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By E. J. Roberts

Hydrometallurgical operations and many processes in the chemical industry require the separation of dissolved material from solids. One of the decisions which has to be made in designing a plant for such an operation is how this separation shall be accomplished. It is the purpose of this paper to set forth the general principles involved in such separations in order that the optimum flowsheet and equipment may be selected. Countercurrent Decantation with thickeners, or C.C.D. as it is generally known, is, of course, only one way of separating dissolved material from undis-solved. Other unit operations such as Countercurrent Filtration (C.C.F.) and Countercurrent Classification (C.C.C.) are widely used. The same principles may also be applied to centrifugally assisted decantation, as with nozzle or solid bowl type centrifugals, and to separations using screens, either gravity or centrifugal type. Another form of countercurrent washing applicable to granular materials is practiced in continuous ion exchange operations. All of these operations depend on two basic principles, or combinations of these principles. In C.C.D. type operations the solids are concentrated into the smallest possible volume of liquor in each step and the resulting pulp then mixed with a more dilute liquor and recon cen trated, the liquors separated from the more dilute stages being advanced to dilute the more concentrated liquor in a previous solids concentrate, as is shown in Fig. I. This will be termed the solids concentration-solution dilution principle, or, for short, solution dilution. countercurrent decantation- type circuits. The second principle used in washing solubles from solids is that of solids concentration-solution displacement. Here the solids are restrained from movement while wash solution is forced through the interstices in a counter-current fashion, as in Fig. 2. In the simplest application of this principle, once the "cake" has been formed, it is not disturbed until the operation is completed. In continuous filters, the cake is merely moved under the successive washes and the displaced filtrates removed as in Fig. 4. Often, however, after one or two displacement washes, a repulping step is introduced, the cake reformed and washed again. This procedure brings the solution dilution principle into play as well as the solution displacement principle. Merely thickening ahead of filtration, which is often operationally advantageous, does not hybridize he circuit. It still can be a pure solution displacement operation from the washing

Jan 1, 1961

By V. D. Smar

The flotation process may be considered an interactive system consisting of many chemical, operational, and equipment variables. Changing anyone of these variables causes an overall system response change. This study examines the effects of simultaneously changing the operating variables of: (1) frother concentration and air flow rate, and (2) frother concentration and collector concentration. It is part of a comprehensive study to look at how changes in several of the major variables may be used to produce interactions which will allow the rougher flotation process to be optimized. Ultimate recovery, flotation rate, concentrate grade and froth quality, are used as the major evaluative criteria.

Jan 1, 1993

By T Brown

Australia is now committed to the most significant period of infrastructure investment since the 1960s and the current climate of project finance and public private partnership (PPP) model uncertainty means it is imperative that the affordability and certainty in delivery of infrastructure projects is maximised.In light of the current and forecast levels of infrastructure investment it is worth drawing comparison with a similar period of Australian expansion when the nation’s first railways were constructed. Similarly to over a century ago, we are following a trend in rapid development and are already reaping the inefficiencies that could be avoided with broader technical planning and improved client coordination.The original rail networks were developed by the individual states before they combined to form a Federation of states in 1901. As a result of the adoption of different gauges by 1917 a passenger wanting to travel by train from Brisbane to Perth had to change trains six times.Similarly in 2011, there is little parity between Australian states on the quality requirements (performance specifications) for road tunnels. Differences between states start most significantly with the size of the specified traffic envelopes, thus the size of tunnel required. Where ambiguity and differences exist in project documentation, performance specifi cations (PS) and broad technical requirements for road tunnel projects, any associated risk in interpretation ultimately ends up being incorporated in the bidder’s (constructor’s) final sell price.Whilst not nearly as inconvenient as having to change train at each state border, and largely unnoticed by the general tax paying motorist, this paper examines examples of apparent minor differences in Australia’s recently constructed road tunnels to highlight the differences in road tunnel specifications.The paper identifies how these small differences manifest themselves in major price penalties between projects and further, highlights the need for further specification review, refinement and standardisation across road tunnel jurisdictions to increase road tunnel affordability.

Mar 8, 2011

By V P. Elpatyevskaya, V S. Arzhanova

Main geochemical problems concerning the environment and mining industry interrelation are connected with the transformation of natural water chemistry by mining wastes. The investigation of many mines in Primorye, the southern part of the Russian Far East, showed that their mining waters have high concentrations of heavy metals and aluminium. Water acidity is primarily connected with the amount of acid-forming sulphide minerals in ores and also depends on the neutralising capacity of rocks. Considerable quantity of metals occur in the waters in dissolved form. Metal concentrations in mining waters exceeds the natural levels by two to five orders of magnitude and can't be reduced to the background levels even after multiple dilution. It is necessary to develop and put into practice new technologies so that to reduce the geochemical impact upon the environment.

Jan 1, 1995

A new porphyry copper gold district has been discovered at Goonumbla near Parkes in central New South Wales. Endeavour 26 North is the largest deposit known to date with a possible resource of 166.4 million tonnes at 0.74% copper, 0.12g/tonne gold and 1.7g/tonne silver, using a cut-off grade 0.3% copper. Mineralisation is primarily bornite in the higher grade zones and chalcopyrite in the peripheral lower grade zones. Most of the copper, gold mineralisation is associated with potassic alteration. Two mineralised quartz monzonite porphyry intrusive stages have been identified and these are related at depth to a large monz- onite stock which may have been the source of some of the mineralisation. On the basis of detailed paragenesis studies, the potassic zone can be divided into three symmetric subzones. The low grade inner potassium feldspar subzone is confined to the later intrusive porphyry. The outer potassium feldspar subzone is the most highly mineralised alteration halo due to the focussed superimposition of two hydrothermal cycles which have overprinted intrusive and volcanic rocks. The fringing biotite potassium feldspar subzone reveals alteration minerals which are developed early in the paragenesis. Fracture controlled quartz sericite alteration with low sulphide content, fringes and, in part overprints the potassic zone. The restricted pipe-like nature of the alteration zones and related mineralisation suggests that Endeavour 26 North is repres- entative of a multiphase focussed porphyry copper gold system.

Jan 1, 1986

By Woodcock J. T

During the dissolution of gold in fully aerated cyanide solutions the CN ion is the active agent, and consequently the usual method of evaluating the dissolving power of such solutions is to determine the CN- concentration analytically. The presence in the solutions of copper and/or zinc which themselves form complex cyanides, may result in erroneous conclusions as to the free cyanide ion concentration determined by titration.In this paper the theory of titration of such solutions has been developed, and potentiometric methods have been used to follow the behaviour of complex cyanides of copper and zinc. The results for cuprocyanides show Cu (CN)s to be the most important copper complex, and in addition they explain the reported low rates of solution of gold in copperbearing solutions which when titrated in the usual way, appear to have adequate free cyanide. An explanation of the misleading value of the titration is given, and suggestions for recognition of the condition are offered. Preliminary results for zinc-bearing solutions show that there is no satisfactory end-point for the titration of CN- in excess of that in the complex Zn (CN) 4=, which dissociates to CN and Zn(CN)g-.

Jan 1, 1950

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, Hara, A. S. Kabir, R. Petrov

Manufacturing of thin sheet is difficult in industries. Some approaches, such as small-draft multi-pass rolling, intermediate annealing, isothermal rolling and high-speed rolling were proposed to overcome the deformability. In this study, different rolling speeds from 15 to 1000 m/min were employed to twin rolled cast AZ31B magnesium alloy to different reductions. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2014

By L. H. McGuire, L. B. Berger

"During the period October 31 to November 4, 1944, tests were conducted by the Bureau of Mines in the Cascade Tunnel of the Great Northern Railway Cc. to determine the effects upon the tunnel atmosphere of the use of a Diesel freight locomotive through the tunnel. These tests were conducted at the request of the company to ascertain whether undesirable conditions might be caused by the discharge of Diesel engine exhaust gas in the tunnel, which was constructed for an electric haulage system and is not provided with equipment for mechanical ventilation. The use of Diesel locomotives on the division that includes the Cascade Tunnel was under consideration as a means of augmenting haulage facilities for the abnormal freight tonnage that must be handled during wartime.As the Bureau of Mines has received requests for information on the extent of contamination of the air of railroad tunnels by Diesel locomotives, this report was prepared to make available for general information the data obtained during the tests in the Cascade Tunnel. As the test locomotive is of a type used on other railroads, and as the bore and grade of the tunnel and the tonnages moved are comparable to such factors on other roads, the data should be sufficiently representative to be of general interest. The exceptional length of the Cascade Tunnel made it an excellent location for obtaining information on the composition of the tunnel air and on the movement of air induced in the tunnel by the passage of trains.The writers are indebted to C. O. Jenks, vice president of the Great Northern Railway Co., who arranged for the tests, and to the following personnel of the railroad who cooperated in the conduct of the tests: I. E. Clary, superintendent, Spokane Division, J. L. Robson, superintendent of motive power, oil and gas equipment, J. F. N. Gaynor, superintendent of electric operations, William Lowney, master mechanic, Spokane Division, and D. F. Marston and Verne Nelson, assistant superintendents of electric operations.The Cascade Tunnel is on the Spokane Division of the Great Northern Railway and pierces the Cascade Mountains some 49 miles west of Wenatchee, Wash. The west end of this division is electrified from Appleyard Station, 2 miles east of Wenatchee, to Skykomish, Wash., a distance of 73 miles. Until the described tests, only electric haulage had been employed through the tunnel since it was first opened to traffic in January 1929.The Cascade is the longest railroad tunnel in the United States - 7.79 miles. The tunnel is single-track, perfectly straight, concrete-lined, and is on an essentially uniform grade of 1.56 percent, ascending from west to east. The cross-sectional area of the tunnel is 314 square feet, the dimensions being shown in figure 1. Elevation of the east portal is 2,880 feet and of the west portal, 2,240 feet."

Jun 1, 1946

For many years the scrubbing of roaster gas carrying sulphur dioxide has been carried out at the plant of the Electrolytic Zinc Co. of Australasia Ltd. at Risdon, Tasmania, using long horizontal tubes. in which the gas stream crossed a shower of water. In order to provide for increased roaster capacity, it was evident that additional gas scrubbing capacity would be required to prevent pollution of the atmosphere.This provided an opportunity to review the whole operation of gas scrubbing and an investigation was initiated to determine the characteristics of a counter-current type of scrubber. It was hoped that a change to this type of scrubbing would also reduce the sulphur dioxide concentration of the gas delivered to the atmosphere to a negligible amount. This, paper outlines results obtained from an experimental tower which was operated under a wide range of conditions, the packing height, gas flow, water flow, water temperature, and concentration of S02 in inlet gas being varied independently. A description is given of the leading features and operating characteristics of the plant units, which are designed on the basis of the experimental results. Operation of the new scrubbing system commenced on October 5th, 1948.THE PROBLEMThe gas which is handled carries S02 which may vary in concentration from 2% to 5%, and reaches the scrubbing system at a temperature of approximately 180 deg. C. An appreciable amount of suspended material accompanies the gas which has passed the cyclone system.

Jan 1, 1949

By K. Fagerlund

Methods for simulation of settler reactions, matte-slag separation and matte settling in copper flash smelting have been examined. The reaction, separation and settling phenomena of slightly oxidized chalcopyrite samples and cuprous sulfide-magnetite mixtures in fayalite type slags were examined at about 1300°C under inert atmosphere. Two methods based on introduction of molten samples of oxidized chalcopyrite concentrates or synthetic matte-magnetite mixtures onto the surface of molten iron silicate slag were tested. In the first method the samples were water quenched and polished specimens were studied and analysed using light optical microscope, scanning electron microscope, energy dispersive spectrometer. In the second method processes taking place after the introduction of samples onto the slag are followed "in situ" using X-ray transmission image monitoring. Great differences were observed in separation and settling behaviour of low and high grade copper mattes produced as a results of interaction of initial samples and slag.

Jan 1, 1997

By R. Agius, A. Nacu

"Adoption of the International Cyanide Management Code, regulatory requirements and community concerns have increased the need to implement suitable cyanide destruction processes at gold operations to meet ever more stringent discharge limits. As standards set for the allowable concentrations of cyanide, cyanide compounds and other contaminants may vary from country to country, jurisdiction to jurisdiction, and even from site to site, there is no “one size fits all” technological solution. Currently the most common cyanide destruction processes used in industry are sulfur dioxide/oxygen, hydrogen peroxide and Caro’s acid. Regardless of the process used, cyanide destruction plants must be reliable and achieve permit guidelines at all times. The selection of the most appropriate cyanide destruction process for an operation depends on several factors, including permit discharge requirements, tailings chemistry, location, site-specific climatic conditions and size of the operation. Only after considering all these factors together can the most effective approach be selected to achieve the permit guidelines economically and technically feasible. Finally performing the correct test work program is the most important step to ensure that the correct process design criteria can be determined to accurately calculate capital and operating costs.IntroductionThe adoption of the International Cyanide Management Code in 2005, stricter regulatory requirements and community concerns prompted by environmental incidents involving cyanide have increased the need to implement cyanide destruction processes at gold and silver operations.Process solutions associated with the extraction of gold and silver contain several forms of cyanide. The most toxic form of cyanide is free cyanide, which can be present as a dissociated cyanide anion (CN-) or gaseous or aqueous HCN. Weak or moderately stable cyanide complexes such as those of zinc, copper and nickel are classified as weak acid dissociable (CNWAD). Although less toxic than free cyanide, weak acid dissociable cyanide complexes are considered “ecologically sensitive” forms of cyanide and are regulated in most jurisdictions. In practice, reported WAD cyanide values are comprised of both free cyanide and weak acid dissociable cyanide complexes. Cyanide complexes with gold, mercury, cobalt and iron are referred to as strong acid dissociable complexes (CNSAD) and are much more stable even under mildly acidic conditions. Another term commonly used in cyanide chemistry is total cyanide, which represents all cyanide compounds present in solution, with the exception of cobalt complexes. Total cyanide levels in solutions are in most cases higher than WAD cyanide values and the difference between the two usually indicates the presence of iron-cyanide compounds. Typically, in Canada CNTOTAL levels cannot exceed 1 mg/L in solutions."

Jan 1, 2017

The estimation of the spatial variation of the b-value of the Gutenberg- Richter relationship is important for both the general interpretation of the mechanism of rock mass response and seismic hazard assessment. The interpretation of b-value as a parameter of rock mass response is discussed in this paper. The methods applied to evaluate the spatial variation of b-value and the algorithm for obtaining the magnitude of completeness and b-value for subsets of data are presented with some verification analyses. The algorithms presented enable the automation of a spatial evaluation of b-value.

Jan 1, 2014

By L. W. Bahney

MANY methods for the determination of gold or silver, or both, in cyanide solutions have been published, which with care in manipulation, and modification in some cases, will give results that are satisfactory. It is possible to classify or group these methods as follows: 1. Evaporating the solution in a porcelain or agate-ware dish containing litharge,1 or in a "boat" made of lead foil. 2. Forming a lead sponge containing the precious metals by means of zinc shavings,2 zinc dust,3 or a piece of aluminum.4 3. Decomposing the cyanide solution with an acid and precipitating the precious metals by the use of one or a combination of some of the following: Copper sulphate,5 sodium sulphite,6 hydrogen sulphide,7 cement copper.8 4. Precipitating the silver by zinc dust held in a Hooch crucible and determination with a standard solution of sulphocyanate.9 5. Electrolysis.10 6. Colorimetry.11

Jan 2, 1915

By Yongbin Yang

Cathodic reduction of oxygen is a process involved in many fields. As is well known, the mechanism of oxygen reduction usually varies considerably with electrode substrates. In this paper, cathodic reduction of oxygen on gold electrode was studied by linear sweep voltammetry with regards to cyanide leaching of gold. As the results shows, the electron transfer number increases as potential shifted negatively and decreases as pH value increases. Besides, the increment of electron transfer number as a function of potential decreases when pH value increases. When pH increases to 13.0, the volt-ampere curve exhibits a relative flat section with currents approximate to the limit current density of a 2e process. By varying dissolved oxygen concentration, the electron transfer number was calculated for pH11.0 at different potentials, the results being 2.387e, 2.732e, 2.982e, and 3.227e at, -0.35V, -0.40V, -0.45V, and 0.50V, respectively. The calculated current densities are in good conformity with measured results.

Jan 1, 2010

By Bruce Geller

The 2005 Prospectors and Developers Association of Canada (PDAC) convention continued the upbeat mood found in 2004. The global mining industry is booming due to higher commodity prices in nearly every sector. Other factors include low commodity inventories, China’s strong resource demands, the weak U.S. dollar, the very strong Euro, global uncertainties, an almost overripe investment climate for natural resources and the highest mining exploration budgets in seven years. Even unglamorous commodities, like iron, uranium and zinc, received copious attention in talks, the investors’ exchange, the core shack and in certain hospitality suites. The following impressions were gathered at the convention and enhanced by conference handouts and some abstracts that are available on the PDAC’s Web site, www.pdac.ca. At least 119 papers were presented, almost twice last year’s number.

Jan 1, 2005

By G. J. Hasenfus

This paper presents the results of an extensive hydrological and geomechanical monitoring program which Gas conducted at a longwall coal mine in W. Va. The field program included monitoring of groundwater levels. overburden hydraulic conductivity, overburden movement, and surface subsidence relative to the passage of the longwall. Overburden geology and rock strength characteristics were evaluated prior to mining. A postmining corehole was drilled to evaluate main roof fracturing. An overburden response model is proposed based on the correlations between hydrological and geomechanical data.

Jan 1, 1988

By K. C. Mills

The objective of this work was to provide process engineers with values of the physical properties of various slag systems involved in high-temperature processes. Software that calculates the thermo-physical properties of slags from chemical composition is available on the www.pyrometallurgy.co.za website. This paper outlines the principles underlying the various models available in the program. The software calculates the following properties of crystalline, glassy, and liquid slags (where appropriate) as a function of temperature: heat capacity, enthalpy, density, viscosity, thermal conductivity, electrical conductivity, and surface tension. We hope, in the future, to update the program to (i) add new models as they become available, (ii) remove any ?bugs? discovered in existing programs, and (iii) provide guidance on the limitations of individual programs.

Jan 1, 2011

By Xiong Dahe

In recent years many creative technologies are applied to SLon vertical ring and pulsating high gradient magnetic separators. SLon-2500 and SLon-3000 vertical ring and pulsating high gradient magnetic separators are created towards larger scale. Through optimizing the magnetic system and lowering the electric current density, their energy consumption is obviously dropped. New magnetic matrixes are developed to raise the beneficial efficiency of valuable minerals. Special SLon vertical ring and pulsating high gradient magnetic separators are developed which can treat coarser particles of 0-5 mm. Through these technology creations, the mineral processing efficiency of SLon magnetic separators is further raised and their processing cost dropped. Therefore, they have been found wider applications. SLon-2500 applied in Essar Steel of India. In 2007, Essar Steel did a test on its Kirandul hematite ore with SLon magnetic separator and got very good results. The feed grade is 59.77%Fe, after SLon one roughing and one scavenging, the total iron concentrate grade is 65.00%Fe and iron recovery 93.86%. In 2008-2010, the company bought 10 SLon-2500 magnetic separators to treat such iron ores. In 2010 the first SLon-3000 was applied to processing ilmenite. The magnetite-ilmenite deposit is located in Pan Zhi Hua, Si Chuan Province of China. The ore processing flow sheet is: Drum low intensity magnetic separator is used to take out magnetite, and then the SLon-3000 is used to recover ilmenite for roughing. The mags of the SLon-3000 are further cleaned by flotation. The SLon-3000 average operational results are: feed grade 9.52%TiO2, mags grade 17.43%TiO2, mags mass ratio 41.01%, TiO2 recovery 75.09%, non-mags grade 4.02% TiO2, non-mags mass ratio 58.99%. SLon magnetic separators Applied to treat 0-5mm limonite: The feed of SLon magnetic separator is usually 0-2 mm which needs to be ground by ball mill. As many Chinese iron ores are poor grades, if we can throw part of tails before grinding, the grinding cost will be greatly reduced. In 2010, a SLon-1500 and a SLon-2000 were specially built to treat 0-5 mm limonite. The feed grade is 26.51%Fe, mags grade 53.20%Fe, iron recovery 64.26, and tails grade 13.66% Fe. SLon-2500 applied to purify quartz. In 2009, a SLon-2500 magnetic separator was applied to purify quartz in Shan Xi province. Its feed is 0-1mm quartz which contains 0.15%-0.25%Fe2O3, the designed non-mags grade need to be less 0.08% Fe2O3. The production results of SLon-2500 non-mags are 0.05-0.06% Fe2O3, much better than the designed data. SLon applied in Si Jia Ying Iron Mine to recover hematite. Si Jia Ying is a big oxidized iron mine located in He Bei Province of China. In 2005-2010, a plant annually treating 10 million tons of oxidized iron ore was built in which 39 SLon magnetic separators are applied. The total flow sheet results are: Feed grade 30.44%Fe, iron concentrate grade 66%Fe, iron recovery 80%Fe, tails grade 9.65Fe%. SLon applied to recover specularite. Li Lou Iron Mine in An Hui Province of China built a plant annually processing 5 million tons of iron ore in 2010-2011. 25 SLon-2000 magnetic separators are applied to recover specularite. The total flow sheet results are: Feed grade 31.65%Fe, iron concentrate grade 65%Fe, iron recovery 80%Fe, tails grade 10.37%Fe. SLon applied in Da Hong Shan Iron Mine. Da Hong Shan Iron Mine is located in Yun Nan province of China. It treats 4.5 million tons of oxidized iron ore annually. 15 SLon-2000 magnetic separators are applied to recover hematite. The total flow sheet results are: Feed grade 35.61%Fe, iron concentrate grade 64.95%Fe, iron recovery 74.08%Fe, tails grade 15.55%. Keywords: SLon magnetic separator, iron ore, ilmenite, quartz, beneficiation

Sep 1, 2012

By George A. Burrell, Frank M. Seibert

The Bureau of Mines, as part of its designated duty of investigating the causes of mine accidents, is conducting at its experiment station in Pittsburgh, Pa., a study of mine gases. Some of the work already done in connection with this study is outlined below. A large number of mine-gas samples have been collected under normal conditions in returns and in splits, and at other points in the ventilating current, also at the face, in the goave or gob, in unventilated places, and wherever the air was still. Samples have also been obtained under abnormal conditions, as after explosions and while mine fires were in progress, or from sealed areas behind stoppings and darns where the air had been stagnant for some time. Chemical changes in the composition of mine atmospheres during mine fires have been studied," and conditions peculiar to certain mines have been investigated. The question of the effect of a change in atmospheric pressure on the escape of gas (methane) in coal mines has been studied. Explosives have been fired in both coal and metal mines, and samples of resulting gases have been collected to ascertain the degree to which these gases vitiate the air. A series of samples in mines where gasoline locomotives were being used have been examined in order to ascertain the degree to which the exhaust gases from such locomotives foul the mine air. Experiments have also been performed in regard to the relative effect of carbon monoxide b upon men and small animals. A preliminary report relating to the inflammable gases in mine air has been published. Full reports of the results of the investigations outlined above will be published as soon as all the necessary data have been gathered. The first part of this report deals with the methods used by the bureau in the collection and examination of the various mine gases; the latter part discusses the bureau's methods of sampling and examining natural gas.

Jan 1, 1913

Many mining operations are uncertain of what costs they should be achieving. The majority of cost estimates are based on historical costs that have added contingency factors. Historical costs are a valuable source of information but a more precise costing method is necessary. There are several alternative methods for predicting costs. A methodology which provides the best indication of the achievable costs is one using a standard inventory list and a bill of quantities. The model is termed a Basic Principles model and addresses basic design principles and engineering constraints.

Jan 1, 1990