Search Documents

By T. Piirainen, T. Alapieti

"The Koillismaa layered igneous complex is the result of igneous activity that occurred 2436±5 m.y. ago. Its crystallization took place in three separate but connected magma chambers, the total volume of which is estimated at more than 2000 km'. These chambers were located partly in a feeder system within Archaean granitoids and partly in an unconformity between these grani­ toids and Early Proterozoic supracrustal rocks. The composition of the parental magma that initially filled the chambers is thought to have been that of a relatively MgO-rich tholeiite. Sulphides and platinum-group minerals are mainly concentrated in the marginal series of the western part, where they are encountered over a distance of 25 km. This marginal series is an originally nearly horizontal series of rock types that displays a reversed differentiation trend, grading inwards from gabbroic to ultramafic rocks, followed bv rocks of the layered series. The chilled margin is not encountered anywhere in its original position at the contact, probably as a consequence of magmatic erosion, but remnants are to be found in the form of elongated xenoliths. Partly melted siliceous fragments from gneissic country rock typical of the lower part of the marginal series indicate pronounced contamination.Chalcopyrite, pentlandite and pyrrhotite±pyrite are the predominant sulphides. The accessory sulphide minerals include covellite, violarite, marcasite, mackinawite, sphalerite and argentian pentlandite. Platinum-group minerals are represented by froodite, michenerite, merenskyite and sperrylite. Other accessories that have been identified are electrum and native copper and gold. The mean of the Cu/(Cu+Ni) ratio in the mineralizations is 0.67 and Pt/(Pt+Pd) 0.31.It is suggested that the sulphide phase was formed in the marginal series as the solubility of sulphur in the basic magma was lowered by contamination, possibly assisted by some other factors. The sulphur isotope data support the juvenile origin of the sulphur."

Jan 1, 1984

By C. A. Pickles, S. J. Splinter, J. Cameron

The addition of copper oxide to a borosilicate slag resulted in the breakdown of the silicate network and a dramatic decrease in viscosity. With increasing borax to silica ratio the viscosity was reduced by two mechanisms. First, rising sodium oxide content promoted cleavage of the Si-O bonds. Second, increasing boric oxide (B2O3) content increased the number of trigonal borate units that were converted to tetrahedral borate units by sodium oxide and copper oxide. The BO4(4-) tetrahedra decreased the local silicate symmetry, thus disrupting the silicate network and lowering the viscosity. The activation energy decreased with increasing temperature and increasing copper oxide content

Jun 13, 1905

By J. M. Smith

This resume provides an account of the work of the Bureau and it's establishment by an Act of Parliament in August 1916. The Medical Bureau is concerned solely with the administration of the medical provisions of the Act. Its main functions are to conduct and to direct or control the medical examinations provided for in the Act. The paper covers the changes in type of silicosis, classification into the three legal stages of silicosis, cancer of the lung and tuberculosis.

Jan 1, 1947

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

Further discussion at the Mniing Institute of Scotland's annual general meeting held in Glasgow, 8th April 1916, of the paper published in Trans. I.Min.E. vol li, 1916, p.169-186 with discussion p.187-188, included oral and written contributions by McLaren R. and Waddell H.

Dec 1, 1916

By T. Sharma, T. C. Rao

Laboratory studies have been carried out on acid leaching as a possible route for the extraction of potassium from glauconitic sandstone. Leaching efficiencies with sulphuric, hydrochloric and nitric acids were investigated. The effects on potassium dissolution of temperature, concentration and type of acid, stirring speed and leaching time were also studied. The results show that it is possible to recover 87.5, 93 and 85% potassium with 5 M H2SO4, HCl and HNO3, respectively. During the initial stages of the sulphuric acid leaching process the chemical reaction at the mineral surface is the rate determining step, whereas during the later stages diffusion through the product layer is rate-controlling. Overall, the process follows a mixed-control model that includes both chemical reaction and diffusion. The activation energy for the dissolution of K was found to be in the range 25.79-106 kJ/mol.

Jan 12, 1992

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By Eric Forssberg, Vigen Zeng

During mechanical grinding high intensity vibration is emitted that contains information on the mill's operating state. Tests, using a laboratory ball mill, studied the influence of operating parameters on the vibration signature. The parameters studied were: mill speed; powder filling; pulp density; grinding period; and pulp temperature. Vibration signals were detected by an accelerometer, amplified by a vibrometer and recorded onto digital audio tape. A digital oscilloscope converted the signals into IBM-compatible data format. Digital signal processing and multivariate data analysis were carried out with specially developed software. The power spectral density was estimated from the time-domain vibration signal. Four new latent variables were used to describe changes in the vibration spectra. A relationship was established between operating parameters and latent variables which could form the basis of a quick and automatic method of monitoring operating parameters in ball mill grinding.

Jan 4, 1993

By D. D. Lei, H. Sevim

Long-term production planning in open-pit mines requires the determination of cut-off grade, mining and milling production rates, a mining sequence, mine life and ultimate pit limits. Since these variables interact in a circular fashion, a genuine solution to the problem necessitates their simultaneous determination. A methodology with this capability is described. This comprises a group of heuristic algorithms and an unconventional dynamic programming algorithm. The method is demonstrated using data for a gold deposit in the western USA

Jul 1, 1996

By Ruddle R. W.

An outline account is given of the smelting of copper and the chemistry of the process. A table provides compositions of the more important minerals from which copper is won by smelting. Roasting is discussed as is smelting using reverberatory furnaces, blast furnaces and flash smelting. A brief discussion of converting covers the upright (Great Falls) converter and the horizontal (Peirce-Smith) converter.

Jan 1, 1953

By M. D. Pritzker

Shrinking-core models are used to describe the physico-chemical processes that are associated with many metallurgical gas-solid and liquid-solid reactions. The models can be used to evaluate rate constants and effective diffusion coefficients from experimental data. This work generalises the model for diffusion through a product layer to cases where the transport of more than one species is rate-controlling

Jul 1, 1991

By R. Scheepers, J. E. Misiewicz, A. C. Fitzgerald

Discussion by A.C. Fitzgerald of the paper, published in Trans. IMM A, vol.104, 1995, p.B121-B135, is presented together with the authors' response. Fitzgerald points out a number of problems with the idea of mineralising fluids leaving no trace in the large volumes of rock traversed before depositing all minerals of value in a particular horizon or rock type with which the required isobaric or isothermic surface also coincides. He suggested that in the case of the Rooiberg tin deposits, the Lebowa Granites may be batholiths that reached the surface and were capped by sheets of their own volcanics. The authors agree that they had considered a possible syngenetic origin for the stratabound deposits, explain that no conclusive evidence for this could be found, discuss the relative ages of the sediments and volcanics of the Rooiberg Fragment and explain the role of its low-intensity deformation and flat dip in the coincidence of an isobaric-isothermic surface with the lithological stratification

Jun 18, 1905

By Fearnsides W. G.

The map shows the sites of collieries and important boreholes in the district, with approximate underground contours of the pre-Permian surface of the Coal-Measures and of the Barnsley Bed

Dec 1, 1916

By M. A. Bussell, G. S. Camm

The study included lode zones at Wheal Pendarves, South Crofty and Rosevale tin mines. Fluid inclusion-containing microfractures are a common feature of the granites and typically show a preferred orientation over quite a large area. The close proximity of a dominant vein or fault controls their density and orientation. They are important pathways for fluids and provide a marker for palaeo-fluid flow. Overprinting provides a reliable representation of the evolution of the hydrothermal fluids in a vein system from early magmatic fluids to late-stage meteoric and basinal brine input. Measurement of microfracture orientation allows estimation of the regional stress regime during a specific hydrothermal event. Since micro- and macro-structures can generally be reliably correlated, these studies assist in modelling the detailed development of complex vein systems. Microfracture density is a good measure of palaeo-permeability, with implications for control of wallrock alteration. The determination of the location and density of microfractures can assist the mine geologist in identifying the location of potentially economic vein structures where macroscopic markers are absent

Aug 1, 1996

By M. D. Gibbs, T. N. Smith, B. Verbaan

When heated in the absence of oxygen, pyrite from refractory gold concentrates decomposes endothermically to pyrrhotite, releasing sulphur. The decomposition starts at the particle surface and progresses inwards, leaving an adhering layer of porous pyrrhotite. Use of the conventional shrinking-core model implicitly assumes a negligible partial pressure of sulphur in the bed, but this pressure is in fact at least equal to the equilibrium vapour pressure of sulphur over pyrite, constituting the principal control of the rate of decomposition. Further experiments showed a decrease in reaction rate as the conversion increased. Both phenomena are attributed to the persistence of non-isothermal conditions in the fluidised bed during pyrolysis, caused by the endothermic nature of the reaction and the relatively slow rates of heat transfer to particles and vapour removal from the bed. Equipment must be developed to maximise these two parameters

Jun 19, 1905

By D. Mireku-Gyimah, R. S. Suglo

Ghana contains auriferous belts which cover 51 800 km2 of its small area of 239 400 km2. From 1493 to 1600 35.5% of the world gold production was from the Gold Coast (renamed Ghana in 1957). This dropped to 8.9% from 1701-1800. For the past fifteen years annual production has averaged less than 2% of the world total. By 1985 only four gold mines were operating, compared with 45 in 1934 and 11 in 1945. Since 1987 Ghana has experienced a boom in gold mining activities. By 1991, 83 new companies had acquired prospecting licences. At least five new companies have started large-scale production. About 650 licensed small-scale mining groups are in operation. The economic and technological factors that have contributed to the decline of gold production in Ghana are discussed. A summary is given of the methods used to mine and recover gold. These cover small-scale workings, dredging, open cast operations and underground mining. The advantages and disadvantages of these technologies and the future of gold mining in Ghana are considered.

Jan 4, 1993

By Winmill T. F.

Among the various theories proposed to account for the spontaneous ignjtion of coal, one which has at times been very strongly held is that the initial heating is due to the oxidation of iron pyrites. From the results described in this paper, it is possible to calculate roughly the rate of spontaneous heating of a specimen of finely-divided pyrites, on the assumption that all the heat developed is used in raising the temperature of the pyrites, and that none is lost. It is clear that where finely-divided pyrites occurs in considerable proportion among coal, it may be the chief factor in originating combustion, but that pyrites can only be the cause of a heating when it is present in considerable proportion, and in a very finely-divided state

Dec 1, 1916

By M. C. Amiri

The plant produces 130 kg slag per tonne of crude steel, to add to the basic oxygen steel-making converter slag stockpile of around 2 500 000 t. The slags contain 1.81% V2O5, which can be rendered water-soluble by salt roasting with NaCl and an alkali such as Na2CO3. Preliminary tests gave less than 3% V recovery from slag under optimum roasting conditions when NaCl, NaCO3 or Na2SO4 was used, but showed that sodium phosphate could make all the V water-soluble when roasted with slag in a ratio of 3:1 at 1 100-1 200 degrees C. Almost complete leaching was obtained within 2 h with water at boiling point. Sodium vanadate was precipitated by acidifying the leach liquor with HCl to a pH of about 2.2

Jun 21, 1905

By Z. H. Khan, A. K. Saha, D. D. Akerkar

The possibility of extracting nickel from a low-iron, highly siliceous nickel ore of Indian origin using roast reduction followed by an ammonia leaching process has been examined. The ore used in the investigation contained 0.82 wt% Ni, 6.20 wt% Fe3O4, 12.04 wt% MgO and 60 wt% SiO2. Phase changes in the constituent minerals on heating were studied by differential thermal analysis which revealed endothermic peaks at 110 and 695 degrees C and an exothermic peak at 810 degrees C. Significant process variables in studies of roast reduction include the amount of reductant, the temperature of reduction and chemical kinetics. Maximum nickel extraction was achieved by reducing the ore with 10 wt% fuel oil at 750 degrees C. The reduced ore was given a preconditioning treatment in concentrated ammonium hydroxide solution to oxidise most of the metallic iron and was then leached in aqueous ammoniacal solution at ambient temperature to dissolve nickel. This gives 88.5% extraction of nickel as soluble ammine complexes.

Jan 4, 1992

By G. D. Nicholls

There have been very few attempts to isolate the various factors that contribute to the overall imprecision of geochemical analytical procedures, due in part to the difficulty of distinguishing between them. The technique of spark source mass spectrography permits a ready distinction between the contributions to overall precision from sampling error and instrumental and other errors. With conventional methods of sample preparation for this technique sampling difficulties are responsible for 80-90 per cent of the overall imprecision. Examination of the probable location of the major difficulties in sample preparation indicates that the preliminary stage of grinding, mixing and extraction of a first aliquot (about 1/100 of the original sample) is generally perfectly adequate. The difficulty lies in the subsequent stages of sample preparation. Dry mixing techniques are unlikely to give good precision if the sub-samples actually examined by the analytical technique are less than 10 mg in amount. Solution techniques are less prone to sampling difficulty. Fusion techniques, unless conducted with great care, can produce more difficulty than dry mixing. Sample preparation is critical to the success of many analytical procedures. Selection of appropriate sample preparation techniques requires just as much care as the selection of techniques for the actual analysis.

Dec 1, 1971