, 1984

By Wilbur I. Duvall, Thomas C. Atchison, Joseph M. Pugliese

Short cylindrical charges were detonated in drill holes in rock to determine the effect that decoupling ( defined as the ratio of the radius of the hole to the radius of the charge ) has on the strain - generating abilities of explosions in rock . The amplitude and period of the strain pulses produced in the rock were studied as a function of distance , size of charge , and decoupling . The main results of these studies were that , for a given distance and size of charge , the amplitude of the strain pulse decreases as decoupling increases and the period of the strain pulse decreases at first and then increases as decoupling increases . A simplified theory of decoupling is presented that satisfactorily explains the experimental results . The information presented makes it possible to predict the effect of decoupling on explosiongenerated strain pulses in rock and thus helps the explosives user evaluate the effect of decoupling on his blasting .

Jan 1, 1964

By J. G. Kirby, F. S. LOTT

The mmber of petroleum refineries in the United States decreased during 1949 from 375 to 367 while the total crude-oil charging capacity of refineries continued to increase. A gain in the through-put capacity of 257,305 barrels daily raised the total to a new high level 6,696,300 as of January 1, 1950. The capacity of the average refinery to process crude-oil increased during 1949 from 17,171 barrels daily to 18,246. The four coastal refinery districts accounted for 178,900 barrels or 70 percent of the total capacity increase and the Illinois-Indiana- Kentucky district 57,950 barrels, or 23 percent. Slight declines in capacity were reported in the Texas Inland and the Arkansas-Louisiana Inland districts. The capacity building on January 1, 1950, 145,600 barrels daily, was less than half the amount under construction a year earlier. Most of the new construction involved enlargement of existing refineries and was confined to the East Coast and Indiana-Illinois-Kentucky districts. Two new refineries, however, were under construction, one in Oklahoma and the other in Texas. The shut-down capacity increased for the first time since 1946, and the 473,302 barrels daily reported on January 1, 1950, was the largest recorded since January 1, 1938. The only refining district showing a decline in the shut-down capacity was the Appalachian No. 2 district. The largest increases were reported in the Texas Gulf, Indiana-Illinois- Kentucky, California, and East Coast districts. The operating ratio of the petroleum refining industry, as indicated by dividing the January 1950 runs to stills of 5,483,000 barrels daily by the total installed capacity January 1, 1950, was 81.9 percent, compared with a ratio of 87.8 percent at the beginning of 1949.

Aug 1, 1950

By Joseph A. Sutton, John D. Corrick

The chemistry involved in the microbial dissolution of iron and copper from such sulfide minerals as pyrite, chalcopyrite, chalcocite, cove11ite, and bornite is described. The chemical criteria used to evaluate the activity of microorganisms on these minerals were changes in pH, ferric iron produced, and oxygen consumption. In a series of experiments in which a ferrous sulfate nutrient solution was percolated over small portions of the above-mentioned copper sulfide minerals for 56 days, the iron-oxidizing bacteria Ferrobaci11us ferrooxidans and Thiobaci11us ferrooxidans were capable of bringing about the dissolution of 23.7 percent of the copper from chalcocite, 56.3 percent of the copper from cove11ite, and 29.8 percent of the copper from bornite by the microbial production of ferric sulfate which reacted with these minerals. Laboratory tests have demonstrated that pure strains of the iron-oxidizing bacteria act as catalysts to the ferrous iron being oxidized by the Oxygen of a system containing pyrite and chalcopyrite. In a series of experiments during which nutrient solution was percolated over pyrite for 70 days, the ferric iron produced by the iron-oxidizing bacteria was 112 to 120 times greater than that produced atmospherically.

Jan 1, 1964

By Stuart Bjorklund

This paper is one of many reporting various aspects of the Bureau of Mines program initiated in August 1939 by passage of the Strategic Minerals Act J the scope of which was greatly expanded by subsequent legislation. In its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The occurrence of chromite in the Knik Valley near Palmer, Alaska, was brought to the attention of the Bureau of Mines in September 1941 by George Johnson, of Anchorage. At that time a preliminary investigation was made by Robert S. Sanford, an engineer of the Bureau of Mines. The area was investigated on June 4 and 5, 1943, by Henry R. Joesting and Leo H. Saarela, engineers of the Territorial Department of Mines. In August 1942, a second chromite occurrence, the Highway deposit, in the Knik Valley, was reported to the Territorial Department of Mines by John E. Ryan of Anchorage.

Jan 1, 1948

By Edward E. Johnson

The U.S. economy boomed in 1965, completing its fifth consecutive year of expansion. Although the advance was somewhat irregular, previous records for production, sales, employment, and income were topped. During the first few months of 1965, as the economy recovered from the depressing effects of the automobile strikes of late 1964, increases were unusually large. The gains moderated in early spring, but were stimulated at midyear by sharply rising capital outlays, excise tax cuts, in? creased Social Security payments, and accelerated Viet-Nam defense expenditures. Gross national product (GNP) in cur-rent dollars rose $49.5 billion or 7.8 percent, to a total of S681.2 billion. In constant dollars (effects of price changes eliminated), GNP increased 5.9 percent, a rate considerably higher than the historical postwar annual average growth of 3.5 per-cent. Demand increased in most final markets and was especially strong for business fixed investment and consumption expenditures. With the exception of construction, most of the increases in GNP were real, since prices increased less than 2 percent.

Jan 1, 1966

By Agnes Y. Lee

The Bureau of Mines has developed an effective hydrometallurgical method to recover high-purity Pb metal and elemental S from concentrates. This low-temperature process eliminates S gases and Pb emissions, in contrast to the current high-temperature smelting technology. The method consists of (1) oxidative leaching with H202, Pb02, and waste fluosilicic acid at 95° C to produce a solution of PbSiF6 and a residue containing elemental S, (2) electrowinning the PbSiF6 solution at 35° C to produce 99.99 pct Pb metal and H2SiF6, and (3) solvent extraction to recover S, leaving a residue containing Cu, Ag, and other metal values. Spent electrolyte was recycled repeatedly, with impurity buildup controlled by controlling the leach parameters.

Jan 1, 1986

By James A. Morgan

FIELD MEASUREMENTS OF NOISE WERE MADE ON THE PERIPHERY OF ENCLOSURES DESIGNED, MANUFACTURED AND INSTALLED BY INDUSTRIAL ACOUSTICS COMPANY, INC. ON THE SECONDARY TACONITE CRUSHER AT THE JACKSON COUNTY IRON COMPANY PLANT IN BLACK RIVER FALLS, WISCONSIN. NOISE REDUCTION ACHIEVED BY THE ENCLOSURES WAS SUFPICIENT TO PERMIT REDUCTION OF CRUSHER ROOM NOISE TO 90 DBA, PROVIDED THAT OTHER SOURCES ARE APPROPRIATELY TREATED AND ACOUSTICAL ABSORPTION IS PROVIDED IN THE CRUSHER ROOM. SECONDARY CRUSHER NOISE WAS REDUCED 10 TO 15 DBA BY THE ENCLOSURES.

Jan 1, 1980

By Walter Kawa

In connection with its research in producing synthetic liquid fuels from coal, the Federal Bureau of Mines studied reactions of iron and iron compounds with hydrogen and hydrogen sulfide in batch autoclaves. The Bureau hoped to gain indirect evidence regarding the chemical changes that iron catalysts undergo when they are used in the hydrogenation of coal. The information obtained may be helpful in identifying the active form or forms of iron catalysts. At 450° C., with hydrogen at hundreds of atmospheres and hydrogen sulfide at 1 or 2 atmospheres, the thermodynamically stable form of iron is ferrous sulfide in the case of the metal, magnetite, ferric oxide, ferrous sulfate, ferrous oxalate, or the chlorides of iron. However, complete conversion to ferrous sulfide was not achieved at temperatures of 400° to 500° C. for kinetic reasons. Extensive sulfiding of iron, magnetite, ferric oxide, and ferrous oxalate occurred below 400° C., and some conversion of ferrous sulfate to ferrous sulfide occurred at 400° C. In the hydrogenation of coal, ferrous sulfide is the form of iron likely to be available for heterogeneous catalysis when starting with the metal, oxide, sulfate, or oxalate.

Jan 1, 1960

By D. A. Hill

This volume contains a summary of the results of past analyses on U.S. Bureau of Mines Contract No. H0122061 which are relevant to electromagnetic location in mine rescue situations. The analytical results indicated that detection of a trapped miner equipped with a special transmitter is feasible in most situations. Location of the miner by surface measurements is also generally feasible within certain errors. The feasibility of miner detection and the accuracy of miner location have been examined theoretically for a wide variety of situations. Agreement with experimental results is generally good in cases where measurements are available.

By M. F. Chambers

The U.S. Bureau of Mines conducted experiments on electrowinning of neodymium metal by using a molten-metal cathode at 650° C and an electrolyte of 50 mol pct NdCl3 (neodymium chloride) and 50 mol pct KCI (potassium chloride). The molten-metal cathodes were alloys of magnesium and zinc or magnesium and cadmium. Current efficiencies were 90 pct with a Mg-Zn cathode and 80 pct with a Mg-Cd cathode; The Mg-Cd cathode was easily separated from the electrolyte. In contrast, the Mg-Zn cathode tended to mix with the electrolyte, making separation difficult. The cathode metals were separated from the neodymium by distillation at 1,100° C under a vacuum of 10-3 torr. Neodymium metal of 99.9+ purity was recovered from the Mg-Cd alloy cathode after 30 min distillation time. The neodymium recovered from the Mg-Zn system contained almost 2 pct Zn after vacuum distillation. Continuous operation using the Mg-Cd alloy cathode was demonstrated.

Jan 1, 2010

By Harold E. Marr

Energy dispersion X-ray analysis was evaluated for possible application in the secondary metals industries for the rapid analysis and identification of copper-base alloys. Laboratory investigations of standard brass and bronze samples indicate that X-ray methods are capable of separating standard alloys into 10 general classes with analytical times of less than 3 seconds per sample for clean, flat samples. A radioactive source of americium 241 with a secondary fluorescer was used as an excitation source, and a lithium-drifted silicon semiconductor detector was utilized for energy discrimination of X-rays.

Jan 1, 1974

By F. P. Haver

A method to recover copper and elemental sulfur from chalcopyrite concen¬trate, using a ferric chloride leach, CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S, was reported by the Federal Bureau of Mines in 1971 (Report of Investigations 7474). Since that time, additional work has been done to improve certain steps in the procedure; that is, the recovery of sulfur from the leach residue, the recovery of copper and iron from the leach solution, and the regeneration of the leach solution. It was determined that over 99 pct of the elemental sulfur in the leach residue could be extracted at ambient temperature with an ammonium sulfide solution. Heating the pregnant solution precipitated crystals of rhombic sulfur (99.5 pct purity) and liberated ammonia and hydrogen sulfide for recycle. Copper with a purity in excess of 99 pct was obtained from the leach solution by electrolysis, using a diaphragm cell, with an energy requirement of less than 0.7 kW-hr/lb. Metal was deposited as a weakly adherent powder that could be easily dislodged from the cathode and withdrawn continuously from the cell in the form of a slurry. During electrolysis, part of the Fe(II) was oxidized to Fe (III) at the anode so there was no chlorine evolution. The leach solution was regenerated by direct oxidation of the spent electrolyte with air or oxygen in a turboaerator at 80° C. This precipitated the iron dissolved during leaching in an easily filterable form, Fe203.xH20, and converted the remaining Fe(II) to Fe(III).

Jan 1, 1975

By J. P. Powell

Systematic waterflooding was first tried in Washington County, Okla., in 1937, when a 40-acre project was begun in secs. 24, 29, 32, and 33, T. 27 N., R. 13 E., jointly by the Keener Oil Co. and the Phillips Petroleum Co. The property later was sold to Lee Morrison. A second project was begun in 1941 in sec. 14, T. 6 N., R. 12 E., by the Oklahoma Oil Corp. Both projects were abandoned by the end of 1942. A third project was begun in 1945 and the fourth in 1948, but 1949 actually was the beginning of intensive waterflooding development in Washington County. The results of previous waterflooding projects are described in Bureau of Mines Reports of Investigations.2 3 4/ Oil production in the county followed a similar trend, dropping to a low of 990,000 barrels in 1945, then steadily increasing until 1956, when more than 4 mil-lion barrels of oil was produced. Most of the increase in oil production is directly attributable to water injection.

Jan 1, 1957

By Francis Church Lincoln, Paul Zinner

"Attention of the Bureau of Mines was first directed to the Gray farm area by the results of several exploratory churn-drill holes completed by the New Jersey Zinc Co., and later by Roland J. Teske and by Judge H. L. Heer.When the Bureau of Mines initiated its investigation of the area, all drilling on the Gray farm had been discontinued, and no mining had resulted from the exploratory work. However, in the opinion of the Illinois Geological Survey, the Federal Geological Survey, and the Federal Bureau of Mines, this drilling,with the preliminary geological studies, was considered sufficient evidence to justify continued exploration to the southeast along a projection of the trend of mineralization developed in the mines to the northwest, or the so-called Black Jack Trough.This report describes the work done and presents the data obtained during the period of Bureau of Mines exploratory work.In its program of exploration of mineral deposits, the Bureau of Mines has as its Primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision or Dr. R. S. Dean, assistant director.Special acknowledgment is due Paul Herbert, geologist, Illinois Geological Survey, for his studies of cores, which greatly influenced the planning and progress of the exploratory work. Acknowledgment is also made to A. F. Agnew and A. V. Heyl, geologists, Federal Geological Survey, for their invaluable aid; to 0. W. Terry, F. C. Lincoln, M. H. Berliner, A. M. Cummings, project engineers; and to E. P. Barrett, district engineer, Minneapolis, and E. D. Gardner, regional engineer, Rolla, Mo., for supervising the program.The Gray ore body is on the Gray farm 5 miles south of Galena in Jo Daviess County, northwestern Illinois. The location with respect to adjoining properties is shown on figure 1. Galena is a city of 4,000 population on the banks of the Galena River, a stream that was formerly navigable by Mississippi River steamers but has now shrunk to the dimensions of a small creek. A gravel road leads from the city to the Gray farm and onward to the Bautsch and Boevers farms to the south of it."

Sep 1, 1946

By William E. Bruce

The Bureau of Mines performed drill calibration tests on two industrial percussive drills of 2-5/8- and 3-1/2-inch piston diameters to determine operating characteristics for their use in conjunction with penetration rate data in developing drillability equations and furthering the knowledge of percussive drills. The use of a linear velocity transducer for measuring piston velocities and application of its instrumentation are described. Data presented include relationships between maximum piston velocity and feed air pressure other results confirm the theory or data of previous investigators, and some comparisons are made with the performance prediction formulas of other investigators.

Jan 1, 1969

By J. T. Popp, C. M. McCulloch

This Bureau of Mines study reviews the geological factors that affect methane in the Beckley coalbed in southern West Virginia, including overburden, coalbed structure, type of and changes in lithology above and below the Beckley coalbed, and presence of fractures in the coal and rock adjacent to the Beckley. Depending on the depth, the Beckley coalbed emits from 216 to 520 ft3 of methane per ton of coal mined, and the Bureau estimates that methane emission in a deep, extensively developed mine in this area may exceed 3,000 ft3 per day per ton of coal mined. Average face cleat and butt cleat trends in the Beckley coalbed measured underground are N 33° W and N 53° E, respectively. Close cleat spacing con- tributes to the friable nature of the Beckley and provides easy movement for methane and water. Because rider coals, splits, and carbonaceous shales may contribute methane to mine emissions, predictions of methane emission based on gas content of the Beckley coalbed alone may be conservative. Beckley coalbed reserves in the study area are 234 million tons. The gas content of the Beckley coalbed averages 407 ft3/ton, and the coalbed gas reserves are 108 billion ft3.

Jan 1, 1976