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By Dominik Gächter, Wojciech Szczepiñski

In early 2020, the construction phase began for the new complex of buildings for Radium Hospital in Oslo – the leading facility for cancer treatment in Norway. Settlements in the surrounding area, caused by pore pressure changes, allowed for the introduction of an alternative solution for the construction of the excavation pit. The presence of solid bedrock and sensitive clay – the same material that causes major landslides in the Scandinavia – in the excavation pit, lead to a combination of techniques, which were never applied in Norway before. For the stabilization of the clay Dry Deep Soil Mixing was applied to allow safe execution of the geotechnical works. Interlocking Bored Piles with footbolts and Jet Grouting columns, in combination with anchors, provided the retaining structure for the excavation pit. Rock injections were performed to avoid any ground water ingress into the pit. Underpinning of fully operational, adjacent buildings was carried out with jet grouting columns. These works were performed from the basement of the hospital and the ‘ACI – Acoustic Column Inspector’ was used to ensure proper installation of 2 m diameter columns to a maximum depth of 25 m. The buildings were later founded on Steel Core Piles, the most common pile type in Scandinavia.

Sep 8, 2021

By J. Kretschmann, A. Müterthies, T. Rudolph, C. Yang, P. Goerke-Mallet

Catastrophic failures of dams and tailing storage facilities (TSF) have triggered the development of integrated ground monitoring concepts for hazard assessment, risk management and public safety. These concepts are based on knowledge and expertise of persons technically responsible for TSF. The aim is to combine this implicit and explicit knowledge with the data of in-situ- and remote sensors. Risk management for TSF must include a comprehensive monitoring program that integrates data from ground based-, air-borneand satellite-based sensors. Researchers at Technical University Georg Agricola (THGA) in Bochum, and EFTAS, Muenster, Germany, are fusing a variety of sensor data to enhance the capability and performance of TSF monitoring to ensure public safety downstream of TSFs. This paper describes the variety of sensors implemented in numerous research projects. It gives an outlook in terms of planned satellite missions with innovative equipment like hyperspectral sensors. The implementation of the data of these sensors in the analysis will increase the understanding of spatio-temporal impacts of mining activities. Future opportunities are explained by a datacube approach.

Mar 2, 2022

By J. G. Haymes

This report by the Bureau of Mines is the first of two proposed papers on evaluation of spectrophotometric, spectrographic, polarographic, and other analytical methods for quantitatively determining impurities in high-purity tungsten. Some of the methods described are standard methods that have been successfully applied to determine low-level impurities, several are modifications of known methods, and some procedures are entirely original. The Bureau of Mines is actively engaged in tungsten research because tungsten has an extremely high melting point, in fact the highest of any known metal. The metallurgist must know the content of impurities in tungsten because of the marked effects even micro amounts of impurity elements have on its physical properties. The Bureau procured a number of analyzed samples of above-average purity from research laboratories of companies engaged in production and fabrication of tungsten. These samples were investigated by the analytical procedures of those companies for several metallic impurities. Subsequent analytical laboratory determination of impurities in these samples agreed with the analyses as reported. With this assurance that analytical methods were basically accurate for metallic impurities, procedures for the determination of several of these elements were modified to lower the limits of detection and increase the sensitivity of methods. Carbon and the gases hydrogen, nitrogen, and oxygen were determined by standard instrumental methods, modified to provide greater sensitivity for reliable determinations when content of these elements was low. After the reliability of the modified procedures was affirmed, they were used as a product evaluation guide in the development of a vapor-plating technique for the production of high-purity tungsten. The following list of elements can be determined by one or more of these methods: AI, B, Be, Ca, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, S1, Sn, Ti, V, and Zn. In addition, a vacuum-fusion method for the determination of H, N, and 0, and a conductometric method for carbon are described. Lower limits of determination and detection for each element listed are given.

Jan 1, 1962

By John H. Schilling

The Gabbs magnesite-brucite deposit is unique in size and is one of two magnesite deposits being exploited in the United States. It is near the town of Gabbs, which is one hundred miles southeast of Reno, in west-central Nevada. The brucite was discovered in 1927; the magnesite was found while exploring the brucite. During World War II, more than 80,000 tons of magnesium metal was produced from about 900,000 tons of magnesite ore mined from these deposits. An additional 5,000,000 tons of magnesite and 1,000,000 tons of brucite have been produced for use in making magnesia refractories and chemicals. Basic Inc., presently the only producer, mines 1.5 ± 0.25 million tons of ore and waste annually using high-selective open-pit rriethods; the ore is up-graded, calcined, and processed into a variety of products. Known reserves of highgrade (less than 5 per cent CaO) magnesite ore total more than 25,000,000 tons, and there are larger tonnages of lower-grade material; brucite reserves are small. The magnesite and brucite are in generally west-dipping dolomite of the upper member of the late Triassic Luning Formation, in the over-riding plate of the Paradise thrust fault. A great variety of dikes and a stock of Cretaceous granodiorite intrude the Luning Formation in the vicinity of the magnesite-brucite deposit. The magnesite bodies are scattered over an area of about a square mile around a prong of granodiorite which extends north from the stock. The brucite is mainly in two bodies in contact with the prong of granodiorite; at the surface and along deeper cracks the brucite has weathered to hydromagnesite and artinite. In the area of magnesite-brucite mineralization, much of the dark, fine-grained, schistose, regionally-metamorphosed dolomite of the Luning Formation has been marmorized to a lighter-colored, coarser-grained, massive dolomite that is intergrown in varying proportions with the magnesite. The magnesite and marmorized dolomite can not be distinguished visually. In addition to the two varieties of dolomite, the gangue in the magnesite and brucite bodies mainly is the various varieties of dike rock, serpentine and a variety of other "contact" minerals, and "post-ore" dolomite and calcite. The magnesite ( and recrystallized dolomite) is believed to have formed by the hydrothermal replacement of the regionally metamorphosed sedimentary dolomite; alternatively it has been suggested that the magnesite is sedimentarv and formed contemporaneously with the dolomite in an embayment of the Triassic sea. Because all the igneous rocks exposed in the immediate vicinity of the magnesite deposits appear to be younger than the magnesite, the ore-forming solutions are thought to be related to a somewhat older granite which crops out elsewhere in the area. The brucite is the result of contact-metasomatic replacement of magnesite during the emplacement of the granodiorite stock.

Jan 1, 1968

By Camila Mendonça Romero Sales

O carbono tem atraído a atenção em pesquisas científicas e aplicações tecnológicas devido à diversidade das propriedades estruturais e elétricas. A proposta deste trabalho é produzir diamantes apartir de hidrocarboneto aromático em especial o Antraceno. Este possui uma estrutura de pelo menos 2 anéis aromáticos, de 5 ou 6 átomos de carbono. Com isso, ele foi submetido à pressão de 3,5GPa a uma temperatura de 1000ºC para a realização do processo de grafitização. Após este processo o grafite produzido foi misturado a liga Ni-Mn no sistema catalisador-solvente para o processo de síntese, com uma pressão de 4,5GPa e uma temperatura de 1300ºC com variação no tempo de realização da síntese de 30 a 120s. Para a realização dos cálculos dos parâmetros estruturais foi realizado ensaio de Difração de Raios-X (DRX) e para analisar os aspectos morfológicos foi realizado análise de Microscopia Eletronica de Varredura (MEV). Os resultados apresentam uma evolução dos parâmetros estruturais em relação ao tempoe temperatura de síntese, pode-se observar a presença de diamante nas amostras produzidas por Antraceno com maiores temperaturas de síntese.

Aug 16, 2017

By Garry Biles

The Eskay Creek Mine is a high-grade gold and silver underground mine in northwestern British Columbia. The mine started operations in late1994. For the first three years, ore was crushed to -50 mm(-2 in.), blended to satisfy smelter terms and shipped to smelters in Japan and Canada. Preliminary evaluations indicated that a complex metallurgical facility, requiring a large capital investment, would be required to recover the precious and other economic metals. So markets for raw ore were identified and underground mining and ore transportation operations began at a production rate of 300 t/d (330stpd).

Jan 1, 2000

By O. T. Rämö, E. Suikkanen

Episyenites are sub-solidus, quartz-depleted alkali-feldspar-rich rocks. They form veins and lenticular bodies in granitoid rocks and migmatites in a late- to post-orogenic or anorogenic setting. Leaching of quartz is usually a response to a flux of weakly saline hydrothermal solution in circulation cells above cooling intrusions, where sufficient fluid-rock ratios and thermal gradients are achieved. Fluid Si-undersaturation is achieved by rapid cooling within the field of retrograde Si solubility or by temperature and pressure increase outside retrograde conditions. Some quartz may also be consumed in metasomatic reactions and in response to pressure fluctuation in sealed episyenite bodies. The small size and overall rarity of episyenites imply that conditions for episyenite formation are not commonly encountered in the crust. In addition to quartz depletion, episyenites record complex histories of metasomatic alteration and hydrothermal mineral growth. Nearly all episyenites have undergone Na-metasomatism, which may have led to the formation of nearly monomineralic albitite, and which is occasionally followed by late K-metasomatism, phyllic alteration, and argillization. Depending on the effectiveness of later compaction, recrystallization and vug-filling episyenites may preserve the macroscopic porosity formed by quartz dissolution and brittle deformation. Vuggy episyenites can act as significant sinks for metals carried by crustal fluids and host many significant U, Sn, and Au deposits worldwide. Rare earth-critical syenitic fenites around alkaline intrusions share mineralogical and genetic traits with episyenites.

By O. T. Rämö, E. Suikkanen

Episyenites are sub-solidus, quartz-depleted alkali-feldspar-rich rocks. They form veins and lenticular bodies in granitoid rocks and migmatites in a late- to post-orogenic or anorogenic setting. Leaching of quartz is usually a response to a flux of weakly saline hydrothermal solution in circulation cells above cooling intrusions, where sufficient fluid-rock ratios and thermal gradients are achieved. Fluid Si-undersaturation is achieved by rapid cooling within the field of retrograde Si solubility or by temperature and pressure increase outside retrograde conditions. Some quartz may also be consumed in metasomatic reactions and in response to pressure fluctuation in sealed episyenite bodies. The small size and overall rarity of episyenites imply that conditions for episyenite formation are not commonly encountered in the crust. In addition to quartz depletion, episyenites record complex histories of metasomatic alteration and hydrothermal mineral growth. Nearly all episyenites have undergone Na-metasomatism, which may have led to the formation of nearly monomineralic albitite, and which is occasionally followed by late K-metasomatism, phyllic alteration, and argillization. Depending on the effectiveness of later compaction, recrystallization and vug-filling episyenites may preserve the macroscopic porosity formed by quartz dissolution and brittle deformation. Vuggy episyenites can act as significant sinks for metals carried by crustal fluids and host many significant U, Sn, and Au deposits worldwide. Rare earth-critical syenitic fenites around alkaline intrusions share mineralogical and genetic traits with episyenites.

By B. C. Christensen

The contract objectives are (1) to develop safe practice guidelines which will minimize the chance of fires in underground fueling areas and (2) to develop a low-cost, reliable, automatic fire protection system for underground fueling areas. The effort described by this report covers the period from 21 June 1976 to 30 September 1977 and accomplished the following tasks: ? Preparation of Data Plan and Data Acquisition, mainly through visits to sixteen mine sites and a literature survey. ? Analysis of the accumulated data, providing design inputs for (a) evaluation of the fire problem; (b) development of safe practice guidelines; and (c) development of recommended design concepts for automatic fire protection systems. ? Preparation of safe practice guidelines for underground fueling areas. ? Preparation of recommended design concepts for automatic fire protection systems for underground fueling areas. ? Design and fabrication of fire protection system for installation at Pine Creek Mine, Bishop, California. ? Install system and perform underground fire tests at Pine Creek Mine.

Jan 1, 1977

Sedimentary pyrites from Tasmania have Se contents that are high for it province showing no overall Se enrichment. Sulphides from Devonian granitic rocks, and related cassiterite-sulphide deposits, Sn-Wand PbZn-Ag fissure veins have similar and relatively low Se contents, and pyrites from Devonian gold-quartz veins have very low Se contents. The high concentrations of Se at Mount Lyell are consistent with enrichment in pyritic Cu deposits in volcanic rocks elsewhere, and the dispersion of Se is consistent with a surface volcanic origin for several of the orebodies. In contrast, sulphides from Cambrian volcanic rocks and associated granitic rocks, and from the Rosebery and Hercules pyritic PbZn deposits, also believed to be of volcanic origin, are impoverished in Se.In the Mount Bischoff cassiterite-sulphide deposits there is no relationship between Se content of sulphides and temperature of formation as indicated by fluid inclusion studies, and sulphides from Devonian ores with different temperatures of formation have similar Se contents.The Se content of Tasmanian sulphides appears to be an unsatisfactory discriminant of their genesis and temperature of formation but in volcanic terrains may be a useful pathfinder for Cu concentrations.

Jan 1, 1969

By J. Perlacia

"As the bulk handling sector continues its transformation to Industry 4.0, the mining industry, and its harsh working and environmental conditions, provides a perfect spot to study the feasibility of remote analysis and maintenance of the components used for bulk handling. The most important and expensive tools have been adapted to the digital era in recent years, from remotely controlled haul trucks to monitored conveyor belts.However, the big items of the installations rely on smaller parts that have been leftaside, mainly due to the difficultyof adapting them to the Internet ofThings (IoT).The paradigmatic example is the lack of monitored rollers, while all the other components of the conveyorbelt installations (the belt itself, motors, drums, etc.) were monitored some time ago. The main problem is that a failure of a single roller can cause the stoppage of the entire conveyor, due to possible damage to the belt. Thus, the implementation of an integral monitoring system of all the components of the conveyor is a must.The research and development department of ULMA Conveyor Components has been working since early 2012 on the development of monitored rollers, testing all the problems until their final installation in different demanding conditions, from the extreme heat in Australia to the freezing cold of Norway. All the tests have been done under actual working conditions, in real installations and have provided valuable knowledge in the identification of problems, their solutions and the final advantages of a roller monitoring system.Background and current stateThe malfunction of a single roller in certain conveyor belts can force the standstill of the entire installation until its replacement, due to the risk of greater and more expensive failures, such as a rip in the belt. In the case of a bulk handling installation, where a continuous supply of material is necessary, an unexpected stop of one hour could result in huge economic losses."

Nov 1, 2019

By A. C. Fieldner

Much activity is called for in the present period of hightened national effort, and wise direction of such a program must always be conditioned by positive knowledge gained in years of slow and painstaking study and development. Research and technologic investigations on coal by the Bureau of Mines have been described in a series of annual

Jan 1, 1941

By N. Gatelier, T. You, J. C. Kandel

ABSTRACT: Underground hydrocarbons storage is a very specific domain for the designer. He is usually free to adjust the section, shape and layout to cope with the geological and geotechnical conditions. This paper presents a panorama of the geotechnical design of mined underground storage caverns, then lists a number of uncommon features encountered in a storage excavated in Sydney, Australia, the Elgas LPG project that had to face major non-isotropic conditions with numerous local variations, impacting on the achievement of the design profiles. Changes in geotechnical design methodology and practice are examined through this project, now in operation, which will have lasted altogether almost ten years. KEY WORDS: underground storage, geotechnical engineering, stability, methodology, design. ZUSAMMENFASSUNG: Die untertaegige Speicherung von Kohlenwasserstoffen unterliegt in der Planung sehr spezifischen Bedingungen. Der planende Ingenieur hat bei der Dimensionierung und Formgebung der Speicherhohlraeume gewisse Freiheiten, muss jedoch vorgefundene geologische und geotechnische Bedingungen beruecksichtigen. Der vorliegende Beitrag gibt zunaechst einen allgemeinen Ueberblick ueber die geotechnische Planung von bergmaennisch aufgefahrenen Speicherhhohlraeumen. Darueber hinaus werden Besonderheiten betrachtet, mit denen das Elgas LPG-Speicherprojekt in einer bergmaennisch aufgefahrenen Kaverne in Sydney, Australien konfrontiert war. Hierbei ging es um die Beruecksichtigung anisotroper Bedingungen mit zusaetzlichen Heterogenitaeten im Gestein und den daraus erwachsenden Schwierigkeiten, die geplante Hohlraumform zu verwirklichen. Ueber einen Zeitraum von fast 10 Jahren, in denen das jetzt in Betrieb befindliche Projekt unterschiedliche Betriebsphasen durchlaufen hat, wurden verschiedene geotechnische Entwurfsverfahren auf ihre Anwendbarkeit geprueft. SCHLUESSELWOERTER: Untergrundspeicherung, Geotechnik, Stabilitaet, Entwurfsverfahren, Planung. RESUME : Le stockage souterrain d’hydrocarbures est un domaine très spécifique pour le concepteur, car celui-ci dispose d'une large liberté pour adapter les sections, les formes et les implantations aux conditions géologiques et géotechniques de l’environnement choisi. Après un panorama de la conception géotechnique des stockages souterrains d’hydrocarbures par la méthode dite des cavités minées, l’accent sera mis sur un certain nombre de particularités rencontrées lors du projet de stockage de GPL de Elgas à Sydney en Australie, creusé dans de très fortes conditions d’anisotropie du massif rocheux, avec de nombreuses variations locales et toutes les implications que cela peut avoir sur le maintien des formes. L’évolution des approches méthodologiques géotechniques durant la dizaine d'années de développement de ce projet depuis les premières études jusqu'à l'exploitation actuelle est également présentée. MOTS-CLEFS : stockage souterrain, géotechnique, stabilité, méthode, conception.

Jan 1, 2003

By E. G. Noble

The effects of hydrogen chloride (HCI) concentration and temperature on the solubility and hydration state of the alkali chlorides LiCI, NaCI, and KCI and the alkaline-earth chlorides, MgCI2, and CaCl2 were investigated by the Bureau of Mines. Saturated aqueous solutions of the chlorides were sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increased HCI concentration caused decreased salt solubility be-cause of the common ion effect. Aqueous solubilities for the chlorides of Ca, Li, Mg, K, and Na ranged from 42.6, 45.2, 35.2, 25.5, and 26.1 pct, respectively, at 20° C to 56.9, 49.4, 37.6, 31.0, and 27.0 pct, re-spectively, at 60° C. In solutions sparged to HCI saturation, solubili-ties for these chlorides ranged from 22.4, 26.5, 3.0, 1.3, and 0.05 pct, respectively, at 20° C to 53.2, 48.8, 28.3, 2.6, and 0.8 pct, respec-tively, at 60° C. The solubilities of LiCI and CaCl2 in HCI solution were high because HCI solubility is low in these solutions. The chlo-ride salts of Ca, Li, and Mg formed hydrates, which depended on tempera-ture and HCI concentration. Monohydrates for LiCI, tetrahydrates and hexahydrates for MgCI2, and dihydrates, tetrahydrates, and hexahydrates for CaCl2 were obtained.

Jan 1, 1985

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf as a function of temperature are given in tabular form. Thermodynamic data were compiled for VOSO4, Cr2(SO4)3, MnSO4, FeSO4, Fe2(SO4)3, CoSO4, NiSO4, Cu2SO4, CuSO4, CuO-CuSO4, ZnSO4, and ZnO-2ZnSO4, together with their stable hydrates.

Jan 1, 1982

By D. Nutakor

Rock joint stiffness is not only a poorly known parameter, but also has no established laboratory measurement procedure. This paper presents methods used to determine the normal and shear stiffnesses of healed joints filled with vapor-altered minerals obtained from the Yucca Mountain site in Nevada. Results show that these joints behave linearly up to 85% of their loading history and are stiff with strengths very close to the strength of the intact rock. Factors that might have contributed to the linear behavior of these joints are discussed and areas requiring further investigation are provided. Joint normal stiffness ranges from 7.16 to 64.77 GPa/mm with an average value of 26.93 GPa/mm, while joint shear stiffness averages 11.41 GPa/mm and ranges from 3.09 to 28.41 GPa/mm. Young?s modulus of the vapor-altered joint infilling was calculated from the stiffness of the healed joint. Young?s modulus of the vapor-altered joint filling material averages 7.89 GPa and ranges from 2.15 to 19.43 GPa. Given the pervasive presence of such altered rock, usually in the form of sub-spheroidal 3-D pockets, this property should be of value in any numerical modeling attempting to describe the mechanical behavior of these tuff formations at the level of detail where inclusions might be a factor.

Jan 1, 2008

By F. S. Young

Previous laboratory and field experimentation has demonstrated the effect of several variables on drilling rate.1-5 These results have been incorporated into optimization theories6-" for the purpose of reducing drilling cost. Minimum-cost drilling theories rely on a combination of historical data and empirical prediction techniques for selecting optimum bit weight and rotary speed. Past solutions have required extensive use of computing equipment because of both the complexity of the mathematical formulations and the large number of parameters involved. Field attempts to apply these computed results have frequently failed because of the uncertainty of input data requirements. Humble has developed an on-site computer system to control bit weight and rotary speed and thereby implement the concepts of minimum-cost drilling. This system can (1) perform short interval drilling rate tests for formation evaluation, (2) use the results of these tests as input information to solve minimum-cost drilling formulas, and (3) control bit weight and rotary speed in accordance with these computed solutions. The purpose of this paper is to describe the computer control system and present results of initial field testing. Theoretical Considerations Minimum-cost drilling (MCD) requires a quantitative evaluation of the variables involved. Several forms of a basic mathematical model have been sug-gested.'?,' "he relationships reported here form the basis for the solution programmed in this work. Four equations are used, expressing drilling rate, bit bearing wear, bit tooth wear, and cost. A solution for minimum-cost drilling assuming constant bit weight and rotary speed over the entire bit life has been programmed for use in computing MCD schedules. This solution is subject to certain limiting assumptions such as those discussed by Graham et a1.I2: 1. Drilling cost is the summation of bit cost, rotating cost, connection cost and hoisting cost. 2. Diamond bits are excluded. 3. Bit life is limited by either bearing failure or tooth wear, or by a combination of operational factors that make it cheaper to pull an incompletely consumed bit. 4. Circulating hydraulics are adequate and do not limit drilling rate. 5. Bit weight considerations exclude hole deviation. 6. Drilling rate is a function of only bit weight, rotary speed, and degree of tooth dullness; that is, the effects of pressure, lithology, fluid properties hydraulics and drill string dynamics are ignored. In equation form, the four MCD expressions are as follows:

Jan 1, 1970

By Robert A. Siokler

Approximately 75 percentage of the earth's land surface is comprised of shale or shale-like materials. Shale itself is composed of the residue from an almost infinite variety of weathered parent materials which have undergone deformations ranging from intense to negligible. Under standard test procedures, shales exhibit a very wide range of physical properties particularly if the test specimen is subjected to a change in moisture content, when the original test values may vary from 0 to 100 percentage. It is this wide variation in physical property values compounded by its ubiquitous presence that makes shale such a problem material to engineers. In reviewing the literature relating to shale, it is evident that the "problem" has been approached from many directions. In order to understand why shales behave as they do, investigators have sought mineralogical, geological, chemical, electrical, and physical answers. Each study yields valuable academic information, but few contribute much of value to the engineer in the field. Many valid relationships between shale strength or competency and clay type, clay content, organic content, water content, grain size, cementation, density, porosity, etc, have been established. Yet it is very difficult to extend these understandings to the in situ condition with results that can be used by the field engineer. One major reason earlier work has not produced better information lies in the ambiguity of the definition of shale. It is apparent that no one laboratory parameter can be successfully used to provide sufficient engineering information to properly describe in situ conditions. For example; shale with swelling clays will produce low strength values provided: the swelling clay is in sufficient quantity, the clay is dispersed throughout the medium involved, and there is a low value of cementation. Shales with high unconfined compressive strengths have been found with very low shear strengths. Sandy shales often provide as many ground control problems as clay shales. Shales of similar nature may provide good roof conditions in one part of a mine yet in another part of the same mine the apparently identical shale may cause substantial problems. A clear need exists to classify shale in a manner which will enable the engineer to better predict the strength and durability of shale-like materials. Studies at the University of Missouri-Rolla (UMR) have focused on finding parameters which influence durability and competency, while being discretely discernible through uncomplicated testing. Initial research concentrated on distinguishing shale8 on the basis of standard physical tests such as: unconfirmed compression, triaxial shear, and slake durability. As results accumulated, however, it became evident that moisture content played a much greater role in determining competency than had been recognized previously. As a result the focus of the research turned to developing tests which would evaluate the influence of moisture on shale behavior. The above work then became a foundation for a second phase of investigation in which a suite of standardized tests were developed to provide a classification procedure. From this study five tests were identified as being critical: Moisture Activity, Atterberg Limits, Submersion, Unconfined Compression, and Shore Hardness.

Jan 1, 1986

By P. Fu, Y. Ma

Residual collectors and their byproducts (e.g., CS2) in flotation effluents can cause water contamination and even result in serious health hazards to humans and animals, Therefore, residual flotation reagents should be removed properly before discharge or recirculation into flotation circuits. In this work, four thiol collectors (potassium ethyl xanthate (EX), sodium diethyl dithiocarbamate (SN- 9), O-isopropyl-N-ethyl thionocarbamate (Z-200), dianilino dithiophoshoric acid (DDA)) were chosen as model pollutants. The collector removal, mineralisation and byproduct formation were compared by sole O3 and O3/UV185+254nm. The degradation rate constants of thiol collectors by O3/UV185+254nm were 2~6 times higher than those by sole O3. The mineralisation of collectors was also remarkably enhanced by O3/UV185+254nm. The degradation efficiency by O3/UV185+254nm had the order: EX>SN-9>>Z- 200>DDA. The Z-200 and DDA were refractory flotation reagents. The degradation of thiol collectors caused the reduction of solution pH and the increase of ORP and conductivity. However, the O3/UV185+254nm achieved more evident changes of these parameters than sole O3. During the degradation of thiol collectors, less than 4% of total sulfur in collectors was emitted into air as CS2 and H2S. Compared to sole O3, the O3/UV185+254nm had additionally included UV185+254nm photolysis and O3/UV254nm, resulting in higher efficiency in removing collectors. The O3/UV185+254nm was an effective process in treating mineral flotation wastewaters containing organic reagents. Keywords: Thiol collectors; flotation effluents; ozone; vacuum-UV; degradation, mineralisation

Jan 1, 2020

By Klaus Pöllath

The Netherlands RandstadRail project makes use of a large range of sophisticated geotechnical techniques to allow a shield driven tunnel to approach the central station of Rotterdam. This paper describes the construction of three deep excavation pits constructed with 1.2 m and 1.5 m thick diaphragm walls. Besides the presentation of the actual diaphragm wall activities special consideration is given to the break-in and break-out situations of the TBM into the deep excavations pits using sealing blocks and partly glass fibre reinforcement in the diaphragm walls.

Jan 1, 2006