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By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016

By H. Perez, A. Lavoie, V. Prévost, P. Létourneau, P. Lind

The Home smelter is a custom copper smelter located in Rouyn-Noranda, Quebec. In 2005, the smelter produced 145,000 t of copper containing 807,000 oz of gold, 20,388,000 oz of silver in addition to 515,000 t of sulphuric acid. Recently, a flexible flow sheet has been developed incorporating the intermittent use of the Noranda Continuous Converter allowing for the increasing or decreasing of production based on market conditions, while attaining 90% or greater sulphur fixation regardless of operating mode. For 2006, the smelter is operating in full production mode and production is expected to be approximately 185,000 tm of copper. Mechanical modifications, process changes, metallurgical concepts, minor element treatments, and operational techniques that have allowed the smelter to develop this flexibility are presented. Current efforts to increase the productivity of the converter aisle and anode furnaces as well as improvements being made to address fugitive emissions are also discussed.

Jan 1, 2007

By J. A. Brusset

THE Greenhill mine of West Canadian Collieries, Limited, is situated at Blairmore, Alberta, and produces 2,500 tons per day of bituminous coal. On Monday, October 25th, 1943, smoke was discovered by a party of firebosses on their regular weekly inspection of air-ways. Probably the fire had been smouldering for several days but, as it had started on the outcrop at the top of an old raise filled with dirt, only a small quantity of smoke could filter through, and the plume of mist that crowns the fan at that season had prevented the fan-man from noticing it. This raise is only about 200 feet from the fan, and is 70 feet long between the fan-drift and the outcrop. It was impossible to prove the origin of the fire, as it had probably started several days before it was discovered, but it is possible that a careless smoker may have thrown a match into the opening at the outcrop, and that the old, dry timber had caught fire. The airways are in No. 2 seam, a bituminous seam 18 to 25 feet thick surmounted by shales and sandstones. Only 45 feet vertically above it is No. 1 seam, 12 feet thick, overlain by a strong conglomerate. In that vicinity, No. 1 seam had been worked out about ten years ago and the strata between the two seams are undoubtedly fissured. The pitch of both seams is 43 degrees.

Jan 1, 1945

By R. N. W. DiLabio

"In a continuing program of mapping glacial dispersal trains, near-surface till samples were collected down-ice from a copper-silver-gold prospect at Onaman River, Ontario, and down-ice from the past-producing gold district at Oldham, Nova Scotia. The program is designed to aid exploration by illustrating glacial dispersal from various types of known occurrences and by identifying postglacial processes that control drift composition at a detailed scale.Native gold was mined at Oldham from arsenopyrite-bearing saddle reef quartz veins in a dome in Early Paleozoic slates of the Meguma Group. Gold abundances greater than 10 ppb in till form a dispersal train at least 1900 m long. Gold abundances between 40 and 100 ppb occur in clusters up to 600 m down-ice from gold-bearing bedrock. Anomalous arsenic abundances in till form a broad train 1100 m long that is significantly different in shape from the gold train.At Onaman River, subeconomic amounts of Cu-Ag-Au occur in quartz lenses in Archean mafic volcanic rocks. A dispersal train defined by the distribution of mineralized boulders and increased abundances of Cu, Ag and Zn in till extends 600 m down-ice from mineralized bedrock. Gold abundances between 10 and 70 ppb do not define this dispersal train, but occur instead in clusters 300 to 600 m down-ice from mineralized bedrock. In vertical sections in the upper 2 m of copper-rich till, Au abundances vary sympathetically with Ag and Cu levels; however, there seems to be no preferential site of Au enrichment in the mineral portion of the soil profile.Several of the mineralized boulders at Onaman River are richer in Au and Ag than the mineralized bedrock from which they were derived. Although some of the high Au and Ag assays were caused by biased sampling of sulphide-rich portions of the boulders, many were caused by leaching of sulphide minerals from 'the boulders, which left a limonitic boxwork that is enriched in Au and Ag. A few of the Au-rich boulders may have been derived from an unknown bedrock source."

Jan 1, 1982

By P. Czaja

The paper presents a patented and copyright protected concept of constructing a shaft lining that goes through rock masses having strong rheological properties and being susceptible to leaching. In the case of salt layers, especially at significant depths (over 900 m) the relative convergence of the heading contour may amount to 40 ?/year. That results in the fact that any other method of securing the shaft lining, e.g. by making it flexible, will not be sufficient to ensure the stability of the shaft reinforcement geometry. In the new shaft lining concept the excessive rock creep into the outbreak inside the shaft diameter will be removed by local and controlled leaching of the shaft cheeks by means of fresh water directed through a porous medium at the contact layer behind the watertight tubing lining. The paper presents the structure of such a lining and an outline of the construction technology. In order to implement such a lining, a typical tubing will be applied. Separate design and manufacturing will be required for the technological rings used to control the leaching process behind the lining.

Aug 1, 2013

By S. H. Seyedein

A mathematical model was developed to study fluid flow and solidification in a single-roll casting system. Fluid flow coupled with energy equations were solved numerically using a finite volume method. A body-fitted coordinate transformation technique was adopted to handle the irregularly shaped domain. In order to couple the continuity and momentum equations, a SIMPLEC algorithm was used. A fixed-grid enthalpy method was considered to model the solidification in the system. The turbulence effect on flow field was modeled using a low-Re k-e model The model developed in this work was further run under various conditions to optimize the operating parameters of the process.

Jan 1, 2004

By D. A. Beattie

Talc is a commonly encountered gangue mineral in metal sulfide flotation. Talc is naturally hydrophobic, resulting in high recoveries if polymeric depressants are not used to specifically reject this MgO containing mineral. We have studied the adsorption of a selection of polymers onto talc using a variety of techniques. Adsorption isotherms have been determined using ex situ depletion techniques and in situ ATR-FTIR spectroscopy has been used to determine adsorption kinetics. Adsorbed layer thicknesses have been determined for the polymers on cleaved talc surfaces using the AFM. The effect of the adsorbed polymer layer on the properties of the talc surface has been quantified through contact angle measurements and single mineral flotation tests. Distinct correlations are observed between the adsorbed layer properties and the flotation performance of the polymers. These observations are discussed with reference to the bubble-particle attachment process and the molecular structure of the polymers.

Jan 1, 2006

By Alexander Smith

"The three principal known mineral deposits of the Taku River area lie in the Tulsequah synclinorium. The axis of this north-south trending structure is along Tulsequah River valley; about 6 miles east of the eastern contact of the Coast Range batholith.The one proven mine of the area, the Polaris-Taku, is on the west side of the valley. It is a gold property, the gold occurring in fine needles of arsenopyrite disseminated in carbonatized volcanics. The mine was originally called the Whitewater, and the adjacent area the Whitewater gold belt. During the years 1937 to 1942 gold having a value of $3,284,000 was produced from 313,500 tons of ore milled."

Jan 1, 1954

By Staff

Introduction The Hedley mine, perhaps better known as- the Nickel Plate mine, is one of the outstanding properties of southern British Columbia. Discovered in 1898 by Woollison and Arundell, prospectors, the property was bonded in 1899 to M. K. Rodgers for the Marcus Daly Estate, of Butte, and development was started the same year. From the high grade of the ore outcrop, and its colour, due to oxidation of the arsenopyrite, it was not difficult to open up and trace the showing. The Nickel Plate ore-shoot, which apparently had been easy to follow on surface, was more difficult to trace underground. In 1903, prospecting on an adjoining property, the Sunnyside, showed commercial ore at surface, but it was only after two years' work that the ore-body was defined and shipments started. From this property, $1,200,000 have been taken out. Prospecting was also carried on on the IXL, Climax, Copper Cliff, Mound, Bulldog, Exchange, Silver Plate, Gold Plate, and other properties, all of which had surface showings, but up to date only the Nickel Plate, Iron Duke, Morning, and Sunnyside have produced commercial ore. In 1904, the Bulldog looked like a very promising mine, but it failed to make good. In 1905, the Sunnyside No. 1 was in the limelight, but it also failed to make the grade. In 1906, an outcrop on the Sunnyside No. 3 looked interesting. Subsequent work. on this claim produced $840,000, and at the same time ore which yielded $400,000 was mined from the Sunnyside No. 4. In 1908, the Nickel Plate ore-body entered a lean zone and, as the diamond drill failed to give satisfactory results, the Daly Estate, after making a profit of $1,151,000, sold the property to the Hedley Gold Mining Company, Limited, for $760,000, retaining, however, a large interest.

Jan 1, 1929

By R. Ghomashchi

Wear, fatigue and corrosion are the most widely encountered modes of failure in materials used in engineering applications, including aero-gas turbines. Although wear is distinctly classified as adhesive, abrasive, erosive, fretting and so on, there are usually more than one wear mechanism involved in the failure of components in service because there are many systems and materials variables active in materials wear that makes it more difficult to study. This is further complicated by the discrepancies between the results of laboratory tests and field data. The present investigation was set up to examine the wear characteristics of M50 and T1 high-speed steels at both room and elevated temperatures to draw a thorough understanding of the wear behavior of this class of high-speed steels. This article focuses on the mechanical and microstructural characterization of wear for T1 and M50 high-speed steels using a pin-on-disk wear machine.

Jan 1, 2005

By L. Becze, B. Pierre, S. Di Carlo, G. P. Demopoulos

From January to June 2007, the autoclave production at the Kidd Metallurgical Site was severely affected as a result of plugged discharge lines and extensive precipitation/crystallization of sulphates that caused massive scaling in different autoclave compartments. Work was performed at McGill University to understand the root causes. The crystallization of zinc and ferrous sulphate salts was investigated in terms of solubility measurements. Scale samples were characterized using chemical and mineralogical-spectroscopic analysis. In this paper, following a description of the Kidd zinc pressure leach operation, highlights from this investigation are presented and solutions used to overcome the problem are outlined.

Jan 1, 2008

By P. H. Riordon

ONE OF the major sources of the world's supply of asbestos lies in a belt of ultrabasic rocks stretching through the Eastern Townships of Quebec where chrysotile asbestos has been mined continuously since 1878. The productive portion of the belt extends from the town of Asbestos in Shipton town-ship northeastward some 60 miles to the eastern edge of Broughton town-ship. (See map). Twelve mines, currently treating an aggregate of over 60,000 tons of rock daily, produce more than one million tons of asbestos :annually. An equal number of mines are now dormant, having for the most part exhausted their reserves. It is evident from the past and present activity, in this belt that it can look forward to at least half a century or more of large scale production. The host rock to the asbestos de-posits is essentially a peridotite which originally contained I 0 to 15 per •cent pyroxene. The peridotite, associated with dunite, pyroxenite

Jan 1, 1962

By J. J. Brummer

"A reconnaissance geochemical survey, using the stream sediment technique, is described. The survey covered an area of about 400 square miles, in the Seal Lake area of central Labrador, underlain by basaltic flows, diabase and metadiabase sills, and sedimentary rocks. Previous work had indicated numerous small copper occurrences within the Seal Lake group of rocks. Stream sediments were tested for the readily extractable copper content and total heavy metal content. The results of the copper survey did not yield any new data on the distribution of copper mineralization. Results of the total heavy metal survey attracted attention to a remote portion of the area (Ten Mile Lake), which had hitherto been regarded as having no economic interest. The anomalous values found, suggested that zinc mineralization should occur in this region. Geological mapping indicated that the rocks exposed belonged to the Letitia Lake Group, which is older than the Seal Lake Group exposed to the east, which contains the copper mineralization of the district.Investigation of the area lead to the discovery of: (1) uneconomic lead-zinc mineralization; (2) radioactivity extending over a considerable area. Evaluation of the radioactive rocks led to the discovery of columbium-thorium mineralization in amphibolite and in diopside-actinolite schists along a contact with intrusive alkali syenite.Thus a geochemical survey, which was planned to evaluate a copper province, resulted in the discovery of lead-zinc-columbium-thorium mineralization."

Jan 1, 1960

By G. Gauvin

Life span of aluminum smelting electrolysis cells can reach up to 3000 days. During this period, cathode blocks go under various physical and chemical changes that could result in an increase of electrical resistivity. The increase may be due to carbon migration from the cast iron to the steel bars, gap evolution between the cathode block and the cast iron, cathode cracking, etc. This paper focuses however only on the collector steel bar electrical resistivity evolution. To reveal the main phenomena responsible for the electrical resistivity increase, chemical analysis, metallographic and electrical resistivity tests were conducted on two steels bars picked from two Hall-Héroult cells after autopsies. Cathode voltage drop and temperature were measured using electrically insulated internal probes and thermocouples on 16 samples from each steel bar. Electrical resistivity can reach up to 1.21µO-m for a steel bar aged 2505 days compare to 0.142µO-m for steel AISI 1008 at room temperature.

Jan 1, 2011

By J. D. Botsford

Westmin Resources Limited's H-W orebody on Vancouver Island is a copper/lead/zinc massive sulphide deposit that has been in production since 1985. The sulphur content of the ore averages 28% and in some stopes is as high as 53%. Several minor secondary sulphide dust explosions have occurred in development headings and cut and fill stopes, but as yet no known explosions have occurred in blasthole stopes. This pa:per reviews the history of sulphide dust explosions in the H-W Mine, factors contributing to the explosions and the preventative measures taken to control them.

May 11, 1988

By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By A. Bendada, P. Servais, X. P. Maldague, C. Ibarra-Castanedo, C. Mohr

Infrared (IR) thermography is a nondestructive, non-contact and non-intrusive technique that allows the fast inspection of large and complex structures with limited accessibility. Pulsed thermography is particularly interesting for the inspection of aerospace materials such as composites given that, after submitting the specimen surface to a thermal front, the most common types of subsurface discontinuities (e.g. porosity, de laminations, dis bonds, fiber breakage and inclusions) can be detected with an IR camera as regions showing abnormal temperature patterns. We present first the case of an aircraft door with water ingress and surface repairs on its honey comb structure. We also highlight the advantages and limitations of thermography for the inspection of aircraft composite parts, such as edge flaps, rotor blades and speed breaks. Finally, we expose some results from a Kevlar® non-planar specimen with Teflon® inclusions at different depths and locations.

Jan 1, 2006

By M. J. Gagnon

The agglomeration of particulate materials is used in many mineral processes to enhance the settling of the fine particles, Depending upon many physical and chemical parameters, the aggregates demonstrate specific density-size distributions, In this study, a fractal model of the agglomeration process is introduced, Based on reliable experimental data and on physical calculation, the model presented helps to envisage the initial formation of the micro-flocs, and to interpret the subsequent interactions between the aggregates in terms of either coagulation or flocculation, Data from different sources, materials and different agglomeration processes are analysed and compared in the light of the proposed model.

Jan 1, 2005

By P. Mageau-Béland, È. -M. Proulx, M. -C. Patoine

Over the past six decades, Hatch has helped several industrial processing facilities in debottlenecking their operations, allowing them to produce more with the same equipment, to reduce and even eliminate expenditure investments, or to increase the return value of their expansion projects. These successes result from the application of a proven analysis approach that can be applied to any industrial facility. A five-stage methodology is discussed and demonstrated with a specific example of a nickel concentrator optimization study. The first stage is an observation stage which allows to meet key actors at the plant, develop mutual understanding of problems, understand operating philosophy, and efficiently collect large amounts of operating and maintenance data. Following is a data compilation stage during which data is analyzed over a representative time period to identify parameters that significantly affect the production, to evaluate data reliability and to define the focus of the upcoming analysis. Quantitative metrics are defined using statistical tools such as pivot tables, histograms, percentiles and MDR (Maximum demonstrated production rate during 3 to 7 consecutive days). Then, the production bottlenecks are identified by a thorough analysis of the facility’s control philosophy, process throughput, equipment capacity, availability, downtime causes, and interaction between components of each circuit. Understanding the maintenance practices and frequency of planned shutdown is also critical to this analysis. Opportunities for improvement are identified in collaboration with the operation, maintenance and engineering teams, ranked as a function of their impact on the bottlenecks and prioritized. The final and most critical stage involves engagement with the plant stakeholders, namely the operators and the maintenance staff members, to present the results of the analysis and obtain their participation in the implementation of the solutions. The benefits of the case study translated into: 10% production capacity gain, improved maintenance planning and avoidance of several million dollars of investment.

Jan 1, 2016

By P. E. Walker, M. E. Reed, R. C. Sims, B. Snowdon, D. E. Fallas

An advanced Flash Furnace feed system is the key to improving furnace performance. Clyde-WorleyParsons has developed a revolutionary pulseless pneumatic injection feed system technology, capable of delivering a range of benefits to operators of Flash Furnaces. The solution was created by combining the pneumatic conveying and injection knowledge, expertise and technology of Clyde Materials Handling with WorleyParsons' flash furnace process and operating experience. Optimal furnace burner performance requires the feed material to be presented to the burner as a stable, pulseless and accurately controlled flow, distributed evenly around the burner tip circumference. These simple requirements appear obvious, but are extremely difficult to satisfy in industrial environments and are not achieved by conventional feed systems. Our analysis of existing operating furnaces has identified the link between pulses in concentrate feed rate caused by conventional drag chain conveyors and rapid fluctuations measured in the furnace pressure. These fluctuations occur at a timescale close to the reaction shaft residence time and lead to unwanted instability in the primary furnace reaction zone - the flame. Through the use of the solution created by Clyde-WorleyParsons, it is predicted that the much more accurate control of feed rates achieved can lead to substantial improvements in furnace output, increased oxygen efficiency and better control of the composition of furnace liquids, such as matte, blister or slag. All these improvements lead to significant increases in smelter output and efficiency, and deliver high economic value compared to the cost of the feed system. Clyde-WorleyParsons' solutions can be deployed on greenfield sites or retrofitted, and therefore, have the capability to improve feed control at both new and existing smelters. This paper will discuss the field test work undertaken to date, the impact of findings and the ongoing analysis of linkages between instabilities in the various components of conventional feed systems and furnace pressure stability.

Jan 1, 2007