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By J. A. Woolf, E. S. Leaver, A. P. Towne

"INTRODUCTION A report giving experiments dealing with factors affecting the floatation of the most commonly occurring silver minerals was published years ago. At that time we could not obtain suitable samples of many of the so-called sulfo-salts of the base metals, which are generally silver--bearing and which comprise an appreciable percentage of the natural silver ores. Since Leaver and Woolf's work was published, samples of impure tennantite and enargite have been obtained, and considerable experimental flotation work has been done with synthetic mixtures prepared from these samples. During the present national emergency, research dealing solely with the recovery of gold and silver must necessarily be curtailed. However, many deposits of strategic minerals and critical base metals contain an appreciable amount of gold and silver, the recovery of which would aid greatly in recovering the strategies by taking care of a considerable part of the cost of treatment. Because of this, the recovery of precious metals should not be overlooked entirely. As the Bureau of Mines is now utilizing all of its facilities for the development of increased domestic productions of strategic and critical minerals, this is the last report not concerned primarily with such minerals that will be published until the war ends."

Sep 1, 1942

By Arthur C. McFarlan

There are two distinct coal fields in Kentucky-the Eastern field constituting a part of the Appalachian coal region and the Western field constituting the southern part of the Eastern Interior region. The outcrop pattern of the State is dominated by the Cincinnati arch. Coal-bearing Pennsylvanian strata occupy a low structural position on either flank, preserved thereby from erosion, which in the past has removed these same beds, though a much thinner succession, from the crest of the arch. General geological relationships are shown in figures 1 and 2. On April 13, 1750, Dr. Thomas Walker discovered the first coal recorded in Kentucky. He entered the State through Cumberland Gap (Cave Gap) and found coal a few miles north.

Jan 1, 1944

By Martin Hertzberg

The early and reliable detection of the self-heating of combustible substances in mines is of considerable importance to the mining community. This Bureau of Mines report describes the results of a variety of studies of incipient combustion and its detection. Heated samples of coal, wood, and various polymers were used to evaluate the relative sensitivities of several types of detectors. The laboratory results indicate that submicrometer particulate detection is the most universal and sensitive method. Carbon monoxide detection was as sensitive as submicrometer particulate detection for pyrolyzing coal but was relatively insensitive to pyrolyzing wood or plastics. The conventional type of ionization smoke detector was the least sensitive for coal and of intermediate sensitivity for wood and plastics. Self-heating experiments with Pittsburgh seam coal piles of varying particle sizes gave ignition temperatures of 170° C for 4-to 7-µm dust, which increased monotonically with particle size. The measured heating rates were compared with data from an adiabatic calorimeter to obtain preexponential rate constants. The preexponential rate constants varied linearly with the surface area per unit mass of sample as would be expected for heterogeneous surface oxidation. The propagation behavior of ignition waves and the overall self-heating appears to depend critically on the magnitude of the convective flows induced, which counteract the depletion of oxygen in the void spaces of the pile. Classical theories of thermal ignition require substantial modification to be applied reliably to such cases.

Jan 1, 1977

By Albert L. Toenges, Frank A. Jones

"INTRODUCTION The introduction of mechanized pining in coal mines, which has speeded loading, has emphasized the importance of efficient underground transportation systems. The purpose of this investigation is to study and analyze various systems now in use, and to derive conclusions therefrom. This report may be helpful to operators who are planning new systems of transportation or who are revising present systems to increase their efficiency. This paper is the first of a series on this subject and describes some systems of transportation utilizing rail haulage.ACKNOWLEDGMENTThe information used in preparing this report was obtained through the courtesy and cooperation of the officials of the companies whose mines wore studied. The descriptions of the transportation systems at the mines included herein have been checked for accuracy, and publication of the data has been approved by the executives of the several operating companies."

Jun 1, 1940

By G. W. Luxbacher

This volume describes the use of the Penn State Mine Ventilation Simulator (PSU/MVS) to model existing mine ventilation systems and, in addition, to evaluate the effect of system modifications. Ventilation survey methods designed to insure computer input data of sufficient accuracy for simulation purposes are covered in comprehensive detail, including quantity and pressure measurement and fan performance testing. The development of input data from ventilation survey results is discussed and illustrated by the use of an actual field survey. Two programs, written in FORTRAN IV with WATFIV, are presented to calculate airway head losses from altimeter pressure measurements. An existing coal mine ventilation system is analyzed and modifications to the system are simulated and evaluated. In addition the application of the PSU/MVS to non-coal mines is briefly discussed. An extensive bibliography on ventilation surveying and simulation is included.

Jan 1, 1977

The Federal Coal Mine Health and Safety Act of 1969 requires that each operator of a coal mine shall take accurate samples of the amount of respirable dust in the mine atmosphere to which each miner is exposed, a measure designed to prevent the development of coal workers' pneumoconiosis. This textbook manual is used in the training of personnel to operate respirable dust sampling devices and to conduct sampling programs. It contains the portions of the act applicable to respirable dust standards, the procedures to be followed to insure compliance with Federal regulations, and descriptions of sampling devices.

Jan 1, 1971

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

To develop more accurate means of measuring low ventilating air velocities in underground mines to facilitate compliance with ventilation standards. The Approach: A commercially available vane anemometer which produces an electrical, rather than a mechanical, output was coupled to electronic circuitry to produce the Bureau's Digital Low Velocity Anemometer (see photo). [ ] How It Works: The experimental instrument has a vane anemometer head which produces an electrical output signal with a frequency directly proportional to the rotating speed of the vane anemometer shaft. The commercially available ABBIRKO FLOWMASTER anemometer head was used in this instrument. In the signal conditioning circuits the electrical signal from the anemometer is converted into pulses, which are counted during either 3-second or 1-minute intervals, depending on the position of the operator's control switch. (Readout is either "instantaneous" or averaged for a period of one minute.) The number of pulses counted is then translated (integrated and divided by a constant) in the logic circuits to get average speed. Average air velocity in feet per minute is displayed in illuminated digits. (See simplified diagram of circuitry.)

Jan 1, 1975

By D. H. Yardley

A major purpose of this contract was to evaluate a variety of dust suppressants to determine their effectiveness in mitigating dust from taconite tailings. During the course of the investigation tailings from pilot-plant tests of Minnesota copper-nickel ores became available and chemical binders were also tested for dust mitigation effectiveness on this mineralogically different material. Field-test plots were established on taconite tailings and wind tunnel laboratory tests conducted. The laboratory tests consisted of comparing treated and untreated samples at wind velocities of 40 mph using a weight-loss method and direct dust emission measurements. It was shown that the emission of fine dust from taconite tailings, in the range of 4.5 microns to 0.85 microns, could be reduced by 99 percent using certain chemical suppressants. It was also demonstrated that a straight water spray on coarse tailings (3/4" to + 10 mesh) reduced dust emission by 95 percent. Although eight different chemicals were tested, most of the tests were made using Coherex, ammonium lignin sulfonate and sodium silicate. These same dust suppressants were used, singly and in combination on almost 75 field-test plots. The Coherex appears to provide the best results in terms of economics and durability. Wind tunnel tests on treated and untreated Cu-Ni tailings demonstrated that applications of dust suppressants reduced fugitive fine dust by better than 99 percent.

Jan 1, 1980

By P. R. Jones

The Bureau of Mines has written a computer program for the design and cost of a shell and tube type heat exchanger, in which a change in phase occurs on the shell side. The total cost, which was minimized, includes the annual fixed charges and annual operating costs. The program was written to meet the following requirements: (1) Triangular pitch, (2) single or multiple pass, and (3) heating or cooling. Price optimum design was obtained for four standard tube diameters and pitch. Standard heat exchangers whose area equaled or exceeded the required area are also listed. The program was made adaptable to various fluids and to various tube dimensions by including many of the required data such as physical properties of the fluids, tube data, and standard shell data as input data.

Jan 1, 1969

By E. G. Davis

A research program to evaluate the use of ceramic die inserts for ferrous diecasting was initiated by the Bureau of Mines at its Tuscaloosa Research Center. Data were compiled from the literature to characterize selected ceramic materials with respect to thermal properties, thermal-shock resistance factors, chemical reactions with molten metals, and processes required to form die components. With this information and a computer model developed for predicting temperature and stress patterns induced in ceramic materials during simulated ferrous diecasting operations, 27 candidate materials were evaluated. After evaluation, only 15 were considered for testing in an apparatus constructed to immerse the ceramic specimens in molten cast iron. Of these, 13 were tested in a modified testing unit in which cast iron was poured onto the specimens. These tests resulted in the selection of three materials for further testing: boron carbonitride (50 pct B4C:5O pct BN), boron nitride-grade M (BN-M, 40 pct BN, 60 pct Si02), and pyrolytic boron nitride (PBN). Tests in a gravity-flow die unit showed that PBN was thermal-shock resistant and could be used in diecasting of ferrous metals.

Jan 1, 1981

By Robert M. Doerr

The purpose of the investigation was to determine the oxidation behavior of selected tungsten-cobalt alloys. Specimens of Wand W-Co containing 0.7, 1.7, 3.4, and 9.7 weight-percent Co were subjected to pure 02 at 1,000° and 1,100° K, and specimens of W-Co containing 29.8 weight-percent Co, at 1,100° K. Reaction kinetics were determined volumetrically. For specimens other than those containing 29.8 percent Co, the reactions proceeded at about a constant rate at either temperature, indicating the formation of a scale of constant protectivity; the reaction rates were essentially independent of the Co concentration. The scales on these alloy specimens consisted principally of WO3 and CoWO4. Specimens of a 29.8 weight-percent Co alloy, consisting primarily of the W6CO7 phase, oxidized with only slight deviations from the parabolic rate law at 1,100° K. The protective scale on these specimens consisted chiefly of Co3O4, CoW04, and W1 8°49; Co3O4 was outermost, and the W18O49 was adjacent to the alloy. The results suggest that the Co-rich outer scale inhibited the inward transport of 0 to an extent sufficient to greatly limit the amount of the nonprotective WO3 formed, so that protective W18O49 formed instead.

Jan 1, 1967

By Walter R. Storms

"INTRODUCTION Geological examination of the Iron Mountain beryllium deposits was begun by a field part 3/ of the Federal Geological Survey in May 1942. Later in that month the occurrence was examined by the author and C. H. Johnson, of the Bureau of Mines, and a preliminary exploratory program was outlined. Trenching and sampling began about June 15 and were completed in July 1942. A large tonnage of beryllium-bearing material was indicate by this preliminary survey, so that additional funds wore allotted for further trenching and sampling, underground exploratory work, and diamond drilling. This later program was initiated in July 1942 and was completed in May 1943. 4/ACKNOWLEDGEMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilisation of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R.G, Knickerbocker, chief, analyzes samples and performs beneficiation tests."

Mar 1, 1947

By R. E. Brewer

Published investigations show that many different chemical reagents have been used in determining the constitution of coals , but only a few studies have been applied directly in evaluating the effects of such reagents on the carbonization products of coal , Most of the treatments have been so drastic that any permissible conclusions that may be drawn are inferential in respect to any favorable effects on the yields and composition of the usual carbonization products .

Sep 1, 1943

By C. E. Wicks, F. E. Block, F. D. Stevenson

The vapor pressures of tungsten (VI ) chloride ( WC1 ) and hafnium ( IV ) iodide ( HFI ) were measured by a metal diaphragm technique . Vapor pressure values were obtained to permit calculation of the thermodynamic properties of the vaporization processes of the compounds . The vapor pressure data of WC16 are represented by the following equations for the liquid , B - solid , and a- solid over the temperature intervals indicated : - log P = 8.194 3,253 /T Liquid , 281.5 ° to 325 ° C : B - solid 230.0 ° to 281.5 ° C : log P a - solid 185.0 ° to 230.0 ° C : log Pam *** = 8.794 - 3,588 / T = 9.615 - 3,996 /T where T is the absolute temperature in degrees Kelvin . The heats of vaporization and sublimation are 14.9 , 16.4 , and 18.3 kcal / g mole , respectively . The entropy of vaporization at the normal boiling point , 330 ° C , was 24.3 eu . The fusion temperature , 281.5 ° C , and transition temperatures , 230.0 ° and 185 ° C , were found by thermal analysis .

Jan 1, 1964

By Nancy Potts, M. G. Barker, W. C. Holliman

"SUMMARYThis report on the characteristics of commercial aviation gasolines presents compilations of inspection test data furnished on their products by manufacturers of commercial grades of aviation gasoline, and special data obtained in Bureau of Mines laboratories on samples of these gasolines. Data and physical samples for the survey were submitted by 15 manufacturers on 18 grade 80, 21 grade 91/98, 22 grade 100/130, end 10 grade 115/145 aviation fuels.The inspection test data supplied by the participating manufacturers consist of octane and performance numbers, tetraethyllead content, dye color, and other characteristics usually listed in aviation gasoline specifications, such as AN-F-48a or ASTM Designation D910-47T. These data are tabulated and averaged by grades in tables 1 through 4 and, as reported, meet the AN-F-48a and similar specifications with a few exceptions. Two grade 80 gasolines show a lean-mixture octane rating slightly below 80.0, and 91/98 grade fuel shows a lean-mixture rating of 90.9 and a rich-mixture rating of 97.5, two 100/130 grade gasolines have a rich-mixture performance number slightly below 130.0, and one 115/145 grade gasoline shows a rich-mixture performance number of 144.5. However, octane and performance number averages are above the mini¬mum requirements for each grade. Tetraethyllead content in the 91/98 and 100/ 130 grades generally is above the maximum outlined in these specifications, whereas dye color for each of the four grades, with the exception of two gasolines in grades 80 and 100/130, is that designated for the particular grade. Distillation requirements, with a few exceptions at individual points, are met by gasolines of all grades. Reid-vapor-pressure, copper-dish-residue, heat-of-combustion or aniline-gravity-constant, freezing-point, and copper-strip-corrosion requirements are met by all gasolines so far as reported. No data for some of these tests wore submitted on a few of the gasolines. One gasoline, grade 115/145, shows a sulfur content greater than the specified maximum."

May 1, 1948

By Arnold B. Hubbard

A thermal decomposition study of the kerogen in three Colorado oil shales was made at different temperatures by heating the shales in the absence of oxygen at atmospheric pressure and measuring the decomposition products (gas, oil, and bitumen) formed. From these data the specific reaction rates, "k", for the thermal decomposition of kerogen were determined for each temperature studied, making it possible to calculate the time required to accomplish a given amount of decomposition within the temperature range. The influence of temperature on reaction rates was presented by plotting the data according to the Arrhenius equation, thus providing a means of estimating the values of "k" for any temperature within the range of this study. It was found that the specific reaction rates for the thermal decomposition of the kerogen in the three sampler were comparatively equal at corresponding temperatures.

Jan 1, 1950

By C. A. Herbert

The old fatalistic idea that industrial accidents were a necessary part of industry and that little, if anything, could be done about them has been succeeded by realization that a majority of the hazards causing these accidents were man-made and that if they could be recognized most of them could be eliminated and the accidents prevented. Recognition of these facts has brought about substantial reduction of accidents in many coal dines, as well as in other industries. Knowledge of the hazards and their elimination has been obtained largely through a study of individual accidents and the causes which led up to them. With this thought in mind tae available data on coal-mine explosions in Illinois were studied.

Jan 1, 1934

By William F. Hahn

This project focused effort on three separate areas: demonstration of a low seam longwall illumination system, design of illumination systems for low coal auger miners, and an assessment of machine lighting systems for machinery used to mine low seam coal. Results indicated illumination systems can be purchased by the mine operators of low coal seams. These systems can be supplied with the equipment as a factory integrated system or can be retrofitted to the machine or longwall equipment.

Jan 1, 1982

By W. P. Yant

This report describes result of a study of the carbon monoxide and particulate matter in the air of the Holland, Tunnel and metropolitan New York made by the Bureau of Mines (which had participated in the development

Jan 1, 1941