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By P. Ret, E. Üstiindag, R. Dieckmann, R. Subramanian, S. L. Sass

"Partial reduction reactions in the Ni-AI-O system, starting with the spinel compound NiAI20 4, are used to form metal-ceramic microstructures. By suitable choice of processing parameters, such as reduction temperature, oxygen partial pressure and time, two different morphologies of nearly pure Ni particles, equiaxed and rod-like, form within a ceramic matrix, which is either a-A12O3 or a metastable ""defect spinel"". Electron microscopy studies were performed for microstructural characterization, phase identification and chemical analysis. The fracture toughness of the Ni-AI2O 3 mixture was significantly improved with respect to that of the original spinel phase. The important issues that must be addressed to form useful metal-ceramic microstructures by partial reduction reactions rue discussed. It is shown that cracking at the original spinel grain boundaries, likely due to the large volume changes associated with the reduction reaction, can be avoided by the addition of small amounts of ZrO2• Initial results illustrating effect of ZrO2 on the microsuuctures are presented.IntroductionEngineering materials used in load bearing circumstances, particularly under extreme conditions (e.g. high temperatures or stresses), generally are formulated with complex microsuuctures. Such composite-like materials can possess properties unobtainable by either of the individual constituents. With metal-ceramic composites, for example, a material can be obtained with an optimum combination of the low density and high strength of the ceramic, and the toughness of the metal. For high temperature service, where demanding conditions are often present, for example, inside jet turbine engines, a successful new material must have low density, high Young's modulus as well as good oxidation resistance, strength, fracture toughness, creep and fatigue resistance. The candidates include intermetallic compounds, and metal-ceramic, intermetallic-ceramic and ceramic-ceramic composites."

Jan 1, 1994

By Pierre Rocque

The Red Lake Mine is located approximately 600 km northwest of Thunder Bay. This 545 tpd (600 tons/day) underground narrow vein gold operation is set to produce in excess of 14.8 tonnes (475,000 ounces) in 2001 at a cash operating cost below 75 U$/oz. The high-grade nature of this deposit (>55 g/t or >1.6 opt) coupled with its complex geological environment and relatively deep location dictated the choice of a very selective primary mining method, Mechanized Overhand Cut and Fill. In addition to geological challenges, mine design issues such as material handling, ground stability and requirements for yieldable ground support are also discussed in this paper.

Oct 1, 2001

By Yao Zhou

Under the United Nations Convention on the Law of the Sea (UNCLOS), the international seabed area (Area) and its resources are the common heritage of humanity (CHH). Patent rights can be incompatible with the CHH doctrine and its underlying principles because patent holders might charge unjustifiably high prices to license patented technology for exploring and exploiting the Area’s resources (creating a "patent holdup" situation), might choose not to license, or might license exclusively when doing so would contravene CHH principles. However, a reasonable patent licensing regime can contribute to sharing the benefits derived from the Area and promote environmental sustainability. Provisions of the UNCLOS that stipulated compulsory technology and financial transfers were removed in the 1994 Agreement relating to the Implementation of Part XI of the UNCLOS but to promote equity and sustainability I propose a voluntary licensing regime modeled on the concept of reasonable and non-discriminatory patent licensing that has been used in other contexts. The International Seabed Authority or another entity will need to coordinate and promote this licensing regime through governance of intellectual property derived from the Area. This proposed approach can better effectuate the CHH doctrine and its underlying principles.

Sep 1, 2014

By W. Barnett

The Limpopo Metamorphic Belt is a complex geological terrane with at least three major deformational events. Tectonically juxtaposed lithology, open to isoclinal folding, crosscutting and re-activated shear zones and metamorphic gneisses and schists make pit slope design and maintenance a risky business. Venetia diamond mine?s Cut 3 is planned to reach 360 m by 2011. The difficult rockmass created problems in the original pit and a new more comprehensive slope design was necessary. Nearly 9 km of geotechnical drilling were undertaken to produce a new geological model and provide geotechnical information near the final Cut 3 face. All existing data from the pit were brought together into a database. SRK Consulting were brought into the project to audit the process and provide most of the manpower for the data analysis. Existing failures were back-analysed and the geotechnical domains identified. Analyses of only the southern domains are discussed in this paper. Geotechnical engineers can design slopes at any angle, but it is up to the managers at the mine to decide what risk they are willing to accept in a slope design. Once the issue of risk was discussed and settled in respect of the consequences of failure, each of the main geotechnical domains were analysed to produce a slope design at5% probability of failure with 15% above the first ramp. A risk assessment of the design was then undertaken to determine what risk the design placed on the equipment, personnel and the profitability of the overall mining operation. The risk assessment indicated minimal risk to the operation. One of the main assumptions of the final design is that the pit slopes will be dewatered. A project was immediately put in place to determine a groundwater model for the mine and to thereby determine the best dewatering procedure. However, it should be obvious that it is practically impossible to prevent benches from getting briefly saturated with water during storm conditions. It was therefore necessary to look specifically at supporting the crests of the ramps in the problematic southern domains to guard against the possibility of crest failure during heavy rains. The data available were re-analysed toward this objective. Spiles were recommended as the most cost-effective support system, and a probabilistic approach was used in the design. The final design has a 5% probability of failure, and the analyses indicate a strong sensitivity of the required spile spacing to the strength of the reinforcement material that will eventually be used. The pit slope parameters derived as per the discussion in this paper have just begun to be implemented at Venetia Mine.

Jan 1, 2001

By Brian R. Zuckerman

The Capitol Area East End Complex is currently being constructed under contract with the State of California Department of General Services on two sites adjacent to the grounds of the California State Capitol Building in downtown Sacramento. The complex will consolidate the headquarters of the Departments of Health Services and Education, which currently occupy several facilities located throughout Sacramento. When completed in 2003, the complex will be the largest civic office project in California history, with approximately 1.5 million square feet of office space and housing nearly 6,300 state workers. The total project is being constructed on five separate blocks in downtown Sacramento, Blocks 171 through 174 and 225. Separate design/build contracts were executed for the construction on Blocks 171 through 174 and the construction on Block 225. The scope of this paper is limited to construction on Blocks 171 through 174, which comprise a square, two blocks on a side, bounded by 15th, 17th, L, and N streets, located immediately to the east of Capitol Park and the State Capitol Building, as pictured in the image shown below.

Jan 1, 2002

By C. E. Van Orstrand

AN intrusive body is a mass of igneous rock that has migrated upward, presumably from great depths. Great variations in form, composition and depth of burial occur. It is not proposed in this paper to go into all of the details of the problem. Instead, it will be assumed here that the intrusive has the form and characteristics represented in Fig. I. According to W. H. Emmons,1 minerals are not deposited in appreciable quantities below the "dead line." Important amounts of ores of virtually all metals may be found around summit cupolas, but only gold, copper and zinc (in limited quantities) are usually associated with trough cupolas. Most students of ore deposits agree that temperature changes are largely instrumental in precipitating many ores in the "hood" and that the difference in temperature between the intrusive and that of the country rock may be the chief factor in determining the mineralogy of a deposit. A problem then of some interest is to correlate the principal physical features of the intrusive with the phenomena of heat conduction as evidenced by the cooling curves and the isothermal surfaces. MATHEMATICAL THEORY In order to show the possible application of heat conduction to the interpretation of the processes of metalliferous deposition associated with intrusives, it will be assumed that the intrusive is a large parallelopiped of dimensions, 2l, 2m, 2n. The equation that represents the flow of heat from the parallelopiped into country rock (v = o, t = o), which has the same thermal properties as the intrusive, is2,3 [ ] In this equation, the origin, x = o, y = o, z = o, is at the center of the parallelopiped. 'v = temperature at point x, y, z, time t. vo = initial temperature throughout the intrusive, t = o. K = coefficient of thermal diffusivity. a, ß, ? are variables of integration. Put n = m in Eq. I, and we have [ ]

Jan 1, 1944

By W. G. Payne, A. C. Richardson, B. L. Gandrud

"INTRODUCTION The Connellsville mine of the Yolande Coal & Coke Co. is in the southwestern part of Jefferson County, Ala., about 30 miles southwest of Birmingham. The mine is on the Blue Creek bed, which is about 6 feet thick and dips at a angle of 18º. The bed is worked by the room-and-pillar method and is mined by both machine and hand methods. The Blue Creek bed at this point yields a high ash, low-volatile coal with excellent coking properties. Because of its exceptionally low volatile content and high coking strength, this coal is excellent for blending with Alabama coals of higher volatile content and weaker coking properties to form blends suitable for production of metallurgical coke.A sample of washed coal taken during this investigation gave the following analysis on an as received"" basis: Moisture, 8.3 per cent; volatile matter-, 20.2 per cent; ash, 8.0 per cent; fixed carbon, 63.5 per cent. The high ash content of this coal limits the quantity which can be utilized when low-ash coke is required. In the Birmingham district it is usually difficult to sell as coking coal a product that contains more than 8.0 per cent ash. To produce a. coal with this ash content at Connellsville presents a somewhat difficult washing problem. This paper gives the results of an investigation that was conducted by the Southern Experiment Station of the U. S. Bureau of Mines in cooperation with the University of Alabama and the Yolane Coal & Coke Co. for the purpose of determining the washing characteristics of the coal and the possibility of reducing its ash content on coal-washing tables.The practice at the Connellsville washery at the time of beginning this investigation was to crush the run-of-mine coal to pass a 1 1/2-inch round-hole screen and to treat the satire output on two primary, 3-compartment jigs. A. middling product was recovered from the primary jigs which was re-treated on a single-compartment rougher jig. This system yields a product of acceptable ash content, but the yield is low and the loss of good coal in the refuse is high."

Feb 1, 1933

By W. James Marold

The New Croton Aqueduct (NCA) was the first major water supply tunnel for New York City. The 50-km (31-mi) long tunnel has 33 open shafts 6 m (20 ft) to 121 m (397 ft) deep. The tunnel and shafts are lined with brick and mortar, with cast iron lining and pressure covers in six pressurized shafts. Details of the 1895 construction are provided and compared to modern construction techniques. The paper provides rehabilitation techniques for the shafts and pressure covers, including grouting, epoxy lining, temporary bulkhead design and installation and placement of tremie concrete 98 m (320ft) below the water level in a 122 m (400ft)deep shaft using a Remote Operated Vehicle (ROV) to monitor the placement.

Jan 1, 2008

By Dale S. Preece, J Paul Tidman, Stephen H. Chung

A discrete element computer program named DMC-BLAST (Distinct Motion code) has been under development since. 1987 for modeling rock blasting (Preece & Taylor, 1989). This program employs explicit time integration and uses spherical or cylindrical elements that are represented as circles in two dimensions (2-D). DMC-BLAST calculations compare favorably with data from actual bench blasts (Preece et al, 1993).

Jan 1, 1998

By John R. Wolosick

MACROPILES are defined as ultra-high-capacity micropiles, with working loads in excess of 250 tons. The piles are typically 9-5/8 to 24 inch (244 to 610 mm) outside diameter. They are drilled and grouted in place, with either large diameter steel bars and/or steel pipe reinforcement. The piles are typically tested to twice the working load. Piles with working capacities of up to 500 tons and tested to 1000 tons have been installed. The paper discusses MACROPILE design philosophy, construction techniques, and two case histories where this innovative foundation system has been installed. Macropiles are descended from micropile technology pioneered in the early 1950s by Fernando Lizzi of Italy.

Jan 1, 2006

By O. G. Lellep

Modern shaft kilns in Europe are fully mechanized and burn cement of acceptable quality at 700,000 Btu per bbl and lime at 3.2 million Btu per net ton. Rotary kilns for cement have increased in thermal efficiency by using exit gas heat for preheating incoming raw material and by recovering heat from outgoing clinker in air-quench coolers. The dry process Lepol or ACL kiln has the lowest fuel consumption, 580,000 to 630,000 Btu per bbl, and very low dust loss, about 1 pct weight of clinker. The Holdebank-Gygi system reaches 720,000 Btu per bbl. The calcinator kiln for the wet process consumes 1.1 million Btu per bbl. IN every country economic circumstances prescribe the method used to produce a commodity at lowest cost. In Pennsvlvania a man's wages for working 4 hr buys a ton of coal wholesale; in Germany a laborer must work 40 hr, or ten times as long. In western Europe, therefore, conservation of fuel is of primary importance, and recent practices of burning lime and cement differ from those employed in the United States. 'This Paper presents data collected during a trip through western Europe in 1953. Considered uneconomical, shaft kilns for burning

Jan 1, 1955

The strippable reserves of bituminous coal and lignite in the United States were calculated in accordance with the prevailing conditions of seam thickness and depth of overburden in each of the several coal-producing areas of the Nation. Within defined limits of seam thickness and depth of overburden, it is estimated that there was a remaining strippable resource of 118 billion tons of raw bituminous coal and lignite as of January 1, 1968. Because of topography, natural and manmade features, and other limitations, only 45 billion tons of the resource are strippable reserves. Of this, 32 billion tons is considered low-sulfur (less than 1 percent), 4 billion tons is medium-sulfur (1 to 2 percent), and 9 billion tons is high-sulfur (over 2 percent) coal. Owing to a cleaning loss affecting that portion of strip coal that is mechanically cleaned, the 45 billion tons of strippable reserves are reduced to 39.6 billion tons of marketable coal. A brief discussion is given for each coal-producing State, summarizing past and present production, historical background, and outlook. Appendix A contains reserve data by State, county, seam, and sulfur content. Appendix B contains the general information and requirements necessary to comply with the current strip mining laws covering 20 States.

Jan 1, 1971

By S. J. Dai

The cadmium and cyanide are main poisonous components in cyanide electroplating cadmium waste water of an electroplating plant in Shenyang. The content of cadmium is about 26 mg/L and the content of cyanide is about 11.782 mg/L in this waste water. The main form of cadmium and cyanide are ions which are Cd2+and CN?. Because the cadmium and cyanide exceeded the standard seriously, the waste water must be disposed before it discharges. The microbiological method of treating heavy metals in wastewater has many advantages. For example, it has a fast adsorption velocity, high processing efficiency, wide range of pH and temperature, few invest, low running cost, no the second pollution and so on. At the same time, the CN? could be degradated by some microbiology. The physical nature, the chemical nature of Bacillus mucilaginosus, the adsorbing condition and adsorbing regular of Bacillus mucilaginosus to cadmium in the wastewater are studied by using Bacillus mucilaginosus as adsorbent removing cadmium from electroplating wastewater. The experimental results show that the adsorbing rate of cadmium is over 92%, under the room temperature(about 25?), stiring revolution in adsorption being 800 r/min for 30 min, pH being 5 , the bacteria being cultured after 5d with the biomass of Bacillus mucilaginosus 40g/L (wet weight). The mechanism in biosorption process of Bacillus mucilaginosus to cadmium is analyzed and discussed by TEM , Zeta potential,and infrared spectroscopy analysis. The results showed, the chemical involving is main adsorbing form, while electrostatic attraction, ions exchange, hydrogen bonding and Van Der Waals force are concerned cooperatively. ?NH2 ?, ?C=O?, ?C=O?NH?CH2, ?CH3, ?OH are main adsorbing groups. At the same time, the floatablity of removing cyanide by Bacillus mucilaginosus is explored.

Jan 1, 2014

Preface The intention of this paper is to provide the reader with knowledge gained here at Memorial University regarding the practical use of the Bruker SDD x-ray detector for applications in image analysis. Included below are descriptions of the detector’s characteristics and observations regarding precautionary use. What is described below is relevant to the XFlash® model 3001 detector only, whereas the model 4010 is the new and currently available detector. The manufacturer has provided up-to-date information and a figure that presents very different behaviour relative to the characteristics described in this paper. That information and figure is also included here as an addendum (see figure 9). Introduction It has been more than two decades since an image analyzer has been proposed based on the unique imaging characteristics and spatial resolution provided by the scanning electron microscope (SEM) together with energy discriminating x-ray (EDX) acquisition (Reid et al, 1984). From the inception of technique, technology of the day has played the major role for making applications increasingly more practical. Computers, digital imaging, and softwares together with computer automation of modern digital SEMs have all played their part in advancing the technique to where it is today.

Jan 1, 2007

By Robert E. Fosse

Driven 14-inch-square concrete piles were used as the foundations of Genentech Hall at the new University of California, San Francisco Mission Bay Campus. The five-story, steel eccentrically-braced frame building is currently under construction at a 43-acre property located in a former large shallow marshy inlet from San Francisco Bay. The piles were driven through 10 to 25 feet of fill and 20 to 60 feet of soft compressible Bay Mud into an underlying dense sand layer. Pile design capacities were developed for traditional allowable stress design, load factor and resistance design, and ultimate design criteria. The ultimate level capacities were for checks of loads occurring when the links in the eccentrically-braced frame yield during an earthquake. A load test program was performed to confirm pile design recommendations. Two test pile locations were selected for compression, tension, and lateral load tests to evaluate pile capacity and pile/soil stiffness under long-term, short-term and rapid loading conditions. Maximum test loads were 1000 kips downward, 350 kips uplift and 50 kips lateral. Foundation construction began by driving 34 indicator piles with a Delmag D46-32 diesel hammer of 113 foot-kips maximum rated energy. All indicator piles were monitored during initial driving using the Pile Driving Analyzer. Restrike data, obtained several days after initial driving, indicated significant pile-soil setup and typical pile capacity increases from 750 to 1000 kips. The majority of the 1242 production piles were then driven to acceptance criteria of 75 blows per foot and a minimum embedment of 10 feet into the dense sand bearing layer. Piles driven to full length without achieving the blowcount criteria were evaluated on a case-by-case basis. Acceptance of these piles was established by evaluating restrike data.

Jan 1, 2002

Jan 1, 1962

By A. Jarosz

The surface manifestation of underground mining usually entails five distinct types of surface movements, which can affect or damage surface structures, facilities and renewable resources. These movements developing at the surface can be described by (Bell, 1975; Bhattacharya and Singh, 1984): - vertical displacement, i.e. subsidence, - horizontal displacements, - slope or tilt, i.e. the derivative of the vertical displacement with respect to the horizontal distance, - curvature, i.e. the second derivative of the vertical displacement with respect to the horizontal distance, and, - horizontal strain, i.e. the derivative of the horizontal displacement with respect to the horizontal distance.

Jan 1, 1986

By L. M. Irwin

This Bureau of Mines investigation relates the physical properties of copper reverberatory furnace slags to changes in composition, The smelting of upper Michigan copper ore presents some problems that probably differ from those of other copper smelting areas. The study of these problems has, however, provided important data regarding slags in general and therefore will be of value to other operations as well. Conclusions reached from this study were: (1) Slag fluidity and refractive indices varied directly with the iron content and inversely with silica, lime, and alumina, and (2) there was no apparent correlation between slag fluidity and its copper content.

Jan 1, 1962

By Juan Enrique Alvarez Ogusko

Rotas hidrometalúrgicas para o beneficiamento do minério de cobre vem sendo estudadas a fim de substituir o processo tradicional por pirometalurgia. No entanto, o uso de soluções lixiviantes como o ácido sulfúrico e a amônia são considerados ambientalmente desfavoráveis ao processo e descarte. Além disso, durante a lixiviação do cobre também ocorre a lixiviação do ferro. O uso de glicina como agente lixiviante é uma alternativa de baixo impacto ambiental já que é um aminoácido capaz de ser metabolizado por organismos vivos. Na lixiviação, a glicina apresenta a capacidade de formar um complexo quelante apenas com o íon Cu2+. Esse trabalho buscou avaliar a capacidade de lixiviação de um minério de cobre concentrado proveniente do Peru. Para isso, três concentrações de glicina em meio aquoso foram avaliadas nas temperaturas de 25ºC (48 horas de contato) e 60ºC (duas horas de contato). O pH da solução foi mantido entre 10,5 e 11 com adição de hidróxido de sódio. Foi possível lixiviar acima de 30% do cobre usando 0,8M de glicina na solução e em ambas as temperaturas de estudo. Além disso, a lixiviação do ferro ficou abaixo de 0,6% mostrando a seletividade da glicina para o cobre durante a lixiviação.

Oct 30, 2017

By Damon P. Vandermaat

Coupon testing allows for the rapid understanding of a material?s likely behavior in service conditions, allowing engineers and operators to make informed decisions about the likely service-life of parts when subjected to field conditions. Bend testing has been identified as the best approach for exploring rock bolt susceptibility to stress corrosion cracking (SCC) in underground mining. The bend test specimens used were 2?3 mm thick slivers of steel, cut from the outer edge of a rock bolt. For the specimens, 1350 grade steel was chosen due to its wide use in the industry. The jigs themselves are small assemblies made of stainless steel that are capable of imparting a bending load on the specimens. The jigs were installed at a coal mine located in the Western Coals West of Sydney, Australia, in such a way as to expose the test specimen to water dripping from the mine roof. It is expected that this approach will yield results pointing to the likely SCC mechanisms affecting the service life of rock bolts, as well as demonstrate the jigs? usefulness as an early warning system for SCC. Furthermore, the coupon tests will be correlated against the results of large-scale laboratory tests.

Jan 1, 2012