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By D. Pearcey, S. T. Vessey, V. Hegde, J. Staples

"Pellet quality has taken on a new dimension during the last ten years. Quality in the seventies was generally defined as adherence to certain physical and chemical specifications. Today, the talk is in terms of how the business is managed, how customer's expectations can be exceeded, not only in product quality, but in service responsiveness.Coke breeze and flux additions, lower silica levels, and improved furnace control practices have all contributed to the improvement of pellet physical and metallurgical properties. Statistical process control has provided additional insight into the parameters that affect pellet quality.Increased customer contact and product quality surveys have heightened our awareness of customer needs and also provide direction for quality improvement test work. Current work is focussed on improving reducibility and understanding the relationship between tumble, fired compression and metallurgical properties.This paper will review the Iron Ore Company of Canada's efforts during the past decade and describe some of its initiatives for the future.IntroductionThe Carol Pellet PlantThe Iron Ore Company of Canada's Carol Project is located in Labrador City in the southwestern portion of Newfoundland and Labrador , approximately 965 Ian northeast of Montreal. The project consists of mining facilities, beneficiation complex and a pellet plant, which began operations in 1962. The pellet plant consists of six Dravo-Lurgi straight grate machines, regrinding, filtering and balling facilities. The current capacity of the Carol pellet plant is approximately 10.5 million tonnes , while the concentrator has the capacity to produce about 18 million tonnes of concentrate.The orebody consists of specular hematite, magnetite and small quantities of limonite and goethite. The average grade of the orebody is approximately 39% iron."

Jan 1, 1991

By Dwayne D. Tannant

The Fox Pit at EKATI Diamond Mine reached a depth of approximately 150 m as of September 2005. The pit is designed with 11 m wide benches excavated using a double benching technique leaving 30 m high bench faces. A series of blasting tests were conducted to improve catch bench reliability and increase the percentage of benches that meet an 11 m catch width. The design changes focussed on reducing damage to the bench crest because maintaining the bench crests is the most important factor in achieving good bench reliability. The most significant improvement was obtained by raising the bottoms of the lower trim blastholes by 0.5 m. This change decreases the depth of broken rock below the final bench elevation, and consequently reduces damage to rock that forms the bench crest below. Another improvement was the use of smaller diameter (165 mm vs. 270 mm) blastholes in the A and B rows for the upper trim blast. This change reduces the charge per delay during detonation, reduces the powder factor slightly, and reduces the energy affecting the final pit wall and crest. As mining and the blast testing progressed, the portion of the bench with crest achievements (>11 m) increased from 57% to 75%.

May 1, 2006

By Suping Yao, Chuanyu Jiang

In the last decade, the copper industry in China has witnessed a significant change. The capacity and production of refined copper has grown remarkably from 1.5 million tons in 2002 up to 5.88 million tons in 2012. And now, China has become the biggest copper producer in the world, counting about 30% of the global refined copper production. This paper summarized modern copper smelting and converting technologies employed in China copper industry, such as OT flash technology, TSL (ISA/Ausmelt), SKS bottom blowing, Jinfeng side blowing, etc…This paper also presents some key development and improvement of these technologies up to date from their practical application in China, what will contribute as great value to any new / or renovation copper smelting projects down the road. As an engineering company in China, NERIN has been involved in many of these projects in the past decade, played an important role in the engineering works and accumulated intensive experiences. NERIN is one of the best choices for the world clients in the copper industry, providing quick engineering service, delivering cost effective projects.

Jan 1, 2014

By Bo-Hyun Kim

Outline ? Strainburst criteria and hypotheses adapted for this study. ? Influence of excavation method on rock mass properties. ? Excavation disturbance factors vs. deformation modulus, etc. ? Estimation of blasting damage zone around excavation. ? Considerations of energy on burst-prone ground. ? Literature review & closed form solution. ? Numerical simulations. ? Summary and future works.

Oct 1, 2010

By E. M. De Souza

"A scientific testing program, sponsored by the Mining Industry Research Organization of Canada (MIROC), was undertaken on the surface and underground facilities of Inca's Crean Hill Mine to investigate the effectiveness of using dry drilling with a dust control system.The surface test work consisted of the monitoring of advance rates and bit life white a series of 165 mm holes, wet and dry, were drilled at both mine air (0.69MPa) and high pressure air (1.72MPa). The results, based on statistical evaluations of field data, indicated that penetration rates can be increased by an average of 24% when drilling dry with high air pressure and by approximately 27.5% when drilling dry with mine air as compared with wet drilling under the same conditions. Dry drilling also has the effect of reducing button wear by approximately 69% using high pressure air. The underground test work employed a dust collection system developed for use with large diameter holes (165 mm) and high pressure drilling. The testing program has indicated that an average increase in penetration rate of 35% can be achieved when dry drilling in rock (waste) and of 49% when dry drilling in ore with high air pressure. Although preliminary dust monitoring did not indicate any appreciable increase in dust concentration during dry drilling, further dust monitoring is still required.A comparative cost analysis has indicated the potential for reduction in drilling costs when dry drilling is utilized. Further testwork is to be conducted to develop a reliable dust collection system for underground production."

Jan 1, 1992

By J. C. Kurnia

Presence of fine dust in air causes serious health hazard for mine operators resulting in such serious problems as coal workers? pneumoconiosis and silicosis. Major sources of dust appear of course along the mining face where the minerals are extracted. Proper control and management are required to ensure safe working environment in the mine. Presented here is the use of a computational fluid dynamic (CFD) approach to investigate the flow and dust behaviour in mining tunnels. The objective of this study is to propose and examine various strategies to mitigate dust dispersion from the mining face and reduce dust concentration to a safe level for the operator. In a companion study, the authors investigated various methods for mitigating dust dispersion from the mining face to ensure safe dust concentration levels in the mine tunnel. Among the examined methods, implementation of brattice to direct the flow from the main airway to the mining face is the most effective method to disperse dust particles away from the mining face. The installation of brattice, however, will limit the movement of mine operators and vehicles in the tunnel. Hence, application of a hybrid brattice which is a combination of a physical brattice along with suitable directed and located air curtains is proposed and examined. Based on the CFD simulation results, over a range of parameters of interest, it was found that the physical brattice blocks the ventilation air and directs it to the mine face while an air curtain located along the brattice outlet offers flexibility in keeping the dust away from the operator allowing more freedom for the operator and the equipment. Results of the modelling over a range of parameters of interest are presented and discussed with the goal of managing dust concentrations within safe limits for the operator.

Aug 1, 2013

By D. O. Tansey

This paper will describe the mechanisms involved in delay blasting and how they are applied with the use of D.S.B. It will examine the control of potential damage resulting from detonations, and show how good fragmentation and efficient recovery of this material blasted can be achieved

Jan 1, 1979

By R. J. Twigg, S. D. Chang

"The production of heavy water, the moderator in a CANDU reactor, is examined following a flow sheet of a typical Canadian plant. The process involves the extraction and concentration of deuterium from natural water through a chemical exchange mechanism with hydrogen sulphide. Consequently, corrosion problems associated with sour environments – the use of hydrogen sulphide - are an everyday problem and have led to the development of a highly refined materials selection and testing program to prevent equipment from failing prematurely.IntroductionHeavy water is a naturally occurring compound in ordinary water and is formed from the combination of two deuterium atoms and one atom of oxygen. Deuterium is a heavy hydrogen atom which has a nucleus of on e proton and one neutron. Hence, heavy water is a combination of heavy hydrogen and oxygen and is chemically known as deuterium oxide. It looks and tastes like ordinary water but it freezes at 3.8°C and boils at 101.4°C. The molecular weight of heavy water is 20 as compared to 18 for ordinary water; the density of heavy water is ten per cent greater than that of ordinary water.Although heavy water and ordinary water exhibit only small differences in their chemical and physical properties, there are large differences in their nuclear properties, the most important of which is the neutron moderating ratio, used to measure the ratio o f the slowing down power to the neutron capture characteristics. For heavy water the ratio is 21000 and for ordinary water it is 50. This high moderating ratio is essential for achieving a high neutron economy. Heavy water is, therefore, chosen as the moderating and heat transport fluid in the CANDU reactor."

Jan 1, 1983

By Navid Bahrani

Introduction ? Today?s economic market is motivating underground mining companies to increase development advance rates and enhance their NPVs. ? For example, block cave mining involves development of kilometers of drifts with multiple pillars. ? The cyclic nature of drill and blast, and its inherent tendency to damage the surrounding excavation rock mass and increase support demand often result in poor advance rates ? This has motivated mining companies to replace the conventional drill-and-blast as the main excavation method with alternative methods such as mechanized excavation. ? There is little experience with mechanized or non-explosive excavation methods in hard rock metalliferous underground mining.

Oct 1, 2010

By R. J. Mitchell

"Centrifuge modelling of earth structures is a well-proven technique for evaluating the performance of prototype structures using physical models. The applications of this technique have increased dramatically during the last decade such that even the modelling of dynamic responses in structures has been accomplished.This paper presents the first model test results used to design a mine backfill. The models were tested using a 3 m radius 30 g-tonne geotechnical centrifuge which was constructed at Queen's University specifically for model studies on mine backfill stability and subsidence. The models represent the first production blast-hole stope to be mined at Westmin Resources Ltd. 's H. ~ Mine on Vancouver Island. This paper includes photographs of:model failures in the centrifuge and correlations of model test results with analyses based on unconfined and triaxial test data.IntroductionDuring the feasibility study and development stages for the H.W. Mine, Westmin Resources Ltd. conducted a comprehensive rock mechanics and backfill engineering program. The results of these studies indicated the need for assurance of backfill stability during pillar recovery on the initial blast-hole mining block. The cemented tailings backfill had to be free standing for heights up to 25 m and the potential for surcharge loading from a weak hanging wall zone, the potential for fill block sliding down-dip and the potential for seismic loading had to be considered in the design of the fill strength. The basic questions to be answered were: what cement content is required and will the resulting backfill costs be economic relative to the proposed mining method and sequence? Figure I shows a typical cross-section through the first mining block . The up-dip stope is to be mined first and backfilled with cemented tailings . The down-dip stope would then be mined and filled. Depending on ground conditions encountered, the complete intervening pillar could be recovered and the void backfilled with uncemented tailings or it could be recovered in small sections by exposing limited back and wall areas, backfilling with waste rock and I or cemented tailings . This latter method is commonly referred to as the Avoca method"

Jan 1, 1987

By J. R. Pronovost, P. M. Tiley, D. W. Watts

"In 1980, J.S. Redpath Limited were retained by Dickenson Mines Limited to increase hoisting capacity from 700 to 1000 tons per day. The hoisting capacity of the present skip-over-cage system could not be increased significantly through design modifications. The other constraint was a minimum of disruption to the current production. The Dickenson shaft was a three-compartment shaft from surface to the 8th level and four compartments before the 8th to the 23rd level. The solution to the problem was to remove the services from the shaft man-way compartment from the 8th level to surf ace by drilling a borehole close to the shaft and rerouting those services through the borehole to the 8th level. A service compartment would then be available from surf ace to the 23rd level.By providing a service hoist in this compartment, the skip hoist would then be free to produce the 1000-tons/day required production. This paper will describe the search for the required hoist and the friction hoist selected for the project, and trace the design modifications required to modify the hoist to suit the Dickenson application and satisfy the Department of Labour safety requirements.The paper has been co-authored by J.S. Redpath Limited and C.L. Tiley Associates, who participated in the design changes and eventual commissioning of the hoist.IntroductionIn the earl y part of 1980, J.S. Redpath Limited conducted an engineering study on the Dickenson Mines Limited No. 1 Shaft materials handling system. The object of the engineering study was to investigate the possibility of increasing the tonnage hoisted from the No. 1 Shaft complex by adding a service cage compartment and service hoist. This would permit utilization of the existing hoisting plant solely for production hoi sting. A further consideration of the engineering study was that any alterations had to be accomplished with little, or no, interruption to production."

Jan 1, 1982

By J. R. Pronovost, P. M. Tiley, D. W. Watts

"In 1980, J.S. Redpath Limited were retained by Dickenson Mines Limited to increase hoisting capacity from 700 to 1000 tons per day. The hoisting capacity of the present skip-over-cage system could not be increased significantly through design modifications. The other constraint was a minimum of disruption to the current production. The Dickenson shaft was a three-compartment shaft from surface to the 8th level and four compartments before the 8th to the 23rd level. The solution to the problem was to remove the services from the shaft man-way compartment from the 8th level to surf ace by drilling a borehole close to the shaft and rerouting those services through the borehole to the 8th level. A service compartment would then be available from surf ace to the 23rd level.By providing a service hoist in this compartment, the skip hoist would then be free to produce the 1000-tons/day required production. This paper will describe the search for the required hoist and the friction hoist selected for the project, and trace the design modifications required to modify the hoist to suit the Dickenson application and satisfy the Department of Labour safety requirements.The paper has been co-authored by J.S. Redpath Limited and C.L. Tiley Associates, who participated in the design changes and eventual commissioning of the hoist.IntroductionIn the earl y part of 1980, J.S. Redpath Limited conducted an engineering study on the Dickenson Mines Limited No. 1 Shaft materials handling system. The object of the engineering study was to investigate the possibility of increasing the tonnage hoisted from the No. 1 Shaft complex by adding a service cage compartment and service hoist. This would permit utilization of the existing hoisting plant solely for production hoi sting. A further consideration of the engineering study was that any alterations had to be accomplished with little, or no, interruption to production."

Jan 1, 1982

By P. K. Chatterjee

"The operations of a large-scale open-cut mine are simulated to produce a user-oriented interactive digital model. SIMULA is chosen as the programming language and a sophisticated data base system is designed to consider the complex information network of large mines. The main features of the program are the mine planning and mine evaluation modules. These modules are responsible for the computation of truck-shovel performance and other equipment details in a mine. Stochastic methods are employed to generate event times. The use of a Data Base Management System and the data base provide an efficient method of information storage and retrieval. Truck allocation techniques have been examined in detail and comparisons between random dispatching and conventional methods are made. The model is intended for mine operators and engineers and the program is well structured and very readable. It is hoped that these features will make the model readily acceptable.IntroductionThe Department of Mining and Metallurgical Engineering at the University of Queensland has been conducting research into computer simulation methods in mining since 1972. The research has been mainly applied to actual operations, with both open-cut and underground mining being equally emphasized. The results of the research to date have not only strengthened the methodology of the approach to complex mining problems, but have also increased confidence in the use of modelling and computer simulation technique s in mining.The model described in this paper translates a complex LHD situation into a user-oriented interactive digital model using SIMULA. The present methods of evaluating truck dispatching and trolley assist are tedious and laborious. This model provide s the engineer with readily acceptable means of rapidly assessing the relative merits of these techniques in a large-scale open-pit operation. Poor utilization figures in many current operations (for example, 40% for trucks, 70% for shovels) are of serious concern to mine officials and computer-controlled dynamic truck dispatching systems have been considered by some of these mines to improve equipment utilization ."

Jan 1, 1981

By Phillip J. Mackey, Susumu Okabe

Copper mining and smelting has been carried out in Japan for over 13 centuries and in fact stretching back into antiquity. In 1889, the first electrolytic copper refinery in Japan based on Elkington’s principles was started by Furukawa Mining at Honjyo in downtown Tokyo based on the multiple or parallel system. Within two decades, a number of other copper refineries had begun operation. Interestingly, but perhaps not surprising given Japan’s long history of copper production, this first refinery in Japan commenced just ten years after the first refinery in the USA (1879), and not long after the first plants in Europe. By 1935, as a result of growth in copper demand, there were six domestic copper electro-refineries in Japan with an installed capacity of 97,800 tonnes/a, while actual production was 71,200 tonnes/a. Since about 1932, the majority of these plants were based on the more common parallel or multiple system. In 1946, just after World War II, domestic production capacity had dropped considerably to 29,000 tonnes/a, however with reconstruction, capacity and production expanded rapidly, with production reaching 81,000 tonnes/a in 1955, 187,000 tonnes/a in 1960 and 307,000 tonnes/a in 1965. The introduction of the first refinery and the early ones that followed and subsequent developments are discussed in this paper. The major technical achievements during the high growth period from 1945 to 1963 included: the use of fire- refined anodes; the introduction of newly-developed rectifiers; the introduction of lead-lined or vinyl-lined concrete cells; improvements in the electrolyte heating system; application of improved anti-corrosion materials and the introduction of heat-insulating surface coverings. In 2018, Japan’s refined copper production totaled 1,595,000 tonnes of copper, with Japan ranking third in the world after China and Chile. INTRODUCTION In 2018, Japan’s refined copper production totalled 1,595,000 tonnes of copper and Japan ranked third in the world for refined copper after China and Chile (Wood Mackenzie, 2019). There are now eight copper refineries in Japan which provide Japan’s production of refined copper. These plants are listed in Table 1 (Wood Mackenzie, 2019), also showing the production trend since 2013; in general, production over this period has been relatively steady. The Toyo plant is now the 7th largest copper refinery in the world after several large plants as rated by capacity in China, Russia and India (ICSG, 2019).

Jan 1, 2019

By A. C. Moerman, C. W. Pelley, K. R. Notley

"The software package described in this paper facilitates the handling of diamond drilling information in the creation and maintenance of a geological information database. Once entered, the drilling information is stored in a direct access file for rapid retrieval. The drill data are sorted into vertical cross sections and interpretation is performed using on-screen menus to define areas of common rock type and outline the mineralized zones. Intersections of individual zones can then be examined and outlined in the longitudinal dimension at a graphics terminal.With the aid of surface-fitting routines, the digitized information can be used to generate three-dimensional models of each zone. From these models intermediate cross sections and level plans can be obtained. Several interpretations are possible and plotter drawings can be obtained. An output file for use by ore reserve estimation software can also be created.Future work will tie this software to geostatistics and mine planning programs and will be aimed at converting mainframe software to run on microcomputers. IntroductionComputer applications in underground mine planning and geology are not new. Operations such as Sherritt Gordono and Kidd Creek have been using software developed about a decade ago for handling geological information and designing stoping blocks. However, general use of such systems has been limited mainly due to the cost of hardware which was affordable only to large corporations. Software to perform the work was usually developed on site and was largely unavailable for use by others, being site-specific, or too expensive for other organizations to purchase.The increasing power of microcomputers and mini-computers, and their relatively low cost compared to the mainframe computers which were previously used, has led to the increased use of computers at mining operations of all sizes. Sources of software for use in geological interpretation and mine planning have increased in number with the proliferation of the use of microcomputers."

Jan 1, 1988

By S. Hobo, M. Yagisawa, T. Uchida, C. Tokoro, T. Kato

In this study, quantitative modeling was carried out for the treatment of simulated waste water containing As(V), Zn(II) and Hg(II) as toxic elements, and Fe(III), Na(I) and sulfate as coaxing ions. The objective was to predict the pH and residual concentrations of all the elements in solution after the neutralization/co-precipitation treatment. To accomplish this, the removal mechanism for As(V) and Hg(II) by ferrihydrite precipitation was first investigated for simulated waste water containing only As(V) or Hg(II). From the experimental results, it was confirmed that the removal mechanism involves not only surface complexation but also surface precipitation. However, surface complexation is the main mechanism for As(V) and Hg(II) removal to meet the target levels regulated in Japan. Next, the surface complexation model was constructed for the removal of As(V) and Hg(II) by ferrihydrite. The specific surface area and site density were determined from reference values proposed by Dzombak and Morel (1990). By comparing the experimental and calculated results, it was confirmed that our constructed model could successfully represent the experimental results. Furthermore, the surface complexation model was coupled with chemical equilibrium calculations and applied to the neutralization of simulated waste water containing As(V), Hg(II), Zn(II), Na(I), Fe(III) and sulfate. The constructed model could successfully represent the pH edge for As(V), Hg(II), Zn(II), Fe(III) and SO42- removal. In addition, the constructed model could represent the ion balance. Thus, our constructed model is useful to estimate the amount of neutralizer that is needed to achieve a target pH.

Jan 1, 2016

By B. Hoare, H. M. Hill

"SYNOPSISTailings volumes, disposal systems, effects of dam failures, construction materials, and concentrator process water volumes are discussed. Earth dams and tailings dams are discussed in detail. Some of the fundamentals of soil mechanics relating to earth dams are presented. Brief notes on optimization are presented. The development of a triplex meter for earth dam instrumentation is described. The advantages of the hydro-cycloned dam over the spigotted dam are outlined. INTRODUCTIONThe realistic and responsible recognition of the pollution problem, combined with the grossly increased volumes of waste material from large modern mining operations, has emphasized the demand for safe tailings dams at minimum cost.Tailings may be defined as the waste material from a mining operation after the process of concentration in which the minerals have been extracted for commercial use. The present revenue from the Canadian Mining Industry is slightly over $4,000,000,000 per year and it is estimated that the quantity of tailings produced exceeds 300,000,000 tons annually. In many instances, the volume of tailings from a mining operation is greater than the volume of crude ore mined on account of the small quantity of valuable mineral recovered during concentration, and on account of the ""swell factor"" resulting from the processes of drilling and blasting, crushing, and grinding of the crude ore. Some of the larger mine tailings deposits contain over 200,000,000 cubic yards and the associated tailings dams are among the largest man-ma.de structures in the world."

Jan 1, 1970

By M. Mahdi, L. So, A. MacMillan, D. Metcalfe, J. Woloshyn, D. Sauter, N. Uys, JP. Janse van Rensburg

For city smelters, with limited real estate, efficient slag cleaning furnaces followed by water granulation to produce an iron silicate product is the preferred process approach. Water granulation, however, consumes large volumes of water and requires high maintenance due to abrasive slag/water slurries. Air granulation offers an alternative to water granulation, which eliminates water use and has low maintenance requirements. Although full-scale operation has not been implemented for copper slags, full-scale operation for platinum group metal (PGM) converter slag has been implemented. A review of full-scale air granulation performance for PGM converter slag is provided. Based on PGM converter slag granulation performance, parallels to copper slag granulation are drawn and full-scale operation for copper slag is modelled using computational fluid dynamics (CFD). INTRODUCTION Typical slag management practices in the copper industry include dumping, slow air cooling, and water granulation, as shown in Figure 1. Dumping is the most commonly used slag handling method for most metal production plants, but presents challenges including the requirement for a large slag pit, requirement for expensive/high-maintenance “hot” mobile equipment, risks associated with transportation of molten slag, and no value recovery from slag as a sellable by-product or from slag as a source of heat.

Jan 1, 2019

By G. Macfarlane

"In 1985, a crushing plant, located in the feed preparation area of Kidd Creek's copper smelter, was modified. The plant, which originally had treated only copper-bearing materials for the smeller, at a rate of 10 tonnes per hour, was expanded to 40 tonnes per hour capacity and modified to treat silica ores to meet the smelter’s flux requirement and also gold ores from the company's Hoyle Pond property. In the storage area adjacent to the crushing plant a 300 tonne per day gold mill was constructed.This paper outlines the construction and first year of operation of the crushing plant and gold mill with emphasis placed on the capital and operating advantages to be gained by utilizing an existing metallurgical infrastructure.IntroductionThe Kidd Creek Mines Ltd. copper-zinc-silver orebody is located 24 km north of Timmins, in Northern Ontario . Mining of this massive sulphide de posit commenced in 1966 and, in the ensuing years, a concentrator and zinc plant were constructed at the metallurgical complex, approximately 17 km by rail from the mine site . At this same site, in 1981, a copper smelter and refinery were commissioned. The smelter which utilizes the Mitsubishi smelting process for the continuous production of blister copper from copper concentrate, has been comprehensively described in previous papers.At the time of the smelter construction, a small (10 tonnes per hour) crushing plant was installed in the smelter's feed preparation area. This plant was used to treat the copper-bearing revert material produced by the smelter, and, apart from periods when slags and matte were produced through furnace drainage at the end of each operating campaign, it was generally under-utilized. This fact, together with the requirement to devise a more cost effective method of providing silica flux for the smelting operation, was the basic rationale for modifying and expanding and crushing plan t. At the same time, development at Kidd's Hoyle Pond orebody had progressed to such a stage that a gold mill of 300 tonnes per day was warranted."

Jan 1, 1988

By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016