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By Steve Kral

The mining industry has had three difficult years. Commodity prices have remained low and investor confidence in the industry has been shaken. And even though the Asian economy appears to be improving, it will be some time before this improvement will translate into better commodity price conditions for mining. In addition, increased environmental and social restrictions that have been placed on the industry in developed and developing countries have made mining a more difficult proposition. And, if that is not enough, the global mining industry has found itself in fierce competition with Internet businesses for investor capital. Despite that gloomy picture, more than 10,500 mining industry professionals from about 70 countries gathered in Toronto, Ontario March 5-10, 2000 for the Mining Millennium 2000 conference. This meeting was a joint effort between the Canadian Institute of Mining, Metallurgy and Petroleum(CIM) and the Prospectors and Developers Association of Canada (PDAC).The joint meeting also featured two trade exhibitions and more than 150speakers. PDAC’s trade show attracted about 400 exhibitors and an additional 200 in the concurrent Investors’ Exchange. CIM’s exhibition attracted about 600 equipment and service companies.

Jan 1, 2000

By J. Wennerstrand

Slender steel piles have found an increased use in Sweden in resent years. These piles are often driven throw soft normally consolidated clay to refusal in till or at the rock surface. In contrast to most other piles the bearing capacity with regard to failure of the shaft is in many cases smaller than the bearing capacity with regard to failure of the soil or rock at the lower end of the pile. Imperfections such as deviations from a straight line of the pile centerline and residual stresses in rolled and welded profiles are important for the capacity of the pile shaft. Even thow the second order moment caused by initial deviations in piles is only half of that in a column with the same slenderness, imperfections can and should be accounted for in much the same way as for columns.

Jan 1, 1989

By Michael Young, Josh Rubenstein, Michael Cooper, Tom Shouldice, Dan Curry

"Xstrata Nickel Australasia’s Cosmos plant in Western Australia is currently implementing a debottlenecking project to increase nickel output while maintaining metallurgical performance and a low unit cost for production. Mineralogical analyses indicated that the processing bottlenecks could be removed by simply reconfiguring portions of the circuit as well as adding capacity with technical advancements – notably an IsaMill™, Jameson Cell, Wemco® SmartCell™ and Larox Filter.The Wemco® SmartCell™, which is particularly suited for coarse mineral flotation, and Jameson Cell, which is particularly well suited for fast floating and fine minerals, combine as rougher scalpers to complete the main stream portion of the flotation circuit. Addition of the two new cells meet the required flotation capacity to handle the forecast increase in nickel feed grade and tonnage.The addition of an IsaMill™ for regrinding allows the SAG mill to produce a coarser primary product, thus enabling increased throughput. The advantages offered by the IsaMill™ include operation in open circuit (internal classification), an inert grinding environment (ceramic media) for better downstream flotation (“clean” new surfaces), compact footprint (easy to retrofit into existing plant) and energy efficiency. With the new rougher capacity addition, the remaining original plant cells were reconfigured to suit the new regrind mill and cleaning requirements. The existing 24 m2 Larox pressure filter was replaced with a larger 32 m2 unit to dewater the increased concentrate output.The paper describes the upgrade at the Cosmos concentrator with particular emphasis on the mineralogical data and metallurgical benefits associated with the changes.INTRODUCTIONThe Cosmos concentrator is located 680 km northeast of Perth in Western Australia. The deposit’s development and operations were started in 1999 by Jubilee Mines NL, Cosmos’ previous owner, with the first production of nickel concentrate in April 2000. The Cosmos concentrator treats a komatiite hosted high grade nickel sulphide ore, with sulphides being predominantly pentlandite and pyrrhotite with lesser amounts of pyrite and chalcopyrite."

Jan 1, 2010

By Gruenewaldt von

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The principles of shear-driven aggregation of particulate matter suspended in fluids, a common industrial method of concentration and separation, were applied to a convecting magma to estimate the time required to sparge or strip the PGE and Cr content and concentrate it into the boundary layers. It was calculated that an ore-grade (e.g. 6 ppm PGE) boundary layer about 1 m thick would require 100 000 years at most to form from a body of magma 500 m deep with a PGE content of 20 ppb. Since concentration would be most vigorous when the magma was warmest, at least half of this concentration would take place in the first 10 000 years. The effect of dispersive pressure in the boundary layer would generate a concentration high of refractories just below the top of each boundary layer and another just above the bottom. If the magma was a double-diffusive system, it might evolve by the downward cascade of enriched boundary-layer material into the hotter, lower magma layers, where depending on saturation levels chromites would equilibrate and sulphides undergo partial or total resorption, enriching PGE levels in any remaining sulphides. This cascade process would in time greatly enrich the lower regions in PGE-bearing sulphides and chromites

Apr 1, 1994

By M. P. Ristenbatt

A new automated post-disaster signaling system, intended to use through-the-earth EM propagation, was demonstrated in the laboratory at an input SNR of -34 dB. The system presently available requires an input SNR of +6 dB, and uses a human-ear detector. The work here demonstrated coherent integration, for the automated system, in multiples of 17 s, up to 1088 s (18 minutes). A repeating pseudorandom (or pseudonoise) signal is used, which offers an ideal auto-correlation at the receiver matched-filter output. A novel decision-variable algorithm achieves the estimate of noise level by using those matched-filter output samples that occur between the signal auto-correlation peaks. This work included corraboration that the received signal power decreases as distance to the tenth power, for through-the-earth propagation. Thus, the above 40 dB reduction in required input SNR permits an automated system to have a range 2.5 times that of the present system. In addition, an automated system permits the possibility of operating receivers around-the-clock; this would reduce the initial-detection-time from a few hours (present system deployment time) to a few minutes (signal processing time).

Jan 1, 1981

By R. H. Batey

"The process control and cost of monitoring mining slurries is normally accomplished using a continuous mass flow system, conventionally embodying a volumetric magnetic flow meter and nuclear density meter. DuPont’s Maxville Mine at Starke, Florida, USA was chosen to examine costs associated with performance of a nuclear density meter. Since it is typical of many mid-sized establishments and has a long history in their use. The published accuracy under ideal conditions of a nuclear density meter is ± 1.0%, but in practice considerable ambiguity of cost in annual production implies ± 2% at best. Using such accuracy in a 400mm (16”) pipe carrying zircon slurry at 75,000 tons/day, the cost of ambiguity, together with initial and running costs, amount to nominally $962,000 per year.Such cost leaves much to be desired. This paper describes an unique continuous, direct mass per unit volume Density Meter used for mining slurries in pipe sizes up to 1000mm (40”), which significantly reduces the cost of ambiguity of measurement and running costs. At the same time the disadvantages of nuclear devices are obviated.In an effort to reduce costs, a 400mm non-nuclear Density Meter was installed at the DuPont Maxville mine. A typical on-site accuracy can be shown to be ± 0.285%, whereby the cost of ambiguity, initial and running costs in the example above shows an annual improvement of $78,660, a reduction of over $880,000 per year.Even higher cost savings may be demonstrated with mass flow systems having gas entrainment compensation. Unlike nuclear and other inferential density meters, the signal quality of this non-nuclear Density Meter is totally unaffected by entrained gas found in mining slurries. This non-nuclear density meter is then ideally used with a vortex velocity domain sonic flow meter, and provides for the first time compensation in wet density or dry % solids, as well as wet or dry mass flow of mining slurries with entrained gas, resulting in enormous reductions in cost ambiguity."

Jan 1, 2013

By R. S. Kinasevich, D. D. Crabtree, D. W. Fuerstenau, T. P. Meloy, A. L. Mular

The effect of such variables as feed size, particle shape, cleavage, and hardness on the relative proportion of impact, abrasion, and chipping events in a tumbling mill is demonstrated. The concept of an average event, which is a combination of the three comminution mechanisms, is introduced. It is postulated that the average event in a particular mill determines not only the size distribution but also the energy-size reduction relationship for the comminution process. Fragmentation of particles in tumbling mills appears to result from a combination of impact, abrasion, and chipping grinding.' The relative rates of size reduction attributable to any of the basic grinding mechanisms must depend upon a number of variables, such as feed size, particle shape, hardness, and the number and kind of particles in the mill. The purpose of this paper is to show experimentally how these variables in the properties of materials affect the size distributions obtained by grinding the material's in a laboratory tumbling mill. The resulting size distributions will be intetpreted in terms of a combination of three comminution mechanisms. METHODS AND MATERIALS In this study, minerals of widely differing properties were ground either separately or as mixtures in laboratory mills using rods or balls for grinding media. The materials used include quartz, Tuolomne, limestone (99.8% CaCO3), barite, corundum, galena, pyrite, glass beads, and crushed glass. The mill used was 8 in. in diam. and 9-1/4 in. long. For the ball milling tests, 17.6 kg of steel balls (36: 7/8 in. balls, 178: 1 in. balls, and 44: 1-1/8 to 1-1/4 in. balls) were used. For the rod milling experiments, 17.6 kg of steel rods 9-1/16 in. long (25: 5/8 in., 10: 3/4 in., and 5: 7/8 in. in diam.) were used. In each test, 1 kg of solids were ground wet at 60% solids at 77 rpm. In all cases except where otherwise specified, the feed to the mill was 4 x 8 mesh material. Size distributions of the ground products were determined by a wet-dry sieving procedure with Tyler series sieves. Size distributions of mixed products containing limestone were determined by dissolving the limestone with acid and sizing the residue. EXPERIMENTAL RESULTS AND DISCUSSION If the size distribution of the product from a tumbling mill depends upon the relative proportion of impact and attrition (abrasion and chipping) events, altering the grinding conditions may change these proportions and consequently alter the size distribution of the product. Data to illustrate this point can be taken from Gaudin's classic 1926 paper.2 In one series of experiments, Gaudin ground quartz of different initial sizes for four hours in a laboratory ball mill with 7/8-in. balls. In Fig. 1, his data are reproduced as the cumulative fraction finer than the stated size for the following initial feed sizes: 13.3 x 9.4 mm, 6.7 x 4.7 mm, 2.6 x 1.6 mm, and 0.83 x 0.59 mm. As the feed size was decreased, a dramatic change in the shape of the size distribution curves took place, even though the amount of minus 100-mesh

Jan 1, 1964

By P. H. S. W. Kulatilake

To exploit an underground mine effectively and safely, it is important to have a good understanding of the geotechnical behavior around underground excavations made in the mine. The aim of this study was to investigate the geotechnical behavior around a tunnel excavated in a metal mine in China at the three-dimensional level. Using the information available on lithology, geological structures, in-situ stress measurements, physical and mechanical properties of intact rock, discontinuities and interfaces between different rocks, a three-dimensional numerical model was built by using the 3DEC software to simulate a tunnel excavation under a high in-situ stress condition. Effect of the discontinuity network, possible intact rock and discontinuity parameter variability, representation of rock masses as discontinuum or continuum material and rock support system on the deformation, stress, failure zone and stability around the tunnel was investigated. A very good agreement was obtained between the collected field deformation monitoring results and the results of the conducted numerical stress analyses.

Jan 1, 2012

By Charles A. Kliche

INTRODUCTION The Northern Great Plains Coal Province which occupies approximately 36.6 ha contains about one-half of the nation's total coal resources. About one million ha are underlain by coal that is considered to be mineable from the surface. The topography of the province is predominately plains, rolling hills, and some badland areas characterized by breaks or sharply eroded hills. Elevations range from about 1500 m above sea level on the west to about 600 m above sea level on the eastern boundary. The average slope of the ground is approximately 2 m per km. Streams in the province drain generally easterly and southeasterly (1). In the United States, the Northern Great Plains Province lies within the states of North Dakota, South Dakota, Montana, Wyoming, Nebraska, and Colorado. The coal within the province is located almost entirely in the states of North Dakota, Montana, and Wyoming. Although it is relatively low rank, the coal within the province encompasses a large portion of the total remaining U. S. reserves. The U. S. Geological Survey estimates the total remaining coal resources of the United States to be 2.6 trillion mt within 1000 m of the surface, and 2.9 trillion tons within 1830 m of the surface. Of this total, only about 177 billion mt are classified as reserves meaning that they are (1) known in location, quantity and quality from geologic evidence supported by engineering measurements, and (2) economically recoverable based on currently available technologies and current market value (2).

Jan 1, 1983

By Peter Richards, Alexander Lewis-Gray, Mark Davies, Nicholas Katsikaros

"Gekko Systems developed the Gekko Resin Exchange Column (G-REX) in order to optimise the recovery of gold in complex leach-to-electrowinning processes, as an intermediate step using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin (Lewis-Gray et al, 2015). Operational experience has been gained at the CGT Ballarat Gold Plant in near continuous operation since 2008, treating unclarified concentrate leach solution. The extension of the technology to higher throughputs and more complex chemistry is discussed.Aurix®100 ResinAuRIX®100 resin is a cross-linked polystyrene alkaline resin developed by Henkel (Virnig et al, 1996). The resin beads are off-white in colour, spherical, with a nominal size of 100% +600µm. This resin is highly selective for gold and silver over many metals, by way of extracting precious metal cyanide complexes from leach solutions with a pH less than 11.5. The higher end of the pH scale produces best selectivity according to the order of preference: Au > Ag > Hg > Zn > Ni > Cu > Co > Fe. Purolite produces the resin and Gekko Systems maintains licensing of AuRIX®100 resin for use in its G-REX column as part of its unique suite of gravity gold handling equipment.Significant cost savings over carbon-in-solution (CIS) systems are realised with AURIX®100 resin, of around 4% to 12% in capital savings and 27% to 40% in operating costs (Virnig et al, 2004). Allied to this is that AuRIX®100 resin is not susceptible to fouling, that is, the resin does not load with inorganic salts or organic compounds which would affect the loading and extraction of precious metals. To counter any potential for fouling by inorganic salts, in service a dilute acid wash is carried out periodically on the resin to unblock resin pores."

Jan 1, 2016

By Barry D. Lichter, Pierre Sommelet

High-temperature heat contents of InAs and GaAs were measured over the temperature range 400°K to temperatures above the melting points using a di-phenyl ether drop calorimeter. Smoothed values of the thermal properties have been derived and tabulated at even temperature interuals . The heats of fusion of InAs and GaAs were determined as, respectively, 8790 ± 200 and 12,590 ± 300 cal per g-atom at the respective melting points of 1210º ± and 1513º ± 1°K, yielding entropies of fusion of 7.26 * 0.16 and 8.32 ± 0.20 cal perºK per g-atom, respectively. A general discussion of the thermal properties of III-V com-pounds is given. THE low-temperature heat capacities of InAs and GaAs have been determined by Piesbergen.1Using a dynamic temperature modulation technique, Miller2 has determined the heat capacities of the compounds as well as GaSb and Ge between room temperature and 650°K; however, it has been observed that values determined by drop calorimetry for GaSb3 and for germanium4 are consistently about 5 pct lower than Miller's results. Cox and Pool10 report values for the heat content of InAs and GaAs and the heat of fusion of InAs. No value for the heat of fusion of GaAs appears to have been previously reported. This paper reports results of high-temperature heat content investigations of InAs and GaAs measured in the range 400" to above 1500°K employing a diphenyl ether drop calorimeter. These results, together with our previous results on III-Sb compounds3 as well as heat-content measurements5 of solid InP and Gap, are used in a general discussion of these compounds. EXPERIMENTAL PROCEDURES High-purity samples of the compounds, stoichio-metric to ±0.1 at. pct, were supplied in the form of crushed crystal fragments by Dr. Carl Thurmond of the Bell Telephone Laboratories. The sample preparation, description of the calorimeter, and details of the heat content measurement have been previously described.3 Samples were sealed in evacuated silica capsules and suspended by a Pt-Rh wire in a Pt-wound vertical tube furnace, heated to temperature

Jan 1, 1970

By Jerry C. Tien

Mining in China dates back at least 4,000 years. Today, with no less than 103,000 metal/nonmetal mines and between 40,000 to 80,000 coal mines, China’s mining industry is undoubtedly the largest in the world. Despite improvements in recent decades, seemingly endless mining accidents continue to make the news. Official coal mining deaths were 6,702 in 2003, and 6,027 miners died in 2004; actual figures may be much higher. Added to these were the 2,699 deaths in the metal and nonmetal industries. Most of these accidents were due to CH4 (methane gas) explosions and fires as a result of inadequate mine ventilation de-sign or practices. A good portion of these accidents occur in small, privately run and often technically illegal mines. During the past 10 years, the Chinese government has attempted to crack down on small and often technically illegal mines without much success. The number of accidents and associated fatalities has not significantly reduced. However, there appears to be a new urgency in China’s efforts to step up mine safety in the country. After its worst reported mine disaster in more than a half century, the government quickly paid reparations to families, suspended high-level officials in charge and announced additonal reforms. One of those was the elevation of the central government’s work safety office to cabinet-level status. There has been increased transparency in reporting and investigation of mine accidents and disasters in recent years. There has also been an increase in public criticism by labor leaders concerning the neglect of mine workersafety.1 This article examines the causes of China’s many mining accidents, current legal and enforcement structures, respective mining health and safety related laws and regulations, recent mining industry developments and the latest effort to curtail small mining operations.

Jan 1, 2005

By J. S. Miller

The Bureau of Mines conducted surface tests to determine the feasibility of using liquid explosives for underground rock fracturing. The effects of configuration, confinement, length, critical layer thickness, and fracture-propping sand on detonation and explosive propagation velocity of desensitized nitroglycerin were studied, using polymethyl methacrylate and glass-plate reservoirs through lengths from 3 to 12 ft, with explosive-layer thicknesses from 0.1875 to 0.0312 in and in aluminum tubes 8 ft long with diameters from 2.000 to 0.125 in. Interval and continuous detonation velocity data were obtained. Under the test conditions detonation velocity was dependent upon explosive confinement and fracture-propping sand. The detonation velocity of a confined nitroglycerin explosion in aluminum tubes can be reduced by as much as 85 percent, when the tube contains fracture-propping sand. The shape of the reservoir, whether triangular or rectangular, has little effect on the detonation velocity or explosive propagation. The critical or minimum explosive-layer thickness between glass plates, capable of supporting propagation, was 0.0312 in. The presence of a fracture-propping sand in the sheetlike layers increased the critical explosive layer thickness to 0.0625 in. In nitroglycerin-filled and nitroglycerin-sand filled tubes, the minimum tube diameters successfully tested were 0.125 in and 0.375 in, respectively.

Jan 1, 1969

By Xi Zhang

A technique for fabricating free-standing, high-aspect-ratio porous and pillar-type Ni structures has been developed using wet Si processing. A wafer of (100) Si was initially etched in HF solution to form deep pores with micron-sized diameter. The aspect ratio can exceed 200. By introducing the as-etched Si into a defined aqueous Ni2+ solution, Ni deposits grew rapidly onto the sidewalls and replaced the Si. Long-time immersion allows the Si sidewalls to be completely converted and thus form a metallic Ni structure with high-aspect-ratio pores. It is known that close-packed submicron Si pillars can be formed by oxidizing and subsequent etching of the macropore sidewalls. Treated in the same Ni solution, high-aspect-ratio Ni pillars were correspondingly emerged by replicating the original pillar-type Si structure.

Jan 1, 2006

By Mark R. Svinkin

This paper deals with application of the wave equation analysis to determine capacities of piles driven in saturated sandy soils. It shows that pile capacity in sandy soils changes with time after the completion of pile driving and depends on the ground water elevation. In saturated sandy soils the setup coefficient ranges between upper and lower curves represented by power functions. For a reliable prediction of pile capacity wave equation input should be adjusted with soil damping. Back calculation of soil damping from known pile capacity performed for five tested piles shows that skin damping coefficient changes with time in the same manner as the pile capacity and can be represented by the power functions for considered damping models.

Jan 1, 1995

By J. F. Butler, H. W. Paxton

The vapor pressures of manganese in equilibrium with several alloys in the iron-manganese-carbon system between 1200° and 1275°K have been measured using the Knudsen effusion technique in conjunction with a vacuum microbalance. The effect of orifice area of the effusion cell upon the measured pressure has been determined. The binary iron-manganese system shows small negative departures from ideality, and the system of mixed carbides, (Fe, Mn)7C3, in equilibrium with graphite behaves ideally. THIS work is a continuation of the investigations in which the Knudsen effusion method has been used to determine thermodynamic activities in systems and at temperatures of interest to metallurgists. In a previous publication,' the free energy of formation of Mn7C3 was determined and some preliminary work on the solution behavior of this carbide with the hypothetical "Fe7C3" was reported. The present work deals with this latter topic and also includes data on the binary ir-on-manganese system. EXPERIMENTAL METHOD The Knudsen effusion method was used to measure the vapor pressure of manganese in both the alloy and carbide sections of this investigation. This dynamic method of vapor pressure measurement presents a problem when studying solid alloy systems in which one of the components has a much larger vapor pressure than the others. Over-all depletion of the alloy in the most volatile component will occur during evaporation so that the pressure of that component will decrease. Even more serious than the over-all concentration change is the surface depletion of volatile component in the alloy brought about by the slow rate of diffusion of this component from the interior to the surface of the solid particle. Since knowledge of this surface composition is necessary in order to relate it to the activity determined through the measurements, changes in surface composition from the analyzed bulk composition are to be avoided in dynamic vapor pressure studies of solid alloys. The system under investigation in this study presents the problem of surface depletion of manganese since its pressure at 1230°K is 105greater than iron and 1020 greater than carbon. Since the existence of a volatile manganese carbide had been ruled out previously,' the high manganese pressure relative to iron and carbon insured that the only species leaving the effusion cell was manganese. Therefore, the effusing species required no analysis so that the manganese pressure was determined directly from the weight loss of the effusion cell. In order to detect small weight losses near the beginning of effusion, a vacuum microbalance was used to weigh the cell continually. These initial weight loss data allowed the rate of manganese effusion to be determined before the surface of the alloy became depleted in manganese. The apparatus used in this investigation is shown in Fig. 1. Temperature was measured using chro-

Jan 1, 1962

By C. H. Herty

"The work on the physical chemistry of steelmaking, as carried out at the Pittsburgh Experiment Station of the United States Bureau of Mines in cooperation with Carnegie Institute of Technology and, the Metallurgical Advisory Board, has covered a series of fundamental studies on the action of oxygen in liquid steel and the application of the findings to open-hearth operation. The staff has varied from 14 to 23 men per year, some of whom have been Bureau of Mines physical chemists and metallurgists, others research engineers of the Metallurgical Advisory Board, and the remainder graduate students employed as research fellows at the Carnegie Institute of Technology. The work on the laboratory studies, and particularly on slag systems, has been in charge of G. R. Fitterer, associate metallurgist, Bureau of Mines, while the plant work has been under the direction of C. F. Christopher, research engineer of the Metallurgical Advisory Board. In all, some 16 physical chemists and metallurgists and 24 research fellows have taken part in the experimental work. Advantage has been taken of the opportunity for cooperation with the University of Pittsburg to have certain phases of this program made the subject of graduate work, particularly the laboratory studies on the deoxidation of steel with manganese-silicon alloys.The general method of studying oxygen has been, first, to determine the solubility of the various oxides in liquid steel. To date the solubility of Fe0 in steel has been determined, over a wide temperature range.3 The straight-line relationship in the plot of solubility versus temperature indicated that under a slag of 100 per cent Fe0 the oxygen was present in the steel as dissolved FeO. A further conclusion drawn from this work was that the solubility of FeO in the metal was proportional at a given temperature to the mol fraction of Fe0 in the slag if the slag contained a large excess of basic constituents. This result was determined from a study of the solubility of Fe0 under slags containing lime and iron oxide in various proportions. These data have been used extensively in determining the saturation of a bath of open-hearth steel under any conditions of slag composition, and results to be given later showed that the solubility curves are consistent with the results obtained in practice."

Dec 1, 1930

By Marcelo Ferreira Martins, Breno Totti Maia, Sandro Luís Zahner, Leandro Martins Perreira, Paulo Roberto Ogliari Hopperdizel, Geraldo Vieira da Silva

O reator EOF foi desenvolvido no Brasil nos anos 80 com características únicas. O pré-aquecedor de sucata e a distribuição dos pontos de injeção de gases oxidantes e combustíveis conferem estas características. Um reator dinâmico e versátil capaz de adequar-se a grandes variações de carregamento de gusa e sucata, porém com equipamentos de injeção calcados ainda nos princípios da concepção da tecnologia. O objetivo deste trabalho é apresentar a etapa 1 de uma seqüência planejada de 3 etapas os desenvolvimentos que visam o aumento de produtividade do EOF. Nessa etapa 1 são apresentadas os ganhos relativos a modificação do número de pontos de injeção de oxigênio e a adequação desses pontos para condição supersônica de sopro.

Oct 1, 2019

By Eleanor Abshire

[THE INCREASING use of hafnium as a vital component in atomic power reactors has brought this metal into recent prominence. A literature survey was made and this bibliography was compiled to provide research and production groups with a ready source of reference to this important metal anti its compounds. This service is rendered by the Zirconium Information Center, which is sponsored by the Department of the Navy, Bureau of Ships, and the F .S. Department of the Interior, Bureau of Mines, tit the Bureau's Northwest Electrodevelopment Experiment Station, Albany, Oreg. The following reference sources have been reviewed for this compilation : Chemical Abstracts; Industrial Arts Index; Crerar Metals Abstracts; Nuclear Sciences Abstracts; Bureau of Mine; Information Cicular 7771, Bibliography of Zirconium; anal Bureau of Mint' Information Circular 7830, Bibliography of Zirconium, suppllement to Information Circular 7771.]

Jan 1, 1960

By D. W. Levinson, L. E. Tanner

DURING the course of an investigation of the zirconium-iron-tin system the zirconium-iron system was reexamined up to 55 pct* Fe. The alloys pre- visible melting3 and X-ray diffraction studies were made of samples of the alloys. The ferromagnetic properties of ZrFe2were determined by Professor P. W. Selwood* using a modified Faraday balance.4 The zirconium-rich portion of the phase diagram is presented in Fig. 1 and compared with the work of Hayes et al.1 The maximum solubility of iron in ß is somewhat decreased while the eutectic temperature is raised. There seemed to be no change in the eutectic composition of 16 pct Fe. Since the base material was so low in iron content, it was possible to establish the maximum solubility in a between 0.017 and 0.025 pct Fe at the eutectoid temperature. The observation of fine ZrFe, particles in the micro structure of a specimen of 0.012 pct Fe alloy quenched from 700°C indicated that the solubility drops below this composition at 700° C and lower. Further study was made of the intermediate phase ZrFe2. wallbaum5 identified the compound initially as ZrFe2 with a C 15 (MgCu2) structure, placing it at 55 pct Fe stoichiometrically. Hayes et al.1 believed they found the phase at about 47.2 pct Fe and called it Zr2Fe3 but reverted to ZrFe, in the discussion of their paper.6 Jordan and Duwez7 confirmed Wallbaum's work as well as finding the same single-phase structure to about 62.3 pct Fe or Zr0-61 Fe2-18. In order to establish the ternary phase relations in the zirconium-iron-tin systema the exact position of this phase had to be known. This was accomplished by X-ray diffraction, visible melting, and metallographic techniques. Elliott8 obtained a single-phase ZrFe2 X-ray diffraction pattern from an alloy of about 55 pct Fe. This was confirmed in the present study with an alloy of 54.81 pct Fe. However, extra lines (attributable to a or ß zirconium) were found in diffraction patterns of the 47.42 and 49.83 pct Fe alloys. The melting characteristics of these same alloys were studied by suspending 47.42, 49.83, and 54.81 pct

Jan 1, 1960