Search Documents

By Richard Dahl, Richard P. Taylor, David H. Watkinson

"Abstract - Detailed mapping of the Eastern Gabbro, Coldwell Complex, Ontario, revealed that the copper and platinum-group-element deposit on the Marathon property is confined to a coarsegrained to pegmatitic gabbro-diorite intrusion, the Two Duck Lake intrusion (TDLI). Exposed along the eastern boundary of the Coldwell Complex, the TDLI was emplaced as a sill whose orientation is slightly oblique to the general structure of the Eastern Gabbro. The TDLI has been subdivided into lower, middle and upper sub-units on the bases of lithological, textural, mineralogical, and geochemical criteria. Both border sub-units are sulfide-, base- and precious metal-enriched, and exhibit abundant evidence of host-rock assimilation. The primary mineral assemblage in the TDLI is plagioclase, olivine, clinopyroxene, Fe-Ti oxides, with accessory orthopyroxene, biotite, apatite; this primary mineral assemblage is essentially preserved in the core of the intrusion (i.e., the middle subunit). The Cu-PGE Marathon deposit, delineated mainly in the upper sub-unit of the intrusion, consists of disseminated Fe-Cu-Ni sulfides, and platinum-group-minerals derived by hydrothermal remobilization from primary magmatic sulfides. Enrichment in Cu and PGE resulted from partial replacement of original Fe-Ti oxides and pyrrhotite in the primary mineral assemblage by reaction with (a) residual magmatic fluid, and (b) fluids derived from the breakdown of host rock xenoliths and hydrothermal alteration along the lower contact of the TDLI. Résumé - La cartographie détaillée de l’Eastern Gabbro, Complexe Coldwell, en Ontario, révèle que le gisement de cuivre et éléments du groupe du platine de Marathon est confiné à une intrusion gabbro-dioritique, de grain grossier à pegmatitique, l’intrusion Two Duck Lake (TDLI). Cette intrusion s’est mise en place sous la forme d’un filon-couche légèrement discordant sur la structure de la bordure orientale de l’Eastern Gabbro. On y distingue trois sous-unités, inférieure, centrale et supérieure, sur la base de zonations lithologique, minéralogique et géochimique. Les sous-unités marginales sont enrichies en sulfures, métaux usuels et précieux, et montrent de nombreux indices d’assimilation des roches hôtes. La paragenèse minérale primaire inclut le plagioclase, l’olivine, le clinopyroxène, les oxydes ferro-titanés et accessoirement et localement, l’orthopyroxène, la biotite et l’apatite : cet assemblage est surtout préservé au coeur de l’intrusion (sous-unité centrale). Le gisement de Cu-EGP de Marathon, situé principalement dans la sous-unité supérieure, comprend une minéralisation disséminées à sulfures de fer, cuivre, nickel, et minéraux du groupe du platine, dérivés de sulfures magmatiques primaires par remobilisation hydrothermale. L’enrichissement en Cu et EGP résulte du remplacement d’oxydes ferro-titanés primaires par réaction avec des fluides tardi-magmatiques, et des fluides assimilés le long de la bordure inférieure de l’intrusion, dérivés de la fusion partielle des xénolites et de remobilisations hydrothermales."

Jan 1, 2001

By AIME AIME

EITHER the 2300 people who came to the Annual Meeting were in a better frame of mind or they were resigned to their fate, or it was a better meeting than usual. Whatever the reason, at the 1nstitute?s 148th meeting the attendance was better than ever before, things went more smoothly than in some previous years, and complaints appear to have been almost entirely absent. Patience was sometimes reauired but. almost without exception, it was forthcorning the well-known recession seems to have given many members enough leisure time to come to the meeting without depriving them of the tangible wherewithal to come.

Jan 1, 1938

By F. G. Horino

This report presents the theory and design of a stiff loading machine used by the Bureau of Mines. The machine incorporates three high-strength steel columns as the restraining member in parallel with the specimen. The theory presented gives the basis of design and the dimensions of component parts of the machine. Laboratory verification of the theoretical stiffness is described using three different setups involving a hydraulic jack and spacers and confirms the stiffness calculations to within 1 percent. Experimental techniques, testing procedures, and special equipment designed for determining the complete stress-strain behavior of NX cores of both hard and soft rock are described. Typical test data are presented as force-displacement curves for two rock types, a marble and a granite.

Jan 1, 1972

By D Gelling

Mineral sands dry plants consist of a large number of repetitive unit operations with significant transport delays, in the form of stream pipes, conveyors and elevators. As part of the P255 mineral sands sponsorship and using the JKMRC developed conductor/non-conductor (CNC) gauges, control loops have been implemented at the multi-duty dry plant of Cable Sands Limited at Bunbury. This paper describes the loops for kV control on a rougher high tension roll machines (HTR). The options available are product grade control and ratio control using the JKMRC CNC gauges, which measure the percent conductors in a stream. The purpose of control is to stabilise the circuit operation against disturbances such as atmospheric and feed disturbances.

Jan 1, 2001

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of the cementation of cadmium, lead, and silver from dilute aqueous solutions. This work is an extension of studies carried out on the Cu-Zn and Cu-Fe systems for which the reaction rate was found to be completely solution phase mass transfer controlled.When the amount of material deposited was greater than 0·2 to 0·4 mg/cm2 there was an apparent enhancement in rate which is attributed to the formation of a roughened deposit. This same phenomenon was observed in the Cu-Zn and Cu-Fe systems. Again, the rate of reaction of each system investigated was found to be solution-phase mass transfer controlled.

Jan 1, 1971

By William R. Wayment

The objective of this investigation was to obtain data on friction-head losses of sand slurries during their transport in pipelines. The data ultimately will be used in designing hydraulic transport systems. Information that was incidental to the primary objective was gathered on degradation, changed percolation characteristics, and critical velocities of the slurries~ Tests were made in a closed-circuit pilot plant, with one type of tailing, through horizontal 2-, 3-, and 4-inch-pipe test sections at various pulp densities and flow velocities. Tests were made in a closed-circuit pilot plant, with one type of tailing, through horizontal 2-, 3-, and 4-inch-pipe test sections at various pulp densities and flow velocities. Approximately 2,000 tests were run in the pilot plant. The ranges of flow velocities used in the experiment were 2.8 to 19 f.p.s. in the 2-inch line, 4 to 14.5 f.p.s. in the 3-inch line, and 4 to 11 f.p.s. in the 4-inch line. Velocities were varied in increments of 0.5 f.p.s. through the entire velocity range in each pipe size. Densities were varied in 3-percent increments from 40 to 70 percent solids by weight except for one series of tests in the 2-inch line; in this series, densities were varied in 5-percent increments from 5 to 65 percent solids by weight.

Jan 1, 1962

Two coal seams were selected and the conceptual designs were based on the geological and physical conditions typical of these seams. As a result of the screening process presented below, the two coal seams selected were the Lower Kittanning Seam in central Cambria County, Pennsylvania and the Pittsburgh Seam in northwestern West Virginia and southwestern Pennsylvania. SELECTION PROCESS FIRST SCREENING OF LONGWALL OPERATIONS The list of longwall operations prepared in Phase I and included in the Phase I report, was used as the basis for a first screening. From this list it was determined which longwall operations were not in the Appalachian coal fields and not in a coal seam of the thickness range of 42 to 72 inches. The first screening eliminated 30 of the listed operations, leaving 48.

Jan 1, 1976

By R. L. Virta

Four companies mined ball clay in four states during 2005. They included H.C. Spinks Clay (owned by Franklin Minerals), Kentucky-Tennessee Clay (owned by Imerys), Old Hickory Clay and Unimin. Production was estimated to be 1.32 Mt (1.45 million st) valued at $53.3 million, based on the results of a preliminary survey of the ball clay industry. Production in 2004 was 1.22 Mt (1.34 million st) valued at $54.1 million. Tennessee was the leading ball clay producer state with 61 percent of domestic production, followed by Texas, Mississippi and Kentucky.

Jan 1, 2006

By Keith A. Heasley

In the past, numerous displacement-discontinuity (DD) models of stratified rock masses have been proposed using a homogeneous isotropic elastic overburden. In this paper, it is postulated that a laminated overburden model might be more accurate for describing the displacements and stress in these stratified deposits. In order to investigate the utility of using a laminated overburden in a DD model, the fundamental mathematical basis of the laminated model is presented and graphically compared with the fundamental behavior of homogeneous isotropic elastic overburden and with field data. Specifically, the stresses and displacements surrounding an idealized longwall panel as determined from the laminated overburden model are presented and compared with results from the homogeneous isotropic overburden and with measured abutment stress data. Also, the remote displacements and surface subsidence as calculated by the laminated overburden model are compared with homogeneous isotropic calculations and with measured subsidence data. The results of this investigation show that the laminated overburden is more supple, apt to propagate displacements and stress further, and better able to fit observed data than the classic homogeneous isotropic overburden. Ultimately, it is suggested that the laminated model has the potential to increase the accuracy of displacement and stress calculations for a variety of mining situations.

Jan 1, 1996

By Caio Luca Joppert

O objetivo do trabalho foi estudar a possibilidade de ajustar as características do biogás produzido a partir da fermentação de vinhaça de modo a torná-lo intercambiável com o Gás Natural (GN), ou um GN substituto (GNS) com características que permitam introduzi-lo na rede de distribuição. São considerados aspectos normativos e técnicos associados à composição química e comportamento durante processo de combustão visando o atendimento aos requisitos normativos estabelecidos para o GN. O trabalho considera a vinhaça, rejeito da produção de etanol a partir da cana-de-açúcar, como fonte para produção do biogás em razão da grande disponibilidade deste resíduo do setor sucroalcooleiro. O Estado de São Paulo (ESP) é tratado com destaque, uma vez que este concentra a maior parte da produção do setor sucroalcooleiro no Brasil. Cálculos de razões de mistura tratada com gases de ajuste foram realizados para verificação das proporções necessárias que viabilizam a utilização da mistura como GNS, tendo como referência especificações da ANP. Os resultados do estudo indicam que a alternativa de geração e beneficiamento de biogás da vinhaça é uma opção tecnicamente viável de conversão de fração considerável deste resíduo do setor sucroalcooleiro em gás com características similares ao GN. Ademais, a alternativa proporciona a valoração do conteúdo orgânico do resíduo, com redução da contaminação dos solos no processo de reaproveitamento dos nutrientes nos processos de fertirrigação.

Jul 31, 2018

By J. W. Thompson

ESTATE IN MINERALS. Minerals beneath the surface may be made the subject of separate ownership either by a grant of the minerals by the owner of the land or by a grant of the land excepting the minerals, and thereby an estate in fee simple is created in the minerals, as corporeal things real. Colby, In re, Iowa, 169 Northwestern 443, p. 444. DEEDS EXCHANGING DIFFERENT MINERALS-RIGHTS OF PARTIES. The lands of two adjoining owners were underlaid with cement rock and clay at a depth of about 100 feet from the surface and with coal veins some 600 feet below the surface. By an exchange of deeds one of the land owners conveyed to the other the cement rock and clay with the right to mine and remove the same without entering upon the surface, but the deed contained no covenant not to injure the surface. The other deed conveyed the coal seam and so much of the rock and other minerals just above and below the coal as might be required in connection with the mining and removing of the coal, together with the right to mine and remove the same, and the adja- cent rock, clay, and other minerals, without entering upon or injuring the surface, with one immaterial exception. The deeds do not define the word "surface" and neither expressly nor by implication did they secure to the coal owner the right to subside the overlying cement rock; but the implication is to the contrary, as the deed gives the right to mine and remove coal without entering upon or injuring the surface. The provision that the coal owner should not enter upon or injure the surface amounts to a clause that the coal mine. shall not be worked so as to let down the surface and this does not create any inconsistency with the provision giving the right to mine and carry away the coal.

Jan 1, 1919

Ore samples generally require preparation before analysis. Serious problems can occur with contamination degradation and particle size effects. Both grinding element contammation and sample cross contamination havebeen bound to be related to sample hardness and operator technique. For best results with minerals relevant to the steel industry, the use of Siebtechnik-type mills required a combination of careful planning, short grinding periods and intermediate sieving of the sample. The results may be extended to most mineral, rock, and refractory sample preparabons.

Jan 1, 1978

By William A. Sloan

"In smelting operations, finely divided material called ""flue dust"" is carried by the moving gases from the roasters and furnaces; it is partly settled and recovered in the flue system. The flue dust from copper smelters contains a high percentage of copper, usually some gold and silver, and occasionally other valuable metals. It is too valuable to throw away and in present practice is returned to the smelting furnaces for re-treatment. A part of this material again passes out with the gases and forms a circulating dust load in the system. The dust that passesout of the stacks into the atmosphere is an important source of loss in copper smelting. Loss of values also occurs by dust being blown away while in transit from the flues back to the furnace, and of course the greater the amount of rehandling the greater this loss.Dust carried in the gas currents causes corrosion of the roof arches in reverberatory furnaces. Returning flue dust to the furnace increases the quantity of suspended dust. Corrosion reduces the life of the arches and shortens the length of furnace campaigns; also the corrosion of arches limits the temperature at which a furnace may be operated. Every ton of material that must be re-treated in the furnaces reduces correspondingly the amount of new ore or concentrates that could be smelted.As the present tendency is toward finer grinding in flotation plants smaller particles will need to be treated at the smelters, increasing the difficulty of preventing losses in flue dusts. Many schemes and processes for a more economical method of treating flue dust have been proposed or tried, but in the main none of them has been successful."

May 1, 1928

By D Bruce

OZ Minerals’ Carrapateena mine is a Sublevel cave mine located in South Australia, approximately 160 km north of the regional centre of Port Augusta. Carrapateena commenced underground development in 2016, with production commencing in 2019 and ramping up to 4.25 Mtpa by December 2020. In pursuit of continual improvement, the Carrapateena mining team sought to identify how it could better interrogate its current productivity levels and its drivers (root causes). During this process the team were confronted by a disconcerting number of different opinions (which often conflicted) on our actual productivity performance which led to a need for review. Although reliable data and a well-designed time utilisation model (TUM) existed, it was still unclear what actions needed to be put in place to improve productivity. This was for the following reasons: • Data sources were disparate unless significant effort was applied to compile them. • Data sources were not available in a format that could be easily viewed or analysed. • General understanding of the data which was collected and how it could be used was poor. • Process of regularly analysing performance and forming tangible actions to improve was lacking rigour. A project was then started with the goal to fix the areas stated above. An initial requirements gathering exercise was undertaken to identify key data sources for site which returned a staggering 42 known systems which were then shortlisted to the key systems that contained operational data and could generate tangible improvements when analysed. This paper discusses the approach to selecting the OZ Minerals Insights Hub as the chosen platform, and the effort and collaboration between cross-functional departments that was involved in transforming the data so it could be displayed in a useful way. The data sources identified included a fleet management system, two planning databases, a control system historian, and a mobile fleet machine data system. New processes were also introduced to digitally capture daily commentary; this was achieved utilising SharePoint Forms. Data pipelines were then developed in the Insights Hub platform to automate the ingestion and transformation of the raw mining data into curated data models for end user consumption. Tableau dashboard packages have been created to support facilitation of short interval control, daily review meetings, and weekly review meetings as well as data analysis of key equipment and locations. These dashboards visualise the mining data models in a form that provides the user a clear picture of what has occurred, why it has occurred, and where to focus improvement efforts. This has resulted in a team which is more accountable, more equipped to assess the root cause of performance, and more regularly able to make data driven decisions. The next step? To build this out from Mine to Mill and create a data indexing tool which will drive self-service reporting, a data agnostic platform and predictive tools that help our people continue to be one step in front.

Mar 29, 2023

By Paul Staples, Paul Messenger, Greg Lane

"Every project is different. While “conventional” SAG and ball mill circuits will suit many projects, for others there are alternatives, which may produce improved outcomes. This paper examines particular examples of recent front end designs which either went against conventional thinking or which employed “out of the box” thinking to realize the desired results.One such example is the design strategy employed for a small capacity gold plant in Victoria, Australia. The selection of HPGR technology for small capacity projects is not generally favoured, given the relatively high cost of small HPGR machines. However, the unusual size distribution of the gold and its liberation characteristics were expected to lead to improved gold recovery offsetting the higher capital cost.Another example is the first large scale application of milling in acid for copper recovery, at a project in south east Asia. The stainless steel, single stage SAG mill using ceramic grinding media was more expensive than a mill constructed of conventional materials. However, the steps of scrubbing, slurrying, grinding and leaching could all be achieved in a single unit operation and the need for thickening and repulping with acid after milling was eliminated.Rod mills were selected for both primary and secondary milling duties for another south east Asian project despite their somewhat outdated reputation. A review of previous industry experience confirmed that rod mills could outperform conventional rod/ball or SAG/ball circuits in cases where the size distribution of the ground product is critical to downstream recovery.These examples are discussed with particular focus on the key drivers in each case."

Jan 1, 2008

By Charles L. Allie

Since Reserve Mining Co. began commercial operations at Silver Bay, MN, some 25 years ago, major improvements in taconite processing technology have become available. In addition, significant new government standards have been imposed on industrial operations. By implementing a $370-million modernization program, Reserve was able to accomplish two major company objectives: the quality of concentrates produced from the Peter Mitchell mine has improved, and the operation meets both present and foreseeable environmental standards. Process modifications at Reserve were designed to: •Reduce the pellet silica content from 9% to 5%; •Increase the pellet iron content from 62.5% to 65.8%; •Implement a tailings disposal system utilizing "best available technology" water quality controls; and •Reduce air emissions by installing "best available technology" air emission controls. By adding dry cobbing, fine screening, and flotation to the concentrating process, pellet silica content has been reduced; the process reclaims and reuses all process waters; all tailings are stored in a zero discharge tailings basin; and all air emission standards are being met. Initial Beneficiation at Silver Bay Reserve's Peter Mitchell mine at Babbitt, MN, is on the eastern end of the Biwabik iron formation. The open-pit mine is approximately 16 km long, 0.8 km wide, and presently has a maximum depth of about 50 m. Principal constituents of the ore body are magnetite, quartz, and iron-magnesium silicates. The company's large commercial plant began operating at Silver Bay, 75 rail km from the mine, in 1955. Facilities have historically had the capacity to process 31.5 Mt/a of taconite, containing an average 24% magnetic iron, into 11 Mt/a of iron ore pellets. Reserve's initial beneficiation process-which existed up to early 1979-consisted of two crushing stages at the Babbitt mine site, two additional crushing and screening stages at Silver Bay, grinding in a conventional rod-ball¬regrind mill circuit, size classification with cyclones, and concentration with magnetic and hydraulic separators. Concentrate produced by that circuit assayed 65% iron and 8.5% silica, with a screen analysis of 94% -44 µm, and a surface area of 9300 cm2/cm3. Pellets produced from this concentrate assayed 62.5% iron and 9% silica (dry basis). Construction began in 1977 to modify Reserve's operation. Process modifications were designed from pilot scale operations that had been operated and researched by Reserve for more than 10 years. There were two design restraints imposed on the process: economic constraints that Reserve continue to use much of the existing processes and structures in the new operation; and a substantial number of government-imposed permit constraints. In effect, the tailings process was designed first and then a concentrating process was developed that would "fit" the tailings disposal system. Operation of the modified process began in June 1980. Crushing Remains Unchanged No changes in process flow were made at either the Babbitt mine and crushing plant or at the Silver Bay fine crusher. Gyratory crushers reduce run-of-mine taconite to -90 mm-diam at the mine. Taconite is then transported to Silver Bay by intra-plant railroad. There are 10 fine crushing lines. Each consists of a double deck screen, followed by a heavy duty short head crusher, a second double deck screen, and second short head crusher. All screen undersize material bypasses the crushing lines, resulting in an open circuit crushing process. Fine crusher product is approximately 98% - 20 mm, 80% -12 mm, and 50% -10 mm in diameter. Each fine crusher line processes about 400 t/h of crude taconite. Cobbing Provides Aggregate for Tailings Dams The first major process change was the addition of dry cobbing, a dry magnetic separation step between the fine crusher and concentrator. Dry cobbing serves two major purposes in the new process. Its principal function is to provide large volumes of dry coarse aggregate for use in construction of tailings dams. This process rejects about 20% of the fine crusher product as tailings with a size analysis of 98% -20 mm and 50% - 10 mm. These tailings are free draining and have high frictional shear strengths-two key requirements for dam building aggregates. Fine crusher product is conveyed to a new dry cobbing building. Here crushed ore is discharged into one of two 30-minute capacity surge bins. Crushed ore is withdrawn by 12 constant speed conveyor belts; each discharges 500 t of crushed taconite into a dry cobbing machine. Each machine consists of a 3-m-long riffle splitter and two vari-

Jan 12, 1980

By J. I. Muñoz González

El presente trabajo verifica la utilidad de la incorporación de algoritmos de inteligencia artificial (IA) en cuanto a mejorar los resultados obtenidos en campañas de sondajes de exploración. Tomando la información geológica, geoquímica y geofísica de un proyecto real de exploración, se simularon 3 campañas posteriores y consecutivas, utilizando algoritmos de “boosted regression”. Luego fueron comparados con los resultados reales de los mismos.

May 1, 2008

By P Vasconcelos, X D. Deng

Numerous supergene manganese oxide deposits are developed inSouth China as a result of weathering of a thick sequence of Paleozoic marine Mn-bearing sedimentary rocks, consisting mainly of limestones, cherts and black shales that were intensely folded and faulted due to multiple episodes of tectonism since the late Triassic. The ore minerals are dominantly pyrolusite, cryptomelane, nsutite, lithiophorite and braunite. The supergene manganese ores contain Mn ranging from 20 to 44 wt per cent; manganese oxide deposits derived from cherts and black shales also contain recoverable levels of Co, Ni, Cu, Pb and Zn. 40Ar/39Ar dating of potassium-bearing manganese oxides reveals that extensive supergene manganese ore formation started at least in the earliest Miocene and persisted to the Present. Ages of the deposits show a close correlation to tectonic stability, with the oldest in tectonically quiescent areas and the youngest in active areas that have subjected to continuous uplift and thus significant denudation. The prolonged wet and hot climate since Oligocene and the balance between weathering and erosion, which is parameter to the tectonic stability, are the ultimate controls on the formation and distribution of South China supergene manganese oxide deposits. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By F. K. McIntosh, L. A. Dahmers

"INTRODUCTION North Carolina has been the leading producer of mica in the United States, accounting for roughly 50 percent of the Nation's output. The producing area is a belt some 100 miles in width lying in the Mountain and Piedmont sections in the western part of the State. Ashe, Watauga, Avery, Mitchell, Yancey, Buncombe, Haywood, Jackson, Macon, Transylvania, Rutherford, Cleveland, and Lincoln Counties supply the bulk of production, while small amounts have been produced in Gaston, Catawba, Burke, Wilkes, Yadkin, Stokes, and Person Counties.To assist the operators and expedite the production of mica during the recent emergency, the Bureau of Mines drilled four of the more promising mica properties in this State. The results of this exploratory program are recorded in this report.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Division, L. B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyzes samples and makes beneficiation tests."

Apr 1, 1948

By A. Tonejc, A. Bonefacic

As can be seen from the phase diagram A1-W1 the equilibrium solubility of tungsten in aluminum is practically nil at room temperature. By quenching from the liquid state (50,000°C per sec), Varic, Burov, and Kolesnicenko2 obtained A1-W solid solutions up to 0.15 at. pct W. The quenched alloys were in the form of foils, 0.2 to 0.3 mm thick. Considering the results of Duwez and Willens,3 it is obvious that this thickness, which makes impossible a sufficiently rapid quenching, was the main reason for the relatively low content of tungsten dissolved in aluminum found by varic.2 he present note shows that the metastable solubility of tungsten in aluminum can be appreciably extended in aluminum-rich A1-W alloys. The quenching technique and the procedure employed for the preparation of the alloys have been described previously.475 The resulting quenched flakes varied in thickness from 1 to 20 µm from experiment to experiment. However, the measurements of the lattice parameters were carried out only with flakes thinner than 5 µm. The areas of quenched flakes were between 0.1 and 15 mm2. The quenched flakes were placed into a 0.3-mm glass capillary tube which was then mounted in a 114.6-mm-diam Debye-Scherrer camera. Straumanis asymmetric film position and nickel-filtered CuKa radiation were used. The lattice spacings were computed taking X(CuKa1) = 1.54050A for resolved and ?(CuKa) = 1.54178A for unresolved doublets. All specimens were rotated at room temperature, 26o +2°C. The lattice parameters were estimated from extrapolation against the Nelson-Riley function. It was estimated that the error in the lattice parameter of the measurements on a single film lies within +0.0004A for lower and about +0.001A for higher concentrations of tungsten. The lattice parameters of the metastable solid solutions A1-W are plotted vs the concentration of tungsten in Fig. 1 together with the parameters measured by previous investigators.' Each point of the present measurements represents a determination of the lattice spacing on different quenched flakes, for a given concentration of tungsten. With experimental accuracy, the lattice parameters of the metastable solid solutions fall on the straight line passing through the already known data.' As estimated from the uncertainties in the lattice spacings of the solid solutions, the alloys were homogeneous within 0.1 at. pct W. The solubility of tungsten in aluminum-rich A1-W solid solutions obtained by a very rapid quenching technique is increased to about 0.95 at. pct W. This value is 6 times greater than the amount known up to now. -he lattice parameters of the resultant aluminum solid solutions with higher concentrations of tungsten than 0.95 at. pct W did not remain constant AUGER electron spectroscopy has been used to clarify the role of impurities in the embrittlement of AISI 3340 steel. Analysis of fracture surfaces has shown that the embrittled condition is correlated with appreciable antimony segregation at grain boundaries. The low temperature (400" to 600°C) temper embrittlement of low alloy steels containing various combinations of Cr , Ni , Sb , Mn , P , Sn , and As has been examined extensively for many years. General reviews of the area have been made by McMahon1 in 1968, LOW' in 1959, woodfine3 in 1953, and Holloman4 in 1946. Recent work by Low, Stein, Turkalo, and LaForce5 has done much in separating the alloy and

Jan 1, 1970