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By H. E. Frimmel

Most of the gold in the Late Archean Witwatersrand Basin is of detrital origin but, in its present form, it is metamorphosed. The only relict detrital features preserved are the morphological characteristics of some placer gold particles. Regional burial metamorphism in the shallower and deeper levels of the Witwatersrand Supergroup reached temperatures around 300°C and 350°C at pressures between 2 kbar and 3 kbar, respectively, estimated from phase relations, chlorite-chloritoid exchange thermometry and chlorite thermometry. Metamorphism of the gold involved compositional homogenization of individual gold particles and partial recrystallization. Various infJ.1tration events caused the partial mobilization of the gold at slightly lower temperatures, between 240°C and 300°C. These infiltrations can be related to crustal extension during the deposition of massive carbonate sequences of the Transvaal Supergroup (around 2.5 Ga), and later to the emplacement of the Bushveld Complex, and to the Vredefort event around 2.0 Ga ago. The mobility of the gold was dependent on the sulfur fugacity prevailing in a particular horizon which, in tum, was determined by the amount of pyrite (and other sulfides) present in that horizon. With the sulfur fugacity being controlled by stratigraphy, low fluid rock ratios in a pyrite-rich horizon were most conducive for the mobilization of the gold. Thus, long-range gold mobilization in the Witwatersrand Basin can be expected to be the exception rather than the rule.

Jan 1, 1994

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019

By Roger Lacroix

Presentation outline Project definition Characterization of mine ventilation systems Strategies in place and results Detailed study (2 mines) Other potential energy savings Conclusions Next steps

Feb 1, 2008

By Marta Polgari, Eva Surova, Bohumil Molak

Abstract -The Ûrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organic­ geochemical methods. Both depositionallocalities were affected by the Lower Jurassic Toarcian anoxic event. Ûrkút shales are rich in organic matter (av. 2.94 wt% total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (?0.2 wt% TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decom­ position of organic matter that also involved Mn reduction.

Jan 1, 1992

By J. H. Hodgson

"Those of us who have been concerned with the problem of geophysical exploration in southwestern Ontario have followed the development of the Poulter method with much interest. I have much appreciated the opportunity of reading an advance copy of Dr. Poulter's clear exposition and of preparing the following brief remarks on the probable applicability of the method to the Palaeozoic area of southwestern Ontario.During the years 1944 to 1946, the Ontario Department of Mines, in co-operation with the Union Gas Company and the Dominion Natural Gas Company, operated an experimental party in the hope of establishing a seismic technique appropriate to the •area. The results were completely negative. During two summers' field work, no reflections whatever were obtained except in one area near Windsor. It is the •purpose of these remarks to inquire whether Dr. Poulter's techniques might yield favourable results.It was the conclusion of the report on our work that two principal causes contributed to the failure of the method. In the first place, the geological column possesses few elastic discontinuities and those that exist appear to have low reflection coefficients. In the second place, the area is drift-covered in general. This drift complicates the situation by absorbing seismic energy and by giving rise to groups of complicating refracted phases which obscure the entire interesting section of the record. The situation is further complicated by the high reflection velocities and the relative shortness of the Palaeozoic section, these factors combining to bring in a reflection from the basement in about half a second."

Jan 1, 1950

By Ian Thomson

OBJECTIVES OF EXPLORATION ? Prove/Disprove presence of potentially economic mineralization ? Keep on budget ? Minimize negative environmental impacts ? Gain a ?Social License to Operate? (SLO) WHAT IS A ?SLO? ? Granted by the local community ? Intangible, informal, non-permanent ? Has to be earned and then maintained ? Defined as ? Ongoing Approval (BSR and AccountAbility) ? Ongoing Approval, broad social Acceptance (Joyce and Thomson) ? Ongoing Acceptance (Nelson, and many others) ?Expression of the quality of a ?relationship?

May 1, 2010

By D. Y. Li, C. D. Ma, T. Zhou, T. J. Cheng

In this paper, a number of experimental tests are carried out to study the strength difference on rectangular prismatic marble specimens with different height-to-width (H/W) rations. The specimens have a nominal size of 45×15 mm in the compressive cross-section (W×T) and different heights (H = 22.5 mm, 45 mm, 60 mm and 90 mm). It is to say that the height-to-width ratios are equal to 0.5, 1.0, 1.33 and 2.0, respectively. The quasi-static uniaxial compressive tests are finished by a servo-controlled INSTRON machine (the strain rate at about 10-5/s), and the dynamic compressive tests are finished by a diameter of 50 mm cylindrical SHPB apparatus (the strain rate reaching about 101/s). The rock failure process of marble specimens is captured by a high speed camera in order to distinguish the fracture propagation behaviour. It is found that the compressive strengths increase when the H/W ratio of marble specimen changes from 2.0 to 1.0 due to the end clamping effect both for quasi-static and dynamic loads. However, when the H/W ratio changes from 1.0 to 0.5, the apparent compressive strengths decrease both for the two loading conditions. The strength decrease of short marble specimens may be attributed to the change of failure mode from shear to slabbing, which can be identified by the fracture patterns of the specimens. Based on the uniaxial compressive tests, the slabbing strength of the marble was found to be about 40% of its UCS for the specimens with a nominal height-to-width ratio of 2.0. In addition, it is found that the dynamic increase factors (DIF) are affected by the specimen’s aspect ratios. It implies that the same aspect ratios should be used to compare the dynamic and static compressive strength of rocks. Meanwhile, both the static and dynamic tensile strengths of the marble are obtained by the Brazilian disc tests. The ratio of the dynamic tensile strength to the static tensile strength of the marble is about 2.68.

Jan 1, 2015

By Howard J. Handewith

"Tunnel boring machines have been tried in underground mining applications as early as 1957. Although tunneling machines hardly threaten to supplant traditional drill-blast-muck operations for drifting, the latest modern machines offer substantial improvements in progress rates over traditional methods under certain conditions.An evaluation guide is offered which identifies conditions that favour machine boring. Different types of costs related to the use of a tunnel machine are discussed. The advantages of the tunnel machine over the traditional method are reviewed. IntroductionThe first tunnel boring machine ever used in a mine was in Quebec in the year 1957. Although less than successful at the time, this experiment served to illustrate the mining industry' s willingness to try new ideas. Since 1957, the manufacture of tunnel boring machines has developed into a full-size industry. Most contractors in Europe and North America will now consider the use of a tunnel boring machine first on any long tunnel that can have a circular section.The modern tunneling machine offers a great potential to the mining industry. Just as the blasthole and raise drill machines have revolutionized mining in the last decade, it is expected that tunnel boring machines will make an equal impact in the future.This is not to suggest that tunnel boring machines will replace explosives in the foreseeable future, but they can supplement drill-and-blast operations. In areas where long drifts, inclines, declines or cross-cuts are needed in a hurry, the tunnel boring machines offer the fastest way to a production return on investment. Figure 1 shows the range of production that two types of tunnel machines have produced as compared with conventional excavation methods in various ground conditions.Rotary hard-rock tunnel boring machines (Fig. 2) commonly produce progress rates in excess of 20 metres per day in uniform ground from 300 to over 2,000 kgl cm2 in unconfined compression strength . These averages are for the completed tunnels. One 7. I6-metre-diameter tunnel boring machine just completed a 1O.7-km tunnel in hard rock of 700 to 2,800 kg/cm>, The last eight months of production averaged 30 metres per day."

Jan 1, 1980

By T. Robson

"A multi-seam underground mining operation employing mechanized room-and-pillar methods provides 35 per cent of Smoky River's annual ROM coal production (2 million tonnes) from the Smoky River coal field. Surface mines provide the balance. Tectonic activity, which has resulted in deformed coal seams and a rugged relief to the area, has provided natural boundaries to discrete mining areas. Coal transportation to the central preparation plant incorporates a 3 km long underground conveying system. The company is committed to efficient resource recovery and a safe and healthy working environment. Introduction The Smoky River Coal operations (SRC) are centered in the Smoky River coal field located in west central Alberta, some 360 km west of Edmonton and 20 km from the Town of Grande Cache (Fig. 1). Combined mining operations produce 2 million tonnes per year run-of-mine coal from which 1.65 million tonnes of high quality, low volatile, coking coal are obtained. The underground mining operation, employing mechanized room-and-pillar methods, provides 35 per cent of SRC's annual ROM coal production (2 million tonnes). Surface mines provide the balance. Tectonic activity has resulted in deformed coal seams and a rugged relief in the area. This has provided natural boundaries to discrete mining areas. Background Exploration of the Smoky River coal field took place over four decades commencing in 1926. McIntyre Mines Limited (parent to Smoky River Coal Ltd.}, commenced development of the property in 1968 having secured a long-term contract for the delivery of coal to Japan. Production of underground coal at Smoky River commenced toward the end of 1969 and has been continuous on the property since that time. Originally, two underground mines were opened. Original planning envisaged the use of room-and-pillar techniques to develop blocks of coal for subsequent extraction by longwall retreat mining. Following initial development, two longwall units were established, the first in November 1970 in No. 5 Mine and the second in February 1971 in No. 2 Mine. Difficulties were experienced on both units, and production commitments could not be achieved. The longwalls were discontinued, and mechanized room-and-pillar was subsequently used for all underground mining."

Jan 1, 1985

By Alan Bauer

IN RECENT PAST YEARS, the mining industry has expanded rapidly and mining engineers have not been generated in sufficient numbers to sustain this growth. Canada has not been alone with this problem, which has resulted in considerable soul-searching as to what the solution might be. Because of the unfavourable economics of running small departments such as mining, metallurgy, ceramic engineering, etc., one approach in some cases has been to put these departments together to form a department of mineral science which now has a broader base structure. Another solution has been the "conversion kit" program which has been conducted both at universities and in industry. At universities, such programs have consisted of converting graduates of other engineering disciplines into mining engineers. In some of the large mining corporations, extensive training programs have been used with the same aim.

Jan 1, 1972

By S. A. Willis

For over 150 years gypsum from Nova Scotia has been shipped via water to the United States east coast. The history of the movement has been one of continual improvements in quarrying, loading, and shipping. At the start, man-size rock quarried by hand auger and black powder was loaded into horse-drawn carts, hauled to the waterfront, and dumped into 100-ton sailing schooners. Last year the Canadian Gypsum Company completed the latest and most modern of these successive installations for the movement of this Nova Scotia product. The new system loads crushed gypsum into 11,600-ton vessels at Hantsport in two hours' time at high tide. At the head of the bay of Fundy are located vast deposits of gypsum. The tidal rise and fall of 45 feet twice a day, with its attendant swift currents, has always presented major navigation and shipping problems. When the tide is low, the Hantsport ship-loading pier is high and dry, with no water within 400 feet. Three hours later a large river has flooded in (running up hill) and large steamers can dock at the wharf. Before high water, the ship has been loaded and -there is a depth of 30 feet or more of water around the wharf. At high water, the ship sails away on the ebbing tide as the river runs in the other direction. Tides are caused by the gravitational attraction of the moon and sun on the ocean. When both celestial bodies are pulling together the 'spring tide' results, which means a 50-foot variation from high to low. This occurs at new and full moon. A week later, when the sun and moon work in opposition, the difference is only 32 feet between high and low water. The bay of Fundy, having a funnel shape (150 miles wide at mouth from Yarmouth to Portland, while the upper estuary at Hantsport is only one mile wide), builds up a tidal influence from 10 feet at the mouth to an average of 45 feet at Hantsport.

Jan 1, 1948

By S. H. Logan

The present discussions throughout the civilized world on the subject of gold for monetary purposes may seem due to general economic conditions during the past year. But for some years previously a small group of authorities had warned the world against the continued disregard of an equitable distribution of existing gold reserves, and had urged the necessity of keeping the supply of new gold equal to the monetary demand, which, according to world production and trade figures, increases on the average about 3 per cent per annum. In 1927, Sir John Aird, the President of The Canadian Bank of Commerce, stated that the United States could spare a billion dollars of the supply it then held, 4 ½ billion dollars. About a year and a half ago the Professor of Banking and Currency in the University of London, Mr. T. E. Gregory, said, "If the world finds it impossible to modify its habits so far as to make an organized effort to economize gold seem less Utopian, it must be prepared to pay for its bad habits, in this and other respects, by a possible loss of material welfare." These clear-cut statements were not heeded, perhaps for one reason because most countries were in the flush of prosperity, and making such great demands upon the mining fraternity for industrial materials as to distract attention, at least to some degree, from gold mining. Now the world knows it faces serious problems, first, of making? fully effective its present monetary reserves, which, although badly distributed, are as a whole ample for the needs of the present, and secondly, of preventing a shortage in the supply of new gold, one that may come within the next few years if the present sources of supply are not enlarged, and if there is no marked change in the technique of gold production.

Jan 1, 1931

By J. Bourgeault

Modem civilization is indebted to that most ancient of the skilled crafts - the art of stone working, as the one consistent means whereby the dim un-recorded past has conveyed to our modem schools of science volumns of facts, written in characters of imperishable stone. Although left, centuries ago, to ruin and decay, architectural examples of the ancient building crafts still remain to the glory of the old master-builders, whose accomplishments in that remote age continue to influence and inspire their modem successors. Present-day architects and builders will leave to posterity just as faithful a record of our modes of living and of the methods now adopted for protection, as if it had been made by written word; and our craftsmen have profited greatly, in meeting modem requirements, by taking advantage of the indurance and utility of stone. Stone in all ages and stages of the world's civilization and development has been the material chosen by the masterbuilder, the one material possessing qualities that render it most desirable in affecting the artistic ideals of each period. It perfects the science of architecture through its durability and thus renders possible the study of man's workmanship in stone throughout periods of civilization of which we have no specific written account. Other materials have been used for the construction of man's habitations, but none have withstood the test of time, nor have established the credit of designer and builder so well as stone. _All other materials fall into ruin and decay, leaving neither mark nor monument for the enlightenment of mankind.

Jan 1, 1925

By W. Grell

"In this paper, two methods of standardizing mill language are proposed; one is based on metric units and the other on English units. Tentative procedures for chemical and screen analysis based on published methods are proposed.Standard procedures for determining work index, and for leaching, flotation, and classification tests are outlined.Objects of Standardization:(1) to improve communication -(a) among gold metallurgists(b) with other branches of mineral dressing(c) with mineral dressing in other countries(d) with general scientific procedure(2) to improve mill control by -(a) standard methods of analysis (i)(ii)(iii)(b) standard methods of calcula tiort(c) standard accounting proceduresin the plantin the mill laboratoryin the assay office(3) to improve mill test work and investigationAreas of Standardization(1) Nomenclature or terminology(2) Measuring techniques(3) Test procedures(4) Accounting procedures"

Jan 1, 1966

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By Alex McEachern

MINING LEADS WAY TO PROSPERITY THE year 1937 will stand out in the history of mining and metal products in Canada as one of which we shall always be proud. The combined contribution of these industries played a large part in leading Canada back to prosperous conditions after years of stress and strain that left their mark upon business the world over. A review of general industry shows a marked improvement over recent years. The upward trend continued un-abated most of the year and not a few of the industries had all they could do to supply the demands. A fact that should be appreciated in a year of wheat failure over an extensive area of the Prairie Provinces is the shifting of the basis of Canadian prosperity from agriculture to that of mining and the use of metals. To the great demand for minerals of all kinds, our mines have well responded and many new high levels were reached. This reflects great credit upon the men who direct the activities of the Canadian Mining Industry. Possessed by a spirit which refused to accept defeat in 1931-1932, they began to increase the efficiency of their departments, explored all channels hitherto untried, and won through to a crowning success. Who among them dreamed that their country's extremity would be their Alex. McEachern opportunity, and that through their united efforts our young nation would be enabled to hold that high position she has attained in world affairs?

Jan 1, 1938

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

By M. Fafard, F. Chevarin, D. Ziegler, H. Alamdari, M Kavand

"Carbon anodes, used in the Hall-Heroult process, are consumed by the electrochemical reaction to produce metallic aluminum. It is also consumed by parasitic reactions with air and CO2. The carbon anode is made of petroleum coke with different particle sizes, butts (recycled anodes) and coal tar pitch. The mixture of fine particles (less than 150 µm) of coke together with the pitch material forms a matrix, binding the large coke particles together. It is generally thought that the binder matrix is more reactive than the other anode constituents. This conjecture was not clearly proved in the literature. The present study is focused on the CO2 reactivity of binder matrix and anode constituents at 960°C, both under chemical regime (100% of CO2) and under a concentration gradient (diffusion). The apparent reaction rates of these materials were measured. The role of the binder matrix in anode consumption and its disintegration (dusting phenomenon) was discussed.INTRODUCTIONThe metallic aluminum production is one of the most important industries in Canada. The Al metal is obtained by the Hall-Héroult process. The principle of this process is the electrochemical reduction of alumina in molten cryolite carried out by an electrical current between carbon anodes and cathode at 960°C (Equation 1). The carbon anode is typically composed of calcined petroleum coke (65 wt.%) and recycled anode (called also butt, 20 wt.%) with coal tar pitch (15 wt.%), playing the role of cement to ensure the cohesion of the anode block."

Jan 1, 2016

By J. F. Fiset, N. Bouzoubaâ, N. Reynier, C. Laviolette, Canadian Nuclear Laboratories

Canadian Nuclear Laboratories (CNL) is developing a disposal strategy for radioactive wastes, which contain significant amounts of uranium, cesium, and mercury. There are safety and economic incentives for the extraction of these elements before permanent storage in deep underground repositories. In addition, the actinide elements are also an important component in rare earth element (REE) ores and considered as impurities. Actinides separation from REE tailings is a significant concern in order to manage radioactive nuclides. Reprocessing mine wastes may present significant financial and environmental benefits. Experiments were carried out with radioactive cemented wastes (RCW) prepared at CanmetMINING. For all of the tested RCW batches, solubilisation yields are above 97% for Cs and 98% for U and Hg. Sulphuric acid leaching with potassium iodide improved the solubilisation of Hg by oxidation and formation of the tetraiodide complex (e.g. HgI4 2-, Kf = 2.1030). Cs and Hg were removed selectively by using potassium cobalt hexacyanoferrate (KCFC) and Lewatit TP214 ion-exchange resin respectively. U recovery using the chelating resin Lewatit TP260 was the most efficient. The presence of high iodine concentration improved the U uptake by the resin. The best U elution was obtained using 1 M Na2CO3, which resulted in 99% U recovery. U was then precipitated as sodium diuranate. A counter current effluent recirculation was performed successfully on RCW. The process was also applied to submerged tailings collected from two U mines and an REE ore. This paper presents an innovative process, using sulphuric acid and potassium iodide, for U, Cs, a

Jan 1, 2016