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By Youngsoo Song, Hyunjung Kim, Junhyun Choi, Siyoung Q. Choi, Gahee Kim

In this study, for the first time, to confirm the effect of bacterial growth phase on the malachite flotation were investigated in a well-controlled Hallimond tube system. The test results showed that the bacteria in the stationary phase exhibit two-fold greater floatability than those in mid-exponential phase. To understand the observed flotation behavior, complementary cell characterization tests and cell attachment tests were conducted. Interestingly, the bacteria at both phases exhibited similar surface properties as well as almost identical amount of cells attached onto the malachite, suggesting that the growth phasedependent flotation behavior cannot be attributed to the variation of cell surface properties and the extent of cell adsorption. On the other hand, cell detachment tests revealed that the amount of cells detached from the malachite surface is greater for the mid-exponential phase than the stationary phase due to the higher fluid drag applied to the cells at the mid-exponential phase, which was explained by the differences in the size and shape of attached bacteria onto the malachite surface. These morphological characteristics were found to cause the bacteria of mid-exponential phase to be separated highly sensitive and easy from malachite surface due to the fluid flow. Second, scale-up selective bioflotation tests were carried out in a 1 L Denver cell in malachite–silica binary mixture systems. Through the tests, we optimized the cell concentration and the malachite fraction in the feed. Overall, high malachite selectively was observed under optimized conditions (both recovery and grade showed more than 90%). The trend was in agreement with classical DLVO interaction energy profiles, which show the relative magnitudes of the adhesive forces between the mineral and the attached cell under equal hydrodynamic conditions.

Jan 1, 2016

By J. Arzúa, L. R. Alejano, P. Rodríguez

"After six years of successful excavation with a support pattern, some roof failures have happened in a room-and-pillar underground mine excavated in a stratified rock mass. In this paper the authors give explanation to the failure mechanisms and redesign the support in order to solve the recent problems of roof collapse.The mine magnesite bed is approximately 14 m thick, and runs in the E-W direction with an average dip of 18º. Due to mine constraints and the inexpensiveness of the ore, the excavation is performed in the mineral itself, avoiding the need for mining dumps and waste excavation. Rooms and drifts are oriented in the mineral bed to form an angle of 19º to the direction of the strata, reducing the roadway gradients to less than 10%. Rooms are 11 m wide and pillars are 7 m wide. They are designed to leave a 1 meter thick magnesite bed in the roof of the rooms to act as a supporting beam. More often than not there is a layer of very poor quality marly shale up to 1 m thick resting on this magnesite beam. Overlying the poor quality marly shale there is a better quality, self-supporting sandy shale.First, a characterization of the involved rock masses (magnesite, marly shale and sandy shale) is performed, collecting the geotechnical data from previous studies and performing new in situ geotechnical surveys to check the soundness of the previous data. A distinction is made between different quality zones inside the mine by means of the RMR classification, associated to the occurrence of faults.Back-analysis of some of the failed rooms and data from exploration boreholes were used to determine the failure mechanisms (associated to Voussoir type failure or occurrence of sub-horizontal joints crossing the magnesite beam). Based on an understanding of these mechanisms, the method used to design the support and to analyse the stability of the different possible thicknesses of the magnesite beams of the rooms and drifts of the mine were improved.Numerical models of the most relevant conditions found in the mine were performed in order to better understand the behaviour of the roofs and to simulate the supporting solution obtained in the previous analyses.The most relevant conclusions with regard to the main elements causing the instability of the roof include the appearance of sub-horizontal discontinuities crossing the magnesite bed, which causes total instability of the roof and usually leads to collapse; excessive thinness of the magnesite beam in the problematic rooms; and the relaxation of the deepest (around 270 m in depth) zone of the mine because of existing faults."

Jan 1, 2015

By F. H. Samuel, P. Burke, F. Mucciardi, J. Gruzleski, S. A. Musmar

A new thermal analysis technique has been developed and tested. It utilizes the enhancement in heat transfer characteristics associated with a recent advancement in heat pipe technology. Heat is extracted from a liquid sample of a melt taken in-situ within a vessel or furnace. The rate of heat extraction is such as to cause the sample to solidify. The technique was tested in both laboratory scale and industrial scale (Grenville Castings, Perth, Ontario). A 356 Al Alloy, subjected to various melt treatments was used to perform the tests. Classical thermal analysis was also performed simultaneously using a preheated graphite cup and at the same melt conditions. The comparison showed the potential of the new technique over classical thermal analysis. The major advantages of the new method are that it conducts the analysis inside the melt (i.e. a physical sample is not removed from the melt), it consumes less time and the cooling rate can be precisely controlled during the solidification process. Moreover, the resolution of the results is better than that of conventional techniques. Aluminium

Jan 1, 2006

By W. R. Lindsay

Anyox, where the Hidden Creek mine of the Granby Consolidated Mining, Smelting and Power Company is located, is situated on an excellent deep-water harbour in Granby bay, at the head of Observatory inlet, about 600 miles from Vancouver and 90 miles north of Prince Rupert. Anyox is the Indian name for the little stream which empties into Granby bay, and means 'hidden creek'. The Ore-Bodies The ore is a replacement deposit and occurs at and near the contact between argillites and a later intrusive greenstone. This contact locally has a general north-and-south trend, an irregular westerly dip, and in the vicinity of the ore-bodies there has been intense folding, accompanied by faulting. The mineralizing solutions supposedly were derived from the Coast Range granite batholith, distant one to two miles to the east and north. The whole area is cut by many dykes of varying widths, which seem to have had but little part in the ore deposition.

Jan 1, 1929

By C. A. Lorenson

THE Marmoraton mine is located a mile southeast of Marmora, a village in Hastings county, Ontario, 130 miles east from Toronto and 143 miles west of Ottawa. Highway No. 14 from Belleville intersects Highway No. 7 at Marmora and the branch line of the Canadian National railway between Trenton and Bancroft passes through the property just east of the open pit. HISTORY AND GEOLOGY The Marmora orebody appears as the whorls of a thumb print on the aeromagnetic survey map released by the Ontario Department of Min.es early in 1950, the survey of the district having been made in 1948 and 1949, under the joint auspices of the Department of Mines and the Geological Survey of Canada. The 'anomaly' appeared to have interesting possibilities, so Bethlehem representatives carried out a ground survey and began drilling the property in June, 1950. A total of 40 holes, aggregating 37,000 feet, were drilled to delineate the ore-body. The Marmora orebody is a re-placement of Precambrian limesto.ne with zones or bands of magnetite interlaid with metamorpl1ic rocks and cut by later intrusives. The ore and associated Precambrian rocks are overlain by 100 to 150 feet of flat-lying Palaeozoic limestone. It is a low-grade deposit averaging 33 per cent iron and requires concentration to raise it to 65 per cent iron grade.

Jan 1, 1958

By J. S. Redpath

Eighty feet of overburden, thirty feet consisting of fine, water-bearing sands, was encountered during the construction of a shaft collar for Chimo Gold Mines Limited at its Louvicourt, Quebec, property. This paper describes the excavation and construction methods used on the project. Open-cut methods, a sheet pile cofferdam, chemical grouting and special blasting methods were used during excavation. Concrete placement was hampered in the lower portion by a heavy water flow, and aided in the upper portion by an unusual method of form bracing. Plant and • pum11ing facilities are also described.

Jan 1, 1966

By Clyde Williams

If you would allow me some liberties, I would re-state the title of this talk as Scientific Research, Our Greatest Resource, because that title would represent more clearly a present-day conception of the metals and minerals situation. It is a subject worthy of careful consideration. Canada and the United States are so similar and interdependent in their national economies that, in the following discussion, examples of conditions in the United States may? be interpreted to apply to Canada as well. Moreover, it is a striking fact that the per capita value of mineral production in Canada and the United States in 1940 was almost the same. Therefore, in the consideration of this subject, I have made no attempt to differentiate between the two countries. The consumption of the world's mineral resources in the last few decades, and particularly during World War II, has been so enormous as to require some form of magic to ensure the continued progress of civilization in the face of a diminishing supply of these resources which are so critically essential. As Dr. C. K. Leith pointed out in 1941, industrial expansion has been so great that, during the first forty years of this century, the world used more of its mineral recourses than in all preceding history. And this did not include the all-out consumption during the succeeding five years of war.

Jan 1, 1947

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By J. A. Finch, R. R. Cunningham

The amount of foam volume generated in relation to the gas flowrate has long been used to define the foaminess of a solution and to characterize surfactants. The vessel geometry and gas flowrate range can affect the foam volume results. A fixed area column was tested alongside a variable area conical vessel with two surfactants. It was found that the fixed area vessel will cause foam volume to expand or contract which masks the effect of the surfactant. The conical vessel showed two regimes of foam volume production dependant on gas flowrate. The low gas flowrate regime revealed the physiochemical nature of the surfactant while a high gas flowrate revealed kinematic properties. Foaming properties of a surfactant is best determined with a variable area vessel at low gas flowrate.

Jan 1, 2009

By S. Huang, K. Xia

"During crushing, rock particle is subjected to complicated loading and the particle shape influences the fragmentation outcome. Thus, a highly controlled laboratory test is desired to establish the relation between the loading and the fragmentation parameters for better understanding the rock crushing mechanism. In this work, a split Hopkinson pressure bar system in combination with high speed cameras is utilized to carry out a dynamic ball compression test, in which the spherical rock sample is adopted to avoid the shape effect. Using the elasticity theory, the history of the axial symmetric tensile stress perpendicular to the diametrical direction along the loading axis is determined, from which the loading rate and the dynamic indirect tensile strength are calculated. With the aid of the moment-trap technique, the total energy absorbed by samples is accurately determined from the one-dimensional wave analysis. Furthermore by considering the kinetic energy of the sample fragments using the high speed camera snapshots, the surface energy is determined for each sample. The relations between the loading rate and the fragmentation parameters, i.e., the number of fragments and the surface energy are established. The application of this method to a granitic rock shows that it is flexible and can be applied to the crushing study of generic brittle solids. INTRODUCTIONCrushers are widely used to break rocks to extract specific minerals in the mining industry, and to obtain rock fragments with desired size distribution in construction industry. During crushing, the breakage of particles can be in either the single-layer mode or the multi-layer mode. In the single-layer mode, the particle breakage can be assumed to be isolated, in which the interaction between particles can be ignored. It is thus suggested by many researchers that highly controlled single particle test should be performed to establish the relation between the input mechanical energy and size reduction for better understanding the crushing mechanism (Yashima et al., 1987; Tavares, 2007; Pitchumani et al., 2004)."

Jan 1, 2015

By Keith Eldridge, Robert Kelly

"Quality management has a/ways played an important role at the Iron Ore Company of Canada; particularly since the early eighties when the iron ore markets favoured buyers as opposed to sellers.Since thot time, IOC's quality system has evolved from basic quality control to the Deming philosophy and its 14 points, and on through various other phases to the ISO 9000 series.ISO 9002 Registration was' first requested by IDC's customers and development plans were prepared in 1988. At this time, Quality System Registration was unheard of in the mining sector and TDC found itself struggling with the concept. The 1U!Xt three years saw the company develop a Quality System to meet ISO 9002 in a two phased approach, setting new standards for the mining industry when registration was achieved in December 1991.The company now sees ISO Registration as the cornerstone of its future quality efforts. IOC's quality system has been integrated with several other initiatives such as loss control and functional training, both of which focus on training and management the workforce to do the job safely, the right way.This paper addresses the steps required to develop a quality system for the mining industry within the guidelines of the ISO 9000 Series and the subsequent integration of other quality related initiatives."

Jan 1, 1994

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

The tensile test results of as-cast A356.2 grain-refined alloy castings show that the tensile strength can be improved by strontium modification (`SrM'), superheating at 900°C OM, and melt thermal treatment of the Sr-modified alloy melt (`SrMTT'). Both SrM and SrMTT processes can greatly improve the ductility (percent elongation) of the as-cast alloy. During solution heat treatment at 540°C, eutectic Si particles undergo fragmentation, spheroidization, and coarsening, thereby affecting their morphology. The effects of solution heat treatment on the tensile properties of the variously treated A356.2 alloy castings can be summed up as follows: the yield strength of the castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg2Si, after which it remains more or less the same with the further increase in solution treatment time up to 80 h; the ultimate tensile strength is also greatly improved within the first 8 h of solution heat treatment and then remains at the same level thereafter, up to 80h of solution treatment. The improvement in UTS is attributed to Mg2Si precipitation, dissolution of Si within the aluminum matrix, and changes in the Si particle morphology (spheroidization). The ductility of the as-received grain refined non-modified (`NM'), grain refined and superheated at 900°C (`SH'), and melt thermal-treated grain refined (`MTT') A356.2 alloy castings can be improved considerably with solution heat treatment e.g. from ~6% in the as-cast non-modified casting to ~10% after 80 h solution treatment.

Jan 1, 2011

By M. Loan

The Zinifex's Hobart Smelter uses the paragoethite process to remove dissolved Fe(III) from concentrated zinc leach liquors. This produces a residue consisting primarily of 6-line ferrihydrite (a hydrated Fe(III) oxyhydroxide), several insoluble components derived from the calcined zinc concentrate neutralization agent and other precipitated phases, such as jarosite and silica. The precipitation of 6-line ferrihydrite in the paragoethite process was studied using a laboratory-scale continuous crystallizer, and the conditions were selected to limit high levels of dissolved silica and jarosite. This approach allowed the reactor pH and the rate of precipitation to be correlated with residue solid-liquid separation, particle size, morphology, residual zinc and sulfate concentrations, and phase formation (e.g., goethite, jarosite, schwertmannite, and 2- and 6-line ferrihydrite). These studies delineated the mechanism of 6-line ferrihydrite precipitation in the kinetically controlled paragoethite process, and its inter-relationship with goethite and jarosite precipitation under conditions where 6-line ferrihydrite is favoured. Unexpectedly, the generation of a more crystalline goethite precipitate with larger "primary" particle size did not produce a residue of improved properties, as bulk aggregates dictate the physical properties of the residue and not the crystallinity. Furthermore, it is difficult to precipitate 2-line ferrihydrite or schwertmannite under existing paragoethite process conditions.

Jan 1, 2006

By M. D. Gerst

The degree to which copper will continue to be in an integral part of the world economy in the future will depend largely on the dynamics of global economic development, the primary and secondary copper resource stock, technological change, and potential environmental constraints. We have characterized the copper cycle of 1994 for all of Earth's regions and for the planet itself (T. Graedel et al., Environmental Science & Technology, 38, 1242-1252, 2004) and recently updated that cycle to year 2000. In this paper, we compare various features of the 1994 and 2000 cycles. The three largest-using regions, Asia, Europe, and North America, all increased their absolute rate of copper use between 1994 and 2000, and all increased the per-capita rate of copper use as well. Globally, the use of copper increased by about 32%, from 11.7 to 15.3 million metric tons, while population increased by only 8%. Various changes are seen in scrap trade, finished products trade, and other parameters of the cycle. We conclude by considering how the rates of technological change and growth in demand, especially in Asia, may influence the copper cycle in the years ahead.

Jan 1, 2007

By R. C. Gilmore, J. McMack, G. E. Bogin, J. F. Brune, C. DeRosa

"Researchers at the Colorado School of Mines are designing and building a 1:40 scaled physical model of a fully operational longwall coal mine. The purpose of the model is to minimize the occurrence of methane explosion hazards by testing various ventilation strategies and determining optimal methane sensor placement throughout the longwall face. Fluid scaling factors were analyzed using Computational Fluid Dynamics software Ansys FLUENT™ at both full and 1/40th scales. Researchers were able to identify key scaling factors and subsequently developed suitable flow parameters that would maintain full scale accuracy of flow patterns in the 1/40th model. KEYWORDS Coal, Longwall, Methane, Explosion, Scale Model, Ventilation, Fluid Dynamics, Richardson, Gob, Porous INTRODUCTION Mine ventilation systems are a key component for ensuring a safe working environment by introducing fresh air from the surface and diluting explosive gases and hazardous contaminants. This holds true for longwall coal mines where the emission of flammable methane gas from the longwall face as well as the gob can create explosive mixtures of methane and air. Therefore, an effective ventilation strategy can help mitigate the potential for accidents within a mine. Developing an effective mine ventilation system (MVS) requires a detailed understanding of the physics of gas transport and how this relates to specific geometries and obstructions in the face. Researching this phenomenon requires the development of computational fluid dynamics models capable of simulating fluid flow and methane species transport that can be validated through physical experimentation. Unique site conditions determine ventilation layouts for every coal mine. Researchers have designed a 1/40th scaled physical model of a longwall coal face and adjacent gob that includes movable shield supports and a movable shearer with rotating cutter drums that can be adjusted to a variety of ventilation conditions. The proposed work will address the need for an improved Mine-wide Atmospheric Monitoring System (AMS), and provide the ability to link existing MVS models with AMS in real time. By accurately representing the coal face, the gob area and the mining equipment, gate roads and bleeder entries, the scaled model accurately represents all relevant structures, geometry, and dynamic conditions. A Plexiglas cover allows full optical access for sensor equipment as well as visual inspection of the fluid flow and species transport."

Jan 1, 2019

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By D. B. Johnson

Acidic, metal-rich waters generated at working metal mines and abandoned mine sites are generally considered to be major pollutants of the environment. However, the metals they contain often have significant value of their own, or as sources of useful mineral products. We have developed novel bioreactor systems that facilitate the selective recovery of various transition metals (e.g. copper, zinc and iron) as defined minerals that can be recovered and recycled. The bioreactors use novel species of acidophilic bacteria. Ferrous iron is oxidised by Ferrovum myxofaciens, a specialist bacterium that forms large amounts of exopolymers and grows as filamentous streamers in flowing mine waters, and the ferric iron generated is precipitated as the mineral schwertmannite, a small proportion of which is used to remove any arsenic present in mine water. Copper and zinc are precipitated as sulphides using H2S generated by consortia of acidophilic and acid-tolerant sulphate-reducing bacteria in a continuous flow, on-line low pH bioreactor. Transition metal sulfides can be segregated by precipitating them, either on-line or off-line, at different pH values. The modular units that have been developed can be configured to treat mine waters of different chemistries. A hypothetical acidic (pH 2.5) mine water stream containing 500 mg/L iron, 100 mg/L of copper and zinc, 50 mg/L of aluminum and manganese, 2 mg/L of arsenate, and discharged at a rate of 10 L/s, is used as an example of the potential application of the mineral-generating bioreactors. The environmental benefits and economic implications of considering mine waters as resources rather than wastes are discussed.

Aug 1, 2013

By W. J. Wolfe

"THE DETECTION OF BURIED MINERAL DEPOSITS by chemical analysis of vegetation (biogeochemistry) or visual observation of plant cover type (geobotany) is based on fundamentally simple principles. The root systems of vegetation collect aqueous solutions from a large volume of moist ground below surface and act as efficient sampling mechanisms by providing a composite sample of a reasonably large area. These aqueous solutions constitute a source of ore-associated metals that may ultimately be concentrated in the upper parts of the plant. Although certain plant species have a limited ability to break down primary minerals and extract elements, biogeochemistry normally detects only metals capable of moving in solution. Metal concentrations in the underlying soil must therefore exist in a form that is immediately available for uptake by the root systems - generally in the ionic state in aqueous solution or in readily exchangeable form on the surfaces of soil clay minerals. As a result, biogeochemical responses are closely related to variables such as soil pH, Eh, exchange capacity and complexing agents that control metal mobility in the surface environment. In terms of cost, reliability and anomaly contrast, soil geochemistry will normally be more useful than biogeochemistry in locating buried mineralization in regions of residual overburden or thin transported cover. However, in areas where the root systems penetrate thick deposits of transported post-mineralization overburden, plants can provide an effective mechanism of sampling below the transported material. Biogeochemical research in Canada, Scandinavia and the U.S.S.R. has therefore focused on the potential use of plant prospecting methods (1) in areas where the upper horizons of podzolic soils do not provide an adequate response to anomalous conditions under thick deposits of glacially transported till and (2) in widespread regions of peat and muskeg terrain where near-surface mineral soils are absent."

Jan 1, 1971