Search Documents

By Carlos F. Perucca, Maria Virginia Ramírez A.

"Chile based SQM S.A., exploits potassium chloride rich salts at the Salar de Atacama, in northern Chile. The process includes the solar evaporation of natural brines existing in the Salar salt bed, followed by conventional flotation to recover Muriate of Potash (MOP) for fertilizer use.This paper describes a structured method developed to aid in understanding the metallurgical response of the solar evaporated salts to conventional flotation. The method uses classical metallurgical data analysis combined with laboratory and plant-scale testing, and rudimentary mineralogical studies.As a result of the study, several changes were made to the flotation circuit which produced an operation that is much more consistent and easier to control, and has an increased recovery. An optimized circuit, currently being financially evaluated, has also been conceptually designed based on the findings of this work.INTRODUCTIONSQM S.A. is the world’s largest producer and distributor of specialty fertilizers, iodine, lithium, as well as a wide array of industrial and specialty chemicals. SQM is a public corporation whose shares are traded in the Santiago and the New York Stock Exchanges.SQM S.A. exploits the mineral rights at the Salar de Atacama in northern Chile. Its production processes involve the solar evaporation of natural brines existing in the Salar salt bed, aimed at the recovery of Potassium, Lithium and Boron compounds."

Jan 1, 2004

By C. V. Umipig, G. G. Hutalle, E. E. Israel

TVI Resource Development (Phils) Inc. Canatuan mine is a polymetallic ore deposit located in the Province of Zamboanga del Norte on the island of Mindanao in the Philippines. The deposit consisted of an oxidized capping of gossan overlying a Besshi type volcanogenic massive sulphide lens which is near surface and flat lying. Construction and development of a sulphide processing plant began in early 2007 and commissioned in November 2008. During the initial stages of sulphide operation, high copper (Cu)-low zinc (Zn) ore was fed to the plant. Marketable copper concentrate at 91-95% recovery was produced utilizing a high-pH bulk sulphide rougher flotation and 2 cleaning stages. Because of increased levels of Zn of the ore body, a Cu/Zn separation circuit was initiated in early 2010 following an intensive laboratory test work program. This Cu/Zn separation circuit was necessitated because of the copper ion pre-activation of the sphalerite that lead to the zinc being readily recovered to the copper rougher concentrate. In-situ activation of zinc (in the pit and stockpiles) was caused by the leaching of secondary copper minerals in the ore (particularly from the dominant copper species, chalcocite and covellite). This problem required the development of metallurgically complex and intensive reagent regime to effectively depress the activated sphalerite. As well, the immediate reactivation of zinc after it has been depressed, at the onset of Cu/Zn separation flotation, added additional metallurgical complexity to the process. Subsequent to the Cu/Zn separation circuit, an unconventional, yet proven effective, simultaneous cyanide detoxification-zinc flotation circuit was set-up to recover the zinc. Laboratory test work results realized Cu-Zn recovery differential from a Cu/Zn separation circuit of over 40-45%. This performance has been achieved in the plant, at 72% Cu overall recovery. With the gradual improvements on-going with zinc circuit capacity and effective zinc separation being achieved, zinc recovery has currently reached 40%.

Jan 1, 2012

By John D. Godfrey

Geological mapping on the Canadian Shield in northeastern Alberta outlined severalgranitoid rock massespotentially suitable as building stone. A particularly attractive prospect, the Chipewyan Red Granite, was subjected to an aerial survey and ground check. The petrologic and fracture characteristics critical for quarrying and use as a building stone were assessed in the course of detailed mapping at two of the most favourable sites. The extension of good rock was tested to shallow depths at one site by shallow diamond-drill coring. , The Chipewyan Red Granite displays a warm red colour, medium grain size and fairly massive texture, and takes a good polish. Deleterious geologic features studied in outcrop and subjected to structural analysis included regular joint systems, quartz veins, pegmatite dykes, basic shear zones and fault zones. Many of these key geologic features are systematic and hence predictable for stone quarrying purposes; other features, such as irregular fracelM tures, are non-systematic and arefar less predictable. The megascopic structural features studied show similar preferred orientations which appear to be collectively related to the tectonic history.

Jan 1, 1979

By Frank van der Meer, Jorge Portocarrero, Alexandra Gruendken

"The number of High Pressure Grinding Rolls (“HPGRs”, also called Roller Press) installations instead of tertiary crushers is rapidly increasing. The technology has been largely accepted in the minerals industry and benefits, such as superior energy efficiency and a lower overall operating cost compared to alternative technologies, have been demonstrated at a number of operations throughout the world.This paper focuses on coarse hard ore operations and reviews the successful installation of the first Roller Press installed instead of a tertiary crusher at the Los Colorados Plant of CMH (Chile) in 1998. It details the experience obtained over the past ten years of operation from commissioning to the present day. It highlights examples of further developments made in the design to improve machine maintainability and availability as well as wear life of the grinding surfaces.A second focus lies on procedures to derive from small scale testing material properties such as wear life, flake formation and strength and their application to industrial size machines to optimize circuit design, especially when Roller Presses are used in closed circuit with screening.INTRODUCTIONRoller Presses (also known as HPGR, High Pressure Grinding Rolls) are considered today state of the art for the preparation of pellet feed. They are also gaining wide acceptance in coarse ore operations. One of the first successful operations in which a roller press was used to replace a conventional tertiary and quaternary crusher is the Los Colorados plant of CMH in Chile.When the Roller Press at Los Colorados was commissioned in 1988, there were 169 Humboldt Wedag roller presses in operation throughout the world. Of these, 14 were installed in the minerals industry. However, these were installed mainly for grinding pellet feed to increase the Blaine value. Up to that time, only three KHD roller presses had been applied for crushing coarse ore in specialized circuits. Moreover, the installation at Los Colorados was the first Roller Press ever to replace a conventional tertiary and quaternary crusher in a hard ore application."

Jan 1, 2009

By F. Ford, J. Dong

"Laboratory and miniplant testwork was carried out to reject uranium from an Iron Oxide Copper Gold (IOCG) deposit that contains an average of 60-70 ppm uranium with high variability. The dominate copper bearing mineral is chalcopyrite with minor bornite and trace covellite. The main gangue minerals are iron-rich chlorite, quartz and magnetite. The main uranium-containing mineral is uraninite (UO2). Downstream processes require the maximum uranium level of no more than 80 ppm in final copper concentrate.Mineralogical examination reveals that uraninite particles are finely disseminated with grain size of less than a few microns in the deposit requiring fine regrind in order to liberate uraninite from chalcopyrite particles. A lab flowsheet was developed to include ultrafine regrind of the rougher concentrate to the particle size of 80% passing 11-13 µm with up to four stages of recleaning in flotation columns. Finer regrind to 80% passing 5-6 µm may continue to improve liberation but does not decrease uranium level in the final concentrate. In each of the successive recleaning stages by flotation column after fine regrind, uraninite is rejected into the column tailings, with the final copper gold concentrate containing less than 70 ppm uranium from a feed containing 83 ppm uranium. The conceptual flowsheet was further tested in an integrated, continuous miniplant showing average 94% copper recovery with average 74 ppm uranium. The uraninite particles that report to the final concentrate are either locked with chalcopyrite or entrained as liberated particles of less than 5 µm in size.IntroductionIron Oxide Copper Gold (IOCG) deposits are copper and gold ores hosted within a large body of iron oxide and are significant ore deposits for copper and gold (Williams, et al., 2005). These deposits can also contain economic levels of other metals such as uranium and rare earth elements. The known sizes of IOCG deposits range from 10 to 4,000 million tonnes with grade of 0.2-5% copper and 0.1-3 g/t gold. One of the greatest IOCG deposits is Olympic Dam in South Australia. It is the fourth largest copper deposit and the largest uranium deposit in the world. Gold and silver in the deposit also contribute significantly to the total revenue."

Jan 1, 2017

By Niklas Willemsen

Introduction to SVCs ? SVC = Static var Compensator ? Dynamic step-less control of reactive power without switching of passive components: ? Voltage control/stabilization ? Harmonics- and flicker mitigation ? Dip mitigation ? Main components: ? TCR (Thyristor Controlled Reactor) ? Tuned harmonic filters ? Control- and cooling systems ? Typical applications: ? Mine hoists ? Large mining complexes ? EAF, SAF, rolling mills, wind/solar farms etc..

Aug 1, 2013

By J. B. Boisvert, P. Oshust

A significant source of uncertainty in the diamond resource contained in kimberlite pipes is the volume of the pipes. Often the material within a pipe will be mined as ore, leaving the actual geometry of the pipe as a significant source of uncertainty. It is desirable to use stochastic techniques, rather than deterministic methods, to model pipe geometry because stochastic techniques generate multiple realizations that are reproducible and can be used to assess uncertainty in pipe geometry. The proposed methodology uses sequential Gaussian simulation of pierce point locations interpreted from drillholes through a kimberlite pipe. Kimberlite pipes are approximately cylindrical in shape; therefore, the data are transformed to cylindrical coordinates to facilitate the simulation of pipe geometry. Rather than using xyz coordinates to define the pierce points, z, ??and pipe radius are used. The radius variable can be simulated in z-??space to generate multiple realizations of pipe volume. Uncertainty in the volume of the pipe can then be evaluated. This methodology is demonstrated with a kimberlite pipe at BHP Billiton’s Ekati diamond mine.

Jan 1, 2008

By Dale C. H. Nevison

One of the most intensive of material rivalries is the confrontation between zinc die castings and plastic injection moldings. Pressed hard by the plastics industry, zinc die casters are learning how to make parts with less material yet without sacrificing quality. The key to this new trend is the technique of Thin Wall die casting. The obvious benefits of Thin Wall are lighter weight and lower cost. Again, obviously, these are the very selling points that put plastics into many appliance and automotive parts formerly made of zinc. One of the factors that has been most conducive to the outstanding growth of plastics has been the increasingly prevalent concept that "adequate" properties are sufficient, especially if there are cost advantages. Most of modern design today is oriented around the reasonable life of a product, rather than indefinitely extended life. This is simply an acknowledgment of the existence of a design environment that pervades many areas, reflecting the life-cyclic desire for change. Too often, so-called "weight-saving" materials end up being very costly - not only in production, but in durability and dependability. Change for the sake of change usually doesn't effect a change for the better. In the majority of cases, the best bet is to design in traditional materials and minimize the material needed, while maximizing the efficiency of the production process. Component prices of products to be produced from either plastics or zinc must be studied in detail to determine which material will produce the lowest cost of manufacture. It is not uncommon for two parts, similar in appearance at a casual look, to have a considerable difference in energy requirements and production costs. Detailed cost estimates of the advantages of each material should therefore be prepared for zinc and plastic parts before the final design and material selection decisions are made.

Jan 1, 1978

By Konstantinos Modis

According to recently established theoretical analysis and under certain conditions, a critical sampling density can be determined for an earth-related space-distributed natural variable. Sampling above this critical limit adds little to the mapping results. The objective of this paper is the application of the above theory to the Sesklo clay quarry in Greece, where Heracles General Cement Company had conducted a sampling campaign to estimate its reserves. The structural analysis of Al2O3 values generated a variogram model, from which the critical sampling density was identified. This critical number was by far lower than the existing sampling density. Clay reserves were then estimated using geostatistics and inverse distance squares in different data schemes with variable densities. The results of the comparisons between the various models revealed that, when the sampling density was greater than its critical value, geostatistics and deterministic interpolation gave similar estimations, which is also in agreement to the theory. The optimal sampling grid finally proposed here, will result to significant cost savings in the next drilling program which is now in plan by the company.

Oct 1, 2009

By Chen Xia, G. Deschenes, Wan-Tai Yen

"Ammonium thiosulphate is a potential replacement for the cyanide in gold leaching. However, the high reagent consumption hinders its practical applications. In order to reduce the thiosulphate consumption, chemical additives were used. The gold leaching tests were conducted on a sulphide copper-bearing gold ore with 0.3M thiosulphate, 0.03M copper sulphate and 3M ammonium hydroxide solution at 44% solids and pH 10.2. Sulphate, sulphite, amino acid and chelating agents were initially used as additives. It was found that chelating agents (EDTA and NTA) could reduce the thiosulphate consumption from 30 kg/t to 17.8 kg/t with some increase of gold extraction. The improvement from other additives was not significant. Other approaches were also attempted to reduce thiosulphate consumption with some success. The thiosulphate consumption could be reduced to about 17 kg/t by reducing copper sulphate concentration fiom 0.03M to 0.0015M; adding 0.04M of EDTA; replacing copper sulphate with 0.001M of nickel sulphate. The increase of pulp density fkom 44% to 60% solids could reduce the thiosulphate consumption to 17 kg/t as well. Limiting the dissolved oxygen content by sparging nitrogen reduced the thiosulphate consumption further to 10 kg/t. It could be concluded that the regulations of copper and oxygen supply in the lixiviant were the keys to reduce the reagent consumption.INTRODUCTIONCyanidation, as the predominant gold leaching method, has been used in mining industry for more than a century. The low reagent requirement and the high performance are the reasons for its great success. However, cyanidation cannot deal with ores containing large amount of copper, nickel, arsenic and zinc minerals. This type of ore may consume more reagents and result in a poor gold extraction. On the other hand, the carbonaceous materials may preg-rob the gold from pregnant solution and make cyanidation a problem leaching method. Further more, the high toxicity of cyanide represents another challenge to modern gold mines. In the beginning of the year 2000, an environmental disaster caused by an accidental spill in Yugoslavia was broadcasted world-widely (Gurevitch 2000). Gold mine operators are facing higher social pressures and increasing costs on environmental protections. The usage of cyanide in mining industry has been banned in some countries and locations such as Czech Republic, Japan, Turkey, California, Colorado, Wisconsin and Montana States. Thus, a non-cyanide lixiviant is required."

Jan 1, 2002

By Helen Francis

Over the last decade, lower ore grades and deeper mine environments have demanded that mining companies develop new technologies (tools and processes) to ensure a mine?s economic sustainability. At Inco Ltd., this demand has lead to the focus of technological development within the area of automation. Delineation (Drilling and Interpretation) is a key step in the determination of ore grade and location and therefore was chosen as a priority area for enhancement through automation. Focusing on the tools (the diamond drill) automation, significant benefits have been consistently achieved in terms of productivity, process efficiency, operational safety, cost reduction, component life cycles and machine reliability. It is suggested that optimum benefits have yet to be achieved, and will not be achieved until the human aspects of automation have been properly addressed. Since project inception, the human aspects of automation were recognized as critical to the success of the diamond drill automation project. However, it was only upon the installation of the Automated Diamond Drill in the field and its continued use on a daily basis that this issue received due attention. The human aspects of automation can be broadly addressed as economic, physical and psychological. This paper, with examples from the field, will discuss the human aspects of automation in each of these areas. The paper will draw from observations and experiences acquired throughout this project and recommend implementation strategies that should be utilized in future automation projects to enhance both the acceptance of automation and the success of the automated process itself.

May 1, 2002

Increasing depths and mechanization of underground mines have led to the production of large amounts of gaseous and particulate contaminants. Over 100 000 lives have been lost due to methane gas and dust explosions in coal mine workings in both the United States and Canada since 1900. There is, therefore, the need to constantly assess and evaluate the performance of existing mine ventilation systems to maintain safe and acceptable mine environmental conditions. This paper advances research initiatives in the control of methane gas in underground mine environments. It uses the results of continuous monitoring of methane gas concentrations conducted in selected coal mines in North America to assess the effectiveness of existing auxiliary ventilation systems to control methane gas concentrations. The results show that the average quantities of fresh air required to dilute, disperse and remove methane gas concentrations within set levels of one minute varied from 5.43 m3/sec. to 27.97 m3/sec. in the development headings. The average dilution times in the headings studied were less than eight minutes. The calculated dilution efficiencies of the auxiliary ventilation systems in the headings varied from 12% to 139%. These efficiencies ranged from poor to excellent. This implies that the auxiliary ventilation systems were capable of controlling the methane gas concentrations below statutory levels but may not be able to cope with large and unusual methane gas concentrations in the headings. This study is significant in the control of methane gas and coal dust explosions in coal mines.

Sep 1, 2001

At the end of a century of mining education in South Africa, it is appropriate to reflect on the past, take stock of the present and ponder the future of mining education. While it is likely that changes in the mining industry will generate an increased demand for mining graduates, the number of suitably qualified applicants to study mining is worryingly small. While good progress has been made in unifying the educational system that previously provided schooling on a racially separate basis, it appears that a decade or more will be required to raise competency levels in mathematics, science and English, and this paper describes the process as it affects mining engineering programs. It also describes the initiatives currently being undertaken by the University of the Witwatersrand and the mining industry to ensure that the South African industry receives an adequate flow of well-qualified mining graduates, despite more than 70% of the intake coming from severely disadvantaged educational backgrounds.

Jan 1, 1999

By Son Hye Jin

Abstract ? KHNP is participating in the construction of Nuclear Power Plant both in Korea and UAE. ? We want to improve our construction project management process. ? So we are now developing the process model on nuclear power plant construction management. ? For the effective adoption of this process, we are planning to develop IT system. ? For the first step, we were established the Information Strategy Plan

Aug 1, 2013

By G. M. Carrie

Introduction The subject of basic refractories is daily becoming of increased importance in metallurgical processes, and there is a constantly growing necessity for the development of better materials. This fact, together with the realization that Canada possesses one of the best sources of such refractories in the British Empire, if not in the world, made it appear? advisable that the subject be presented to the Empire Mining and Metallurgical Congress at the 1927 meeting. Having been in close touch with developments in the Canadian product during the past five years, G. M. Carrie was requested to prepare such a paper. The Canadian producers of magnesia refractories have succeeded in developing the product to a place where it has almost entirely displaced imported materials from the Canadian market. These developments were made possible by a close study of the methods of preparation of the material, and by an exceedingly careful control of the manufacturing process so as to obtain a thorough blending of the different constituents with the resultant uniformity of composition. This point is very important to the metallurgist, as un-uniform materials are a potent cause of difficulties in most manufacturing processes and the constant trend is towards their elimination. The temperature at which the Canadian material is burned ensures high specific gravity and thorough shrinkage. The grain size of the product is so controlled that the voids are only just sufficient to allow of proper bonding, thus making possible a dense, hard bottom affording high resistance to erosion and shock. Careful proportioning of the constituent elements absolutely prevents disintegration.

Jan 1, 1927

By David Stephenson, Hugo Granados, Steven Klohn

"HudBay’s Constancia project is a copper molybdenum concentrator located in southern Peru. In 2010 Ausenco was contracted to perform a feasibility study optimization review which resulted in an improved design with significantly increased throughput capacity at a minimal increase in capital cost. Construction began in 2012 with commercial operation commencing in May 2015. This paper outlines the process plant design as well as describing the plant’s major equipment selections, start-up and early operations experiences.IntroductionHudBay Mineral’s Constancia project is located at 4200 meters above sea level (masl) in southern Peru, approximately 630 km south-east of Lima, Peru. The property can be accessed by road from Cusco, Peru, (approximately 110 km to the north), or from Arequipa, Peru (approximately 215 km to the south). Matarani, accessed via Arequipa, is the closest port.Constancia is located within the Yauri-Andahuaylas metallogenic belt. The region contains several large copper-gold-molybdenum porphyry deposits such as Antapaccay (by Glencore) and Los Chancas (by Grupo Mexico), and copper skarn deposits such as Tintaya (by Glencore) and Las Bambas (by MMG). Constancia’s ore reserves contain copper and molybdenum with trace amounts of gold and silver.Ore is mined by an open-pit operation. The process plant recovers copper and molybdenum concentrates, storing tailings in a conventional tailings management facility. Infrastructure at the site includes a grid power supply (via a 70 km overhead transmission line from Tintaya), water supply, workshops and an accommodation camp. Mine life is 22 years.Site construction works began in 2012 with first copper concentrate produced in late 2014. The project was executed for approximately 1.75B$USD.Ausenco’s design approach focussed on developing a capital efficient copper molybdenum concentrator. This paper outlines key features incorporated in the concentrator design, plant layout and equipment selection, as well as start-up experiences and early operational results."

Jan 1, 2016

By R. England

"This paper describes the objectives and design parameters for the operation of a computerized In-The-Hole (I. T.H.) Drill. The principal objective is to add computer control to an Inco 00-60 I. T.H. (CMS-CD-90) drill in order to drill holes with greater accuracy. The computer provides control of the angle of the hole by maintaining the orientation of the drill head, and optimizes the straightness of the hole by maintaining a constant force on the drill bit.The second objective is to provide the greatest degree of operational automation, so the objective outlined above can be accomplished with a minimum of operator intervention.In order to provide full operational automation it was necessary to also provide the capability for the computer to add and remove drill rods. To accomplish this, a rod-handling mechanism consisting of a rod storage rack and rod manipulator arms was used.IntroductionMining machinery that lacks automatic control has been found to show a high degree of variation in work output and performance quality when operated by different personnel. Differences in operator attitude, judgment, and skill are reflected directly by production statistics. The addition of automated control has the potential for considerable improvement in machine life and performance. Even with a more acceptable mine environment and much safer conditions than ever before, situations still exist where it is preferable to remove personnel for reasons of safety as well as productivity. Typical advantages of such situations are automated skip loading and hoisting, and the use of remote control load-haul-dump units exposed to open stopes.Other cases arise where heavy work is required under conditions where lighting is poor, floors are slippery, noise levels are high and dust and oil mist exist in the atmosphere. I.T.H. drilling is carried out under such conditions and is one operation where automation can easily be justified."

Jan 1, 1987

By D. E. Calisaya, É. Poulin, A. Desbiens, R. del Villar, A. Riquelme

"A 15 cm diameter by 732 cm height, fully automated pilot column was installed in the Agnico-Eagle’s Laronde concentrator (Québec), for evaluating the performance of newly developed sensors and advanced process control algorithms. For eventual comparison purposes, the pilot column is continuously fed with the same slurry feeding the copper-circuit third cleaner column. It is equipped with electrical conductivity-based sensors for estimating the three variables used in the multi-variable control algorithm under evaluation: froth depth, fraction of wash water underneath the interface and gas hold-up. Froth depth is regulated using a PI controller while a predictive controller is formulated as the minimization of the tracking errors of gas hold-up and bias rate, keeping several operating constraints between their practical upper and lower limits. In particular, an unreachable high set point of gas hold-up can be selected in order to maximize the bubble surface area available for particle collection, while maintaining bias rate above a minimum value required for froth cleaning. The proposed strategy may indirectly help optimizing flotation column operation by using these secondary variables, without the implementation of a real-time optimization layer.INTRODUCTION Flotation columns have already been used for more than 30 years, mainly in cleaning stages, as a result of their froth washing capabilities. Despite their widespread usage, the measurement of some pertaining variables and their use for automatic control is rather scarce. Among the most important variables directly related to the process metallurgy (concentrate grade and recovery), froth depth (hf) is the only one normally monitored and controlled. Even though commercial sensors are available, gas hold-up (eg), a variable directly related to concentrate recovery, is seldom measured and never controlled. Another important variable, bias rate (Jb) responsible for concentrate cleaning, is simply not measured at all, as there is no commercial sensor available. Therefore, besides froth depth, continuous monitoring of process variables is limited to flow rates (gas, feed, tailings, wash water), i.e. to manipulated variables. Some new available sensors have been industrially tested, e.g. the Sonar-TracTM for eg (O'Keefe, Viega & Fernald, 2007) and the McGill hold-up sensor (Tavera & Escudero, 2002). Others, for bias rate and frother concentration, have been successfully validated at laboratory scale by Laval’s LOOP researchers (Maldonado, Desbiens, del Villar & Chirinos, 2008b; Maldonado, Desbiens, del Villar & Aguilera, 2010a). Some devices have been extensively used for monitoring bubble size and space distri-bution, e.g. McGill bubble viewer (Gomez & Finch, 2007) and others."

Jan 1, 2012

By Gunnar Nord

Introduction ??Atlas Copco has customers both amongst Miners and Contractors ??We believe that the contractor's approach to tunnelling is worthstudying ??For a tunnel contractor the incentive is speed as ?30 % of the costs are material related ?70 % of the cost are time related ?A tunnel contractor favours utilizing of the face ?A miner favours utilizing of the gear ??Statement; In mining, a long term average advance rate of more than 10 m / day can be achieved with the excavation techniques availabletoday

May 1, 2009

By F. Mohamm

"Recent changes in regulations and scientific advances concerning selenium bioaccumulation have placed greater importance on non-biological treatment systems for selenium control. Mining wastewater contains hexavalent selenium (selenate) as the predominant aqueous species and possibly small amounts of tetravalent selenium (selenite). Non-biological removal of selenite is accomplished readily and cost effectively by ferric co-precipitation and adsorption using ferric oxyhydroxides sourced from ferric salts or iron anodes in electrocoagulation cells. Selenate on the other hand is difficult to remove. It is often incorrectly assumed that electrocoagulation is suitable for removing both selenite and selenate. Selenate removal efficiency by electrocoagulation is low and the amount of waste residue produced high. In contrast, BioteQ’s Selen-IX™ process removes selenate very efficiently and produces a much smaller amount of stable residue. The process combines selective ion exchange with electro-reduction of selenate in electrocells that physically resemble electrocoagulation cells but are designed and operated differently. This paper summarizes four years of pilot scale demonstration on a wide range of mine waters and discusses the key benefits and limitations of Selen-IX™. The pros and cons of combining ion exchange with electro-reduction in comparison to direct electro-reduction of selenate are also reviewed.INTRODUCTION Selenium in Mining and Mineral Processing Effluents Similar to sulphate and metals, selenium presence in mining and mineral processing wastewater originates from minerals contained in the mined deposits. Therefore, no organoselenium species are typically present in these kinds of waters and inorganic species including selenite (SeO32-), selenate (SeO42) and elemental selenium account for the majority, if not all, selenium present in these streams. Elemental selenium is not always present in mine water but is often contained in smelter wastewater. To comply with new environmental regulations, a successful water treatment plant must remove selenium from all these forms effectively and economically without generating by-products that are difficult to dispose of or manage. Elemental selenium can be dealt with using filtration or gravity separation in clarifiers often assisted by flocculants and/or coagulants. Mine impacted waters typically contain other forms of suspended solids which are removed from water in this way. Once the solids are removed, the selenium species that remain untreated are the dissolved forms. In mining waters this is mostly selenate with small fraction of selenite. In smelter wastewater, the majority could be selenite. It is well established that tetravalent selenium is readily removed from water by using ferric iron co-precipitation at pH > 4 (NAMC SWG, 2010). Ferric hydroxide/ferrihydrite solids act as the adsorbent for tetravalent selenium when it is in one of the ionic forms of biselenite or selenite. This treatment for tetravalent selenium is highly efficient. Therefore, tetravalent selenium removal is generally not an issue and is often easily incorporated into lime neutralization or unit operations such as electrocoagulation used for removing other metals present in mine impacted waters. Another option of dealing with tetravalent selenium is sulphide precipitation in acidic pH which produces SeS2 and can separate selenite from other metals and/or sludge produced at neutral to alkali pH."

Jan 1, 2017