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By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Industrial minerals may contain the same elements in approximately the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques.• quantitative measurements by ebsdCommon automatic techniques describing the mineral contents and the occurrence of minerals in free and locked particles, are based on optical-, backscattered electron (BSE)- or X-ray-signals. There are various commercial software systems on feature analysis by backscattered and X-ray signals in combination with image analysis (e.g. Oxford Inca Feature, CSIRO QemScan).Especially in silicates, the occurrence of similar elements in the different minerals is common. Sometimes the various minerals not only contain the same elements, but also approximately the same amount of each element. In these cases BSE imaging and chemical analysis are not always sufficient for identification."

Jan 1, 2003

By H. U. R. Kattentidt, W. L. Dalmijn, T. P. R. de Jong

"Research at Delft University aims to develop systems for automatic inspection and sorting of bulk solids which can be applied in the mineral processing and recycling industry. A recent development includes an automatic sorter based on airport X-ray inspection technology. It is designed for continuous inspection and sorting of 5 – 150 mm solids and has as objective a cost effective and high capacity on-line inspection and sorting.Dual energy X-ray transmission imaging provides instantaneous data about particle dimensions and the atomic number distribution. The system provides particle thickness and average atomic number on a pixel level at scanning speeds between 250 and 500 lines / second. With existing X-ray components inspection speeds between 0.5 and 2 m/s at approximately 1-meter inspection width and between 1.5*1.5 and 5*5 mm2 sensor resolution can be achieved.Imaging algorithms that were developed by Delft University for applications in recycling, waste cleaning and other applications acquire shape, size distribution and composition data. Currently on-line processing of a product at a rate of around 200 particles per second is possible using a standard PC. Experiments with a demonstration X-ray unit indicated good potential for various applications in solids processing. They include continuous inspection of organic content, sulphur, chlorine, ash, and metal distribution. It is applicable for coal cleaning, ore sorting, industrial minerals, and various applications within waste cleaning and recycling. Dual energy X-ray transmission fundamentals and recent progress in system development and applications are presented."

Jan 1, 2003

By Natalie J. Shackleton, Deryck de Vaux, Cyril T. O’Connor, Vratislav Malysiak

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. The objective of the study was to investigate the effect surface passivation and inadvertent activation have on flotation and how this can be managed so as to increase the separation of pentlandite and pyroxene. The aim was to minimise the percentage pyroxene reporting to the concentrate and simultaneously maximise the pentlandite recovery. The testwork incorporates the addition of an activator (copper sulphate), a complexing agent, such as DETA (diethylenetriamine) and a dispersant (polyphosphate) at pH 6 and pH 9 in an attempt to alleviate the surface passivation of pentlandite and inadvertent activation of pyroxene. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion."

Jan 1, 2003

By Vladimir I. Ryaboy, Konstantin M. Asonchik

"At flotation of sulfide-barite ores of one of deposits sulfide and barite concentrates are obtained. In sulfide cycle potassium xantogenate as a collector in consumption of 200 g/ton, methylisobutylcarbinol (MIBC) as a foaming agent in consumption of 30 g/ton and also liquid glass are used. In barite cycle tall oil as fatty acid collector in consumption up to 400 g/ton is used.Sulfide concentrate represents mainly gold- and silver-containing pyrite. The contents of gold makes not less than 10 g per ton, silver - not less than 278 g/t. Barite concentrate contains up to 86% of barite.Factory is working in water recirculation conditions. Owing to that in barite cycle fatty acid collector is used, technological water from tailing repository contains fatty acids soap up to 25 mg/l. Before submission into sulfide cycle this water is conditioned with active carbon to delete the main part of fatty acid collector. The active carbon consumption makes 0,4-0,5 kg per 1m3 of water or 1,5-2 kg per ton of ore. The above mentioned consumption of active carbon improves reducing of contents of fatty acid collector from the initial concentration of 25-30 mg/l to 4 mg/l. At concentration 4 mg/l fatty acid collector does not render negative influence on flotation index in sulfide cycle. At the absence of active carbon pollution of sulfide concentrate and its irrevocable lost are observed."

Jan 1, 2003

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed, dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimization.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By Benoit Clermont, Jan Lux

"Magotteaux and Anglo Platinum started a co-operation program with the main aim of establishing the optimum milling configuration measured in terms of throughput, fineness and energy consumption.For this purpose, a fully instrumented pilot milling plant, supplied by Magotteaux (Pty) Ltd, and equipped with a 0.9 x 1.0 m ball mill, was erected at Frank concentrator (Merensky Pt ore). The primary ball mills at Frank concentrator were surveyed in order to set the conditions for the base case. This data was then replicated in the pilot mill under the same configuration. Thereafter, a series of different parameters were varied in order to attempt to optimize the milling system.Only grate versus overflow discharge and open versus closed circuit will be discussed in this paper.It should be noted that this paper does not attempt to give a universal solution as to what milling configuration is optimum in all cases. The conclusions apply for this particular case and probably most others, but it would be advisable to consider each case on its own.CONCLUSION• Overflow versus grate dischargeAn overflow mill has a “pool” of slurry around the toe of the ball charge, which creates a counter lever to the ball charge. This will reduce the absorbed power in the range of 10-15% (depending on the case) and will consequently result in a coarser grind. The tests found a 4% gain in grinding efficiency (Wio) with an overflow mill but this is probably not significant.This lower absorbed power and coarser grind can be counteracted by increasing the ball charge (if below maximum) and/or by increasing the mill volume when removing the grate discharge (a typical grate takes up about 300mm of the mill length).• Open versus closed circuit"

Jan 1, 2003

By P. Harris

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By Zoran M. Stevic, Mirjana M. Rajcic-Vujasinovic, Zvonimir D. Stankovic

"Huge electrochemical investigations have been performed on Technical faculty in Bor (Serbia) which main goal was the clarification of the copper sulfide minerals behaviour in hydrometallurgic and flotation processes. Modeling of these processes was a part of the effort for better understanding of the reaction mechanisms.The consideration of electrical analog circuit and mathematical model of processes at interfaces copper sulfide/electrolyte (CuS/(CuSO4+H2SO4), Cu2S/H2SO4 and CuFeS2/H2SO4), based on studies of the overvoltage – time transients, will be presented. The transients were obtained using single pulse galvanostatic method and electrochemical cell with standard three electrode assembly. In that goal it was developed an original system for computer measurements that enables the application of several methods for electrochemical investigations (galvanostatic, potentiostatic, cyclic voltammetry, electrochemical impedance spectrometry etc). The system was tested and adjusted using commercial electrochemical equipment made by AMEL, Milano.In the first stage of consideration the different equivalent electrical circuits have been tested by computer programme OrCAD 9.2 in order to identify the circuit with responses equivalent in shape to experimentally obtained ones. In that way it was established a configuration of an analog electrical circuit for investigated electrochemical system. That phase enabled only very rough determination of values of circuit components and their relative ratio.In the second stage the method for determination of all elements of electrical analog circuit is described. It is based on mathematical consideration of a given circuit on one hand, and valves of the overvoltages at selected times, obtained from charging and discharging parts of galvanostatic transients, on the other."

Jan 1, 2003

By Stephen Gay, Dewetia Latti

"When improving a plant a mineral processing engineer would like to know the mineral composition distribution. In order to assess this distribution in particles, as compared to the corresponding distribution in particle sections, a procedure needs to be applied to the observed particle sections. Such a procedure is called a stereological correction. There exists many stereological correction procedures, but one group of such procedures is based on using those stereological equations that do not require making assumptions regarding particle shape or texture. These equations are called geometric probability equations.Davy derived a geometric probability equation to estimate the covariance of mineral composition distributions for particles from both particle sections and linear intercepts. This covariance can be used to measure the variance of the particle composition distribution of each mineral. The equation as presented by Davy requires textural information; however the equation was modified by Gay to be more directly applied to particle sections and linear intercepts. The variance obtained from applying this equation is fundamental to the binary stereological correction procedures developed by Gay and his colleagues; the covariance is fundamental to the multiphase stereological correction.Thus far, validation of both the binary and multiphase stereological correction has been achieved using numerical simulation. This paper shall present results comparing the covariance (and variance) estimates from Gay’s equation with actual three-dimensional information obtained from serially sectioning particles. This involved mounting a set of particles and continuously sectioning all particles uniformly so that the three dimensional structure of the particles could be obtained.The mineralogical data to which the equations described above were applied were derived from two individual size fractions from a hard-rock titanium deposit. The deposit contains a range of minerals and of mineral textures and the two size fractions selected were:"

Jan 1, 2003

Hydrofluoric acid (HF) is traditionally used in plant operation to separate feldspars from quartz. It acts during the conditioning step as a pH regulator and an activating agent providing an excellent selectivity. However, a corrosive chemical environment and the ecological impacts from the potential fluoride ion contamination are limiting factors to use this chemical agent at an industrial scale. Investigations of the amine-feldspar interactions in the absence and presence of non-linear long-chain alcohols were carried out on two ore samples. The presence of alcohol molecules led to form a closed packed layer only on the surface of feldspars. The highest order and packing at the feldspar surface were observed with a particular alkyl chain structure as Guerbert alcohols. A new flotation process was developed and tested at both lab and pilot scales on different feldspar ores. The Guerbert alcohols allow to perform a feldspar concentrate with very low content in quartz (2.3-3.5 %) and feldspars recovery from 78 to 81 % while the aliphatic isoalcohols show a more higher recovery level (88-89 %). New HF-free process is strongly dependent on the pH range (1.7-2.5) and sulphuric acid consumption during conditioning steps. Optimal amine/alcohol weight ratio is ranged between 0.8 and 1.0. The values below 0.8 decrease strongly the flotation selectivity and the quartz recovery within the feldspar concentrates is higher than that occurs with HF.

Sep 1, 2012

By Sun Chuanyao, Jia Muxin

Generally, if the bond valence (BV) between metal ion and oxygen of the mineral is greater than 0.8, only surface species –Me-O-H or –Me-O exposures on the mineral interface, if the BV is between 0.2-0.8, the metal ion exposures on the interface, and if the BV is less than 0.2 the metal ion dissolves into water. The PZCs of oxide minerals and island silicate minerals are determined by the bond valence of the bond in the mineral crystals, the higher the bond valence the lower the PZC of the mineral. So the PZC sequence of Al2SiO5 minerals is kyanite> andalusite> sillimanite. The general rule for framework silicate minerals is as: The higher the Al content, the lower the PZC of the mineral, when the ratio of Al to Si in the tetrahedron skeleton is below 1:3. The higher the Al content, the higher the PZC of the mineral, when the ratio of Al to Si in the skeleton is between 1:3 and 1:1. The general rule for layer silicate minerals is summarized as: the three-layer silicate minerals have much lower PZCs than that of the two-layer silicate minerals. The threelayer silicate mineral with the octahedron layer occupied by lower charged cations has lower PZC than that of the three-layer silicate mineral with the octahedron layer occupied by higher charged cations. The twolayer silicate mineral with the octahedron layer occupied by lower charged cations has higher PZC than that of the two-layer silicate mineral with the octahedron layer occupied by higher charged cations. The layer silicate mineral with Al substitution in the tetrahedron layer has lower PZC than that of the layer silicate mineral without Al substitution in the tetrahedron layer. Such pyroxene minerals whose M1 is occupied by a trivalence cation and the M2 is occupied by a monovalence cation has lower PZCs than those both M1 and M2 are all occupied by bivalence cations. Such hornblende minerals whose M2 is occupied by a trivalence cation and the M4 is occupied by a monovalence cation has lower PZCs than those both M2 and M4 are all occupied by bivalence cations. There is no Si4+ or 4 coordinated Al3+ exposures on the surface of framework silicate minerals, the metal ions of three layer or chain silicate minerals are compact between tetrahedron layersor chains, they hinder the metal ions to interact with oleate acid radical, the metal ion octahedron layer exposures on the surface of a two layer silicate mineral, but the the oleate acid radical can not attach to a metal ion by replacing a –OH- that connects three metal cations in the same time, So the floatability of such silicate mineral is bad. The metal octahedron chain style of an island silicate mineral affects it floatability, the mineral exposures octahedron chain metals with two dangling bonds in two directions floats better than the mineral exposures octahedron chain metals with two dangling bonds in one direction.

Jan 1, 2003

By Ralph J. Holmes, Victor Sharp, Steven J. Spencer, CSIRO Minerals, Kevin J. Davey, Jonathan J. Campbell, Peter L. Phillips

"Improved measurement tools for monitoring and control of AG/SAG mill performance have a high level of interest in industry. Historically, acoustic emission monitoring has been widely used on SAG/AG/ball mills and hydrocyclones to provide new information on the conditions inside these devices affecting their performance. The current work was focused on a new technique using surface vibration monitoring of a number of pilot-scale and production-scale AG/SAG mills to yield insights into the events occurring in the mills. The development of relationships between signal analysis outputs and mill operating conditions can be used for soft-sensor measurement of mill process variables. The technique used an array of accelerometers mounted on the mill lifter bolts linked to a fast data acquisition system which monitored the surface waves generated during operation. Details of the system are presented. Mill operating variables were adjusted systematically to provide a wide range of operating conditions for surface vibration signal collection. The experimental approach is discussed.The signals acquired during the experiments were analysed using a range of techniques. The results show that strong relationships exist between measured vibration power (both total power and within certain frequency bands) and mill load level/power and mill speed. A new method for extraction of power spectral density and band power information on features of interest in a mill rotation cycle is also presented."

Jan 1, 2003

By Wayne I. van Drunick

"Energy balance modeling has recently been shown to be a competent tool in the estimation of SAG mill discharge rheology. Work performed by van Drunick and Moys (2001) validated the ability of an energybalance filter to estimate the slurry density from an operating SAG mill. The importance of rheological data is highlighted by several authors who show the effects on load behaviour and thus mill performance. Energy balance models were developed to account for the dynamic energies in the mill discharge sump. The models then made it possible to infer the mill discharge density. A sampling campaign was performed and the errors from the sump energy balance were within tolerable limits.Since the initial results were published, it has been decided to further develop the modeling techniques in order to focus on balancing the energies around the entire mill. The critical measurements for the energy balance will be the temperatures of all the streams entering and leaving the mill, including energy losses to the environment. Metso’s OCS© (Optimising Control System) currently controls the 3 SAG mills at Anglogold’s Mponeng Gold Plant (South Africa). The OCS has built-in Kalman filtering tools to effectively handle variances and noise in the models and the mill circuit data respectively. The new models are therefore constructed in the OCS platform, and will be run in parallel with Metso’s current modeling and filtering systems. The work is a collaborative effort between Anglogold, the University of the Witwatersrand and Metso. The benefits of energy modeling, compared to mass modeling, are that energy data are more accurately measurable than mass data. The inferred mill parameters can therefore be improved provided that a competent set of models is produced to process the (accurate) thermal measurements."

Jan 1, 2003

By Vladimir P. Nebera, Kostas A. Matis, Piotr M. Solozhenkin, Anastasios I. Zouboulis

"Considered combination of two processes-selective sorptions of metals on biosorbents, inorganic sorbents and their following flotation by dissolved air(DAF). The process of biosorption, using as sorbent suspended non-living biomass (of Streptomyces genus, S. clavulgerus and S. griseus, fungi-Penicillium chrisogenum and Phizopus arrhizus, active slime) in fine particulate dispersion, combined with the application of flotation, for the consequent solid / liquid separation of metal-loaded biomass, has been studied for the removal of toxic and noble metals from dilute aqueous solutions. Biomass of microorganisms possesses great sorptive capacity, exceeding capacity of synthetic and natural sorbents. For instance, Micrococus luteus sorbed gold for 2h Au 253mg/g.The optimal conditions of effective flotation (more than 90%) of actinomyces biomass, loaded with toxic metal-cadmium were found. The adsorpbing flotation technique for copper, arsenic (III, V), chromium removal of metals on pyrite mineral fines (suitable industrial by- product) is an effective process.Dissolved-air flotation was also apllied in the case of dolomite/lead aggregates removal. A fatty acid was used as a flotation surfactant. The presence of dolomite fines aids the efficiency of the process, in comprarison with the flotation of alone lead hydroxide.A laboratory investigation was undertaken on the gold-thiourea system over the whole pH range, aiming at the separation complex of gold [Au(CS(NH2)2]2+ by flotation from dilute solutions. The reagents were found to improve gold recoveries remarkably: the recovery reached over 95%. A separation technique has been investigated, involving gold adsorptionon powdered activated carbon. Foam flotation was employed for the subsequent solid/liquid separation, using sodium oleate as surfactant. The content of Au were 500 mg/L in froth and recovery gold about 100%."

Jan 1, 2003

By M. Brozek, W. Pawlos

"The separation of raw materials in the separator with ferromagnetic liquid occurs due to differences in magnetic and gravitational properties of respective components in relation to each other and to the liquid. In the separator with wedge-shaped pole shoes and the working space axis inclined at a certain angle to the horizontal direction, the paths of grain movement at fixed separation conditions depend on its physical properties. Due to this, the levels of grains outlet from the separator working space are differentiated according to differences in their physical properties. The distance between the levels of outlets from the separator working chamber depends on magnetization of the liquid which is proportional to the liquid density, on the magnetic field intensity and the inclination angle of the separator working passage to the horizontal axis. The separation accuracy is higher the larger is the distance between the outlet levels.The paper will present the methods of visual observation and recording of movement paths of coal grains of different physical properties in the paramagnetic liquid which was the water solution of manganese chloride. The paths were recorded with a video camera in the working chamber by means of a specially constructed device, acting as a periscope, which were then transformed into digital images. Experimental movement paths were confronted to the paths obtained in a theoretical way by means of solving differential equations of movement by a numerical method, achieving good compatibility of experimental and theoretical results. The equations of movement were solved with taking into consideration the drag force, expressed by formula for laminar and dynamic conditions of motion.The course of the path of grain movement depends on grain and liquid physical properties, magnetic field intensity and inclination angle of the working space to the horizontal direction. The two latter parameters can continuously control the process of separation."

Jan 1, 2003

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool, HeapSim. Some of the sub-processes that are modelled include mineral kinetics, particle size effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation. The interplay of these various sub-processes is illustrated in the paper.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. The first is focussed on chalcocite heap bioleaching, which shows that by nature of the reaction the process is strongly dependent on the initial supply of acid to the mineral site. In heaps this acid supply can be severely limited by the rate of diffusion from channels of flowing solution into stagnant zones of the heap, whereas in narrow-bore laboratory columns this effect is not observed."

Jan 1, 2003

By N. Raeis Hosseiny, S. H. Bassir

"Chador-Malu iron ore is one of the most important iron mines of Iran.About 98 percent of Fe in the ore is in shape of Magnetite, Hematite, Martite, aqua oxide of Iron and the other irons are with ferrous silicates, actinolite, cholorite and ferrous dolomites. 1% of Fe has replaced in pyrite. The phosphor distribution in the ore is non-hemogenous and its average in the whole of the deposit is 94%. It is in shape of Apatite.This mine contains considerable phosphor, which makes it useless for metallurgical uses. At this mine the phosphor is reduced in the iron ore at two steps. At the first step, magnetic part of the ore is separated from the gangues and phosphors by magnetic separator. At the second step, the ore is enriched by the flotation methods. Experimental flotation methods to obtain the optimum conditions are as follows:• Effect of Starch as Hematite depressant with ATRAC as Apatite collector• Effect of Sodium silicate as Hematite depressant with ATRAC as Apatite collector• Effect of ASAM as Apatite collector with Sodium silicate as Hematite depressant• Effect of ATRAC (BEROL) as Apatite collector with Sodium silicate as Hematite depressant• Effect of ASAM & ATRAC mixture as Apatite collector with Sodium silicate as Hematite depressant• Effect of Kcarbonate as pH-modifier• Final test to Optimize pH, Collector, DepressantAt this research we have found the optimum circumstance of the flotation of Chador-Malu iron ore in order to decreasing phosphors of iron oxide and floating of Apatite to make pure Hematite.To reach the optimum conditions, some tests were done with different amounts of pH, collector and depressant. The results are as follows:"

Jan 1, 2003

By Máximo Pérez, Julio C. Videla, Rosa Dzioba

"This paper reports the hydrometallurgical treatment of gravity concentrates of gold samples and outcrops associated with graphite ores obtained from:• flotation tailings of crystalline graphite minerals• outcrop samples of graphitic rock associated with auriferous minerals and free gold located in the Villa Union district and surrounding areas - La Rioja Province - Argentina.Previous studies of the flotation potential of crystalline graphite minerals failed to consider the presence of noble metals.The samples represent a mineralized zone of crystalline graphite which is distributed in different formations with a NE - SW trend in Maz, Punta Colorada and Las Ramaditas hills, covering an area of about 300 square kilometers."

Jan 1, 2003

By Johan C. van Dyk, Johan W. van Zyl, Martin J. Keyser

"Coal is a crucial feedstock for South Africa’s unique synfuels and petrochemicals from coal industry and it is used as the main feedstock to produce synthesis gas (CO and H2) via the Sasol-Lurgi Fixed Bed Dry Bottom gasification process. Detailed coal characteristics are essential to predict gasification behaviour when a specific coal source is to be gasified.The principle aim of this paper is to highlight and discuss those specific coal characteristics, which affect gasification behaviour and stability.In order to determine the suitability of a coal source for gasification purposes, the coal is characterized and the results compared with historical data. Benchmark data, where it was possible to operate the gasifier with ease and relatively high stability, is used as a reference.Coal sources with extreme properties (i.e. low reactivity, ash content <10% as is used by Dakota Gasification Company, or “brown coal” with moisture >30%) can probably be gasified in a Sasol-Lurgi Fixed Bed Dry Bottom gasifier provided that certain operational changes are implemented. Other properties, like high caking and extreme ash content for example, require blending to acceptable levels."

Jan 1, 2003

By Mikhail I. Khersonskaya, Mark I. Mantsevich, Andrey V. Tarasov

"Due to depletion of the existing ore deposits the content of non-ferrous metals in produced ores has an inevitable tendency to decrease. Processing of low-grade ores is associated with production of low-grade selective concentrates and poses serious problems for the non-ferrous industry relating to increasing losses and expenses for waste treatment and disposal.The main component contaminating selective concentrates is iron sulphides.Copper-nickel, copper-zinc and polymetallic ores have been discussed as most important types of ores requiring removal of iron sulphides.One of the promising directions for development of selective flotation technology is the use of lowmolecular organic depressors. An advantage of organic compounds is in the possibility of multi-variant structure of organic molecules, which permits selection of a most efficient reagent for the given conditions. Another way for improving the grades of concentrates is concentration of valuable constituents associated with iron sulphides in an intermediate product and upgrading of the latter by chemical and metallurgical techniques.In order to remove iron from nickel concentrates, specific process conditions have been developed for selective flotation of pentlandite with the use of an organic depressor for pyrrhotite. The use of a depressor for flotation of high-grade copper-nickel ores ensures an increase in the nickel content up to 14% in the nickel concentrate produced as compared with 7% when using conventional process conditions, along with a nickel recovery improved by 2-3%."

Jan 1, 2003