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By Raj Thamburaj

"Over the last few decades, the emphasis on affordability and reduced cost of ownership has necessitated the development of innovative processes to carry out repairs in aero engine components. Conventional weld and braze repairs have evolved into advanced, sophisticated processes using state of the art knowledge in lasers, robotics and materials technology. This paper illustrates past and present scenarios in an attempt to illustrate progress that has been made in this area. The problems encountered in the past have been detailed along with the solutions that have been developed and commercially implemented to address these issues. Apart from technical progress, this presentation also addresses the progress made in business approaches and in Certification/Regulatory issues surrounding aero engine repair. Progress in Technology Repair technologies have also been the embryo from which new and revolutionary manufacturing technologies have evolved as well. Electron Beam Free Forming and LENS are examples of how a completely new manufacturing concept can evolve what was originally only a process to join metals. The current and future potential of these spin offs is discussed providing examples of application. While several problems have been solved over time with the implementation of advanced repair technologies, the demands of the industry have created new challenges. The paper describes these issues, outlines potential solutions and discusses the future of repair technologies in terms of the far reaching influence it is sure to have in design, manufacturing, maintenance management and life extension. Progress in Business Trends.Business approaches to repair and maintenance have also gone through considerable change with the introduction of ""Power by the Hour"" and other similar arrangements between the companies responsible for engine overhaul and the end-users. Program Based Logistics (PBL) is yet another innovation to provide a win-win situation for the repair service provider and the end user. This paper traces the development of these business initiatives and highlights successful applications. Progress in Repair Certification, Regulatory Issues.Understanding of the issues surrounding certification of repairs has also evolved with time and regulatory issues have been clarified considerably. Procedures for analysis and testing are much clearer and ""Check Lists"" are being drafted for certifying repairs on various engine components. The PMA phenomenon has added yet another dimension to the issues regarding certification and these are discussed as well."

Jan 1, 2010

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Arsenic in mineral processing solutions and effluents is commonly removed and immobilized via iron(III)-arsenatecoprecipitation. The effect of re-crystallization of 2-line ferrihydrite on the long-term stability of iron(III)-arsenate coprecipitate is still not fully understood. This work investigated the redistribution of arsenic and iron during 2-line ferrihydrite transformation at different pHs and temperatures over time. X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical extraction were employed to characterize the crystallinity of the iron oxyhydroxides. Results showed that the amount of arsenic released into solution during aging increased significantly with increasing media pH.

Jan 1, 2014

By X. Z. Yuan

Contamination introduced by the impurities from the feed stream can impact the PEM fuel cell performance dramatically. The presence of these unwanted trace species such as CO, H2S, NH3, can adversely affect the fuel cell functioning. It has been reported that the major impact of CO and H2S contamination on the fuel cell performance is kinetic while the effect of NH3 contamination is speculated as membrane conductivity reduction only. In this paper, a model regarding the NH3 contamination is described and the mechanism of the NH3 contamination is illuminated by the model calculations.

Jan 1, 2005

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004

By M. J. MONEA

Canada's only economic high-swelling bentonite deposit is mined in Wilcox, Saskatchewan, by A vonlea Mineral Industries Limited. The bentonite resulted from devitrified and altered volcanic ash released during the Laramide Orogeny. Volcanic ash was deposited in a pre-Cretaceous basin that was formed by salt solution collapse structures. Sedimentary rocks in the Wilcox area belong to the Snakebite Member of the Upper Cretaceous Bearpaw Formation. Bentonite beds are 61 cm, 46 cm and 30 cm thick; these are separated by 365 cm and 182 cm of shale respectively. Saskatchewan bentonite is used primarily in the oil well industry.

Jan 1, 1984

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By L. Zeka, I. Ndala, J. Frenay, S. Gaydardzhiev

"Reductive leaching of cobalt (III) from a heterogenite bearing ore has been performed. Pyrite was added to the system and simultaneously bioleached in order to provide ferrous iron as reducing agent. Within such arrangement the iron ions are continuously re-circulated inside a Fe 3+ / Fe 2+ loop. As a result Co(III) is solubilized in the presence of Fe 2+ ions in concentrations well below the stoichiometric requirement. The ore has been initially subjected to acid pre-leaching in order to guarantee that the available Co (II) has been entirely removed. Two technological parameters have been studied to show influence on the degree of cobalt leaching: concentration of ferric iron in the inoculum and the presence of bacteria. The bacterial role could be mainly viewed in supplying ferric ions in the system which chemically react with the pyrite to generate ferrous ions used as Co(III) reducing agent. Co(III) dissolution has been less efficient when the concentration of total iron in the system was low, but also when microorganisms were absent. SEM observations on leached heterogenite have evidenced bacterial attack on the mineral; however the precise role of bacterial presence on cobalt (III) leaching is still to be elucidated.INTRODUCTIONCobalt accompanies quite often copper in secondary oxidized ore deposits (Rumbu, 2013). In such associations cobalt is found both as CoII+ as well as CoIII+ (Deliens, 1974). In contrast to cobalt (III), cobalt (II) is leached relatively easy in sulphuric acid solutions. Cobalt (III) when present in mineral form belongs to the heterogenite mineral group with a simplified chemical formulae Co2O3.H2O or CoOOH. In order to be brought in solution, heterogenite should capture two electrons, likewise shown in reaction 1 below:"

Jan 1, 2016

By Ron Jessulat

"IntroductionBrunswick Mining and Smelting Corp. Ltd. is a IO 500 tid base metal producer. Development is carried out by Jarvis Clark MJM-21 3-boom development jumbos, using Tamrock E400, 410 and 550 pneumatic drills. Typical drift size is 13 ft by 18 ft with a 12-ft advance per round. Blast holes are 1 ½ in. in diameter while reamed holes are 3 in. in diameter. AN/FO is the principal blasting agent, being loaded by C-I-L model60R intermediate loader. The detonators are NONELS and DETINELS. Sulphide dust explosions occur during blasting when dusts from certain minerals such as pyrite and pyrrhotite are ignited by name from the detonating shots. The result is a secondary unwanted explosion with a characteristic shock wave and name front that are very destructive to mine services such as ventilation ducting, electrical cable, and ventilation control doors.A typical reaction in the Brunswick orebody occurs according to the chemical formula:4FeS 2 + IIOs-2Fe2O3 + 8SO2 + 3458--(Enright , 1988)The hematite (FeO3) is deposited as a red dust in the blast area while the toxic sulphur dioxide gas (S00 contaminates the underground workings . The presence of S02 gas disrupts production until it is purged from the area by the mine ventilation system or dissipates slowly in those areas where the vent ducting has been melted by the name front or torn down by the shock wave.Sulphide dust explosions exact a high economic toll. Direct costs in damaged materials and wages are probably exceeded by the value of lost production and disruption to the mining cycle. In addition, the health and safety concerns associated with sulphide dust explosions cannot be ignored."

Jan 1, 1993

By W. G. McBride

The mining industry has already become highly technical in all its branches and this has brought about specialization in mining engineering. Increasing demand for mineral products, exhaustion of high-grade or easily worked deposits, and narrowing of the fields for exploration and development, are forcing mines to greater depth and to working material of lower grade and more complex composition. The Robinson Deep at its Turf shaft has reached a depth of 7,640 feet and expects to go to 8,500 feet; Miami Copper, under normal market conditions, profitably mines ore running only 16 pounds of copper to the ton; Alaska Juneau is making a profit on ore running about $1.15 per ton in gold; and many mines are handling ores of an extremely complex nature. In each case, the success of these operations has depended upon the application of sound scientific principles and good business methods to the problems involved. It may be safely assumed that mining at great depth and the exploitation of low-grade, or complex, ores will become more and more important as time goes on, and this means that greater and greater demands will be made upon the technical skill and business ability of the mining engineer. To meet this condition, the more or less haphazard methods of training the young engineer that have prevailed in the past will have to be replaced by a careful and well-ordered system of engineer-training. Upon the industry and the older mining engineer falls the duty of providing means to assist the deserving student to prepare himself properly to meet the increased demands that are falling upon his profession. Consideration of the training of the mining engineer involves a decision as to what constitutes his field of usefulness. Technical control of methods and processes obviously falls upon the engineer, but there are still many who doubt his usefulness in the executive field, particularly in positions involving close contact with the men and work. Many engineers have failed as shift-boss or foreman, but this has been generally due to fault in the management in using men who were temperamentally unfit to lead others or who lacked the necessary preliminary training.

Jan 1, 1932

By M. G. Goudge

IT IS ENOOURAGING indeed to note during the past year that, despite a slackening off in many markets and with numerous major difficulties and problems to solve, the mining industry of Nova Scotia was maintained at a very high level. The value of the Province's mineral production for 1957 amounted to approximately $65,000,000. This represents a drop of only 1.5 per cent from the figure of the previous year. Coal Atlantic Collieries, Ltd., opened a new coal mine during the year at Bras d'Or. This colliery is equipped with the most modern type of mechanical equipment available, with transport of the ?coal by a belt-conveyor system. Other mines in the Province continued to mechanize their operations by the addition of Diesel haulage locomotives and other mechanized mining equipment. New wash plants are in operation and .an additional one is planned.

Jan 1, 1958

By J. E. Gill

"THE YEAR 1959 appeared to be a good one in which to attempt a summary of progress in the location and study of sulphide deposits in Canada because a temporary surplus of metals caused prices to fall and many geologists who had been working like beavers were suddenly not so hard pressed. So it was •decided to arrange a Symposium. The response to the call for contributions was excellent and the result is the interesting collection of papers that follow.Activity in the search for massive sulphide deposits has never been as intense as in Canada since 1954. That was the year when the airborne electro-magnetometer first became generally available on a contract basis. These instruments work best on massive sulphide bodies, as do most of the ground electrical survey devices, so much of the new information relates to these. It was decided, therefore, to focus attention in the preparation of symposium papers on such masses. This served also to keep the survey within reasonable limits."

Jan 1, 1960

By X. Grant Chen, A. R. Farkoosh, M. Pekguleryuz

Nano-scale Al-(Fe,Mo)-Si dispersoids form during solution treatment in grain interiors (intradendritic regions) of cast Al7Si0.5Cu0.3Mg alloyed with 0.3Mo (wt.%). Unlike the Q-Al5Cu2Mg8Si6 and ?-Al2Cu age-hardening precipitates which coarsen resulting in loss of strength in Al-Si-Cu-Mg alloys, these Mo-containing dispersoids are thermally stable and retain their strengthening effect at elevated temperatures. Consequently, the age-hardened Al7Si0.5Cu0.3Mg0.3Mo (wt.%) exhibits high strength and creep resistance at 300 °C.

Jan 1, 2014

By J. M. R. Carvalho, M. T. A. Reis, M. R. C. Ismael, M. J. N. Correia, S. M. C. Santos, J. M. Carvajal

A sulphide zinc concentrate (Zn-40%) has been leached in sulphuric and chloride media to optimize the conditions for the recovery of zinc and copper. Previous results showed that extractions of 95% zinc and 20% copper can be achieved in just one stage, after two hours of leaching at 80°C with a solution 0.5M in Fe2(SO4)3 and H2SO4 and a solid/liquid ratio of 5%. This work presents the results obtained in the leaching experiments carried out in sulphuric and chloride media using two and three crosscurrent stages and a countercurrent process simulation for a solid/liquid ratio of 10%.

Jan 1, 2008

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By S. Torres, J. Álvarez, R. Castillo, R. Fuentes, C. Sandoval, R. Parra, Myakalwar A. K., M. Velázquez, J. Yáñez, D. Sbarbaro

Rapid analytical assessment in copper mining industry is a limiting factor for operational purposes and for the improvement of processes. The present work aims to review the analytical assessment in the copper industry utilizing emerging spectrochemical techniques such as laser induced breakdown spectroscopy (LIBS) and UV-Vis-IR Hyperspectral Sensing. LIBS is a plasma based spectroscopic method where the sample surface is irradiated by high power laser. The light emitted from the plasma contains atomic -molecular spectral information and can be detected using a simple CCD based spectrometer. UV-Vis-IR Hyperspectral Sensing is produced by the reflection of light from the sample’s rough surface in all directions and it can be collected by using an ellipsoid or paraboloid mirror arrangement. The electromagnetic radiation emitted by the samples in the UV-Vis, NIR and MIR region can be used for molecular characterization. The spectrometer splits different wavelengths through a CCD arrangement in 2D spatial and spectral dimensions, thus a hyperspectral cube of data is generated. Chemometric techniques such as principal component analysis (PCA), K- nearest neighbors (KNN), support vector machine (SVM) among others, can be applied to LIBS and Hyperspectral data for better classification and quantification purposes in copper ores. Real- time determination of elemental and mineral species used for online processing control will help to achieve the copper industry 4.0. INTRODUCTION The demand for copper mineral resources is intensely growing with the increase in population, per capita GDP, the development of new technologies and the increase in global living standard. With the rise in consumption of copper, it is important to optimize mining and metallurgical processes tending to the copper industry 4.0 (Ge, Song, Ding, & Huang, 2017). The real-time analytical assessment in the mining and metallurgical processes is a crucial part for allowing the global improvement in mining industry. The features considered for better analytical assessment are the instrumental automation and interconnection, real time results, low cost, quality in terms of accuracy and precision. Furthermore, improving recovery (extraction), timing and quality of final products avoiding environmental impacts. Some elements such as Cu, Fe, Ag, Au, Mo, S, As, Pb, Zn are important to be determined in the process control. Additionally, rapid mineral identification of few species such as CuFeS2, Cu4FeS5, FeS2, CuS, Cu2S, MoS2, Cu3AsS4, FeAsS, among other can be challenging.

Jan 1, 2019

By John A. Dresser

Seventy years ago a period of prospecting and mining activity began in the Eastern Townships of Quebec that seems to have been quite equal to that of recent years in the Rouyn field. In the following six or seven years a large amount of work was done over a widespread area. About fifty deposits gave some shipment of ore, from a few tons upwards, and as many as five hundred occurrences of copper were made known in the district by official records. Comparing the scale of commercial undertakings of that time and of the present day, these developments must have occupied quite as large a share of the capital and man-power of the Province as northern Quebec employs today. Working conditions at that time were not very favourable. The country was then only newly opened for settlement, and colonists were few and widely separated. Roads of the class built today were unknown. A single line of railway, the Grand Trunk, crossed the district from east to west. Colonization companies controlled large blocks of land on which they owned mining rights and usually reserved these rights in whole, or in part, when selling the lands. Then, as now, the precious metals belonged to the Crown. Yet the work was not without its successes. One of the first deposits discovered, the Acton, was, for a few years, one of the most profitable producing copper mines of its time. Another, the Eustis mine, has been in almost constant operation ever since, and is now vigorously pushing further development. At least two others, now quiescent, proved profitable operations, and several made considerable production. The manufacture of sulphuric acid in Canada was begun by the founder of the Nichols Company at Capelton, on a deposit that is now being re-developed, after a long and creditable career.

Jan 1, 1928

By A. Yoshida, H. Miura, S. Yamaguchi, Y. Oyama

A discussion is given on the ionic equilibria and precipitation reactions in seawater based on thermodynamic analysis, in order to understand the solubility of nutrient salts from dephosphorization slag for marine phytoplankton. Solubility of constituent ions in aqueous solution in equilibrium with solid phases are determined using thermodynamic data. It is proposed that CO2 potential defined as log Pco2 should be considered as an additional parameter to the Eh- pH diagram for the ionic equilibrium of slag components in seawater, since magnesium and calcium carbonate precipitation reactions determine the solubility of ligand ions in nutrient salts, such as phosphates, silicate, and sulfate.

Jan 1, 2004

By G. M. Humphrey

It is a great honour and privilege to be here in this distinguished company of the outstanding men in the mining industry and the political life of Canada. I fully recognize that I am so honoured as a symbol of the combination of American and Canadian leaders in industry who are partners in the sponsor-ship of the Quebec-Labrador iron-ore mining development which we are undertaking, and as such I want to express our great appreciation of the co-operation and assistance we have met on every hand in Canada, and the genuine friendliness and never-failing courtesy which we are always accorded. We are quite aware that it springs primarily from the very high regard in which our partner and sponsor, Jules Timmins, and our other Canadian associates are held. Their high standing among you is well known and we quite naturally fall heir to the benefits of the great esteem in which you hold them. Jules Timmins and his long-time associate, John Knox, were the original inspiration for our participation in this venture. It was their enthusiasm and vision which caught our interest and led to our joining with them in the years of exploration and search which have brought us to the threshold of this great development where we stand today. So much has been written of the details of our exploration and plans for future development that it would bore you for me to review them further here, but there is a phase of this development, and an extremely important phase of it, which I think has passed almost unnoticed and which it may be well worth while for me to bring to your attention this evening.

Jan 1, 1951

By Jamal Asfahani

Abstract - Natural gamma ray well logging, an effective tool in geophysical prospecting, is used to investigate the radioactive and phosphatic layers in the Khneifiss mine in Syria. The interpretation of the gamma ray measurements, using numerical methods of analysis developed previously and applied successfully in some phosphatic areas in Syria, make it possible to define precisely the phosphate thickness from place to place in the study area. This technique has been successfully applied while studying seven boreholes in the area. Sixty-three core samples from phosphatic layers in the boreholes have been analyzed, using gamma ray spectrometry for the determination of P2O5 , U, Th, and K. Good correlation between P2O5 content and U concentration has been found. The total count gamma logs correlate reasonably well with the U core analysis, suggesting that radioactive equilibrium exists in the U decay series. These gamma logs can be therefore used effectively to quantitatively map the distribution of P2O5 and U. The characteristics of both subsurface phosphatic sand and phosphatic rocks have been investigated and outlined using a statistical approach. The affinity of uranium to some trace elements such as V, Sr, Cu, and Ni has been verified using correlation matrices of these elements.

Jan 1, 2002

By O. Bernal

The Sociedad Minera Cerro Verde S.A.A, a subsidiary of Phelps Dodge Mining Company, operates a copper mining facility located in southern Peru. This "mine-forleach" operation currently produces 90,000 mtpy of copper cathode from secondary sulfide ore utilizing crushing, leaching, solvent extraction and electrowinning processes. The leach solution handling and application rates have undergone constant development over the years. This paper discusses the improvements in leach application designed to: 1) satisfy the needs of the "lixiviant request rate", which requires the use of application rates as low as 3.5 L/h/m2 and as high as 15 Llhlm2 with variable rest periods according to the leach kinetics, and 2) alleviate the poor solution distribution on the surface of the leach heaps inherent to drip emitters. Low application rates result in poor surface solution distribution and the formation of upside down cones of dry, non-leached material in the top meter of stacked ore, with heavy jarosite and iron salt precipitation; moreover, ferric iron is lost as insoluble precipitates. On the other hand, high unit flows associated with poor agglomerate quality can lead to uneven solution flow patterns within the heap leading to solution short-circuits, fines migration, and ponding with adverse effects on acid consumption and recovery.

Jan 1, 2007