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By P Louden, C Rothnie, G Showers

Tiwest employs several methods to assess the quality of heavy mineral concentrates in ore and process samples. Mineralogy is determined using a method called MA98, developed in conjunction with JKMRC over the last three years (Zhang and Whiten, 2001). A range of other techniques are also used to characterise ore, heavy mineral concentrates and mineral products. MA98 is the culmination of efforts since 1989 to determine mineralogy from chemical analysis without recourse to heavy liquid fractionation, which has traditionally been used to discriminate between light-heavy , zircon, rutile and leucoxene. The major advance with MA98 is the use of statistical mass balancing for all chemical species, as opposed to reliance on key chemical species for each mineral. Three magnetic fractions are analysed by X-ray fluorescence spectrometry, with a minerals balance performed for each. Heavy mineral concentrates processed by this method include drill samples, process samples from the wet concentrators and Dry Mill, and mineral products. TBE can be avoided for higher heavy mineral grade samples since quartz is determined from SiO2 balance. In this sense the method is sufficiently universal and robust to cope with a wide range of sample types and compositions. The MA98 algorithm provides abundant information in addition to mineralogy, including TiO2 and Fe2O3 grades of ilmenite and leucoxene, and concentrations of weakly magnetic zircon and kyanite. Information such as this is invaluable in tracking different minerals through the processing plants. Other ore assessment procedures used by Tiwest provide for modelling of orebodies by mineral sizings, Fe in zircon, and FeO and U+Th in ilmenite. Microscopy is used to provide important qualitative information such as grain shape, surface staining and degree of cementing. These quality measurements are included with mineralogy in geological ore models and are available for mine scheduling. In using the above methods to characterise heavy mineral concentrates, Tiwest is better placed to predict and monitor plant performance and product quality from any ore zone.

Jan 1, 2001

By P Duuring

Late-Archean banded iron formation (BIF)-hosted deposits in the Yilgarn Craton of Western Australia are less well understood compared to the larger Paleoproterozoic, Superior-type BIFhosted deposits of the Hamersley Province. The Weld Range greenstone belt, in the Murchison Domain of the Yilgarn Craton, hosts two Archean, high-grade deposits, Madoonga (68 Mt resource at 57.7 wt per cent Fe) and Beebyn (62 Mt resource at 59.6 wt per cent Fe, ASX announcement 2008). Five main types of high-grade (>55 wt per cent Fe) iron mineralisation at Weld Range each display characteristic grades, tonnage, and contaminant levels, which affect exploration strategies and beneficiation methods:1. ‘Residual’ ore formed as a result of two generations of hypogene alteration of BIF. The first alteration phase replaced silica-rich bands with siderite and/or Fe-rich dolomite; the second phase involved the removal of carbonate gangue minerals and the concentration of residual Fe oxide-rich bands in the BIF via volume reduction. The product is a high-grade, high-tonnage Fe orebody, with minor contaminants.2. Magnetite-bearing shear and fault zones cut BIF along lithological contacts. These zones of secondary magnetite formed as a result of the addition of hypogene magnetite via the circulation of Fe-rich, hypogene hydrothermal fluids through BIF. This type of mineralisation produces narrow (low-tonnage), high-grade magnetite-rich ore zones with high levels of contaminants (eg SiO2, Al2O3) due to the difficulty in mining these zones.3. Specular haematite ± quartz-bearing shear and fault zones cut residual orebodies and magnetite bearing structures. They share similar characteristics to magnetite-bearing structures.4. Goethite-haematite supergene ore zones are controlled by brittle faults that cut BIF. These faults promoted the flow of supergene fluids through BIF and resulted in large ore zones with variable Fe grades and contaminants.5. Detrital deposits comprise transported BIF fragments and are intensely goethite-haematite supergene-altered. These orebodies are locally extensive, with moderate Fe grades.

Jul 11, 2011

Solid Energy New Zealand (SENZ) uses a 20+ year period for integrated planning of all its business activities. It has an ongoing program of coal resource assessment to optimise future mines within this 20 year period, using a six step resource and mine planning process. Desktop review and conceptual study at preliminary Levels 1 and 2 are based on general coal resource information. Further coal resource investigations are carried out for the more detailed evaluations in secondary assessment, prefeasibility study, feasibility study and detailed engineering from Levels 3 to 6. At Levels 1 and 2, completing conceptual planning, including preliminary resource evaluation and economic appraisal to the target cost uncertainty level of ¦33 per cent, is challenging in New ZealandÆs highly variable geological and geographical conditions. Where coal deposit geometries are relatively simple, approximate methods for determining pit limits using overburden strip ratios, seam thickness, physical boundaries, and quality cut-offs may be sufficient. Many New Zealand coalfields are however complicated structurally, with multiple seams and extensive folding and faulting. Coal seams are characterised by variable dip, thickness, and quality over relatively short distances. In the North IslandÆs Waikato coalfields, coal is typically overlain by weak sediments and clay rich strata that necessitate very flat cut and fill slope angles. The proximity of these deposits to major infrastructure (including towns, highways and rail lines), significant environmental features such as the Waikato river and lakes, and valuable dairy farmland, add further complexity. Traditional preliminary mine planning techniques applied in these conditions are insufficient. Pit optimisation software, widely used in the metalliferous mining industry since the 1980s, offers the ability to analyse many more specific factors affecting pit limits, mine layouts, and economics, with more rigour and for a much larger number of scenarios, than traditional methods allow. SENZ therefore decided to adapt and use æWhittleÆ pit optimisation software for Level 2 analysis of several Waikato opencast prospects. This paper describes this work.

Jan 1, 2005

China has abundant bauxite resources, but these resources are mostly of a diaspore, which has a feature of low Al2O3 to SiO2 mass ratio, typically ranging from four to six. Compared to other materials, this kind of raw materials consumes more alkaline and energy in the process of metallurgy, and incurred a high alumina production cost. To solve this problem, researchers in China have done a lot of work on removing of the silicon from bauxite. Under the impetus of these works, in 2003, the first flotation plant of diasporic bauxite in the world was constructed in Zhongzhou, Henan, China. Seven years of operating experience shows that this technology can signifi cantly reduce the costs of following-metallurgy processing. These efforts are an important reference for the processing of similar resource. In general, for Western scholars it is diffi cult to fully understand these works because most of them are published in Chinese. In this paper, a detail introduction for the research progress on China bauxite de-silica flotation was presented, these works involved crystal chemistry, wettability of bauxite minerals, collector and modifi er in bauxite fl otation and flotation practice, etc.

Sep 13, 2010

Zinc sulphide concentrate from Mount lsa, Australia, was leached in acidic sulphate-chloride solutions using ferric ions as oxidants under atmospheric pressure. The parameters of temperature, particle size and concentrations of ferric and chloride ions were evaluated.The shrinking core model can be used to describe the leaching which is limited by the electrochemical processes in the initial leaching stage, and by both surface reaction and pore diffusion processes subsequently. The apparent activation energy measured in the initial leaching stage is 49 kJ/mole over the temperature range 60 to 90°C.About 99 per cent of the contained zinc in the -45+38 µm particle sample dissolved at 90°C in a 0.5 M H2SO4/0.1 M Fe2(SO4)3/0.8 M NaCI solution within two hours. Some nine per cent of sulphide sulphur was oxidised through to sulphate; the remainder was convened to elemental sulphur.The mixed sulphate-chloride system has advantages over separate chloride and sulphate systems due to the low reagent cost, high leaching rate and possible selective leaching of zinc sulphide concentrate with high lead contents.

Jan 1, 1994

By Ramsay WRH, Morand V

Structural, mineralogical, and textural data from the Tarnagulla Goldfield demonstrate that the area has undergone three significant phases of deformation. The first phase of deformation (Dl) predates the intrusion of the Tarnagulla pluton, which has been dated using K/Ar as 391 ¦ 5MY. We regard this pre-granite deformational event as the major regional deformation. Gold-bearing quartz veins have been deposited in dilational sites on west-dipping reverse faults. These sites demonstrate a geometry related both to faulting associated with Dl and the plunge of the Fl fold axes. This evidence, together with chronology of unmineralised ? D2 and D3 faults, the absence of quartz veining associated with D3 events, and the deformation of carbonate-quartz-biotite-sulphide aggregates within Sl by later S2, lead us to conclude that the bulk of the mineralisation was essentially syn- or late Dl. S'80 values for fluids in equilibrium with vein quartz from Central Victoria have indicated equivocal support for either a magmatic or metamorphic origin. Our evidence supports a pre-magmatic origin for mineralisation at Tarnagulla and hence tends to favour a metamorphic fluid source.

Jan 1, 1995

By Davey CJ

An integrated computer software system has been developed by Fluor Australia for modelling, mine planning and production scheduling of single or multi-strata deposits. Modelling of both quantitative and qualitative variables (e.g., thickness, basal elevation, density, grade/ash content) is performed via continuous, minimum curvature surface representations. These may be developed from inverse distance weighting or geostatistical kriging interpolation techniques in conjunction with bicubic spline surface interpolation. The modelling process, rather than being purely mathematical, incorporates facilities for reflecting structural geology interpretations (e.g., faulting, pinchouts) and geological boundary conditions (e.g., subcrop and outcrop). Volumetric programs provide the facility for continuous integration over models (at any specified integration increment) for any number of specified irregular polygonal panel areas or regular rectilinearly defined block plan areas. Multi-variable integration is available, incorporating any or all operations of addition, subtraction, multiplication and division to provide multi-strata tonnages, etc., (e.g., Volume 1 * density 1 + Volume 2 density 2). These programs provide true three-dimensional integration with the facility for calculating results on an area by area, level by level, strata by strata as well as overall basis.

Jan 1, 1983

By G L. Simmons, K M. LeVier, R Kappes

The low potential hydrophobic state of pyrite in amyl xanthate (PAX) flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at NewmontÆs Lone Tree Plant in Nevada. Initially, the N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments, and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Experimental results show the importance of the pyrite surface state and the rather interesting features of the activation process.

Jan 1, 2005

By G L. Simmons, K M. LeVier, R Kappes

The low potential hydrophobic state of pyrite in amyl xanthate (PAX) flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at NewmontÆs Lone Tree Plant in Nevada. Initially, the N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments, and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Experimental results show the importance of the pyrite surface state and the rather interesting features of the activation process.

Jan 1, 2005

By D R. Lueking

A technology involving separate unit processes for the generation and use of ferric ions for the oxidation of sulphidic minerals has been developed. The technology utilises a stand-alone automated bioreactor for ferric-ion generation (termed SAAB-FIG) and produces a low pH, ferric ion-rich leach liquor with a high oxidation potential. This leach liquor is then employed, in a separate unit process, to oxidise sulphidic minerals and regenerate ferrous iron that may subsequently be recycled to the bioreactor for the continual generation of ferric ions. The technique was successfully applied for the recovery of copper from chalcocite (Cu2S) and chalcopyrite (CuFeS2), as well as other ores and concentrates containing copper sulphide minerals. Coarse ore, ground ore and concentrates were treated with acidic solutions containing 8 to 12 (g/L) Fe(III) ions at a variety of temperatures. This process yielded over 50 per cent of the contained copper from both chalcopyrite and chalcocite samples. Maximum reaction rates and copper recoveries were found to be highly dependent upon temperature and pH and leach liquors containing bacterial cells displayed little difference in their leaching efficiency when compared to cell-free leach liquors.

Jan 1, 2000

By Duke J. H

Advanced computer aided geological modelling techniques are now available to the geologist to allow the rapid evaluation of a gold orebody at various stages of its development. The types of grade estimation techniques used change during the various stages as the density of drilling and knowledge of the deposit increases. At the prospect evaluation stage drillhole intercept selection techniques are coupled with preliminary 2D (vein or layer) modelling or 3D block modelling techniques to arrive at a geological resource estimate. At the prefeasibility and feasibility stages more sophisticated 2D and 3D modelling techniques, such as domain controlled grade interpolation with anisotropy, are used along with interactive open pit and underground mine design, to calculate recoverable reserves. At the production stage closely spaced blasthole sample data is modelled quickly and coupled with interactive grade control facilities. Shot volumes, tonnages and grade estimates can be databased to provide reconciliation figures. These modelling techniques are embodied in MINEX-3D, an Australian software system which, with the emergence of the 386-based PC and high resolution (VGA or better) graphics, makes a whole range of advanced geological modelling techniques available to most exploration and mine geologists.

Jan 1, 1989

Adsorption isotherms, zeta potential and coagulation techniques have been used to exa- mine the mechanism of metal activation on SiO2 and ZnS surfaces. The importance of surface nucleation or precipitation of metal hydroxide coatings is'established and identified-by characteristic charge reversal patterns. The significance of surface coatings in sulphide and non-sulphide flotation is discussed.

Jan 1, 1973

By Ono K, Oishi T

Electrochemical determination of the oxy- gen partial pressure in the Fe-0-SiO 2 ternary systems saturated with solid silica was done by measuring the activity of oxygen in a silver bath in equilibrium with the molten slags using zirconia solid electrolyte galvanic cells. From the data obtained, the activity ~Faii.st composition relations were calculated

Jan 1, 1980

By Zhijing Z, Huiling Z

The influences on flotabilities of dolomite and magnesite with modifiers and influences on the function of collectors and modifiers with Mg+z Ca+2 were studied. The flotation results of artificial mixed mineral showed that using combined salified water glass and (NaPO3)6 as a modifier for magnesite-dolomite separation can obtain an excellent Selectivity.

Jan 1, 1993

The production of 100,000 tonnes per year of synthetic rutile from the processing of ilmenite, coal and copperas (iron sulphate) produces 200 cubic metres per hour of effluent water. A 2.0 hectare biological filter, comprising natural and man- made wetlands, has been built into the last stage of the effluent water treatment system. It is an area of shallow water (

Jan 1, 1988

Discovered in 1954 and mined since 1966, the X41 copper orebodies have produced over 143 Mt @ 3.3 per cent copper. By June 2002 the production from these orebodies had depleted the Mineral Resource to 36.6 Mt @ 2.8 per cent Cu (including 31.5 Mt @ 2.5 per cent Cu combined 2002 Ore Reserve). Mine production will ramp down to cessation beyond ten years. The 2002 Copper Business Study was commissioned to review the status of the Mount Isa copper business and to optimise the long-term strategy of the operations. The study resulted in a vastly improved geological and geostatistical model, and financial studies led to the optimisation of mine cut-off grades. Utilising these new models, a near-mine target generation workshop was conducted by the copper stream geology team. The workshop focussed on exploration for new ore sources and the extension of existing orebodies to supplement the Mineral Resource inventory for future conversion to Ore Reserves. Several prospective targets were identified and the Conceptual Northern 1100 Drilling program was subsequently designed. This paper shall discuss the practicalities of near-mine target generation in Mount Isa, the issues faced when locating and preparing drill sites in a mature mine environment, and the preliminary results of the drilling program so far.

Jan 1, 2003

By Oxenford R. J

An important rutile-ilmenite-zircon bearing sand deposit was discovered by local farmers at Eneabba, 300 km by road north of Perth in 1970. These heavy minerals occur in a series of ancient strandlines and associated dunal deposits at elevations from 85 m to 170 m above the present sea level and are situated,30 km inland. The strandlines were deposited on wave- cut platforms in an ancient bay bounded by Mesozoic sediments during a series of regress- ions from a high sea level, probably during late Tertiary or early Pleistocene times. The immediate source of the heavy minerals in the Eneabba deposit is a widespread low content of those minerals in the nearby Mesozoic sedi- ments. The high-grade southern portion of the Eneabba deposit has been closely drilled and is now being prepared for production by Allied Eneabba.Pty. Ltd., a subsidiary of Allied Minerals N.L. This part of the deposit is 11 km long and up to 2.5 km wide. It is characterised by little or no overburden and the average depth of mineralisation, bounded by a 2.5 per cent heavy mineral cut-off, is 12 m. The water-laid strandline deposits at the base of the mineralisation are generally high grade, ranging from 20 to 60 per cent

Jan 1, 1973

By E Haren, A Winchester

The CSA Mine has a long and varied history from initial discovery in 1871 through to the present. Lead-zinc mineralisation was mined historically near the surface. Today copper and silver are extracted from the deeper regions of the mine. The mine has passed through a number of owners over this time, each with a unique operating philosophy and understanding of the mineralisation. Cobar Management Pty Ltd re-opened the mine in 1999 and has undertaken extensive drilling programs to expand the resource and gain a better understanding of the mineralisation characteristics. Presently mineralisation has been located over a strike length of 1.2 km and to a depth of over 2.0 km with over 30 mineralised lenses from four identified ore systems. The refinement of geological and mineralisation models led to further discoveries and prompted a review and modification of resource modelling processes. Advanced statistical analyses prompted the implementation of ordinary kriging as a grade estimator. Improved stationarity from enhanced geological domaining has been supported by variography and kriging neighbourhood analysis studies. Resource models at CSA are now quantifiable in terms of mineralisation style and estimation reliability. The new techniques are assisting the definition of more mining fronts, which are creating new opportunities to increase mine output.

Jan 1, 2006

By T Tran, F Lucien

Supercritical fluids (SCFs) have gained recognition as solvents for the extraction of a wide range of organic materials. Their principle advantages over conventional organic solvents are that they possess much more favourable transport properties and that such properties can be easily altered by adjusting the system temperature and/or pressure. More recently, SCF solvents have been employed in the extraction of metal ions. The direct extraction of metal ions using SCFs such as CO2 is normally not possible due to the charge neutralisation requirement for solubilisation. However, extraction can be achieved with a SCF solvent containing an organic complexing agent as a cosolvent (Laintz et al, 1992; Laintz and Tachikawa, 1994; Dehghani, 1996). The role of the SCF is therefore similar to the role of a diluent in conventional liquid-liquid or solvent extraction processes. In this regard, SC-CO2 is a particularly good diluent since it exhibits good solubility for many organic complexing agents. The extraction of metals with SCF solvents has been examined mainly in the analysis of environmental samples and the treatment of metal contaminated wastes. Nonetheless, some interesting results have been reported recently on the extraction of rare earth metals, which highlight the potential of SCF solvents in mineral processing applications (Laintz and Tachikawa, 1994; Dehghani, 1996).

Jan 1, 2000

By Moorrees C

Carbonic acid leaching of crude iron-containing magnesia derived from Savage River magnesite yields a magnesium bicarbonate leachate with a substantial soluble iron concentration. The iron concentration depends upon the leaching conditions (particularly time, temperature and pulp density) but is generally in the range 0.005-0.5 g/litre. If this soluble iron is not removed prior to the precipitation of the magnesium as a hydrated carbonate, then this product will be contaminated by the iron, and will not yield a final product (high-purity magnesia) that meets specifications.The soluble iron content of the magnesium bicarbonate leachate can be reduced to an acceptable level by addition of solid aluminium sulphate either during carbonic acid, leaching of the crude calcine or to the clarified leachate. Chemical analysis and X-ray diffraction revealed that the iron is precipitated as an iron-containing hydrotalcite-type compound, [Mg6(Al,Fe)2(OH)16]CO3.4H2O. The actual composition of the precipitate depends on the amount of aluminium sulphate added and the precipitation technique used. Because precipitation of iron in this manner also results in reduced magnesium recovery from the leachates, It WIll be necessary to develop methods for recovering the magnesium component of the precipitates.

Jan 1, 1984