Search Documents

By Balint F

The Izok massive sulphide deposits are located in the Northwest Territories of the remote western Canadian Arctic. Together they represent one of the highest grade undeveloped zinc-copper resources in North America. Metall Mining Corporation is presently engaged in a feasibility study on developing the Izok property as well as actively exploring for additional reserves. The Izok deposits are Archean-aged, volcanogenic massive sulphide (VMS) bodies hosted within and near the top of a thick sequence of predominantly felsic pyroclastic rocks. The hangingwall package includes additional felsic volcanoclastics, dacitic and basaltic flows, thin sulphide-rich iron formations, and turbiditic sediments. The felsic volcanics are intruded by syn- to late-hydrothermal dacitic dykes and sills and post-hydrothermal gabbroic dykes and sills. Both intrusives are interpreted to be volcanic feeders to overlying flows. All lithologies are cut by much later irregular granitic pegmatite dykes and regionally metamorphosed to pyroxene homfels grade. The deposits occur within a large kilometre-scale soda-depleted alteration zone. The immediate footwall and hangingwall rocks to the deposits are characterised by zones of muscovite-biotite (with or without sillimanite), lesser chlorite-biotite-cordierite (with or without anthophyllite), and locally intense silicificified and albitised zones. All lithologies have been affected by a later calcic metasomatic alteration. As currently defined, the Izok Zn-Cu-Pb-Ag deposits comprise a cluster of four complexly-zoned composite lenses: the Northwest, North, Central, and newly discovered Inukshuk deposits. The first three deposits are amenable to open pit mining while development of the Inukshuk deposit will require underground methods. The combined mineral inventory of the Northwest, North, Central and Inukshuk deposits at present totals 15.6 million tonnes with a grade of 2.4 per cent Cu, 13.8 per cent Zn, 1.4 per cent Pb, and 74.6 g/t Ag.

Jan 1, 1993

By Glaessner M. F

The island chains of the Western Pacific (Fig. 1), on account of their related origin, and the similarity of the rocks that compose them, constitute in the main a most homogeneous mineral province. They lie in a complex "mobile" zone of the earth's crust, that formed a geosynclinal area separating the continental margins of Australia and South-Eastern Asia (the so-called Sundaland) from each other, and from the margin of the Pacific Ocean proper (FIg. 2). The whole region was drowned at the close of the Ice Age, as a result of the rise of sea-level that accompanied the melting of the great ice caps in the polar regions, leaving only the higher portions as islands and peninsulas, many of them separated only by shallow seas or "shelves."The geosyncline was infilled with Mesozoic and Tertiary sediments that have undergone varying intensities of folding and metamorphism, and has been subject to intermittent periods of volcanic activity, continuing into the present. Midway between the two continental margins there is a narrow belt of pronounced negative gravity anomalies, with an extraordinary S-shaped convolution in the vicinity of the Banda Sea and Celebes, that marks the core of this unstable region. The folding within the "mobile" zonetrends parallel to it, so that the islands in its vicinity, which are regions elevated by folding, are all elongated in the strike direction of the folds. This explains not only the linear shape of Sumatra and Java, but the arc of islands enclosing the Banda Sea, and the peculiar shape of Celebes.Parallel to the belt of negative anomalies, at a close remove from it, is the line of Recent, or active volcanoes, that extends along the whole length of Sumatra and Java...

Jan 1, 1947

By U Rehm

The biggest hard rock double-shield tunnel boring machine (TBM) in the world, with a diameter of 12.4 m, is currently excavating the North-South Bypass, which includes a crossing under the Brisbane River, Brisbane, Australia, to relieve the often congested road traffic in the city centre. Ten years ago a 10.7 m Mixshield giant helped to handle the Olympic Games in Sydney linking the airport with the city centre for an improved transportation of fascinated visitors. In Shanghai, currently the biggest TBM in the world with 15.43 m diameter presents excellent performance rates; and in Paris a convertible Mixshield could be quickly changed from earth pressure balanced (EPB) to slurry type in order to handle the very heterogeneous ground conditions. In Madrid a 15.2 m EPB giant finished its tunnel job four months ahead of schedule. Large-scale TBMs have proved their economic and innovative potential to create the current and future underground architecture of mega-cities. TBM technology has made further large innovative steps in the last decade. State-of-the-art is a TBM for very heterogeneous ground conditions comprising hard and soft rock with additional high groundwater pressure. The machine concept is adapted to the various ground conditions and allows for a quick and flexible application. Ground treatment by means of additives developed to a helpful tool in this connection. To meet the special challenges of urban tunnel projects of nowadays it is of very high importance, beside applying highest developed technology of TBM, to have a comprehensive technical support during the project phase and to develop positive relationships between all participants of the project which last longer than only for one project.

Jan 1, 2008

By E Whiteman, L Reyneke, H Horsch

Heavy mineral sand deposits are a source for the economically important element titanium, which is contained in minerals such as ilmenite and rutile. In heavy mineral deposits ilmenite displays various degrees of alteration. Natural weathering of ilmenite involves the removal of Fe and thus results in an increase in the Ti-content. Minerals such as pseudorutile, ferropseudobrookite, anatase and the ill-defined mineral aggregate leucoxene, which consists mainly of various amounts of remnant ilmenite, pseudorutile, ferropseudobrookite and anatase, are typical replacement products of ilmenite. Ferropseudobrookite occurs as a recrystallised, optically and chemically distinct mineral phase. Textural relationships suggest a diversity of physicochemical conditions including weathering and metamorphism that led to the formation of complex mineral assemblages and textures. In the heavy minerals industry the alteration products of ilmenite are generally referred to as æaltered ilmeniteÆ and/or leucoxene. The distinction between æaltered ilmeniteÆ and leucoxene is not consequently defined and is very much dependent on economic factors and specific mining operations (ie determined by deposit specific mineral assemblages). Generally the term leucoxene is used in the heavy minerals industry as a collective description for ilmenite alteration products with TiO2-components ranging from 65 - 95 per cent. A detailed comparative mineralogical investigation including microscopic, SEM and QEMSCAN« techniques show that it is possible to identify and quantify the replacement products of ilmenite on a micron scale. QEMSCAN« generated particle maps were graphically compared with photomicrographs taken by applying reflective light microscopy. The resulting information can be integrated over the entire sample with respect to composition, absolute and relative mineral abundances, grain sizes, volumes, densities, textural relationships and liberation potentials. This provides a powerful tool for a first appraisal of the physicochemical behaviour of bulk samples and individual particles during metallurgical processing.

Jan 1, 2008

By N McKenzie, F Brodbeck

The North-South Bypass Tunnel is the first project to get underway as part of BrisbaneÆs transport plan, which aims to improve the urban road network. The total length to be excavated is 6.8 km, which includes 4.8 km of driven tunnel and associated road connections. Construction commenced in August 2006 with project completion targeted well before the contractual completion date of October 2010. Due to the local geology, in particular the hard Brisbane tuff and neranleigh-fernvale formation, a combination of tunnel excavation methods are used. The majority of the tunnel is excavated by two tunnel boring machines which have a rate of progress of 16 - 20 m per day in rock having a compressive strength of between 80 and 150 MPa. Ten roadheaders operate at a rate of up to 2 m per day excavating the remaining tunnels, such as ramps, access tunnels, cross passages and merges. The tunnel team are managing the challenges and complexities associated with tunnelling through the hard Brisbane rock. A major challenge arose during the planning of the initial mainline excavation underneath the Royal National Association Showground in Bowen Hills. This section contains low rock cover and historical maps indicate that the showground is located within a former topographic depression (alluvial valley), which a creek once flowed through.Due to traffic merge design requirements, both tunnel boring machine (TBM) and roadheader excavation methods were required to be used in this challenging geological profile. The answer was to stabilise the alluvium above both TBM section tunnels from the surface prior to excavation and to operate the TBM in single shield mode with immediate grouting of annular void from the tail shield. In addition, the roadheader section of tunnel required additional support by spiles and canopy tubes installed from the tunnel face.

Jan 1, 2008

By Millett R

In January 1989, Western Mining Corporation (WMC) acquired the Perseverance and Rocky's Reward orebodies and associated infrastructure from the Agnew Mining Company (AMC). AMC had closed the operation in August 1986 and it had been on care and maintenance since that time. To return the operation to full production as quickly as possible it was planned to mine the Rocky's Reward orebody by opencut mining and treat this ore whilst the underground Perseverance workings were rehabilitated. Removal of overburden from Rocky's Reward thus commenced immediately with a target of April 1989 for delivery of the first ore to the concentrator. Extensive rehabilitation and upgrading of the concentrator commenced in late January, and continued in stages for an 18 month period. The first stage consisted of overhauling all existing equipment and completing a crusher upgrade commenced by AMC prior to the mine closure. During this period, it was necessary to recruit a workforce and re-establish all the required support structure. In late April the plant commenced commissioning trials on mullock. The first ore was crushed on the 11th May 1989 and concentrate produced the following day. From May 1989 to June 1990 the plant was producing nickel concentrate whilst further upgrading continued. During this period, the flotation capacity was tripled by installation of a bank of eight Wemco 144L flotation cells in rougher-scavenger duties and two 12 metre by 2 metre diameter columns in cleaning duties. The existing vacuum drum filters were replaced by two Larox PF32 pressure filters, eliminating the need for solar drying and allowing the flash drier to be fed direct from the filters. These, along with a major borefield expansion and further work to the crusher increased the nominal plant capacity from 600,000 to 1,000,000 t/yr. The plant achieved the 1,000,000 t/yr rate in April 1990.

Jan 1, 1991

The Mammoth Copper Deposit consists of three distinct orebodies adjacent to the Mammoth Fault. This fault is arcuate, changing from a normal tension fault to a shear strike fault just to the north of the mine. Movement on the fault was probably contemporaneous with deposit- ion of the adjacent sediments. In the upper levels the No. 1 orebody occurs within a brecciated zone in the footwall of the fault, but at depth the No. 2 and 3 orebodies are stratabound by two brecciated lithologic horiz- ons. The host rocks are impure sandstones, arkoces and quartzites, which in the mine area are near the top of the Lower Proterozoic Myally Beds. Overlying these beds is a conglom- erate siltstone sequence which has been assumed to be the base of the Gunpowder Creek Formation. North and south of the mine the conglomerate rests on an erosional unconformity representing a major time break, but in the mine the uncon- formity and conditions of deposition of the conglomerate are obscure. Some mineralization is contained within the conglomerates. The sulphides present are chalcocite, bornite, chalcopyrite and pyrite. Chalcocite is dominant in the upper levels but could be en- riched by supergene processes. At depth, bornite becomes the dominant copper sulphide with lesser amounts of chalcopyrite, pyrite and primary chalcocite. Throughout the orebody minor digenite and covellite occur and arsenic is a minor constituent bound up with the pyrite. The bulk of the sulphides occur in stringers, fractures and breccia interstices but finer grained primary bedded sulphides can be observed. The genesis is probably a complex process in- volving active tectonic movements extending from deposition to post lithification giving numerous phases of brecciation and redistribut- Ion.

Jan 1, 1974

By L Reynolds

The portable infrared mineral analyser (PIMA) was trialled to determine the extent and intensity of any hydrothermal alteration halo associated with gold mineralisation in the Hyde-Macraes Shear Zone (HMSZ) of the Otago Schist.   Twelve diamond drillholes through the HMSZ were analysed with the PIMA at a sample spacing of 1 m. The drillholes were selected on two traverses along the line of strike and down-dip of the mineralisation in and around Panel 2 of the Frasers underground development.   The study showed that the Hangingwall shear of the HMSZ has a more distinctive infrared signature in intersections with high grades. The Hangingwall shear in these drill holes is defined by a shift in the wavelength of the Al-OH absorption feature from ~2220 nm to <2210 nm. This shift is attributed to a change in the mineralogy from phengite to muscovite. Overprinting this trend in some of the drillholes is the presence of the 2210 nm Al-OH absorption feature, ascribed to kaolinite. Kaolinite also tends to be present in numerous other regions of the schist above the Hangingwall shear associated with steeply dipping faults and foliation parallel joints. In drill holes with low grades the Hangingwall shear does not exhibit any obvious infrared signature.   At the scale of study, the PIMA does not provide evidence for an alteration halo associated with hydrothermal mineralisation above the Hangingwall shear. Possible tectonic movement may have displaced any alteration halo that once existed, away from the zone of mineralisation. For this reason, PIMA apparently cannot be used for predicting the location of the Hangingwall shear during exploration drilling. However, the study did show that the PIMA could define the Hangingwall shear when the rocks were sufficiently altered and mineralised.

Jan 1, 2007

The working of alluvial deposits has from all times been a popular form of mining, not only from the simplieity of its operations, but also, in its more primitive stages, from the possibility of carrying it on without large capital, without skilled lahour, expensive plant, long terms of preparatory work, or, in fact, any other requisite than a shovel, a dish, and a stout pair of arms. It is possibly one of the oldest industries, and probably, also, it has been one of the most profitable.In tbe Australian States the happy days of rid alluvial deposits, when gold was to be hltd for the shovelling, are now almost over. The lust for gold has caused almost every corner of the world to be ransacked, and the more easily earned wealth to he exhausted: for the most part there remain now those deposits only which are too poor to be profitably worked by means of the implements and methods of old times. But, though the deposits have become poorer, the keen inventiveness of man has devised means whereby such large quantIties can be treated at a cost so low that he can still make a profit out of them. In this article, out of the many means devised, three only will be referred to-viz., hydraulic sluicing, bucket dredging, and hydraulic dredging. All mining may be divided into three principal operations-1st, the breaking down and conveying of the ground to where it is to be treated for the recovery of the metallic values, 2nd, the treatment of the material for the recovery of those values; and, 3rd) the removal of the worthless material or tailings. In all mining the object is to effect these three processes for the least expenditure of money commensurate with the highest degree of efficiency.

Jan 1, 1907

By Krouse RH, Aleinikoff JN, Nokleberg WJ, Church SE, Newkirk SR

A belt of volcanogenic massive sulfide (VMS) deposits and occurrences extends for over 150 km along the southern margin of the Yukon-Tanana terrane in the eastern Alaska Range. The VMS bodies occur mainly in the Jarvis Creek Glacier subterrane (JCGS), one of the highest structural/ stratigraphic levels of the Yukon-Tanana terrane. The JCGS consists of a VMS--bearing metavolcanic rock member and a metasedimentary rock member. The VMS deposits and enclosing rocks exhibit two periods of regional metamorphism.From northwest to southeast, the major VMS districts are the Bonnifield, Hayes Glacier, McGinnis Glacier, and Delta districts. The Bonnifield, Hayes and McGinnis Glacier district sulfide bodies consist of pyrrhotite and lesser amounts of pyrite, chalcopyrite, with or without arsenopyrite, sphalerite and galena. The larger, 800 km Delta district deposits and occurrences contain variable amounts of pyrite and pyrrhotite and lesser amounts of primarily chalcopyrite, galena, sphalerite, and arsenopyrite.The sulfide accumulations are interpreted as Kuroko-like deposits that formed along the submarine volcanic part of a Devonian, continental-margin igneous arc. U-Pb isotopic data from zircons from the metavolcanic rocks indicate an age of about 370 Ma (Devonian). 207Pb/204Pb ratios for sulfides from the districts are similar and indicate lead was in part derived from first cycle sediments eroded largely from Precambrian crystalline rocks. 207Pb/204Pb ratios from feldspars in Devonian metavolcanic rocks are similar to those in sulfides, and indicate incorporation of radiogenic Precambrian lead into the Devonian magmas. A Precambrian crystalline source for quartz in metasedimentary rocks is indicated by 2.3 Ga old zircons. Common-lead isotope studies of igneous phenocrysts in metaigneous rocks and sulfides in volcanogenic massive sulfide deposits indicate a unique isotopic signature. The data permit an exotic origin of the Yukon-Tanana terrane with respect to North America.

Jan 1, 1990

By M Fimeri, R Williamson

Sample sizing in the iron ore industry requires significant manual effort to collect, transport, and sieve the samples as well as record, process and report the data. Efforts have been made to automate this process, which essentially emulate the manual process, except that a person is replaced by a robot. Even in these cells, the sieving and sizing operation consumes a significant proportion of robot time. The proposed doubling of production from AustraliaÆs iron ore mines over the next five years will place increasing pressure on sample sizing and interest is increasing in alternative automated methods. One such method is the adaptation of computer vision technology which has been successfully introduced into the mining industry in a range of applications including feed size distribution to SAG mills and oversize detection from screening stations. The limitation of this technology is that only the top surface is visible and this is used as an indicator of total size distribution. Obviously in a sample plant, where 100 per cent of the sample must be measured for acceptable quality assurance, this approach is unacceptable. In order to capture 100 per cent of the sample using computer vision technology a monolayer must be formed either by spreading the sample across a moving surface, such as a conveyor or vibrating platform, and passing this under a camera. This will become a æsurgingÆ load which presents specific problems for some types of computer vision systems, namely those relying on a 2D approach. In this paper a 3D computer vision technology will be described which overcomes the problems associated with measuring particle size in a monolayer and experimental results will be presented which demonstrate its effectiveness for lump and fine iron ore sample size measurement.

Jan 1, 2008

Vatukoula, the Fijian equivalent of gold rock, is the name of the community embracing the gold mines owned and operated by Emperor Gold Mining Company Ltd., Loloma (Fiji) Gold Mines, N.L., and' Dolphin Mines Ltd. It is situated in the Tavua Goldfields approximately five miles from the northern coast of Viti Levu, the largest island of the Colony of Fiji.The climate is sub-tropical, there being a definite wet and dry season. The wet season is somewhat variable in length but usually extends from December to March, during which time most of the rainfall for the year is recorded.Although the average annual rainfall is 71 in., more than twice this amount has been recorded. Precipitation at the rate of 5 in. per hour is not uncommon and 15 in. of rain has been registered in 24 hours. The mining methods adopted, therefore, had to suit these wet conditions.The occurrence of gold in the Tavua area has been known since 1872, but it was not until 1932 that discoveries were made which led to the formation of the present operating companies. In 1934 the Emperor Gold Mining Company Ltd. commenced operations, followed in 1935 by the Loloma (Fiji) Gold Mines, N.L., and later by the Fiji Mines Development Ltd., now known as the Dolphin Mines Ltd. Up to the end of 1951 these three mines had produced 2,501,688 tons of ore from which 1,277,881 oz. of fine gold and 347,429oz. of silver were obtained, realizing in Fijian currency £13,025,153.The three mines are situated close togeth.er on contiguous mining leases, and, although under common management, are operated as separate en,tities. Since 1944 all the...

Jan 1, 1953

Acclaimed as one of the most remarkable orebodies anywhere on account of its length and richness, the Oroya Shoot occurs on the eastern side of the Kalgoorlie gold mining district close to the contact of a fine-grained with a coarse-grained greenstone, and in association with sediments. In the same stratigraphic position on the synclinal flanks of a large drag fold there are a number of other flat ore pipes, smaller, but almost as rich in tenor. Although differing in control structure they are believed to be related genetically as all show a characteristic development of a bright-green ore known locally as "green leader". Folding and bedding structures have played an important part in formation of the ore shoots.INTRODUCTIONThe Oroya Shoot is the biggest individual bonanza of Kalgoorlie's Golden Mile. It has been stoped almost continuously over a length of 4,300 ft., and about 2,000,000 oz. of gold have been won from it. Naturally pillars are not left in the best sections of such an orebody and the detailed geology of stoped out portions can only be inferred from examination of adjacent workings.No mention is made in the literature of the actual makeup of the orebody although a few structures are shown on some of the old cross sections. A diagrammatic cross section, Fig. 1, adapted from Stillwell (1929) illustrates the form of the Oroya Shoot.Gustafson (1937) drew attention to the role of folding, previously unrecognized, in Kalgoorlie geology, and indicated that the Oroya Shoot is associated with a minor drag fold on the east limb of the Brownhill Syncline, itself part of a larger left hand drag on the Central Anticline. The latter in turn appears to be part of a regional right hand fold system as shown by Campbell (1953).

Jan 1, 1959

QEMSCAN« technology is a widely accepted automated e-beam technique providing quantitative and statistically robust mineralogical data to the mining industry. It uses X-ray mapping combined with backscattered electron (BSE) brightness to identify minerals in almost any type of geological material (Gottlieb et al, 2000). Besides the modal mineralogy also the liberation, associations, average grain size and other textural information can be obtained. The aim of this study is to test reproducibility of this technique by setting up and running standard tests on different QEMSCAN« systems. Multiple sample blocks were prepared by our standard operating procedure as epoxy-mounted, carbon-coated, polished blocks. The replicates were measured under the same conditions and measurement parameter settings on different QEMSCAN« instruments. The relative standard deviation (RSD) for the set of measurements was calculated. Generally the reproducibility of the systems themselves was found to be excellent, ranging between 0.4 and 1.5 per cent RSD. The more significant change in the reproducibility was found to be caused potentially by the sample preparation and variation in the mineralogy of the replicates. The measurement parameter settings together with these variations can account for almost 15 per cent RSD for minerals of low abundance. For analysed samples good results for the main phases present in quantities higher than 2 - 5 wt per cent of the total mass of the sample were confirmed with RSD generally below six per cent. Following the experiments, the parameters having the biggest influence on the performance of the QEMSCAN« and its precision are discussed in detail. The importance of sample preparation procedures and measurement parameter settings is emphasised. It is shown that experience and excellence is necessary for getting the most from the automatic mineralogical methods like QEMSCAN«.

Jan 1, 2008

By McIlveen GR

The water pollution hazard posed by the derelict Conrad mine site, to the water and associated stream sediment of Borah and Maids Creeks and the nearby Copeton Dam storage, has been assessed. Mine water, tailings and tailings dump leachate have polluted water and stream sediments in Borah Creek downstream of the mine site. Acidity, arsenic, copper, lead, iron, silver and zinc are the principal pollutants. Under dry and low flow conditions, mine water was found to be the dominant polluting source, however, leachate and run-off from tailings dumps were also significant under and following wet conditions. Soluble arsenic, lead, iron and silver species in mine water and leachate were found to be rapidly incorporated into sediments, but acidity, copper, and zinc persisted in the creek water. Under low flow conditions, the water of Maids Creek is polluted with copper and zinc (up to 4.4 and 34 mg/l for copper and zinc respectively) and the pH is decreased (from pH 5 - 7 to pH 3 - 6) by entry of Borah Creek water. Values found in Maids Creek were variable and related to flow regime and distance downstream from Borah Creek confluence. Water in Copeton Dam storage, having a much larger volume of water with a higher bicarbonate buffering capacity (50mg/l versus 15mg/1), is not affected by entry of Maids Creek water. Polluted sediment from Borah Creek has contaminated Maids Creek for 2km downstream to Copeton Dam storage. Stream sediment downstream of the Borah Creek confluence, contains up to 1.0% As and 1.4% Pb in the less than 200 micron size fraction. Under high flow conditions, arsenic was found to be moved out from the mine site as insoluble species, associated with suspended sediment in Run-off.

Jan 1, 1988

In the years prior to the outbreak of war in 1939 Australia's production of copper had declined from a peak of about 80,000 tons in 1911-1915 to approximately 25,000 tons in 1939. This production met the need of the slowly growing national requirement and gave an excess for export. However, with the intensification of the war effort in 1942 due to the imminence of a Japanese invasion of this country, or at least a blockade of the sea lanes, it became necessary to expand production of armaments, and consequently the demand for copper increased beyond the capacity of the industry. Importation of copper to Australia during the period 1940-1944 was 131,000 tons.When exploration of the Mount Isa orebody was first being carried out in 1928, No. ID diamond drill disclosed the presence of some copper ore lying outside the limits of the Black Star orebody2, but it was not until 1941-1942 that the development of No. 7 level in the Black Star orebody enabled the existence of a lode of copper ore of economic grade to be established. At the request of the Commonwealth Government of the day a programme of development for copper production was undertaken whilst lead smelting was continued as before the war.A series of flotation tests on up to 1,500 tons of ore at a time, was undertaken and the concentrate so obtained was stockpiled. These tests were conducted, using one section of the lead mill, and demonstrated that a concentrate grade of 22-23% Cu with a recovery of 80-85% might be expected.These recovery figures were afterwards much improved, and 93-95%was obtained before the close of smelting in 1946.

Jan 1, 1953

IN preparing a sample of refined lead for analysis, it is necessary to exercise great care to avoid contaminatien, as the amounts of the various impurities present in market lead are very small. The lead is cut into convenient-sized pieces, which are flattened out with a hammer, so that, on putting tbe lead through the rolls, strips of about one inch in width and Ij32iu. in thickness are obtained. The hammer, anvil, and rolls should be carefully cleaned before use. The strips oflead are cut up into pieces of about one inch square. If the lead is roIled out very thin and cut up into small pieces there is considerable risk of the acid acting too violently and causing loss through frothing over. A blank assay on all the reagents used should becarried right through, along with the actual analysis of the lead. This is of the greatest importance, particularly with regard to the determination of such impurities as iron, sulphur, arsenic, and antimony.METHOD OF ANALYSISThe method of analysis is as follows: Take two lots of 600 gIm. each, place in a large beaker, add 2000 cc. distilled water and 750 cc. concentrated HNOs. Cover with a clock glass and warm on a hot asbestos plate until all action ceases. (If any white precipitate forms, filter off and examine for Sn and Sb.) Add 420 cc. H2S04 (1-1), and stir well while adding the acid: Allow PbS04 to settle, pour off the clear liquid into a 12-in. porcelain evaporating dish, and start evaporating down, the dish being placed directly on an 8-in. ring gas burner. Wash the precipitate three times by decantation using approximately 1200 cc. hot water for each washing, and stir well...

Jan 1, 1922

Neutralisation, normally using lime, is the most widely used method for treating high flows of acid mine drainage (AMD). Lime costs can be very high however. If carbonate sources could be used to achieve pH values above six, costs could be greatly reduced. For example, use of locally quarried limestone at Mt Lyell could potentially reduce alkali costs from about $A 3.5 to $A 1 million/year. Methods for enhancing the effectiveness of limestone and magnesite for neutralising Mt Lyell and Savage River AMD respectively have been examined through a series of investigations. Small-scale testwork found that the maximum pH economically achievable with ground limestone was about five, due to slow dissolution rates and surface armouring. The problems of surface armouring were greatly reduced by the use of crushed limestone or magnesite at high pulp densities (75 per cent solids w/w), enabling pH values >6 to be achieved in a practical time frame. The use of particle sizes in the range 6 mm and finer also reduces costs by avoiding the need for grinding, and reduces the problems of solid-liquid separation and solid recycling that arise if large additions of ground carbonate are used. Pilot scale tests were carried out using tumbling drum reactors with limestone and Mt Lyell AMD and a pulsed-bed static reactor with magnesite and Savage River AMD. pH values averaging 6.2 and 6.4 were achieved with Mt Lyell and Savage River AMD respectively. Approximately 80 per cent of feed acidity was neutralised. A preliminary engineering design and cost estimate has been completed on the pulsed-bed reactor and shows that the concept is technically feasible and, if results are confirmed, economically attractive. Further pilot testing is planned.

Jan 1, 2002

By F Melcher, M Wiedicke, A Wittenberg

Ferromanganese nodules form a specific category of widespread marine mineral deposits. The tremendous increase in metal prices during the last decade raised new economic interest in their exploration. The German Federal Institute for Geosciences and Natural Resources (BGR), which had been engaged in nodule research in the 1970s and 1980s, renewed its activities on this subject based on an exploration contract with the International Seabed Authority, signed in 2006. BGRÆs licence area û comprising 75 000 km2 û is located between the Clarion and the Clipperton Fracture Zones. In this so-called nodule belt north of the equator the sea floor reaches water depths of >4000 m. About 900 million tonnes of manganese nodules are expected there. In this study the fine-scale distribution of important elements in manganese nodules and crusts from a variety of locations was investigated. Besides 11 samples from the RV SONNE cruise SO-25, numerous samples from additional locations were included in this study for comparison. In general, the sample suite includes two genetic types of precipitates, manganese nodules and Co-rich crusts. A detailed characterisation of the distribution of major, minor and important trace elements in manganese nodules based on in situ microenergy dispersive X-ray fluorescence (¦-EDXRF) analysis is presented here. The data are compared with bulk major, minor and trace element data as well as with quantitative electron probe microanalysis (EMPA) data sets. The element distribution maps and profiles produced by ¦-EDXRF analysis with short or extended (in case of profiles) counting times, allow precise selection of æregions of interestÆ for further detailed investigation using high spatial resolution techniques (eg scanning electron microscope (SEM)-EDAX; laser ablation-inductively coupled plasma mass spectroscopy (LA-ICPMS); isotopic studies).

Jan 1, 2008

By E de N, B H. Usher, F D. I Hodgson

Due to the haphazard application of static tests in South Africa, several methods and interpretations have been followed. This has resulted in confusion amongst practitioners and regulators in the use and validity of these methods. Research was done over a two-year period to define standardised methods and interpretation of results. This included laboratory testing and continuous consultation with all interested parties throughout the country. The research yielded a modified ABA, based on several existing methods. The methodology includes AP determination using hydrogen peroxide, and an analysis of the supernatant by ICP. This has the advantage of not only registering reactive sulfur, but also provides the NAG pH, that enhances the interpretation and QC of the tests. Analysis of the supernatant provides an indication of heavy metal solubilisation, should acid conditions arise. One hundred and seventeen samples were compared to Leco S analyses and provided a good correlation. The Leco values were slightly elevated due to the reporting of total S as opposed to æreactive SÆ. The NP method deviates from the usual methodology, in that H2SO4 is used (to provide a field analogy) and the fact that a 24-hour stabilisation period is allowed before back-titration. The latter modification appears to prevent psuedo-buffering by transient phases. These methods have also been tested for repeatability and prove to be robust. A very simple macro-driven spreadsheet, æABACUSÆ, was also developed. This spreadsheet allows the entry of basic data and provides a detailed interpretation and graphical display of typical ABA data. In cases where drill holes are used, the Pennsylvanian approach of volume calculation can also be done with ABACUS. The results of the research have been distributed to interested parties in South Africa and it is hoped that these methods and their application will find widespread acceptance.

Jan 1, 2003