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By L. B. Pankratz

Enthalpies above 298° K were determined for AgCl to 1,400° K and for AgBr to 1,200° K by copper-block calorimetry. Before melting, both compounds showed an anomalous increase in enthalpy, an effect associated with lattice defect formation. Melting points and heats of fusion were determined to be AgCl, 730° K and 2,945 cal/mole; AgBr, 700° K and 2,030 cal/mole. The heat capacity of both melted substances decreased with increasing temperature over the entire liquid ranges investigated. Enthalpies above 298° K were tabulated at even temperatures along with derived entropy increments and heat capacity values. The results were combined with the known heats of formation and entropies at 29.8.15° K to obtain values of the heats and free energies of formation over the range 298.15° to 1,400° K for AgC1 and 298.15° to 1,200° K for AgBr.

Jan 1, 1970

By David Van Horsen

Operation and maintenance of California?s water tunnels is an important factor and vital link in California?s infrastructure. These tunnels are owned and operated by a variety of large and small private and public water and power utility companies, municipal agencies, and irrigation districts. Visionary pioneers such as Michael O?Shaughnessy (San Francisco Hetch Hetchy Water Supply System), William Mulholland (Los Angeles Department of Water and Power and Metropolitan Water District of Southern California?s Colorado River Aqueduct), and John Eastwood (Southern California Edison Big Creek Hydroelectric Project) built large and small water supply, irrigation and hydroelectric tunnels, which have supplied environmentally friendly-water supply, renewable electricity, and uninterrupted service to a burgeoning population and economy. This paper introduces these pioneers and describes several case histories and lessons learned during condition assessment and rehabilitation of tunnels providing enlightenment of California?s vital water projects.

Jan 1, 2008

By A J. Eggers

With gold first discovered at Carrick in 1864, exploration and mining on the Carrick Goldfield in Central Otago, New Zealand, has now been ongoing for more than 130 years. Recorded historical hard rock production from up to 52 different mining claims from 1864 to about 1921 is 24,047 ounces (oz) of gold.   Since 1980 Amoco Minerals New Zealand Limited, CRA Exploration Pty. Limited, Amax Gold Mines New Zealand Limited and Summit Gold (New Zealand) Limited have conducted modem systematic exploration campaigns targeted at locating shear controlled gold bearing quartz lodes and stockwork deposits. More than NZ $1million has been spent by these companies on aerial photography, geological mapping, stream sediment surveys, soil and rock chip geochemistry as well as reverse circulation (RC) percussion and diamond drilling.   RC drilling by Summit Resources in 1997 has identified a 1,500 m long zone of low-grade gold mineralisation at Lower Carrick, with an average grade of 1.00 g/t Au over a 14 m average thickness. This gold mineralisation, hosted within a low angle shear zone, has analogies with the Hyde-Macraes Shear Zone in eastern Otago. Recent exploration and drilling at Carrick has revealed the potential to discover large (>0.5 million ounce (Moz)) low-grade bulk shear controlled quartz vein and stockwork gold deposits similar to those now being mined at Macraes.

Jan 1, 1997

By R. Venugopal, T. C. Rao, N. Suresh

Experiments were carried out using the cyclone to treat coal in the size range -2.0+0 mm. The diameters of the cyclone outlets (vortex finder and spigot) were varied to study their effects on cyclone performance. The cyclone products were deslimed over a screen with an aperture of 0.075 mm. The performance of the separator was studied for washing coarse coal (-2.0+0.075 mm) and fines (-0.075 mm). Performance curves were plotted for the separation of -2.0+0.075 mm coal. The concept of a generalised distribution curve was adopted to predict cyclone performance. A mathematical representation was derived from the generalised distribution curve. The specific gravity of separation for individual size fractions showed a decreasing trend with decreasing particle size down to 0.85 mm, beyond which a reverse trend was noted. It was also found that the fine size fraction (-0.075 mm) does not separate on the basis of size or specific gravity but follows the water distribution

Apr 1, 1995

By Richard D. Miller

This Bureau of Mines publication contains analyses and related source data for 271 natural gas samples from 22 States collected during calendar year 1982. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by the mass spectrometer and chromatograph. The results of the investigation of the occurrences of helium are published annually to make the information available to the petroleum industry and the general public. Twenty-six publications have presented the results of 13,051 gas analyses vide prior to 1982. The first 3 bulletins (1-3)3 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960; these bulletins have been supplemented annually by information circulars (4-17, 19-24, 26) containing 7,833 analyses of samples collected since 1960.

Jan 1, 1983

By Ruilin Yang

"Blast vibrations are essentially a strain/stress wave propagating in rock or structures inthe vicinity of a blast. However, blast vibration has always been quantified in terms ofpeak particle velocity (PPV) or acceleration (PPA), and a meaningful relationshipbetween blast vibration and strain/stress has not been established. The determination ofthe dynamic strain from blast vibration may improve quantification of blast damage andselection of a blast vibration limit for critical structures or high walls. Dynamic strainrelates to rock mechanics or material strength more directly than peak particle velocity(PPV). This paper documents a method to calculate the three-dimensional dynamic straintensor from recorded blast vibration signals. The method is based on determination of thedisplacement gradient at a point of interest for each time instance during the vibrationduration. The method to calculate dynamic strain is applicable to generic seismicwaveforms including near and far field blast vibration from a production blast withmultiple blast holes. In order to minimize measurement errors the specifications of thespacing between monitors and the sampling frequency of the vibration recording aredescribed."

Jan 1, 2012

By Tom Treleaven, Andrew Williams

Several contracts were let in Greenwich, Connecticut, for the installation of a sanitary sewer. The majority of the excavation was in rock and involved numerous challenges due to the following conditions:

Jan 1, 2003

By L. C. St. Arnaud

"Open pit mines can produce large disturbances within regional hydrogeologic systems. The degree of disturbance and the consequences on the local environment depend on the size of the pit and on the physical setting of the mine. Comparisons and contrasts are presented for three Noranda base metal open pit mine sites.The Brunswick Mining and Smelting No 6 open pit has a surface area of 11 ha and a depth of 185 m. It is located within complexly deformed schists and meta-volcanic rocks. The massive sulphide and iron formations visible along the north and southwest walls of the pit generate acid drainage. Mining ceased in 1983, and the pit is presently being filled with waste rock and neutralized drainage water. Water balance calculations estimated a total fill up time of sixteen years. As the water level rises, leakage to groundwater could take place across a fault zone intersecting the pit.The Mattabi Mines F-Group pit has a surface area of approximately 3 ha and a depth of 50 m and is also set in meta-volcanic rocks and acid generating iron formations. Production at this site ceased in 1982, and the low pH pit water is neutralized and pumped into a nearby lake at least every five years. Major water inflows are from precipitation and groundwater. Groundwater mounds within adjacent high land surrounding the pit provide a natural hydraulic barrier to groundwater flow, except for the southeast side. As a consequence, the pit water elevation is being kept below the elevation of the nearby creek in which some of the pit water could drain.The Bell Copper open pit covers an area of 40 ha and is 270 m deep. With present ore reserves, the mine might be in operation until 1992. The geology around the pit consists of andesitic tufts, siltstones and shales, and the acid generation potential of the rock is relatively low. A recent hydrogeological study estimated fill up time by precipitation and groundwater to be in the order of 260 years.With increasingly more stringent requirements for mine closure, it is anticipated that more detailed hydrological and hydrogeological studies of open pits will be required to determine post-closure environmental impacts and the suitability of open pits for mine waste disposal."

Jan 1, 1990

Numerical modelling was used to examine priming of bulk commercial explosives. Data for the HOM equation of state were calculated using a representative chemical composition, while Forest Fire model data were calculated, using a Pop plot which was estimated on the basis of existing sensitivity data, albeit for cap sensitive, small diameter explosives. The length and diameter of the primer, the location of the detonator in the primer and the shape of the primer form a set of parameters which are investigated. The effect of confinement and borehole diameter are also demonstrated, as reflections of shock waves create regions of high pressure in the explosive. The results are presented in terms of pressure and decomposition histories in the explosive and are interpreted in an engineering fashion to form rational suggestions for optimization of the priming process in the field.

Jan 1, 2002

By Alcides Eloy Cano

Los recursos minerales de un depósito está en función de las dimensiones de la geometría del cuerpo mineral, así como sus reservas minables permiten saber el verdadero valor económico de su contenido. En este sentido, la Geotecnia es una herramienta que define las condiciones de los esfuerzos in situ, predice el comportamiento alrededor de excavaciones subterráneas e interactúa con las labores próximas, así como también la distribución de esfuerzos. Por ello, el presente trabajo señala la aplicación de esta herramienta a una mina subterránea de Oro localizada en el Perú, donde se tiene bloques de mineral económicos, así como señala su accesibilidad con leyes encima del Cut-Off. De forma que se recupera el mineral económico a través de las rutas críticas de carguío, en función de la viabilidad de autosostenimiento.

Sep 12, 2011

By Congling Shi, Marek Borowski, Yue Wang, Jianwei Cheng, Xixi Zhang, Xuan Xu

As the first barrier to prevent accidents caused by explosions in underground coal mines, the integrity and stability of mine seals have great effects on mine workers’ lives and underground production safety. In this paper, the mechanical responding performance of typical mine seals under the impact load are studied by using numerical simulation method. By such simulation studies, the safety of different seals subjected to the explosion load is evaluated. Seals’stability are also investigated under effects caused by various influence factors including thickness of mine seal, cutting depth into surrounding rocks, rock type, and the roof-tofloor convergence under given the explosion load. The research results can provide theoretical basis and reasonable improvements for mine seal’s construction practices for improving its anti-explosion performance.

By Congling Shi, Marek Borowski, Yue Wang, Jianwei Cheng, Xixi Zhang, Xuan Xu

As the first barrier to prevent accidents caused by explosions in underground coal mines, the integrity and stability of mine seals have great effects on mine workers’ lives and underground production safety. In this paper, the mechanical responding performance of typical mine seals under the impact load are studied by using numerical simulation method. By such simulation studies, the safety of different seals subjected to the explosion load is evaluated. Seals’stability are also investigated under effects caused by various influence factors including thickness of mine seal, cutting depth into surrounding rocks, rock type, and the roof-tofloor convergence under given the explosion load. The research results can provide theoretical basis and reasonable improvements for mine seal’s construction practices for improving its anti-explosion performance.

By Andrey V. Tarasov

To carry out a physicochemical substantiation of a transition to ?soft? modes of reduction of calcine obtained by desulfurizing roasting of nickel concentrate produced as a result of copper-nickel converter matte separation in a nickel anode production circuit, an analysis has been conducted of the macrokinetic behavior of actual calcine samples in the presence of gaseous H2-CO mixtures and solid reductant additives. Within a temperature range of 900°C to 1100°C the main regularities typical of the calcine reduction process with individual gases (H2, CO) also take place when using a gaseous mixture. Under the conditions of low-temperature (900°C to 1000°C) nickel oxide reduction with products of fuel oil conversion in the presence of coke, the role of the latter is insignificant from the technological viewpoint. As a result of the present investigations, we have obtained analytical expressions of macrokinetic parameters of the reaction interaction within the [NiO] calcine-H2-CO-C-CO2-H2O-O2-N2 system.

Jan 1, 2005

By M. J. Beus, B. Stewart, S. Iverson

Synopsis U.S. Mine Safety and Health Administration (MSHA) accidents statistics have identified ore-pass hazards as a significant safety problem in U.S. underground metal mines. The statistics show that nearly 75% of injuries are directly or indirectly related to pulling or freeing of ore-pass chutes, the use of hand tools in ore passes, fails of broken rock in ore passes and structural failures of chutes or gates and ore-pass walls. Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) are investigating hazards in and around ore passes in hard rock mines. Risk assessment methods, such as fault-tree analysis, have been employed to identify the most probable causes of orepass failures, define research priorities and analyse the factors that result in malfunctioning and unsafe ore passes. Static and dynamic loads are being measured in a laboratory setting with the use of a reduced-scale orepass mock-up. Field tests are being initiated in mine ore passes to determine static and dynamic loads. Data from the test ore passes are being compared with data from the mine to characterize true system behaviour. Computer modelling with the use of closed-form solutions, finite-element analyses and a newly developed particle flow code predicts static and dynamic leads from the flow and the impact of ore and waste in the ore pass. Preliminary results indicate that dynamic impacts from ore and waste rock might be considerably greater than expected. The total static load is substantially less than is typically used fur the structural design of chute and gate support members. It is suggested that damping factors, normal and shear stiffness and mass frictional characteristics have a significant effect on particle flow and resulting impact loads. This is being verified with the use of results from laboratory tests, field tests and particle flow analyses. Ore passes are vertical or steeply inclined openings in a rock mass through which ore and waste are transported and where they mar also be stored. A typical underground mining system is shown in Fig. 1. The arrows indicate the locations of ore passes and loading pockets and their relative configurations. The control of material flow is potentially one of the most hazardous operations in underground mining. According to MSHA data. most of the ore pass-related accidents in the U.S.A. are associated with the loading-unloading cycle and removal of blockages from ore passes. In particular, attempts to free ore hang-ups have resulted in multiple fatalities. The hazards are obvious; there is uncertainty as to when the ore will break loose and miners are unable to escape falling rock to a safe location. Although ore passes and chutes and gate systems for underground metal and non-metal mines roust meet the requirements specified in the U.S. Code of Federal Regulations (CFR). Parts 57 and 75, recent structural failures of ore-pass linings and gates have underlined the lack of adequate ore-pass design standards available to both MSHA enforcement staff and mine engineers. Because of the importance of an ore pass to the safe operation of a mine design criteria need to be assessed and new guidelines developed. Researchers at the Spokane Research Laboratory of the Nationals Institute for Occupational Safety and Health (NIOSH) are investigating hazards in and around ore passes in hard rock mines and studying design criteria for ore passes. The near-term goal is to conduct laboratory and field experiments and computer modelling to evaluate the ore-pass design criteria currently used. Literature searches, field site

By Simon Strong, Tim Brown, Luis Ignacio Sanz Vivanco

"One of the most significant technical and practical challenges facing the tunnel construction team on the Legacy Way road tunnel project in Brisbane, Australia was how to erect the pre-stressed precast concrete slabs to form the smoke duct in the tunnel boring machine (TBM) tunnels. An essential part of the tunnel ventilation system, the smoke duct, extends the full length of the 4.6km long twin, two lane tunnels. The vast majority of the tunnels (approx. 4.3km) were constructed using two 12.4m diameter double shield TBMs. The refurbished Herrenknecht machines broke several world records on the way to completing the tunnel excavation works in just over nine months. With the excavation complete the focus turned to solving the complex civil tunnel fit out challenges. A key component of the civil fit out of the tunnels was constructing the smoke duct in the TBM tunnels which was designed as a precast solution. The slabs which each measure 8.62m long by 2.0m wide by 200mm thick and weigh close to 9 tonne need to be erected above cast in situ corbels whilst other tunnel finishing works continue. The space proofing clearance offered by the design to the support corbels below and the precast segmental lining above was in the order of only 100mm. This paper details the events of how the Transcity JV tunnel fit out team, comprising some of Europe and Australia’s leading tunnel construction specialists, drew upon the global strengths of the existing JV member companies and the global reach of leading TBM manufacturer Herrenknecht to develop an innovative system to solve this challenging problem. This globetrotting story, which starts in Australia, visits Europe and mainland China before returning to Brisbane where it all began."

Jan 1, 2016

By M. L. Fuller

OWING to the nature of the die-casting process, freshly cast alloys are undoubtedly not at equilibrium from the standpoint of alloy phase relationships. After casting, therefore, they tend to undergo phase changes, with the ultimate effect of reaching a state of equilibrium at the aging temperature, beyond which no further change takes place. This phase alteration undoubtedly is one of the primary causes of the changes in dimensions and physical properties that zinc-alloy die castings undergo during aging. It is planned to report on this problem in a series of papers of which this is the first. The writers have made a study of commercial zinc die-casting alloys over a period of several years, utilizing the X-ray diffraction technic of determining the phase composition changes in the alloys. Up to the present, two principal phase changes have been observed which are capable of causing dimensional changes: (1) the segregation of secondary constituents from the zinc-base solid solution and (2) the beta aluminum-zinc decomposition. The latter is the subject of the present paper and studies on the former will be reported upon at a future time.

Jan 1, 1934

By Clélia Ribeiro de Oliveira

Os Aços Inoxidáveis Super Duplex (AISD) constituem sistemas termodinamicamente metaestáveis à temperatura ambiente, de elevada resistência à corrosão por pite em meios contendo cloreto e exibem moderada resistência mecânica. Os AISD possuem diversas aplicações industriais e a principal delas é no setor petroquímico, principalmente nas plataformas offshore. O propósito deste trabalho foi o de analisar a microestrutura e as propriedades mecânicas de juntas soldada por arco elétrico com eletrodo revestido (SMAW) em aços da norma ASTM A890/A890M graus 5A e 6A. As análises foram realizadas sem tratamento térmico pós-soldagem. Procedeu-se ensaios microestruturais (MO e MEV) e ensaios mecânicos (Charpy a -46 e 25 ºC e microdureza) na zona fundida (ZF). Os parâmetros de soldagem foram bem definidos para que não ocorresse fragilidade no material. A microdureza na zona fundida ficou entre 330 e 340 Vickers, o que está de acordo com o valor especificado pela norma Norsok, que é menor que 350 Vickers. No ensaio de impacto Charpy a absorção de energia foi em torno de 86 J para temperatura ambiente e 54 J a -46ºC para ambos os aços. A concentração de fases da austenita na zona fundida ficou em torno de 39%, dentro da faixa estabelecida pela norma ASTM A890/A890M que é de 35 a 65%. As fraturas mostraram-se predominantemente fibrosas, caracterizando elevada plasticidade do material, mesmo em temperaturas negativas.

Jan 16, 2018

By Donald R. Johnson

Apparatus providing simultaneous differential thermal analysis, thermo-gravimetry, and evolved gas analysis, has been developed by the Bureau of Mines specifically for thermal study of oil shale and other solid, natural fuels. The apparatus is described in detail, and simultaneous analyses on a single sample of an oil shale mineral, nahcolite, and a thermal analysis demonstration compound, calcium oxalate monohydrate, are presented to demonstrate the instrument's capabilities.

Jan 1, 1970

By G. A. Gamble

Fans used to ventilate subway, passenger rail and vehicular tunnels are similar to the fans used to ventilate underground mines. However, tunnel ventilation fan systems are typically designed to meet NFPA 130 or 502 standards, while mine ventilation fan systems must comply with the appropriate federal mine safety regulations. As a result, fan operation requirements and performance criteria, as well as typical fan and duct configurations differ significantly for tunnel and mine ventilation applications. Variations in environmental conditions in tunnels as compared to mines also result in differences in fan performance and material specifications. The need to enclose tunnel fans within building structures creates space restrictions impacting fan size selection that are not commonly encountered in mine fan installations, resulting in different approaches to selecting fans for the two types of tunnels. This paper discusses the various similarities and differences in design considerations for tunnel and mine ventilation fans.

Jan 1, 2009

By L. Watters, R. Terry, D. Placha

Dense medium cyclones are the preferred means for cleaning 1/2 in. x 14Mesh to 28Mesh (12.7 mm x 1.0 mm to 0.6 mm) raw coal and are becoming a common choice for cleaning raw coal from a nominal top size of 2-1/2 in. to 3 in. (63.5 mm to 76.2mm) down to 14 Mesh to 28Mesh (1.0 mm to 0.6 mm). During the last ten years, dense medium cyclone circuitry design has undergone changes which have combined to improve process efficiency. This paper describes these improvements and compares present day design with the design used prior to the mid 1980's. Improvements in the following areas are described: Raw coal desliming, cyclone configuration, drain and rinse applications, dilute medium circuitry, and instrumentation and control.

Feb 24, 1997