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By C B. Valentin

It is acknowledged that the analysis of iron ores using X-ray fluorescence (XRF) for major and minor elements is best carried out on fusion discs. This method of sample preparation eliminates mineral and particle size effects which can lead to biased results when using pressed powder pellets. However, the fusion disc method is costly as it requires a high capital investment in platinumware, requires experienced operators and uses expensive fluxes. Also, the dilution effect complicates the analysis of trace elements. For many applications, such as exploration and mining control, the method of XRF analysis of iron ores by pressed powder pellet probably provides data of adequate quality. Kumba Iron Ore, an iron ore producer in South Africa, recognises this and carries out most analyses of iron ore by pressed powder pellet and uses the automated fusion method mainly for certification of in-house calibration standards and quality control (QC) samples that are used for validation of pressed powder pellet method purposes. Automated fusion is also used for analysing the composite export shipping samples. All the other exploration, production, despatching and plant operation samples are done by the pressed powder pellet method. Automation of sample preparation procedures should improve the quality of data for pressed powder pellets. To compare the precision of the three methods of sample preparation and XRF analysis, 20 aliquots of a QC standard were prepared and analysed by each procedure/preparation method. The results and statistical data on the most important elements, Fe, K2O and P, are as shown later in Table 2.Clearly the precision is best for the auto prepared fusion discs, as expected, and worst for the manually prepared pressed powder pellets. However, the data generated from the auto prepared pressed powder pellets compare remarkably well against those from the auto prepared fusion discs.

Jan 1, 2007

By D E. Ralph, D-J Kim, G-J Ahn, Y-H Rhee

The amount of discarded dry batteries are presently found to be increasing globally and waste cathode active materials of the lithium ion battery industry are among them. Hydrometallurgical operations are being applied to recover the valuable metals from these waste batteries. To find an economic and environmentally friendly process, the bioleaching process was applied in the present investigation for recovery of valuable metals. Its principle is the microbial production of sulfuric acid and simultaneous leaching of metals. Bioleaching of spent lithium ion secondary batteries, containing LiCoO2, has been studied in this investigation. A new method for recovery of cobalt, potentially the basis of an economic and environmentally friendly process was examined. The present study has been carried out using chemolithotrophic and acidophilic bacteria Acidithiobacillus ferrooxidans, which utilises elemental sulfur and ferrous ion as the energy source to dissolve metals from spent batteries. Bio-dissolution of cobalt was found to be faster than lithium. The effect of initial Fe(II) concentration, initial pH and solid/liquid (w/v) ratio were studied in detail. Higher Fe(II) concentration showed a decrease in dissolution due to co-precipitation of Fe(III) with the metals in the residues. Similarly, at higher initial pH values and higher solid/liquid ratio (w/v) metal dissolution was found to be inhibited. The optimised conditions for bio-dissolution were solid/liquid (w/v) ratio û 10 g/L, initial Fe(II) concentration û 3 g/L, elemental sulfur û one per cent (w/v) and initial pH û 2.5. In the optimised conditions, cobalt dissolution was observed to be about 60 per cent, whereas that of lithium was ten per cent after 20 days. A first order kinetic model was derived to study the rate of dissolution of both the metals.

Jan 1, 2006

Titanium dioxide (TiG ) is produced 2 commercially by two methods generally referred to as the "sulfate" route and the "chloride" route. The SCM Corporation, in supplying 15% of the world's demand for TiO 2, uses both of these processes. Of the two processes the sulfate route is generally regarded as the older and more established technology. Worldwide the sulfate route accounts for some 70% of total Ti02 production. However, in the U.S.A. the chloride process accounts for 80% of production. The processes vary in chemistry and raw material requirements. In the "sulfate" process finely ground ilmenite or titanium slag is digested with sulfuric acid to produce a porous "cake" vrnich is extracted with water and recovered liquor. The solution is treated with scrap iron to reduce any ferric ions to the ferrous state which is then crystallised and removed as ferrous sulfate heptahydrate. The liquor is concentrated by evaporation and hydrolysed to form the insoluble hydroxide which is filtered and washed free of impurities. This is converted to the dioxide by calcination at 800 - 1000¦C and milled to break up any aggregates. The "chloride" process uses a higher quality feedstock of natural or synthetic rutile and/or high grade titania slag. The feedstock is mixed with ground high-purity coke and chlorinated at 950¦C in a fluidised bed. The resulting crude titanium tetrachloride is purified by distillation and chemical treatment. The purified titanium tetrachloride is burned with oxygen or oxygen enriched air to give titanium dioxide and chlorine, which is recovered and recycled to chlorination. Titanium dioxide pigment from both processing routes undergoes similar finishing techniques. It is subjected to further stages of wet and dry milling, then coated with layers of inorganic oxides in order to enhance its properties for specialist applications.

Jan 1, 1986

Although laterite ores already provide a significant proportion of the world's nickel and cobalt production it is anticipated that they will surpass sulphide ores as a source of nickel in the next century. The most recent period of greenfield nickel project construction was during the 1970s when it was notable that all of the eight new plants were based on treating laterite ores. This was because of the relatively large selection of available high grade laterite ore deposits amenable to cheap open cast mining and a paucity of high grade sulphide ore prospect alternatives. Of the three processing options for treating laterite ores: 1. smelting for the lower horizon saprolite ore, 2. ammonia; and 3. acid leach for the upper horizon limonite ore, smelting currently accounts for about 80 per cent of nickel production. In the future, as saprolite ore grades decline because of relatively high exploitation rates, the incentive to process the large untapped reserves of limonite ore will increase. The high cobalt content of limonite ore also makes it ideally suited to processing by a hydrometallurgical rather than smelting route. With only two exceptions, all saprolite smelting operations have a Class 2 nickel end product (largely ferronickel) and do not produce a cobalt by-product. As a result of technological advances, the modified ammonia leach process for limonite and transition ore as undertaken at Yabulu, now allows the production of pure nickel metal as a Class 1 product, along with significant tonnages of cobalt by-product. The mixed Ni-Co sulphide intermediate product of the pressure acid leach processing of limonite ore at Mon is converted to Class 1 nickel and cobalt metal at Fort Saskatchewan, Canada.

Jan 1, 1996

By H Aral, L Malishev

The carbothermic chlorination of titaniferous materials such as rutile, synthetic rutile (SR), upgraded slag and ilmenite in a fluidised bed is an established commercial process. In this work, ilmenite sourced from the Murray Basin area of South Eastern Australia was chlorinated and an assessment of the chlorination characteristics of the ilmenite, in terms of pre-treatment, type of reductant and reaction time was made. Selective chlorination of Murray Basin ilmenite to remove Fe and Mn was achieved in this work. A synthetic rutile sample containing around 93 per cent TiO2, one per cent Fe2O3 and 0.5 per cent MgO was produced at a chlorination temperature of 1000¦C with around 25 per cent loss of Ti as TiCl4. Raising the reductant to ilmenite ratio in the chlorination reactions increased the amount of Ti chlorinated. However, complete chlorination of Murray Basin ilmenite to produce FeCl3 and TiCl4, was not achieved under the conditions used in this work. Pre-oxidation of Murray Basin ilmenite before chlorination had little affect on its reactivity, compared with æas receivedÆ ilmenite. In contrast weathered West Coast ilmenite chlorinated appreciably better than West Coast primary ilmenite, in terms of bed residues remaining and amounts of elements removed. The presence of large amounts of Mg and chrome spinel grains in the Murray Basin ilmenite used in this study are likely to make it difficult to chlorinate directly in a commercial chlorinator. However, this is not to say these ilmenites will be unsuitable for chlorination applications. Further work is needed in the separation of Mg and chrome spinel grains from Murray Basin ilmenites and the products resulting from these tests could then be assessed in terms of chlorination performance, so that further processing options can be explored.

Jan 1, 2000

By P K. Seccombe

Sulfur isotope data are available for 18 low-sulfide orogenic gold systems hosted by the Lachlan Orogen in eastern New South Wales including those in the northern Hill End Trough (Hargraves, Hill End, Napoleon Reefs, Sofala-Wattle Flat, Stuart Town, Windeyer) and adjacent areas (Bodangora, Lucknow, Springfield), the Gilmore Fault Zone (Adelong, Sebastopol) and those in the Parkes district (Calarie, London-Victoria, Wyoming One-Myall United). Other systems for which data are available include Mongarlowe, Murrumbateman, McMahons Reef and Yalgogrin. The d34S data for many of the larger deposits including Adelong, Bodangora, Calarie, Hargraves, Hill End London-Victoria, Lucknow, Sebastopol, Sofala-Wattle Flat, Stuart Town and Windeyer (Group 1) are all very similar and have average d34S values close to zero per mil. Near 0ë d34S signatures imply that sulfur was sourced from a magmatic reservoir. Furthermore, the large Wyoming One deposit has d34S values significantly below 0ë with the data implying that sulfur was sourced from a fractionated magmatic reservoir. Group 2 deposits include those at Mongarlowe, Murrumbateman, Napoleon Reefs, McMahons Reef and Springfield . These deposits have average d34S values significantly above 0ë. With the exception of Springfield where sulfur was probably sourced from the Hill End Trough, Group 2 deposits are an order of magnitude smaller than Group 1 deposits. The results suggest that many of the larger orogenic-related gold deposits hosted by the Lachlan Orogen in eastern New South Wales derived sulfur and gold as a result of leaching and recycling from a magmatic reservoir. Alternatively, there may have been direct mantle-derived input; however, this is considered unlikely on geological grounds. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Townsend MG, Evans RB

In Northland, New Zealand, localised large deposits of halloysite clay have been produced by in-situ alteration of rhyolite volcanics of Pliocene or Pleistocene age, which were erupted through pre- Pliocene sedimentary strata and locally through Pleistocene basalt; and which were subsequently onlapped by further basalt flows. Alteration to clay has been a result of both hydrothermal and of meteoric processes, and decreases in intensity of alteration with increasing depth.The raw material is crushed and fractionated to produce a product of less than 2 micron particle size, which is of exceptional whiteness and brightness. The unique properties of the clays render them highly desirable for specialised ceramic purposes.

Jan 1, 1990

CONTENTSSummaryIntroductionGeographical and Geological Outline of the RegionGrowth of the Mining IndustryTable 1: Production StatisticsGeneral GeologyRecent Alluvium and River GravelsSambeto SeriesMudstone and Basalt ContactVatukoula SeriesIntrusivesStructureGeologic HistoryLodesTable 2: Principal Lodes and Their OrebodiesMineral Assemblage and ParagenesisOre Shoots and Their ControlEmperor MineLoloma MineDolphin MineExplorationConclusionAcknowledgmentReferencesSUMMARYThe Tavua Goldfield was found in 1932 within a basin, both topographical and structural, near the sea on the north side of Viti Levu, Fiji, and has produced over £13,000,000 (Fijian) worth of gold and silver from the three mines...

Jan 1, 1953

The Hartley layered mafic igneous complex within the Great Dyke of Zimbabwe contains economically-recoverable quantities of platinum group metals and gold, nickel, copper and cobalt. The recoverable metals are concentrated in a thin gently-dipping stratigraphic unit - the Main Sulphide Zone. The Hartley Platinum mine, jointly owned by BHP and Delta Gold NL, is scheduled to come on stream at the end of 1996 at an initial mining rate of 2.16 million tonnes per annum and will produce approximately 150 000 oz of platinum and 3300 tonnes per annum of nickel, as well as saleable amounts of palladium (110 000 oz), rhodium (11 500 oz) and copper (2232 tonnes).

Jan 1, 1996

By Sharma T

Laboratory investigations have been carried out on direct leaching of lead-zinc complex sulphide ore and zinc concentrate using ferric chloride. From the investigation it was observed that the use of 0.15 M and 2 M FeC13 gave an optimum dissolution of metal ions from ore and concentrate respectively. The kinetic studies conducted showed that the leaching reaction followed a shrinking core model for galena and sphalerite. The presence of impurities such as pyrite had increased the dissolution rate and reduced the consumption of ferric chloride. Further, the studies were conducted to recover dissolved zinc from the chloride solution by selectively precipitating it as zinc ammonium chloride.

Jan 1, 1992

The Directional Drill Monitor (DDM) is an advanced instrument for real time in hole surveying. It was developed by Du Pont (Australia) to suit Australian gassy coal mining conditions. The instrument consists of three units: i. Down hole transmitter ii. Acoustic transducer iii. Data receiver processor unit (i.e. up hole unit). This paper describes the function of each unit in detail and highlights the importance of the DDM in long hole drilling efficiency. Surveying is carried out independent of hole depth. Each survey takes 2-3 minutes to complete, the frequency of surveying to control borehole trajectory is determined by the accuracy required for a particular hole.

Jan 1, 1992

By Das A. K

Investigations were carried out to understand the effect of liquid viscosity (u = 1 x 10-3 - 5 x 10-' Ns/m2) on the size of primary bubbles formed at high gas injection rates (Q = 100 - 1000 cc/s, U = 0.04 - 0.42 mach) under room temperature conditions using flush tuyere (3 mm diameter) operating vertically upward. Tuyere pressure fluctuations were correlated to the mode of bubble formation by simultaneously filming the bubble and the corresponding tuyere pressure fluctuations displayed on an oscilloscope screen. A simple mathematical treatment is presented to estimate bubble size in viscous liquids. The theoretical results are compared with the experimental measurements.

Jan 1, 1987

The Jurassic Walloon Coal Measures crop out over much of the Moreton Basin and contain numerous thin, banded coal seams which have been mined at various locations since the 1870s. Historically most mining has been by underground methods. Increased exploration during the 1970s and 1980s has led to the delineation of significant open cut coal resources and to the development of the Oakleigh, Jeebropillly and Ebenezer open cut coal mines in the Rosewood-Walloon area. Over 2 170 million tonnes in-situ of shallow, high volatile bituminous coal with a mean maximum vitrinite reflectance of between 0.5 and 0.6 have been proven in the Basin.

Jan 1, 1991

The Kidston Gold Mine i s located in northern Queensland some 2 Ukm northwest of Townsville. I t is the largest gold mine in Australia and produces approximately 25 percent of Australia's gold and one percent of the world's gold.Initially, traditional mining industry management approaches resulted in the rejection of what appeared to be an attractive low-grade deposit as an uneconomic proposition. Critical re-examination revealed that the rejection was based upon managerial inflexibility and traditionally over-conservative methods of mine evaluation, construction, operation, projected commodity prices and contingency factors. "Ihus it tradition was to prevail, the Kidston prospect would never have been realised.

Jan 1, 1985

By Ibrahim AR

The experimental phosphate mine of abu Tartur has been recently placed into production. Some problems'have been encountered in maintai- ning grade control due to the differences between early block estimates and actual produ- ction grade. An area of 100 km2 is evaluated by using four methods of evaluation , namely polygonal, inverse distance , inverse distance squared and geostatistical methods. The results of calculations are compared statistically with the control values of grade and thickness. The comparison showed that the. kriging technique gave better estimations for the relative ore reserved, while for grades or thickness any of these techniques except the polygonal can be Used.

Jan 1, 1986

This report on the 5th International Conference on Underground Space and Earth Sheltered Structures, which was held at the University of Technology, Delft, the Netherlands, on 2 to 5 August 1992, was submitted to the members of the Australian Underground Construction and Tunnelling Association. The report describes the conference themes and outcomes and puts forward some observations about a growing world-wide interest in the promotion of appropriate uses of underground space. The report recommends the creation of an Australian centre for research to bring together a wide range of professional disciplines and to focus attention on the potential benefits of using underground space.

Jan 1, 1993

By Ryan CG, Ramsden AR, Sie SH, French DH, Griffin WL

Proton microprobe and electron microprobe analysis are being used in combination for in situ determination of the trace element contents of oxide, sulphide and silicate minerals in a sample of the Merensky Reef. Initial results indicate that chromites contain only Ni, Zn, Ga, Zr ar d Nb. Platinum-group elements, if present, are at concentrations less than 2 to 6ppm. Ru, Rh and Pd are the only platinum group elements to be consistently detected in the sulphides. PentLindite is the most important host for these elements with the concentration of these elements being dependant upon the mineral association in which it occurs

Jan 1, 1989

By Shibata Y, Shimizu R, Fukushima A

Kobe is divided by the Rokko Mountains, runn- ing from east to west. The southern section of Kobe is highly developed in contrast with the northern section, but big, new residential pro- jects like the Hokusetsu New Town and Hokushin New Town are steadily being developed. To handle future traffic between the two sections of the city, the double-tracked Hokushin Line, now under construction, will connect the Shin Kobe Station of the Kobe Municipal Transit (Kobe's subway system) to the Tanigami Station of the Kobe Electric Railway. The locations of Kobe city and Hokushin Line are shown in Fig.-1 and Fig.-2 respectively.

Jan 1, 1987

By T Iwadachi, T Fujisawa an, G R. Alvear

A large amount of Be2C and BeO is formed during the Cu-Be alloy production process, because beryllium is a highly reactive element. Carbide and oxide formation impairs the production yield and the quality of the Cu-Be alloy products, and therefore should be minimised. As a first step for solving these problems in the process, the following thermodynamic properties of the Cu-Be-C-O system were investigated. Based on the results, the equilibrium relations of the Cu-Be-C-O system were clarified and the operational conditions of the current Cu-Be alloy production process were also examined and discussed.

Jan 1, 2000

The hydrological cycle in nature, with particular reference to Australia . 2. The definition of water pollution drawing on the experience of several major countries. 3. A description of the pollutants in water, and why they are pollutants. 4. The classification of waters as defined by major overseas countries. 5. The criteria and standards developed by major overseas countries for the classification of waters. 6. A brief- summary of the legislation adopted by overseas countries for the control of water pollution, and of the organisation and administration of controls. 7. A study of Australian legislation and administration of controls of water pollution. 8. General observations and conclusions.

Jan 1, 1971