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By Steve Dubnewych, Jon Kaneshiro, Calvin Jin

The Joint Water Pollution Control Plant (JWPCP), operated by the Sanitation Districts of Los Angeles County (the Districts), treats wastewater generated by over3 million people and processes wastewater solids generated by over 5 million people. The JWPCP Tunnel and Ocean Outfall Project, if constructed, would be one of the major marine outfall projects in the world. The new tunnel and ocean outfall system would provide relief to the existing outfall and allow inspection, maintenance, and repair of the existing tunnel and outfall system, portions of which were constructed as early as the 1930s. Geologic conditions are challenging along the alignments within the study are a being considered. Conditions include saturated alluvial soils, weak sedimentary rock, mixed face conditions, and squeezing ground conditions. Other significant challenges include the potentials for encountering up to 11 bars of water pressure, crossing seismically active faults, and encountering gassy and contaminated ground conditions. This paper discusses the details of the proposed project and the associated challenges.

Jan 1, 2007

By G. Huang, S. Vytla

Computational fluid dynamics (CFD) is a continually developing numerical technique by which complex fluid flow problems can be solved on computers. To be able to transfer CFD expertise to analyze and design a face-ventilation system, a comprehensive validation study of current CFD tools against mining-related benchmark experiments is required. In the last four years, such studies, funded by National In¬stitute for Occupational Safety and Health (NIOSH) under Grant #R01 CCR415822, were conducted in the Department of Mining Engineering at the University of Kentucky. A wide array of ventilation schemes and mining configurations were considered. Recently, an additional study was performed in cooperation with the NIOSH Pittsburgh Research Laboratory. This study was dedicated to the methane behavior in the empty (containing no equipment) face area with a blowing curtain and a 10. 7-m (35-ft) setback. In this paper, the authors present and discuss the computer-simulation data and compare them with data collected during the laboratory studies at the NIOSH lab.

By Ralph Harris, Qi Xia

"Gold cyanidation rates are known to be limited by the rate of oxygen dissolution in the cyanidation tanks. The effect of solids loading on the oxygen dissolution rates is not obvious and the results of previous studies are ambiguous. The present paper presents an analysis of oxygen dissolution rates using a ""spent"" commercial gold slurry diluted to various levels of solids loading. It was found, in an 170 litre stirred tank reactor using an inverted cone sparger, that under certain high loading conditions, there was a decrease of as much as 50 %, i.e., there was a halving of the rate of oxygen dissolution as compared to that in clean water. In particular, it was observed that, due to gas flooding of the impeller, there was a drop in kLa even with an increase of gas velocity. Gas holdup reached a maximum value of only 1.7 %. The total power consumption was between 0.06- 0 .10 kw/m3 within the range of gas velocity before flooding occurred. The decrease in oxygen dissolution rate with increased solids loadings is believed to be mainly due to the increase in the apparent viscosity which reduced the turbulence and shearing effect and resulted in larger bubbles and hence reduced the reaction area a. The interrelations between solids loading, gas holdup, flow pattern, power consumption, and liquid mass transfer coefficient are discussed.IntroductionThe reactors generally used in gold cyanidation are Stirred Tank Reactors (STR). Compared with other types of reactors like fluidized bed reactor and column reactor, STR is of particular importance due to its wide application in industry. It is reported that the stirred tank reactor is used for more than 50 % of the world's chemical production (Xu and McGrath, 1996)."

Jan 1, 1997

By D. J. Thorkelson

New data indicate Wernecke Breccia-associated iron oxide copper-gold (IOCG) deposits likely formed from moderate-temperature, high-salinity, non-magmatic brines. The breccias formed in an area underlain by a sedimentary sequence that locally contained evaporites (potential source of chloride and possibly sulfur) and was thick enough to produce elevated fluid temperatures. Metals (Fe, Cu, Co, U) were probably derived from host strata, transported as chloride complexes, and precipitated due to changes in fluid temperature and pressure during brecciation. These new data suggest that the spectrum of genetic models for IOCG deposits that typically invoke formation from magmatic or hybrid magmatic-non-magmatic fluids should be expanded to include those systems that formed in a non-magmatic environment. Modifications to the definition of IOCG systems are proposed that reflect the degree of involvement of magmatic and/or non-magmatic fluids and the nature of the mineralizing environment. A division into magmatic, non-magmatic, and hybrid magmatic-non-magmatic IOCG types is suggested. Typical magmatic end-member IOCG deposits include Lightning Creek and Eloise, Australia. Hybrid magmatic-nonmagmatic IOCG examples include Ernest Henry and Olympic Dam, Australia. The Wernecke Breccia and Redbank deposits are suggested as possible representatives of non-magmatic IOCG end members. Endmember magmatic IOCG deposits have similarities to some porphyry deposits, whereas non-magmatic IOCG end members share characteristic with some sediment-hosted Cu deposits, suggesting that the range of IOCG deposits may form a link between intrusive- and sediment-related deposits

Jan 1, 2007

By R. Schwarz, E. Pusch, A. Juch

"The paper describes in general the objectives, goals as well as theoretical background of "METSI"-project proposal submitted to German BMBF (Federal Ministry of Education and Research). The METSI project is a starting point for technology and know-how transfer of German water management and water treatment technologies to South African Mining industry. "METSI" is Setswana, one of the eleven official languages in South Africa, and means "water". It stands also for "Management System for the Implementation of Environmentally Sound Water Supply Technologies in South African Mining Areas with Involvement of all Relevant Stakeholders". The project focuses on development, design and implementation of mathematical models that consolidate and evaluate existing data and generate substantiated projections of "water" amount and quality. METSI covers a wide range of scientific, technical, social as well as economic questions related to "water in mining"."

Jan 1, 2011

By Benkendorff P. N

Cement production in Australia approximates 6.5 million tonnes per year. Cement clinker is sourced from 15 plants which operate 28 kilns. Cement grinding is conducted at 14 of the clinker plants plus 7 grinding plants. Average annual capacity per kiln or plant is lower than in many overseas countries, but kilns introduced since 1970's have been of larger size more in keeping with size trends overseas, although still smaller than the large units overseas. Substantial economies in capital and labour costs can be achieved in large production units, particularly with dry process kilns using precalcination techniques in which part of the fuel is introduced in the static preheater section ahead of the kiln while the balance is added to the kiln in a conventional manner. Precalcination techniques have been introduced to the Australian cement industry but as cement transport costs form a major part of supplying diverse market areas, the size of kilns is likely to remain less than maximum owing to balance with distribution costs. The cement industry uses significant amounts of thermal and electrical energy which can be minimised by proper selection of equipment and technology. Labour costs are also significant and can be contained by automation and computer control of the process.

Jan 1, 1989

By D. -H. Park, G. -j. Kim, Y. -J. Park, C. -S. Hong, S. -Y. Choo

To evaluate the quantitative tunnel behavior influenced by characteristics of discontinuity, this pa-per executes the parametric study using 2 and 3-dimensional DEM analysis. First of all, this study finds that displacement and the stress of shortcrete are proportioned to frequency of joint and rockbolt axial force is adversely proportioned too. Secondly, it is found that the most sensitive in-put parameter used in Barton-Bandis(BB) model is residual friction angle. Finally, when joint sets are encountered at tunnel excavation face, to identify the most critical joint orientation is very crucial for a stability of tunnel. La thèse a pour but d’étudier les influences sur la stabilité du tunnel, au niveau du réseau de la discontinuité et de la valeur de sa nature aquis par le projet récemment exécuté en vue de mener à l’analyse quantitative de cette stabilité, en appliquant chaque différent paramètre comme la fréquence de diaclase, la constante de résistance des modèles de Barton-Bandis(BB) ainsi que la relation entre le sens d’excavation du tunnel et le réseau de diaclase en 3 dimensions. En fait, cette étude nous a montré que la fréquence de diaclase s’accroît proportionnellement au déplacement et à la contrainte du béton projeté. L’angle de friction résiduel s’est montré le plus sensible à la stabilité du tunnel parmi les modèles de BB. Aussi à travers l’analyse à 3 dimensions, il s’est vérifié que si l’angle de pente du groupe de diaclase est horizontal entre l’axe du tunnel et la direction, il donne une influence importante sur le comportement du tunnel. En particulier, l’influence était la plus importante sur un fond rocheux dont la diaclase horizontale est grande. Um das quantitative Verhalten des Tunnels zu bewerten, eroertert dieses Papier eine parametrische Studie mit Hilfe der DEM Analyse. Auch wird hier eine zweidimensionale Analyse von Ver-bindungen verschiedener Frequenzen in der Gesteinsmasse, eine sensitive Analyse von allen der im Barton-Bandis-Modell (BB) genutzten Parameter und eine Dreidimensional-Analyse mit ver-schiedenen dreidimensionalen geometrischen Veteilungen von Verbindungen ausgefuehrt. Erstens: Die Studie findet heraus, dass Vedraengung und Druck im Shortcrete proportional zur Frequenz von Verbindungen und Axialkraft der Steinbolzen antiproportinal ist. Zweitens: Es wird herausge-funden, dass die am meisten Sensitiven der im BB-Modell angewendeten Eingaben die am Ende uebriggebliebenen Reibungswinkel sind. Und schliesslich wird herausgefunden, dass wenn Ver-bindungsteile an der Tunnelaushoelungsoberflaeche ausgemacht werden, fuer die Tunnelstabiltaet die Identifikation der meist kritischen Verbindungsorientierung sehr bedeutungsvoll.

Jan 1, 2003

By Ralillie Lopes Carvalho

O presente trabalho apresenta um estudo da influência do tratamento de nitretação a plasma sobre a dureza de lâminas utilizadas em prensa-facas de um picador de toras industrial. Tais peças são fabricadas em ligas com alto teor de Cromo e Carbono, assemelhando-se quimicamente aos aços para trabalho a frio AISI da série D. Para o estudo em questão, pequenas amostras das lâminas receberam tratamento térmico de têmpera e duplo revenido,e posteriormente foram nitretadas a plasma por 30, 90, 180, 360 minutos, em temperatura de 450°C, com pressão fixada em 2 Torr e mistura gasosa de 20%N2 e 80%H2. Logo após foram realizadas análises metalográficas com auxílio de microscópio óptico, ensaio de dureza superficial e perfil de dureza com microdurômetro em escala Vickers. Os resultados mostraram que para todos os tempos de tratamento houve endurecimento superficial em relação ao material não tratado, onde o tempo de 180 minutos propiciou a formação de camada com maior valor médio de dureza superficial “1171,20 HV”.

Aug 16, 2017

By Frank R. Field, Randolph E. Kirchain, Elisa Alonso

"There are a number of environmental incentives for increasing recycling, including the reduction of waste, energy and resource use. Recycling can also be advantageous for manufacturing firms in both the short and long term. Secondary material can substitute for primary material, potentially dampening primary material price increases and reducing the pressure for greater primary extraction. This paper examines the potential for and dynamics of recycling for the case of platinum using a dynamic, behavioral simulation model of the primary and secondary markets. Since the secondary supply of platinum depends on a supply chain separate from primary extraction, recycling can diversify the risks of primary supply instabilities. Over time, recycling can cut primary consumption, reduce overall costs to firms, and possibly reduce the impact of price fluctuations upon firms.IntroductionThe benefits of recycling, from the perspective of the environment, are many, and the environmental benefits of increased recycling are considered a step towards increased sustainability [1, 2]. Life cycle assessments indicate that obtaining materials from secondary sources generally requires less energy and has fewer environmental impacts than extraction and refining of primary materials [3]. Analyses of materials flows show that, in addition to landfill volume reduction, recycling reduces primary material consumption, affecting long term materials scarcity [4, 5].The benefits of recycling are not limited to the environmental. Firms can benefit from the lower energy costs of recycling, especially that of metals whose primary extraction and refining are particularly energy-intensive (e.g., aluminum). The routine participation by firms in secondary materials markets (e.g., www.recycle.net) shows that this advantage has not gone unnoticed.Recycling can also benefit firms whose costs can be significantly affected by changes in material prices resulting from material shortages and material scarcity, with potentially permanent effects upon firms [6-8]. This paper focuses on the impact of recycling in the face of platinum scarcity for supply chain downstream firms."

Jan 1, 2008

By S. Tuttle, R. Sisson

"Suncor Energy Inc. has proposed a 2.2 billion dollar expansion to the current oil sands operation, which will more than double the productive capability of the facility. As part of the application for this expansion, a comprehensive closure plan had to be developed and filed.Closure planning includes a systematic evaluation of the area to be developed, the development activities planned, the goals and objectives of the corporation in re-establishing landforms and ecosystems at the same time as running an effective operation. As early as is practical during the mine development, surface contouring is completed, soil is reconstructed, and vegetation, surface drainage and wetlands are re-established. Once active reclamation is complete and vegetation has been re-established, Suncor monitors maturation of landscapes and ecosystems to provide the submission basis for reclamation certification"

Jan 1, 1999

Rheological Behaviour of Clay-Rich Gangue Mineral Dispersions During Hydrometallurgical Treatment Alumino-silicate minerals invariable may present an intractable challenge in hydrometallurgical operations employed in low grade nickel, copper and gold ore leaching or high level nuclear waste (HLNW) processing. The interactions and reactivity of alumino-silicate clay gangue minerals such as muscovite/sericite, chlorite, kaolinite and smectite under acidic (eg pH <3) or alkaline (pH >13) conditions can have a striking impact on the particle interactions. These may manifest in undesirable pulp rheology, poor extraction rates and challenges in the subsequent "handleability" and solid-liquid separation processes (eg dewatering). In the present work, a review of investigations involving the interfacial chemistry, interactions and rheological behaviour of aqueous dispersions of mica-group, layered alumino-silicate clay (muscovite / sericite) and chalcocite minerals as a function of pH in the range 2 - 9 and time at 25¦C, is presented. Particle zeta potential, reflecting interfacial chemistry, indicated a strong pH-history and particle volume fraction dependency. Pristine particles' zeta potentials measured from high to low pH indicated mineral-specific isoelectric point (iep) at pH range 2 - 5. Subsequent measurements from low to high pH showed pH-history dependency with iep shift to higher pH values, the extent of which also depended upon particle volume fraction and aging time. Pulp pH-mediated particle interactions revealed by shear yield stress analysis displayed a bifurcation behaviour and good compliance with DLVO theory. The maximum pulp yield values occurred at the iep whilst weak rheology was observed where the magnitude of the particle zeta potential was greatest. The pivotal role played by both pulp chemistry and suspension conditions in regulating the particle interactions and concomitant rheological behaviour is highlighted. The implications of the findings with regards to clay-base pulps' handleability and its control during aqueous processing are discussed.  

Sep 13, 2010

By Ajoy K. Singh, B Mohanty, P K. Singh

A study was conducted to investigate the damage potential to underground multiseam openings caused due to vibration generated by open-pit coal mine blasting. The objective was to recommend optimal explosives weight per delay to be detonated in open-pit blasts to ensure the safety and stability of underground openings. Sixteen blasts with varying charge weights and initiation sequences were conducted at Samleshawari open-pit mine and eighty four blast vibration data were recorded in the Hingir Rampur underground colliery in India. Analysis of vibration data showed that roof of the underground openings vibrated with much higher amplitudes compared to those in pillars and floors. The amplifications of vibration in the roof at the junction were upto 4.3 times the pillar vibration. It was observed that coal chips detached from roof when the peak particle velocity reached 131 mm/s or higher. The vibration magnitude recorded was higher in upper-seam openings than in belowseam openings. Rapid attenuation of vibration was recorded in below-seam openings at similar locations. Appropriate particle velocity-charge weight-distance equations were established to calculate the safe explosive weight per delay to be detonated in open-pit mine for the safety of multi-seams workings of underground mine. The support for the galleries and junctions were further modified for the working seams to ensure greater safety.

Jan 1, 2011

By Shinji Sassa, Naoki Takahashi, Eiji Kohama, Wakaki Tsuda, Hidenori Takahashi, Ikuo Towhata, Yoshiyuki Morikawa

"Abstract Deep mixing method has been employed increasingly in recent years as a countermeasure against subsoil liquefaction. Column-type solidification, however, has been thought to have little effect as a liquefaction countermeasure, because the shear deformation of unimproved soil between the columns cannot be reduced. In recent years, experimental results have been reported that imply that solidified columns can reduce the shear deformation of unimproved soil around them. A new arrangement has been proposed to mitigate lateral flow induced by liquefaction. In this study, a series of dynamic centrifuge model tests was conducted to verify the lateral flow resistance of stabilized columns. The results indicate that stabilized columns can reduce the lateral flow of liquefied ground if the column displacement and the column head rotation are restricted. This paper concludes that it is important to restrict the displacement and the rotation of the column head by surface improvement to mitigate the lateral flow of liquefied ground.INTRODUCTIONDeep mixing method has been employed increasingly in recent years as a countermeasure against subsoil liquefaction. The solidified body formed by the deep mixing method is usually block or lattice shape, composed of solidified columns that overlap each other horizontally. Lattice-type solidification has been shown to be effective as a liquefaction countermeasure despite the presence of unimproved soil inside the lattice wall, because the shear deformation of the interior soil is restrained by the wall (Suzuki et al., 1989). On the other hand, it has been thought that column-type solidification cannot reduce shear deformation of unimproved soil around columns, because the displacement of a solidified column is less restricted than that of a lattice wall. Column-type solidification has been reported to have little effect as a liquefaction countermeasure, but to be superior in terms of construction cost and applicability around existing underground structures (Koga et al., 1986). However, there are experimental results implying that solidified columns have reduced the shear deformation of unimproved soil and mitigated its liquefaction (Yasuda et al., 2003; Tanaka et al., 2003). Yamamoto et al. (2006) conducted dynamic analyses of ground improved with lattice- and column-type solidification. Their results showed that column-type solidification with an improvement ratio of more than 35% reduces excess pore water pressure generated by earthquakes. Furthermore, the new column arrangement shown in Figure 1(a) has been proposed to mitigate lateral flow induced by liquefaction. It was developed and has been verified using dynamic model testing in a 1 g field (Takahashi et al., 2010a; 2010b; 2013; Towhata et al., 2010). The stabilized columns in this configuration interrupt lateral flow in any direction, unlike those placed in square and triangular arrangements."

Jan 1, 2014

By A G. Mitchell

Stream sediment geochemical analyses were collated from open-file mining company reports and assembled in the REGCHEM computerised database at the Institute of Geological and Nuclear Sciences Limited. The database operates on an IBM-compatible PC microcomputer using an application programmed in dBASE IV and termed GEOEXPL. By August 1992, data for 6383 stream sediment samples from 6335 different sites in the Coromandel Peninsula region (Hauraki Goldfield) were entered, giving a total of 29 292 separate elemental analyses. Preliminary statistical analysis using PROBPLOT on a set of data collected by AMOCO from the Mahakirau-Whangapoua area shows that these data are a complex mix of subpopulations related to mineralisation and different source rock types. Thresholds of 37 ppm copper, 31 ppm lead, 112 ppm zinc, and 2.3 ppm molybdenum, defmed by arithmetic models for the combined data set, separate the individual element sets into 'first order anomalous/lesser anomalous and background' subpopulations as follows: copper five per cent/95 per cent, lead five per cent/95 per cent, zinc one per cent/99 per cent, and molybdenum 15 per cent/85 per cent.

Jan 1, 1992

By Eric Schraml

Wardrop Engineering and the Placer Dome?s Campbell Mine Design Team utilized leading edge directional raise boring techniques and an innovative, remote controlled application of steel fibre reinforced shotcrete ground support to achieve improved mine ventilation and a superior, safety focused secondary emergency egress. While more standardized methods may have provided a sufficient solution to either the requirement for a ventilation raise or for a traditional escape ladder way, innovative methodology ensured both objectives were met with a single, enhanced solution. Placer Dome committed to provide a solution that minimized energy consumption, optimized air delivery and facilitated an escape way focused on minimizing the negative physiological aspects associated with mine evacuation. The project was successful in providing a new airway, returning 47 m3/s (100,000 cfm) from the 39 Level to 30 Level, minimizing risk to the raise equipping crew and providing a fully equipped escape hoist. The resulting secure escape environment provided an efficient means of evacuating personnel working at depth without necessitating a potentially dangerous exhausting climb to surface. The project has substantiated, that optimized safety focused design can be achieved without jeopardizing project economics.

May 1, 2002

By Fernando Romero Lage

"Crushing and screening theory and application has remained fairly consistent in the last 50 years. The application of such equipment is guided by varied formulaic conventions and rules that due to the entropic nature of the process, remains more an art than a science. The variability of conditions creates an environment in which trial and error becomes the principal means of process balance and control. This paper illustrates some of the theories behind the process, plus other assumptions, postulates, myths and misconceptions that exist within the crushing and screening industry.INTRODUCTIONContinuous material balance calculations are habitually performed in the design of new comminution circuits as well as in the valuation of existing circuits. A continuous material balance calculation is one in which the input rate of material is equal to the output rate for each unit functioning in the circuit. At continuous analysis, there is no accumulation or losses of material within the system, as it is when performing a discrete event analysis.In order to produce viable and manageable mine-to-mill material, whether it is ready to leach or ready to mill, we must reduce the material in a series of stages. The power demand increases as the material size decreases, as it is when folding a piece of paper successively. As with the paper, there is a crushing size limitation that is a consequence of the mineral properties such as work index, moisture, viscoelasticity, etc. Comprehensive knowledge of crushing plants in both the aggregate and the mining industries show that, after three stages of crushing, a particle size distribution originating from a blasted deposit can be reduced from an nominal maximum size of 500 mm to a nominal maximum size of 12 mm. if the last stage of crushing is set in closed circuit, the screen openings will be able to yield a smaller top size.Achieving steady and continuous material balance poses major difficulties as crusher lose their settings, screens blind or peg, and material characteristics change geographically or seasonally. Overloading conditions in crushers and screens are nothing but counterproductive, and the net losses of an unbalanced circuit can be overlooked when mining operators are paying a lot more attention to the evermore complex systems downstream.It is not simply the crushing of the mineral but achieving the right size for the downstream milling process that will yield the maximum amount of energy savings."

Jan 1, 2010

By E. D. Gardner

Open-cut mining of copper ores in the western United States is a relatively new industry. At first the mining methods were mainly adapted from those used at open-cut iron mines and at quarries, but now efficient practices that are more suitable for the copper deposits have been developed. The pioneer in this field is the Utah Copper Co., of Bingham, Utah, which deserves great credit for working out much of the early procedure. Stripping began at that mine in 1906, and the large Garfield concentrator was put in commission in 1908. Next in order of development were the Nevada Consolidated Copper Co., at Ely, Nev. ; the Chino mine of the Ray Consolidated Copper Co., at Santa Rita, N. Mex. ; the New Cornelia Copper Co., at Ajo, Ariz. ; the Sacramento Hill mine of the Copper Queen Branch, Phelps Dodge Corporation, at Bisbee, Ariz.; and the open cut of the United Verde Copper Co., at Jerome, Ariz. The Sacramento Hill mine began to produce in 1923, and the United Verde open-cut mine has produced ore mainly in connection with stripping. The writer visited the Utah Copper mine in September, 1923; the Nevada Consolidated in August, 1923; the Chino in July, 1924; and the New Cornelia, the Sacramento Hill, and the United Verde open cut at various times during 1922, 1923, 1924, and 1925, mostly in connection with other work.

Jan 1, 1927

By John Reilly

Traditional methods of project procurement of have remained virtually unchanged in the U.S. infrastructure construction industry for more than 50 years. The traditional method, Design-Bid-Build (DBB), uses a two-step process that separates planning and design from construction. Design is generally done by the public agency and their consultants and the subsequent construction contract is procured from the private sector, almost always by a “low-bid” approach. This method has worked well for many projects, delivering quality work for the lowest bid price. This is particularly true for those projects where the work, and the public agency’s management procedures, are well understood by the contracting community and there is relatively low uncertainty in the work or conditions, particularly geotechnical conditions for underground construction. However, concerns exist with the DBB process. It is time consuming because all planning and design work must be completed prior to beginning any construction work and it is of concern for complex or large projects, plus those with significant risk, where the separation of design and construction, in conjunction with pressures resulting from the low-bid environment, often result in substantial cost and schedule increases. Frequently, these increases occur in a non-productive, inefficient, adversarial work environment leading to claims, disputes and costly litigation (Quick 2002).

Jan 1, 2007

By R. Hansson

Zincite and spinel phases are present in the complex slag systems encountered in zinc/lead sintering and zinc smelting processes. These phases form extensive solid solutions and are stable over a wide range of compositions, temperatures and oxygen partial pressures. Accurate information on the stability of these phases is required in order to develop thermodynamic models of these slag systems. Phase equilibria in the Fe-Zn-O system have been experimentally studied for a range of conditions, between 900 and 1580°C and oxygen partial pressures (pO2) between air and metallic iron saturation, using equilibration and quenching techniques. The compositions of the phases were measured using Electron Probe X-ray Microanalysis (EPMA). The ferrous and ferric bulk iron concentrations were determined using a specially developed wet-chemical analysis procedure based on the use of ammonium metavanadate. XRD was used to confirm phase identification. A procedure was developed to overcome the problems associated with evaporation of zinc at lowpO2s and to ensure the achievement of equilibria. An isothermal section of the system FeO-Fe2O3-ZnO at high ZnO concentrations at 1200°C was constructed. The maximum solubilities of iron and zinc in zincite and spinel phases in equilibrium were determined at pO2=1*10-6atm at 1200and 1300°C. The morphology of the zincite crystals sharply changes in air between 1200 and 1300°C from rounded to plate-like. This is shown to be associated with significant increase in total iron concentration, the additional iron being principally in the form of ferric iron. Calculations performed by Fact Sage with a thermodynamically optimized database have been compared with the experimental results. Keywords: Phase Equilibria, Fe-Zn-O, Quenching, Wet-Chemistry, EPMA, XRD, ISP.

Jan 1, 2004

By A. Muwila

Hercules? is a low nickel austenitic stainless steel developed at Mintek that has a typical composition of 9 wt% Mn, 0.05 wt% C, 2wt% Ni, 0.25 wt% N and 16.5 wt% Cr. A more corrosion resistant version of Hercules? (Hercules? B) with 0.5 wt% Mo has also been developed. Potentiodynamic tests performed on Hercules? B in a 5wt% sulphuric acid solution showed it to have improved corrosion resistance comparable to that of AISI 304. The effect of a varying Mn content on the corrosion resistance of Hercules? B has also been investigated and the results discussed in this paper. From the corrosion test results, it is clear that decreasing the Mn content of Hercules? B increased the corrosion rate, while increasing it decreased the corrosion rate. Keywords: austenitic stainless steel, % ferrite, molybdenum, manganese, nitrogen, electrochemical corrosion tests, potentio-dynamic scans, microstructure, chemical analysis.

Jan 1, 2007