Search Documents

By R. Rumpold, J. Antrekowitsch

"The continued increase of the automobile production leads to a higher platinum, palladium and rhodium (PGM) demand. Due to the high value of the PGMs the recycle of these metals from automotive catalysts is of special interest. Pyrometallurgical processes, which are only focused on the PGMs, represent the state of the art of automotive catalysts recovery. However, hydrometallurgical recycling processes offer additional recovery of other valuable metals and compounds. The method presented in this paper is based on a combination of hydrochloric acid and hydrogen peroxide to dissolve the valuable metal fraction which can be precipitated afterwards.INTRODUCTIONPlatinum and the corresponding metals from the PGM group, especially palladium and rhodium are well known as catalytic active materials. They support chemical reactions which are inhibited. This effect is used to decrease the amount of harmful compounds like hydrocarbons, carbon monoxide or nitrogen oxides in automotive exhaust gases. The generation of these toxic substances is based on incomplete combustion, which in turn is caused by non-ideal conditions in the combustion chamber. Catalytic converters minimize the harmful compounds by supporting the following Reactions 1 – 3 (Votsmeier et al., 2009).CO + ½ O2 ? CO2 (1)CnHm + (n + ¼ m) O2 ? n CO2 + ½ m H2O (2)2 NO + 2 CO ? N2 + 2 CO2 (3)Platinum and palladium are very effective for the oxidation (Reactions 1 and 2), while rhodium supports the decomposition of nitrogen oxides by carbon monoxide (Votsmeier et al., 2009). The classical three way catalyst was a platinum – rhodium combination with a Pt:Rh ratio of 5:1 (Hagelüken et al., 2005). Today the platinum, palladium and rhodium ratio is highly variable and strongly depends on the engine type as well as on the car producer. Diesel engines are operated with a super stoichiometric air addition in comparison to spark ignition systems. Therefore the exhaust gas composition and off gas temperature is different. Based on the high oxygen amount, diesel engines produce less carbon monoxide and hydrocarbons but more nitrogen oxide in contrast to gasoline engines. This leads to various requirements for the catalytic converters."

Jan 1, 2012

"Pilot plants for pressure hydrometallurgy represent special design and project execution challenges. Over the past twenty years, Zeton has designed and fabricated a variety of world-class pressure hydrometallurgical pilot-plant facilities for the nickel industry, and this paper discusses design considerations and strategies related to such projects. Project execution methods are also discussed, and guidance is given for the selection of materials of construction and for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical pilot equipment. The paper concludes with a discussion of the need for process similarity with future commercial operations and the realities of pilot-scale equipment.INTRODUCTION The process technology developer or owner and the designer/fabricator of a new pilot-plant facility are faced with some difficult technical choices even after the decision to build a dedicated plant has been taken. A pilot-plant project is usually on the critical path of a large commercial project involving investments many multiples greater than the capital cost of the pilot plant. Schedule savings in the design, manufacture, and commissioning of the pilot plant or in a rapid completion of the experimental program can be disproportionately beneficial to the overall development project. However, inappropriate shortcuts resulting in major oversights can be disproportionately problematic. A number of considerations and suggestions for both the project execution approach and the process engineering design of pressure hydrometallurgical pilot-plant facilities are presented as a guide for potential owners and operators of new pilot-plant equipment and facilities. These suggestions are particularly applicable to the nickel industry, where the majority of our firm’s prior hydrometallurgical experience was obtained. This paper is an update to an earlier publication (Martin, 2004), offering an opportunity for a new generation of metallurgists and engineers to learn the specialist requirements of pilot- and demonstration-scale plant design, which are key functions in the development and commercialization of new processes."

Jan 1, 2017

By M. A. Upham

"MINING is Canada's second largest basic industry, producing material with a gross value of 2.5 billion dollars, led only by agriculture with 2.9 billion dollars. It pro-vides employment, directly and in-directly, for three quarters of a million people. Since the Second War, the value of mineral production in Canada has tripled. Economists forecast that over the next 15 years its value will triple again. Canada is a basic and leading supplier of nickel, iron, copper, zinc, lead and uranium. It is also a major oil producer, leads the world in the production of asbestos and in five years will be the leading producer of potash, a basic constituent of fertilizer.It can be seen that Canada's wealth and economic progress lies in being a primary producer of economic minerals and in building secondary industries to manufacture finished products from these raw materials. Canada's future in the field of mineral production looks bright, with our resources just starting to be tapped. Outside of the large expanse of Soviet Russia, we are by far the world's most fertile mineral exploration area."

Jan 1, 1967

By Catherine N. Mulligan

Thickening of mine tailings is a relatively new concept for their sustainable management. Removal of water from the tailings to form a paste instead of slurry disposal decreases environmental and geotechnical concerns. As the use of these pastes is relatively new, their behaviour requires investigations such as liquefaction and seismic stability, freeze-thaw behaviour, consolidation and leachate characterization. Slurry density, ore type, particle size distribution, specific gravity and environmental conditions can all influence paste characteristics. In this paper, the effect of the above-mentioned parameters is examined. New developments in water removal, and additives (such as flocculating agents, cements, organics, fertilizers, etc) leading to low moisture content tailings are reviewed, and the potential for thickening to enable sustainable management of mine tailings is discussed with respect to storage volume requirement, use of virgin land, consolidation of the tailings, land use after decommissioning.

May 1, 2007

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By Wignall. T. K., J. De Geoffroy

Statistical models are fitted to the observed distributions of eighteen characteristics of the population of commercial porphyry deposits of North and South America. The statistical base required for the formulation of the statistical models includes 58 commercial porphyry-copper-molybdenum deposits of the Cordilleran Belt from which geological, geometric and economic data were collected. Predictive and composite models are derived from the statistical study to assist explorat10n. planning, engineering studies and fmanc1al analyses as required for the development of new porphyry deposits in the Cordilleran Belt.

Jan 1, 1973

"6.1. Mineralogical Techniques ApplicableTo the Platinum-Group Elements6.1.1. IntroductionThe named platinum-group minerals (PGM) usually occur as grains smaller than about 200 microns and, even when present as larger grains as in nuggets, these are often complex multimineral intergrowths. Therefore, the PGM must be examined by microscopic techniques and, because all named PGM are opaque, they are suitable for microscopic study by reflected light. Special techniques for concentrating PGM and preparing suitable polished sections are detailed in Chapter 5. Another characteristic of the PGM is that the majority have very high reflectance at 589 nm, i.e., over 450Jo, but they range from about 38 to 74%. In contrast, micro-indentation hardness has a wider range from - 60 to - 3,000 kg I mm, and the PGM range from brittle to malleable.The small grain-size of PGM imposes certain limitations, or complications, on the usual mineralogical determinative methods of reflectance, micro-indentation hardness and X-ray diffraction. In addition, certain combinations of elements in some PGM render electron-probe analyses difficult. The usefulness and shortcoming of these methods, as applied specifically to the PGM, are discussed in the following sections. These are not, however, meant to be exhaustive descriptions of the techniques, which are fully described in other texts.6.1.2. Micro-Indentation HardnessDetermination of the Vickers Hardness Number (VHN) is discussed in detail in recent publications, such as Bowie and Simpson (1977) and Craig and Vaughan (1981). In addition, the recommendations of the Commission on Ore Microscopy (COM) of the International Mineralogical Association (IMA) are given by Criddle (1980). The usual small grain-size of the PGM, however, precludes the widespread use of this technique and very few PGM have, in fact, had their VHN determined at the COM-recommended standard load of 100 gf (cf. Cabri, 1981b, in Chapter 7). Examination of VHN data reported in the literature reveals that the few PGM whose microindentation hardness has been measured have incomplete VHN data, measured with loads other than 100 gf (Chapter 7). The small grain-size may also result in unreliable VHN data because, even though the correct load may have been applied, a thin grain will give erroneous data due to the matrix, or the grain may even shatter or pop out of the section. On the other hand, micro-indentations may give useful qualitative diagnostic clues. Moncheite, for example, shows fractures near the indentation (Chapter 7, Plate 1). In other cases, intergrown PGM produce different-sized indentations: e.g., froodite-michenerite-gold in Cabri (1972); isoferroplatinumtulameenite in Cabri et al. (1973); michenerite-moncheite in Cabri and Laflamme (1976) and Chapter 7, Plate 1; altaitemichenerite- testibiopalladite in Hudson eta/. (1978) and Plate 1, Chapter 7."

Jan 1, 1979

By Bob A. Hamaguchi

The Trojan Tailings Pond at Highland Valley Copper developed in only 15 years from a biologically inactive water body into a productive lake with a well established aquatic ecosystem. This process was assisted by a few simple and inexpensive procedures including fertilization and introduction of essential organisms. The success at the Trojan Pond has encouraged the use of similar techniques in other water bodies on the mine site. This paper details: ??The history, water quality and thermal behavior of Trojan Tailings Pond ?Techniques used in fertilization; introduction of micro-flora (algae etc.), large aquatic plants, zooplankton and invertebrates ??Selection and sources of suitable transplant materials ??Rate and extent of vegetation establishment ??Biomass production ??Rates of organic sediment accumulation over tailings ??Bacterial activity in the sediments ??Improved water quality through the bioaccumulation of aqueous metals in plants and the subsequent bacterial binding or precipitation of that metal during decomposition in the tailings sediment. Robert A. Hamaguchi graduated with a Mining Diploma from the British Columbia Institute of Technology in 1971, followed with a Bachelor of Applied Science in Mineral Engineering from the University of British Columbia in 1975. Since graduation, he has worked for numerous open pit mining operations throughout British Columbia. In 1991, he joined Highland Valley Copper working as an Environmental Engineer responsible for government liaison, reclamation, decommissioning and other environmental duties. Heather M. Larratt graduated from the University of Calgary in 1978 with a B.Sc. in Environmental Biology (First Class Honors). She has provided drinking water management and reservoir design for numerous cities and irrigation districts in British Columbia for 20 years. Heather has also worked for 12 years in reclamation of mine water, including passive SRB water treatment systems. Mark R. Freberg joined Highland Valley Copper in 1991 after working at number of mining operations in British Columbia and the Northwest Territories. He graduated in 1979 with a Bachelor of Applied Science degree in Mineral Engineering from the University of British Columbia.

May 1, 2001

By B. J. Walsh

ABSTRACT Segregation of sphalerite minerals in zinc concentrates into christophite, marmatite and ordinary sphalerite by means of magnetic fractionation is investigated. A Frantz ferromagnetic filter, 1.2 amp., and a Dings magnet, 0.3 amp., is used to fractionate seven zinc concentrates produced in the Province of Quebec. The Dings magnetic product contains the pyrrhotite, and the sphalerite as christophite. The Frantz magnetic product contains sphalerite as marmatite, while the Frantz nonmagnetic product contains ordinary sphalerite. The results indicate that the magnetic susceptibility of sphalerite increases with increasing isomorphous iron content and that a satisfactory separation into christophite, marmaite, and ordinary sphalerite may be accomplished by magnetic fractionation. INTRODUCTION SPHALERITE, the chief ore of zinc, is almost never pure zinc sulphide. Iron is almost always present isomorphously replacing an ?equivalent amount of zinc. What may be referred to as &apos;ordinary&apos; sphalerite contains up to 10 per cent iron. More highly ferriferous varieties, with 10 to 26 per cent or more iron, have been named marmatite .and christophite.

Jan 1, 1951

By B. R. Hart, S. S. Dimov, J. Fournier

Carbonaceous matter (c-matter) in sulphide ores can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob, gold from a cyanide leach solution. This paper describes a standardized procedure for characterization of c-matter in an ore sample providing detailed information on its composition, maturity and preg-robbing capacity. The procedure utilizes the following complementary analytical techniques in conjunction with several chemical tests and assays: SEM/EDX Raman spectroscopy and TOF-SIMS. Results of the test can be used as a predictive tool to estimate the impact the c-matter will have on the gold recovery process. A comparison between predicted preg-robbing behaviour and cyanidation test results are presented.

Jan 1, 2011

By H. R. Stoger

"In 1994 world trade grew by 9%, the fastest annual increase since 1976. Dry cargo shipping rates are at an all time high.Panamax size bulk carriers are receiving19 000 US dollars per day for trans Atlantic round trip voyages. This is good news for the ship owners but not such good news for the industrial users of ocean shipping.The main emphasis of this paper will be on bulk carriers, the charter market and what industrial companies can do to reduce their costs of ocean transportation which is critical to Canadian exporters. Let us look at the charter market in general.Bulk carriers come in four main sizes:1.The Capesize bulk carriers of 110 000 to160 000 tons that are primarily used to transport iron ore and coal;2.the Panamax bulk carriers of about 70 000tons dwt. This is the largest size (with a beam of 105 ft) that can transit the Panama Canal.3.the Handymax bulk carriers of 40/45 000tons dwt; and4.the Handysize bulk carriers of 20/35 000tons dwt.The handysize vessels are usually craned or geared and carry a variety of bulk cargoes including steel. Ship sizes have increased over the years and the mining industry now uses primarily capesize or Panamax bulk carriers.International chartering is conducted through an international network of shipbrokers. There is usually one broker representing the ship owner and another broker who represents the charterer. The major chartering centers are London and New York but a great deal of chartering activity is conducted in regional markets such as Hongkong, Oslo, Montreal and Hamburg.The Biffex Index or Baltic Freight Index is a good measure of dry bulk freight rates. The Biffex is composed of ten major routes. In May1995, the Biffex was at 2310 points. A year earlier it was at 1354, an increase of about 56%."

Jan 1, 1996

By Pierre Gauthier

Is the hydrogen economy of the future just another fish story? Absolutely not! There have been many changes affecting the energy equation over the last 10 years and conditions have changed. In this presentation, we will examine the reasons why, in the very near future, hydrogen production and distribution will be increasingly visible on many industries? radar screens.

May 1, 2007

By H. L. Martin

A joint federal-provincial approach in gathering basic information from industry on mine production, concentrator operations and ore reserves, initiated during 1978, is a major step toward the goal of achieving better government-industry communication through a common data base. Information from questionnaires sent out by provincial governments is shared with the federal government; correct interpretation is ensured by mine visits conducted jointly by provincial and federal representatives. Initial focus is on nonferrous metal mines. The federal Department of Energy, Mines and Resources (EMR) is responsible for a national analysis that is aimed at the early detection of worrisome developments-and their reasons-in the flow from resources to reserves and from reserves to supply of these metals. The heart of the national analysis is the annual construction of a "monitoring curve", showing each metal&apos;s aggregated mine production as it would decrease over time if no new reserves and production capacity were to be added from the year of analysis. For a given metal, a comparison of monitoring curves from year to year can reveal early signs of supply stagnation. In anyone year, a monitoring curve in conjunction with foreseen needs for Canadian mine output will show the production gap that would have to be filled from reserves and production capacity yet to be developed. The production gaps for copper, nickel, zinc and lead, the four leading base metals mined in Canada, are shown for the 20-year period ahead, in the context of production achieved during the past 20 years. It is shown that reserve levels commensurate with likely future production levels would require that average annual reserve additions during 1978-98 exceed the average annual additions during the preceding 20 years. Reserve levels of all four metals have declined in recent years. A review of significant discoveries in the last five years suggests that this fall in reserves is not the result of a lack of exploration successes, but of stagnation in development for various economic reasons.

Jan 1, 1979

The Anglo Platinum Mogalakwena North concentrator was one of the first three hard rock mineral processing applications to utilise a HPGR circuit in preference to a SAG milling circuit. This was driven by the extreme competence of the ore that had given rise to throughput issues on the original South Plant. Despite more than adequate capacity and performance of the individual comminution units, the circuit has struggled to obtain full design capacity. A thorough review of the integrated performance of the circuit revealed a wide range of bottlenecks and underutilised parts of the circuit arising from design issues. Interestingly, the major opportunities lie in materials handling issues and mismatch of loads about the circuit. This paper presents the high-level outcomes and the associated opportunities, and is pertinent to all HPGR circuit designs.

Jan 1, 2012

By A. Galibois, H. Monette, J. L. Collins

This paper deals with the problem of caving, which occurs in varying degrees in blast holes before loading. It is shown that the distribution of the amount of caving in materials may be described by a gamma density function. A decision model to determine the optimal depth of over-drilling 'in order to minimize the expected additional cost per hole is described. Two different policies are discussed. In addition, charts which permit the mine operator to realize significant savings have been drawn for different actual situations.

Jan 1, 1971

By C. -K. Fang

"Aging effect on the wear resistance of alumina particulate-reinforced 6061 aluminum matrix composites with a block-on-ring wear tester has been investigated. Specimens with various Al2O3 volume fractions of 0%, 10% and 20% were employed in this work. Experimental results indicated that over-aged monolithic 6061 Al had the best wear resistance, as compared with under-aged and peak-aged conditions. For the composite containing 10% Al2O3, over-aging and peak-aging resulted in similar wear resistance, which was higher than that for underaging conditions. For the composite containing a high volume fraction (20%) of Al2O3, the wear resistance reduced with the increase in aging time. Although longer aging time was favourable to the wear resistance of monolithic 6061 Al, it was detrimental to that for the Al2O3/6061 Al composite with high volume fraction of particles. IntroductionMetal-matrix composites (MMCs) have received attention in many engineering applications because of the demands for high specific strength (strength-to-weight ratio) and specific stiffness, good high temperature capabilities and wear resistance. The manufacturing processes of fiber-, whisker-, and particulate-reinforced MMCs have been well developed (Hosking et al., 1982). Because of the reduction in fabrication cost, the applications of MMCs have been widely extended to light weight-bearing sleeves, calipers, automobile parts (brake rotors, drive shafts, connecting rods, piston rings, and cylinder liners), sporting goods, aerospace components, tanks (wheels, speed brakes, and track shoes) and other industrial applications. Among the three types of metal matrix composites, particulate-reinforced MMCs are promising because of their homogeneous and isotropic material properties and low cost. Additionally, they can be formed using conventional metal processing techniques."

Jan 1, 2003

By Horace Freeman

"IN THE writer's opinion, the most important industrial re-search problems in Canada concern development of technology for the treatment and commercial utilization of the recent discoveries of v.ast quantities of easily concentrated iron ores in both eastern and western Canada. They exist in both magnetite and hematite forms. The subject is doubly important because of the lack of metallurgical coking coal in Canada. Methods for utilizing our lower grade eastern and western coals for reduction purposes must be developed. We are fortunate in our supplies of oil and gas, which can supply the heat requirements for processing or for thermal electric plants, which are now competitive with hydro-electric plants in the industrial areas. These are among the reasons which have prompted the writer to continue the development of the co-current rotary kiln direct-reduction process outlined •in his report to this Institute at the 1956 Annual Meeting ( 1) in the face of the scepticism which has surrounded the numerous costly failures in 'sponge' or 'direct' iron production. The work involved in bringing the concentrating ores of Canada to the metallic state involves, firstly, concentration of the ores; secondly, preparing the concentrates for reduction; thirdly, reduction of the 'reconstructed' ore; and finally the steel making process. These briefly will be dealt with in order, giving emphasis to the most important of these steps, the reduction process which is the main subject of this paper."

Jan 1, 1959

By Linlin Tong, Xiangling Song, Guobao Chen, Zhenan Jin, Hongying Yang

Biooxidation of a high arsenic-bearing refractory gold ore was investigated to determine the arsenic removal efficiency by the cultured bacteria and to examine the effect of biological pretreatment on subsequent gold cyanidation. The biooxidation pretreatment process utilizes the ability of adapted acidophilic bacteria to oxidize pyrite and arsenopyrite and release the encapsulated gold. The released gold can be efficiently extracted by the subsequent cyanidation process. The biooxidation experiments were conducted with cultured bacteria using various sizes of agitation tanks. Leaching results showed that over 96.26 % arsenic extraction could be obtained from this ore after 6 days of bioleaching with continuous stirred tank reactor (CSTR). Gold extraction during the cyanidation process was increased from 29.35% to 96.71% after biological pretreatment. The content of arsenic in the biooxidation residue was reduced to below 0.3%. The transformation process of As was considered as [AsS]2- ? As (?) ? As (?) during the biological pretreatment.

Jan 1, 2014

By B. Haneman, J. A. Gorst, W. Slabbert

"The Bayer process involves the digestion of bauxite in caustic liquors at high temperature and pressure. Typically the digestion section of the plant involves the heating of liquors up to the digestion temperature followed by flashing of the digestion product to atmospheric pressure with the flashed steam used to pre-heat the incoming cold slurry. Despite the heat recovery, the digestion process is a high consumer of energy. The application of tube digestion technology in such plants has resulted in significant improvements in refinery energy efficiency with associated benefits of process simplification and refinery flow sheet capital cost reduction. This paper reviews the potential application of this technology to other metals within the non-ferrous industry.THE BAYER PROCESSA typical Bayer flow sheet is shown in Figure 1. The raw feed material bauxite (containing aluminium hydroxide as gibbsite Al(OH)3 and boehmite AlO(OH)) is digested in caustic liquors (caustic soda is the solvent) at high temperature and pressure. This process extracts the alumina and silica and any carbon present on the ore. The slurry is then flashed down to atmospheric condition allowing for heat recovery from the flashed vapour and producing slurry supersaturated in alumina.Following the digestion process the mud is removed via thickening and then pressure filtration to remove fine particulate and produce a clarified liquor with dissolved alumina in solution. The resulting pregnant liquor is then cooled allowing the alumina in solution to precipitate as aluminium trihydrate Al(OH)3. The precipitated hydrate is then filtered and washed and classified into fine and coarse fractions. The fine material is returned to the precipitation process as seed while the coarse fraction is calcined at high temperature to produce alumina. The filtrate from the filtration process (spent liquor) is then heated by the incoming pregnant liquor before being fed to an evaporation process which produced the strong caustic liquor required in the digestion process. Finally, the mud from the thickening process is washed to recover caustic and then fed to tailings ponds. The washer overflow is then mixed with the digester product to increase super-saturation."

Jan 1, 2012

By Tom Demorest

SMART is an association of mining companies that meet regularly to coordinate the technology development needed by the mining industry. Since 1995, the member companies and institutions have directed research and influenced the manufacturers and suppliers to improve surface mining technology and services. SMART actively supports learning seminars, collaborative research projects, and user groups. Members of SMART include some of the major surface mining companies in North America and Australia. These companies have recognized the value that collaboration can bring to the needs of individual organizations as well as the global mining industry.

May 1, 2009