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By Olav Mellgren

Part I. The interaction between potassium ethyl xanthate and lead salts has been studied thermo-chemically. It is shown that ethyl xanthate reacts with lead carbonate, basic carbonate, thiosulfate and sulfate according to principles of simple chemistry, whereas reactions with lead sulfite, metasulfite, basic thiosulfate and hydroxide at high pH are associated with secondary reactions. A new compound "xanthogen thiosulfate" is postulated. Part 11. Adsorption of ethyl xanthate on galena has been studied quantitatively and thennochemi-cally. It is shown that an ion-exchange mechanism governs the adsorption process and that the heat of adsorption of xanthate on galena is equivalent to the heat of reaction of ethyl xanthate with bulk lead salts. It is concluded that the entropy content of the surface "compound" on galena is different from that of a corresponding bulk lead salt. Alkali depression is in part shown to be due to the instability of the xanthate-galena system at high pH and to the formation of basic lead salts. Sulfate and carbonate ions are shown to have a stabilizing effect on the xanthate-galena system. PARTI. THERMOCHEMISTRY OF ETHYL XANTHATE AND OF ITS REACTION WITH LEAD SALTS In the past little attention has been paid to the chemistry of lead xanthate. It is known that xan-thates form slightly soluble compounds with lead and that suspensions of lead xanthates in alkaline solution decompose rather readily.' The solubility of lead ethyl xanthate is of the order of 2.6 x 10-6 moles per 1. At increasing pH the xanthate concentration of a saturated solution contains more xanthate. Thus at pH 11 this xanthate content is about 100-fold larger than at pH 7.1 Xanthates are known to be consumed when added to a suspension of slightly soluble lead salts such as lead sulfate and lead carbonate. It is unknown to what extent this xanthate consumption is due to a simple chemical reaction because, frequently, observations are made which reveal secondary reaction products in such reactions. Thermochemical study of the reaction between xanthate and lead salts offers a means to clarify the significance of these reactions as the enthalpy changes can be accurately predicted from heat of formation of lead salts in pure solution reactions. In the present work the heats of formation of lead ethyl xanthate from potassium ethyl xanthate and lead salts are determined and some thermochemical aspects of xanthate in solution are studied. The results of these investigations are presented in Part I. In Part II the heat of adsorption of ethyl xanthate on galena surfaces is presented. All enthalpy changes were measured directly in a microcalorimeter. Calorimeter: The calorimeter used for measuring enthalpy changes was similar to that used by Redinha and Kitchener2 which was based on a description by Derbyshire and Marshall.3 Other useful references4,5 are listed. A sketch of the calorimeter

Jan 1, 1967

By J. S. Mason

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Detailed paragenetic studies of the post-tectonic fracture-hosted vein mineralisation have demonstrated a complex paragenesis, reflecting a multi-phase combination of regional metallogenesis and tectonics through time. Previously published work regarding paragenesis and zoning was oversimplified. Two major epochs of mineralisation resulted in the emplacement of the A1 group of assemblages, from which lead, copper and silver were the main metals mined, and the A2 group, whose galena is only moderately argentiferous but which were major sources of lead and zinc. Tectonic and tentative isotopic evidence points to post-orogenic relaxation as the mechanism for development of the A1 assemblages in the early Devonian, whereas the A2 assemblages are believed to reflect Variscan extensional regimes and regional metallogenesis in the early Carboniferous and Permian

Jun 19, 1905

Tokyo Metropolitan Government designs the stormwater storage plans in underground, as a measure of flood control in completed urban district and improvement of combined sewarage system. This time, introducing those plans, we report about IKEJIRI and SIN-KOMAZAWA STORAGE TRUNK LINEs design and construction. They are located in Meguro river basin of the Morigasaki drainage area. Both storage trunk lines have capacity to store 15O,000m3 of stormwater. They are in use for countermeasure of flood till Meguro river's strengthening (intensity 50 mm/h) is ended. And after the strengthening, they will be in use for improvement of river water quality, through the storage of combined sewage and first runoff, which, otherwise overflows weirs and flows to river in a rainy day. These storage trunk line's full length is about 5700m. Boring diameter 66140 mm (f = 2672m) and 47800 mm (I = 2866m) of these tunnels are constructed by Mechanical Shield tunnelling method. And boring diameter 3600 mm x 4000 mm (R = 180m) is constructed by NATM tunnelling method. We began works in 1983, and have a mind to complete in 1987.

Jan 1, 1987

By S Wright, W Bruckard

The current status of battery collection and recycling schemes in Australia are explored in light of current developments in product stewardship and increasing pressure to decrease materials going to landfill by originating equipment manufacturers. Used consumer batteries, both single cycle and rechargeable contain a mixture of valuable metals and potentially toxic materials that may become a resource/revenue stream to offset the cost of disposal/recycling. Although the volume of batteries discarded in Australia is modest compared to other global population centres, the expected increase in battery use with increasing equipment portability and future developments in the automotive industry, provide an opportunity to recycle. The requirements for a battery recycling facility in Australia and the most promising processing platforms that may exploit the resource with enough flexibility to cope with battery developments and market trends, are explored.

Jan 1, 2006

By Thomas. L. O.

Apart from a few sketches and incomplete maps, mainly topographical, and one or two detailed maps of placer-creeks, there is little information on the topography and geology of most of the country adjacent to the sections of the Alaska Highway in the Liard River area, particularly that part east of Kechika river. In 1943, the Geological Survey of Canada made a recon-naissance from Fort Nelson clown the river of that name to the Liard, thence up the latter to Hell Gate, and also up Beaver river for a distance of fifty miles. The whole of the area covered was found to be underlain by sedimentary rocks, not a single igneous dyke being seen. The British Columbia Department of Mines began reconnaissances near the highway both in and north of the drainage basin of Prophet and Muskwa rivers with a view to finding structures favourable for the accumulation of oil. In Liard River valley near the mouth of Smith river and at intervals from there clown to Devil' s Portage occur warm springs whose character and origin are not definitely' known, since they have not been investigated (21, p. 38A). Similar springs are said to occur at several localities over a broad belt extending from Muskwa river across the Liard to the Nahanni River country (26, p. 11). On Liard river below the mouth of Dease river, stratified sands, gravels, and clays of Pleistocene (?) age are constantly met with and in one or two places are underlain by sandy clays. The distribution of the latter, however, is very limited in the section cut by the river west of the Rocky mountains. The only range of these mountains that reaches the Liard is the high limestone ridge which approaches the mouth of Vents river from the southeast and then almost vanishes a few miles to the northwest of it (27, pp. 43-45). In general, the ranges of the Rockies in the area under consideration have been but little explored, but they are undoubtedly very largely sedimentary and, with the exception of some volcanics and intrusives on their western flanks, are probably almost entirely so. Unlike the high, deeply incised ranges in southern British Columbia, they dwindle in elevation north of Terminus mountain to low-wooded ridges separated by wide swampy valleys, and practically lose their identity between it and the Liard. The foothills, which, along the Liard, have a width of 38 miles (from near the mouth of Trout river to Hell Gate) are composed of a great series of alternating shales and sandstones, with some limestones, all folded closely together, which resemble those found in the foothills farther south (27, pp. 50, 19-20).

Jan 1, 1944

By Rakesh Sehgal, Pushkar Verma, Mohit Sharma

"SJVN Limited successfully commissioned its Rampur HEP (412 MW) in 2014. The project has been planned to operate in tandem by directly utilizing the Tail Water of SJVN’s prestigious Nathpa Jhakri Hydro Power Station 1500 MW located upstream. The initial filling of voluminous water conductor system of RHEP with 10.50 m diameter, 15 Kilometer long Head Race Tunnel, involved more than 1.5 million m3 of water. The filling operation of such a large diameter tunnel constructed in young folded Himalayas which always offer less ideal sites for tunnelling and their subsequent operations under pressurized conditions is worth sharing with tunnelling fraternity. The paper covers meticulous planning, execution, precautions taken, and performance monitoring during filling process keeping in view the fragile geology, low rock cover zones, shear zones in close vicinity of thickly inhabited areas, squeezing zones, hot water zones encountered during excavation.1.0 RAMPUR HYDRO POWER STATION IN BRIEFRampur Hydroelectric Project (412 MW), is located in Himachal Pradesh (India). This project is a downstream development of Nathpa Jhakri Hydro Power Station (1500 MW) constructed on river Satluj and commissioned during 2003. Both the projects today are now successfully working in tandem. The upstream NJHPS has been constructed on the left bank of the river while the downstream Rampur HPS is located on right bank of the river (Figure-1).The major length of HRT of Rampur project lies on right bank of river before it crosses under the river in its initial reach (Figure-2). The main features of the project are as below:• 10.50 m diameter 15 km long HRT ending in a 155.75 m deep, 38.00 m diameter surge shaft.• 3 steel lined pressure shafts, 5.4 m dia, 211-220m long.• Surface valve house 69 m long x 10.50 m wide x 23 m high housing 3 No. butterfly valves• 3 No. surface penstocks 5.4m dia 368-382m long, bifurcating into six penstocks, each of 3.80 mdia. to feed six generating units of surface power house 158 m long x 24.50 m wide x 48 m high, with Francis turbines each of 68.67 MW capacity."

Jan 1, 2016

By A. J. Lynch

Mineral processing models have been discussed for many years but it was not until digital computers became available about 1960 that serious attempts at circuit simulation could be carried out. Even then the work was primarily academic until PCs could be used by engineers in plants and design offices in the mid-1980s. Since then simulation has moved quickly and it is now at the point that most processes can be simulated reasonably accurately for purposes of design and optimization. There are still some significant deficiencies, notably in dry grinding and separation, and in the chemical interactions in flotation. Future work will involve: ?improvements of existing models ?dynamic simulation for automatic control and, in particular ,for training which is a weak link ?using advanced simulation models to predict liberation and separation from data acquired from SEM-based liberation analysers. Eventually mineral processes models will be part of total simulation systems which will incorporate mining and downstream processes including all environmental impacts.

Jan 1, 1999

By O A. Cottrill, G A. Oldfield, S B. Nowell

Host-rock û wallrock major and trace element geochemistry associated with epithermal gold mineralisation in the Hauraki Goldfield of New Zealand is poorly documented, even though rock geochemistry is a recognised tool in exploration. Such responses assist in recognition of the regional scale imprint of fossil hydrothermal activity, and indicate targets for detailed evaluation within these alteration zones.   Recent investigation of gold deposits in the Waihi (Gladstone), Golden Cross (Empire), Thames (Waiotahi) and Coromandel (Tokatea) areas indicate enrichments of Au, As and Sb in the andesitic wallrocks hosting mineralisation. Of the other elements examined, Si, K and Rb are enriched, and Na, Ca, and Sr are depleted at all deposits. These trends are best developed in the vicinity of veining. In deposits with clay alteration dominating (Waiotahi and Tokatea) there is also depletion of Mg, Mn, Zn and Cu. Ba and Cr are variably enriched or depleted within different styles of alteration. Base-metal enrichment in the wallrocks is not a feature of Hauraki deposits.

Jan 1, 1990

By Sune Eriksson, Stig Peterssonsune, Christer Fridfeldt

"Boliden Metal Corporation has developed a technique to treat complex copper concentrates containing large amounts of lead, zinc, arsenic, antimony and bismuth which cannot be treated in conventional smelters due to the impurities.Tests were carried out to treat such complex copper concentrates in the TBRC. They were performed in a pilot-plant TBRC with charges of 5 tons. These tests resulted in a new method to treat complex copper raw materials and produce a blister copper low in impurities. The background and data from the test work are presented as well as a flowsheet for a full-scale process.IntroductionThe Ronnskar Works is situated on the coast of the Gulf of Bothnia, 40 miles east of the Boliden Mine. Smelting began at Ronnskar in 1930 to process the complex ore extracted from the Boliden Mine. The Ronnskar Works has subsequently developed into a relatively integrated smelting plant.Copper and lead sulphide concentrates from Boliden's own mines as well as purchased copper raw materials are processed. The main products are refined copper and lead, but full utilization of the raw material also yields other metals and some metallurgical and chemical by-products. The products include gold, silver, zinc clinker, white arsenic, arsenic salts and arsenic metal , selenium and selenium compounds, nickel sulphates, sulphuric acid and liquid sulphur dioxide."

Jan 1, 1981

By C. C. Clark, D. J. Benton, J. B. Seymour, L. A. Martin

"The U.S. National Institute for Occupational Safety and Health (NIOSH) is conducting research on jackleg use and related accidents in underground metal mines. This paper provides an analysis and overview of jackleg drill usage, accidents, operational characteristics and alternatives, based on information from injury reports, legacy research, stakeholder input and published literature. The results indicate that jackleg drills are involved in more groundfall accidents in underground metal mines than any other drill, and jackleg-drill-related injuries are most prevalent at the face in the course of installing initial ground support. Practical mechanized alternatives to jackleg drills for drilling and bolting under incomplete support in narrow underground openings have not yet been realized. Small, versatile mechanized bolting equipment needs to be developed to address jackleg-drill-related accidents and improve safety at mines where jackleg drills are being used. IntroductionJackleg drill is a generic name for a handheld, rotary, percussion rock drill equipped with an attached reaction leg to provide stability and thrust (Fig. 1). All of the drill and leg controls are located near the operator’s handle at the rear of the head portion of the drill. Jackleg drills are classified according to the bore size of their pneumatic pistons, which normally range from 6.03 to 8.26 cm (2.375 to 3.25 in.) (Kurt, 1982; Clark, 2012). Jackleg drills typically weigh 46.7 kg (103 lb), but the weight can approach 54.4 kg (120 lb) after being fitted for operation with drill steel and air and water hoses (McKibbin and Clark, 2001). In underground mines, jackleg drills are commonly used to drill 3.8-cm (1.5-in.) diameter holes up to 1.83 m (6 ft) deep in rock."

Aug 1, 2016

By V A. Tsukerman

Prospects a new energy saving method for an efficient destruction of the sturdy and hard materials (rocks, ores, frozen soils, concrete blocks, etc) û the Electric Pulse Discharge (EPD) method of materials destruction for green processing in mining and processing of mineral raw materials are considered.The EPD-technologies give additional possibilities for solving ecological problems at the expense of increase of integrated approach of utilisation of minerals and industrial wastes. The scientific and technical level of executed development of EPD method is sufficient for organisation of design work to develop substantially new equipment. A number of plants have been developed and tested, including plants for processing raw material with minerals of jewels, plants for selection of mica from rocks, and plants for processing the merging of artificial mica.

Jan 1, 2002

By G. Bonnell, W. Lidkea, M. C. Bétournay, E. Edwardson

"Hydrogen fuel cells are a known technology, having been applied to stationary (e.g equipment, buildings, and power plants) and vehicle applications (e.g transit buses and space shuttles). There is currently a growing need to provide alternate power systems to diesel fuel for underground mining vehicles to improve underground air quality and reduce production costs and greenhouse gas emissions.To date, however, fuel cells have not been exposed to underground mine air and physical conditions. A testing program was carried out to provide information on the vulnerabilities of fuel cells as part of a number of proof-of-concept projects to apply hydrogen power to underground mining vehicles. The fuel cell type of choice for the industry, the proton exchange membrane, would function at the range of temperatures encountered in underground and surface operations, and use hydrogen that is stored under low pressure and risk.A small fuel cell stack was tested in a cooperative project between CANMET, the Fuelcell Propulsion Institute, Inco, the Ontario Ministry of Labour, Sandia National laboratories, and H-Power. This article will review the tests carried out to measure the effects from high humidity, mineral dust, diesel emission gasses and diesel particulate matter, as well as from shock and vibration provided to the unit in underground conditions at Inco’s 175 Orebody minesite and Stobie mine. The test results provided will show that the unit was not affected by the underground conditions; physically and electrically, the unit performed without any reduction in operation or adverse effects imposed."

Jan 1, 2005

By M. C. Bétournay

Hydrogen fuel cells are a known technology, having been applied to stationary (e.g. equipment, buildings, and power plants) and vehicle applications (e.g. transit buses and space shuttles). There is currently a growing need to provide alternate power systems to diesel fuel for underground mining vehicles to improve underground air quality and reduce production costs and greenhouse gas emissions. To date, however, fuel cells have not been exposed to underground mine air and physical conditions. A testing program was carried out to provide information on the vulnerabilities of fuel cells as part of a number of proof-of-concept projects to apply hydrogen power to underground mining vehicles. The fuel cell type of choice for the industry, the proton exchange membrane, would function at the range of surface operations, and use hydrogen that is stored under low pressure and risk. A small fuel cell stack was tested in a cooperative project between CANMET, the Fuelcell Propulsion Institute, Inco, the Ontario Ministry of Labour, Sandia National laboratories, and H-Power. This article will review the tests carried out to measure the effects from high humidity, mineral dust, diesel emission gasses and diesel particulate matter, as well as from shock and vibration provided to the unit in underground conditions at Inco?s 175 Orebody minesite and Stobie mine. The test results provided will show that the unit was not affected by the underground conditions; physically and electrically, the unit performed without any reduction in operation or adverse effects imposed

May 1, 2005

By William H. Holley

Thirteen additional preservative/fire retardant systems were applied to Ponderosa pine and evaluated for flammability both before and after water leaching. The more promising four systems were given a thorough evaluation for flame spread, toxic gas and smoke density levels, resistance to decay, and compressive strength. The most promising system on the basis of history of usage in the mine, ease of application and low cost as well as overall performance is the Fyreprufe/ACC Albi 107A/ 144 combination. A survey of inspection tools and instruments, identified equipment which could be assembled into an inspection kit for use in determining the extent of decay and/ or impregnant retention levels in mine timber. A literature search identified those high fire hazard areas found in a typical mine. Timber and other wooden structures used in such areas should be treated with an acceptable fire retardant system. A survey of insurance companies revealed that the use of such treated timber in the mines would probably have little or no impact on the rate structure.

Jan 1, 1980

By A. C. Fieldner

THE Bureau of Mines has received many requests for Information concerning the methods its laboratories use for analyzing coal and coke and determining their heating value. The fuel investigations now conducted by the Bureau of Mines are an outgrowth of the work undertaken at the Government coal-testing plant erected in 1904 at the Louisiana Purchase Exposition in St. Louis, and the methods for proximate and ultimate analysis of coal used by the Bureau of Mines are based on those originally adopted by the chemists of the coal-testing plant and followed in the subsequent chemical work of the Government fuel-testing plants at St. Louis, Mo., Norfolk, Va., and Pittsburgh, Pa. The many valuable suggestions and criticisms received from N. W. Lord, director of the School of Mines, and from E. E. Somermeier, professor of metallurgy, of Ohio State University, at that time, are greatly appreciated; development of many of the methods for the proximate and ultimate analysis of coal now used by the Bureau of Mines is chiefly clue to these men.

Jan 1, 1951

By Paul Downing

Identity Theft Outline • What Are MY Chances??? • Types Of Thefts • Sources Of Theft Info • Stolen Identity vs. Background Checks • Information/Data Safeguards • Corporate Data Handling • Reclaiming Your Identity • Monitoring Your Identity

Jan 1, 2006

The relationship between neural network (NN) performance and the parameters that form the architecture of the neural network is complicated. This paper studies an issue that is still controversial—the effect of the number of neurons and number of hidden layers on NN performance. This paper tests if the above parameters affect network performance when the NN is trained according to the quick stop strategy. It was determined that the number of neurons did not have any effect on the NN performance for a single layer or a double layer network. It was also found that the training error and calibration error could be poor indicators of the prediction correlation coefficient.

Jan 1, 2003

By K. Schrijver, G. Beaudoin

"Four occurrences of galena-cemented sandstones, exposed in the Lower St. Lawrence - Gaspésie area, are described. They constitute a new, insufficiently explored type of deposit in Quebec.One mineralized body, a minor occurrence, is hosted in Lower Devonian rocks deposited in an estuarine, intertidal river channel during a marine regression; major cements are dolomite and sulphides. Another occurrence, a drilled prospect, is hosted in Upper Silurian rocks deposited unconformably on Cambro Ordovician basement during a marine transgression. With galena and quartz as main cementing minerals, it is similar to some well-known, economic sandstone-lead deposits. A third and fourth, a drilled prospect and a minor occurrence, are hosted in Upper Cambrian rocks deposited on continental slopes. In both, sulphides mainly occupy a secondary porosity. The differences between the third and fourth occurrences are: (1) cementing translucent minerals (carbonates and barite in one; chlorite in the other); (2) chronology of final subsurface dissolution (prior and subsequent to sulphide precipitation, respectively); and (3) important fracture porosity only in the barite-bearing deposit.The diversity of the four occurrences, and the unequal geological knowledge of their respective features, prohibit the formulation of uniform guidelines for further exploration.IntroductionThe attention of the mineral exploration community is drawn to four occurrences of galena-cemented sandstones (Fig. 2A) in the Cambrian of the Taconian Orogen and in the Siluro-Devonian basin of the Lower St. Lawrence and Gaspésie area (Fig. 1). In view of the fact that sandstone-lead deposits (Bjerlykke and Sangster, 1981) are, or have been, mined in several countries (e.g . Laisvall in Sweden: see Rickard et al., 1979; Largentiere in France: see Foglierini et al., 1980), the mere presence of occurrences in Quebec indicates that the mineral potential of some parts of the Appalachians requires further evaluation.Exploration for the deposits considered here is essentially restricted to geological methods and drilJing (e.g . Mainguet Suares and Samama, 1969), since the response to geophysical methods is virtually nil, at least in the initial, surficial stage of an exploration program. As the particular disciplines of geology utilized in exploration depend a great deal on the geological setting of a mineral occurrence, the diversity of the Quebec deposits is of prime importance. Therefore, the four occurrences (Fig. I, Table 1) studied by the authors are herein briefly described with emphasis on their stratigraphic and tectonic setting, and on the evolution of pore space and sequential occlusion of pores and fractures. Prior to further research in and around the occurrences, now in progress (e.g. Beaudoin, 1987; Beaudoin et al., 1987), it is hoped that the following outline will be useful to the explorationist."

Jan 1, 1987

Site specific geotechnical data, deposit characteristics and method of mining are key factors when assessing an appropriate slope design philosophy. Mining geotechnics should be viewed as an iterative design process linked closely with mine planning, development and operational safety constraints. This case study presents geotechnical investigations for slope design at Macraes Flat Gold Mine using kinematic, probabilistic and economic analyses tempered with knowledge of site specific conditions. The recommended designs not only reduce early waste stripping tonnages but also provide data to optimise final walls.

Jan 1, 1992

By J. C. Fowler

The field testing of the Seismic Mine Monitor System is described. This system consists of nine geophones buried about 40 feet deep over a ten-square-mile area, the amplifiers and electronics needed to get the signals to the mine office, and a central processor unit to detect and locate explosions and large roof falls. Since the problems associated with the original installation were solved, this system has worked for 2 1/2 months. The system has detected roof falls in the pillar areas and has located blasts as small as 114 pound of dynamite. The location accuracy has, in general, been within 250 feet. The system is now being used to gather long-term data on the seismic activity of the mine.

Jan 1, 1974