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By P. M. Chapman

Risks to aquatic receiving environments from uranium mining and milling fall into three categories: physical (habitat change), chemical (e.g., uranium, selenium, total dissolved solids [TDS], metals including vanadium), and radiological. Although all categories of risk need to be managed, chemical risks are the most significant and are typically chronic rather than acute. For instance, selenium toxicity is primarily manifested as reproductive impairment due to maternal transfer, resulting in embryotoxicity and teratogenicity in egg-laying vertebrates. Risk is best assessed using a weight of evidence approach focused on ecosystem services. Risk management should be based on both risk assessment and adaptive monitoring.

Aug 1, 2010

By Theophile Yameogo

Much has been said about the methodology of geomechanical design in underground excavations. However, the geological, hydrogeological and geotechnical complexities encountered at the production horizons in the Athabasca Basin commanded for a novel approach in the geomechanical assessment and design of underground openings. Rock mechanics engineers at Cameco McArthur River have been able to establish a practical methodology that goes beyond known conceptual approaches. In this paper, the author describes the original challenges and unique approach in the geomechanical assessment for drifts and chambers development. The example of the successful development of the 510-8225N Chamber will also be presented.

Aug 1, 2010

By Ward G. Wilson

Best practice in the design and construction of soil cover systems for mine waste management has advanced extensively over the past two decades. While significant progress has been achieved, we still have little experience with respect to proven performance for cover systems that must last hundreds of years. Some cover designs appear to be functioning well, while at the same time the performance of many more are now being called into question. This presentation evaluates the integrity of cover systems from both a global and local perspective in relation to the uranium industry within Canada.

Aug 1, 2010

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016

By Leiting Yue, Peng Ren, Yu Shen, Zhihong Liu, Haibao Shao, Longgong Xia, Feng Yu

The Kennecott-Outotec Flash Converting technology has been proven as an advanced and mature process in 5 individual plants during the past 2 decades. High grade copper matte (65–72%) produced in the flash smelting, or other smelting technologies is granulated to 3-5mm granules in a water torrent, and further crushed to fine powder (≈50µm) and dried to contain less than 0.3% H2O. Oxygen enriched air, together with fine copper matte powder and lime flux are injected into the reaction shaft by a matte burner. The copper making and slag making reactions will happen in very short time and distance during the particle falling and settling. However, industrial practice has found negative effects caused by sodium contamination. Na is introduced in the copper matte granulating process, and appears as Na2SO4 on particle surface. When Na content was high, scaling problems in the boiler will be worse, and the processing air will be blocked by the growing accretion around the matte burner, and as-produced blister copper is always high in S and O. In this present study, an industrial matte sample was used in the experimental work. Na was introduced into the matte powder by Na2SO4 solution soaking. The burning behaviour of the doped copper matte powder has been investigated as a function of the impurity concentration and processing temperature. Morphology and composition of these samples explained how Na2SO4 converts and reacts in the oxidizing atmosphere, and how they or their converting species influence the burning behaviour of matte particles. Cross-sections of as-prepared samples were analyzed with SEM-EDS, and the reaction mechanism has been carefully interpreted. Results from the present study can benefit both academic and industrial people. INTRODUCTION "Flash Converting" technology was developed jointly by Kennecott Utah Copper Smelter and Outotec (Finland) OY in 1992. The first industrialization of the technology was in Utah Smelter in 1995. Since 2006, it has been successfully applied in Xiangguang Copper, Tongling Jinguan Copper Branch, Fangchengang Jinchuan Copper, and Ningde Southeast Copper. The technology has also been further developed in those smelters. At present, roughly 2 million tons blister copper is produced annually through the Kennecott-Outotec Flash Converting technology, accounting for more than 10% of global primary copper production. The technology has advantages of high efficiency, high sulfur capture rate, good in environmental issues, mature equipment supporting, high automatic control level, low comprehensive energy consumption and flexible connection with the smelting unit, which make the technology to be one of the best choices in investing a new large-scale copper smelter or updating an old copper project in the world.

Jan 1, 2019

By C. L. Belyk

There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique geological model which may also have unique processing implications. Primary uranium production in the past decade has come from a handful of these deposit types: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic. Processing implications for each of the fifteen deposit types can vary widely between and within different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy ? including clay and carbonate species and content, hardness, porosity, uranium mineral morphology, and carbon content. Processing roadblocks may occur as a result of one or more of these characteristics for any of the fifteen deposit types. Future technological advances and innovative thinking around uranium ore processing could provide avenues for roadblock removal setting the stage for additional and economically-viable uranium production from traditional and non-traditional uranium ore deposits.

Aug 1, 2010

By Kimberly Morrison

Strategically located within the Uravan Mineral Belt District of western Colorado, the Piñon Ridge Project is the first new uranium mill being proposed for construction in the United States in over 25 years. In 1992, dramatic changes to the US regulatory environment for uranium ore processing occurred making regulatory compliance an increased challenge for a new facility. Proposed as a 6.3 million tonne uranium milling operation, the mill will receive ore from a number of mines in the region. The project includes design and permitting of a uranium/vanadium processing facility, tailings cells, evaporation ponds, and ore stockpile pads. The focus of this paper is to provide an overview of the US regulations and how these regulations were applied to design of the mill facilities, as well as provide a status update on the project as the mill license application was submitted to the Colorado Department of Public Health and Environment (CDPHE) in November 2009.

Aug 1, 2010

By D. Fredlund

The decommissioning of uranium tailings facilities often requires the design of a suitable cover system. In northern climatic environments there is a portion each year that can be considered to be ?inactive? while the remainder of the year can be considered to be ?active?. There are numerous engineering design assumptions required when analyzing both the ?active? and the ?inactive? portions of the year. Cover systems are subjected to complex boundary conditions and nonlinear unsaturated soil properties. The proposed paper describes the steps necessary for the preparation and the analysis of a multi-year climatic database for the design of a cover system in northern environments. The paper also explains how climate can be classified and how observed variations from one year to the next can be taken into consideration in cover design. The results of climatic records at two different sites are used to illustrate conditions that need to be taken into consideration when designing soil cover systems.

Aug 1, 2010

By Z. Manafi

Bioleaching of a copper sulfide ore containing "activated pyrite", using a mixed culture of mesophilic bacteria, was studied. This type of copper ore had been found unsuitable for flotation because it produces a concentrate containing relatively high iron concentrations and, therefore, a low copper grade. Microscopic observations showed that pyrite particles had been activated by the formation of a thin film of chalcocite. Hence, a bioleaching process was considered as an alternative to treat this ore. Following shake flask and acid consumption tests, column tests of the crushed ore (75% -12.5 mm) were initiated and the effects of culture medium, agglomeration, and irrigation type on copper recovery were studied. The results showed that all the columns containing bacteria had copper recoveries around 90% compared to the abiotic control column with a recovery of 50%. It was concluded that bioleaching could be successfully utilized to process copper ores containing activated pyrite.

Jan 1, 2007

By J. F. Wright

Introduction Previous to 1924 the mining fields of Manitoba and adjoining territory had not been prospected in detail, and the reports of the exploration of the mineral discoveries to that date had been discouraging. As a result of the apparent failure of all the mining operations, some considered that geological conditions in the country westward from lake Superior extending across western Ontario, eastern and northern Manitoba, and northern Saskatchewan, were different from those in the northeastern part of Ontario, where large gold mines had been developed. Discoveries of importance thus were necessary to renew interest in the mining possibilities of this part of the Canadian Shield, and the successful operations at Flin Flon and Howey in large part were responsible for the beginning of the present activity in what may be described as the part of the pre-Cambrian Shield within central Canada. In Manitoba, the more important developments at present are in the Central Manitoba, Gods Lake, and Knee Lake fields. The large area from west of Flin Flon east to Herb Lake, also, is being explored carefully for gold deposits of merit. A number of properties in Red Lake, Woman Lake, and Pickle Crow areas are being drilled and explored underground. Many of the mines of the Lake of the Woods area, that were producing gold 30 years ago, are re-opened, and new prospects in this field and in the country to the east are being explored. The recent development of Little Long Lac mine in an area near the railway, and considered by some to have been thoroughly prospected years ago, has stimulated interest in the areas formerly prospected. In the autumn of 1934, the belts of greenstone and sediments in the country east of lake Nipigon were staked, and deposits in these fields will be explored in detail this year. This paper is presented to discuss the general features of the geology and gold deposits of the various prospecting fields in Manitoba and adjoining territory. Details of a number of the areas and mines will be presented at this meeting in papers by Barton on Little Long Lac, Tanton on Sturgeon River, Baker on Gods Lake, and Brownell and Kinkel on Flin Flon. Although mining was not active in most of this territory previous to 1930, geologists of the various government departments continued field studies and interesting reports were issued.

Jan 1, 1935

By A. Bhowmik

Uranium Refining is the process in which undesirable neutron absorbing elements such as Boron (B), Gadolinium (Gd), Cadmium (Cd), Europium (Eu), Samarium (Sm) and other heavy metals (Fe, Ni, Co, Ca, Mg etc.) are removed to make it nuclear pure. At present, Uranium refining is carried out by solvent extraction process by using organic based solvent e, g. TBP diluted with Kerosene. The above process generates lot of nitrate bearing liquid waste and degraded organic. In order to eliminate use of hazardous organic and ammonia for Uranium refining altogether, a new process has been developed. In the new process, Yellow Cake is dissolved in nitric acid and uranium peroxide hydrate is precipitated selectively from the solution leaving all the impurities in the solution by using commercial grade hydrogen peroxide at a pre-defined pH, U conc., temperature and stoichiometric quantity of hydrogen peroxide under mild agitation. The precipitate is filtered and washed with DM water to obtain nuclear pure product meeting purity standard as per ASTM C ? 753-99.The product is spray dried and calcined to obtain uranium oxide. The process eliminates use of organic, flammable, toxic chemicals, consumes less quantity of nitric acid and uses environfriendly chemical hydrogen peroxide. The process is simple and can be integrated in the mill. A patent application is entering national phase in several countries including CANADA and abstract/full paper is available in WIPO publication no: WO/2009/013759.

Aug 1, 2010

By M. Abdollahi, M. R. Khalesi, Y. Kianinia, A. Khodadadi Darban

High cyanide consumption during the processing of gold ores with high sulphide minerals can make the typical cyanidation uneconomic. Also cyanide is a toxic material and environmental concerns of cyanide compounds are serious. Optimization of cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, the kinetic of their dissolution and estimation of formation of cyanide complexes which consume the free cyanide. In this paper, a methodology to estimate cyanide consumption by modeling the minerals and gold leaching kinetic based on a liberation model and speciation of all possible cyanide related species in the solution is presented. The results showed that this methodology could successfully estimate the cyanide consumption based on mineralogical data with very lower number of parameters compared to empirical models present in the literature, while it offers the prediction of formation of all cyanide complexes which could be used for optimization purposes.

Jan 1, 2017

By Elizabeth Edwards, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg, Kurtis Judd

Mineralogical characterization of the tailings showed the deportment of Ni to be similar in the Vale and Glencore tailings, with 60% of the total Ni locked in pyrrhotite, and the balance 40% associated with pentlandite. The overall Ni dissolution was correlated with the individual dissolution extents of pyrrhotite and pentlandite as functions of four leaching regimes: ‘anoxic acid’ (with and without pH control), ‘oxic acid’ (oxygen sparging), ‘oxic acid’ (air sparging), and ‘oxic ferric’ (air sparging). The results showed that the maximum Ni dissolution was obtained during the pH controlled oxic acid leach with oxygen sparging at pH 1.5, while the anoxic acid leach at pH 1.5 resulted in minimum Ni dissolution (10–15%) from pyrrhotite. An overall Ni mass balance showed that pyrrhotite and pentlandite dissolve simultaneously in the presence of Fe(III) and oxygen, in contrast to the preferential dissolution of pyrrhotite in the absence of Fe(III). Sulphur mass balances revealed that the yield of elemental sulphur is maximized (65%) during the oxic Fe(III) leach at pH 0.6. Furthermore, the kinetics of Ni leaching and elemental sulphur formation from pyrrhotite tailings leached with ferric sulphate between 55–80°C was investigated at constant oxidation-reduction potential. Elemental sulphur yield increased with increasing temperature, but no observable trend could be linked to ferric or ferrous ion concentration.

Jan 1, 2017

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By David Lewin

The journey toward cleaner coal-fired power generation is driven by technological improvements, more stringent regulations around greenhouse gas and other air emissions, and the potential of one of Canada?s most abundant resources. Within this context, EPCOR is leading efforts to commercialize gasification technology to produce electricity with near-zero emissions. By turning coal, oxygen, and water into synthesis gas through a gasification process ? and then capturing CO2 ? it is possible to dramatically reduce greenhouse gas and smog-related emissions. EPCOR is conducting front-end engineering and design work on an Integrated Gasification Combined Cycle technology (IGCC) utility-scale plant ? in conjunction with the Canadian Clean Power Coalition ? at its Genesee site, west of Edmonton. EPCOR, the Alberta Energy Research Institute, and Natural Resources Canada have each contributed $11 million to the $33 million project. A critical element of the project features the capture of CO2, which would be piped underground for long-term sequestration, or for use in enhanced oil recovery (EOR). The combination of IGCC and CO2 sequestration, at this scale, has not been used anywhere else in the world.

May 1, 2008

By Z. D. Hora

Air hough diatomite is known in many parrs of British Columbia, deposirs of mineable size have only been found in the area between Kam/oops and Quesnel in the sourh-cenrral parr of rhe province. Ar Quesnel, commercial producrion has continued since 1950 from diatomite lenses up ro 35m rhick. OCCURRENCES of diatomite are reported from many parts of British Columbia, but deposits of mineable size are known only from the area between Kamloops and Quesnel. Only Quesnel deposits have yet reached the production stage. Commercial production dates back to 1950, and up until 1979 approximately 22,700 tonnes of diatomite had been produced. Most extracted diatomite was processed until 1980 by Crownite Industrial Minerals Limited in Quesnel to produce an oil absorbent and animal bedding. Smaller shipments are used to make insulating bricks on the lower mainland. Deposits near Quesnel extend 40 km along the western bank of the Fraser River from Quesnel to Alexandria; most production has come from Lots o. 6132 and 906. Di atomite is present as discontinuous lenses up to 35 m thick. Diatomite beds Industrial Minerals in Canada are of Upper Miocene age and are overlain by plateau basalts. Diatomite consists almost exclusively of Melosira granulara diatoms that are usually very small and mixed with variable amounts of clay, ilt and volcanic ash. In recent years, extensive beds of diatomite were identified near the confluence of the Chilcotin and Fraser rivers. Diatomite in this locale is a part o f the Upper Miocene to Pliocene Chilcotin Group of sedimentary rocks that are overlain by olivine basalt and related luffs. A deposit near Red Lake is situated 50 km northwest of Kamloops. Diatomite beds occur in the Tranquille Series of Eocene age and are similar in composition to those in the Quesnel area. The Red Lake deposit is abo ut 4 m thick but its areal extent is only a few tens of hectares.

Jan 1, 1984

By Z. D. Hora

Limestone of economic interest is widespread in British Columbia. Triassic deposits on Texada Island are a convenient 1idewa1er source of li111es1one for cemen1 and lime for 1he Pacific orthwes1. Permian limes/one near Pavilion Lake is used for quicklime, and a deposit near Kam/oops is used for cement. Quarries at Dahl Lake and Pwrmigan Creek serve local pulp and paper needs.

Jan 1, 1984

By H. Tokuichi, H. Ohta, K. Sato

A physical separation technique of tantalum capacitors from waste print circuit boards is in a development phase in Japan. A tantalum capacitor consists of an exterior coating of resin (epoxy resin) mixed with silica fillers and a sintered tantalum compact, the latter of which is impregnated with manganese dioxide (MnO2). In this study, we developed a process to recover tantalum oxide from tantalum capacitors by roasting, fluidized-bed separation, and hydrometallurgical treatments. Our aim was to recover tantalum oxide with high purity from waste tantalum capacitors. In this process, the exterior resin was selectively decomposed by roasting without oxidation and pulverization of the sintered tantalum compact at a proper temperature. Furthermore, the decomposed resin with silica filler on the surface of the sintered tantalum compact was mostly removed by fluidized-bed separation. The surface of the sintered tantalum compact was cleaned by ultrasonic irradiation in an acid solution to remove the MnO2 paste as well as residual Ag paste and silica filler. The impregnated MnO2 in the sintered tantalum compact was leached as Mn(II) ions using acid solutions via the reducing effect of tantalum metal to recover purified tantalum oxide.

Jan 1, 2014

By Joel Werner

Weak metal prices, declining head grade, and increased operational costs are forcing many open pit mining companies to look to their balance sheets for significant cost reductions in order to remain competitive. Maintenance continues to represent a significant proportion of the total operating costs in the mining industry. Compared with the other major cost components of the mining process very little effort has gone into maintenance optimization. The potential payoff from maintenance optimization on the cash cost of the commodity is enormous. A large percentage of these costs are incurred in unscheduled maintenance events, which typically cause serious disruptions to the production process. These maintenance induced production losses can be a significant contributor to the overall operating costs. A structured proactive maintenance approach using the latest advances in technology can achieve dramatic cost reductions and productivity improvements. Remote condition monitoring systems are becoming increasingly commonplace and have the potential to identify problems prior to failure. Detection of equipment degradation prior to failure will enable repairs to be scheduled thereby reducing costs and interruptions to production. Remote condition monitoring technology has evolved rapidly in recent years, with a host of new tools becoming available to assist mine operators in improving their maintenance operations. These tools have capabilities such as: remote real-time vital signs and performance monitoring, alarm/event handling, trend analysis, and maintenance workflow management. When these monitoring tools are used in conjunction with a mine management system the vital signs data can be integrated and associated with maintenance history, predictive maintenance data, operational information, and geographical information. This integrated approach to the management of vital maintenance data will help shift the mobile equipment maintenance paradigm from reactive to proactive. This paper will introduce a proactive approach to the management of the maintenance process and the tools required to facilitate this process.

May 1, 2003

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014