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Al2O3,-WC Composite powder for cutting tools was synthesized by self-propagating high-temperature synthesis using A1 powder as a reducing agent. WC, W2C and Al2O3 were concurrently formed in WO3Al-C system. It was found that the complete reaction was achieved with excessive addition of carbon and appropriate processing parameters such as degree of dilution, particle size of aluminum, compaction pressures of green pellets and carbon source. The final product which was leached by 50% HN03+HF diluted solution was consisted of Al2O3-55wt% WC having 2-3um of mean particle size.

Jan 1, 1999

By Arthur W. Cooper

This paper contains a review of the development of blast furnace? slag handling and processing technology in the Ironmaking industry over the past 30 years, with an emphasis on economic and environmental factors. The requirements and practice of air-cooling slag for use as aggregate and of pelletizing and granulating slag for use in cement manufacture are described. The operation of slag pits, slag pots or ladles, the slag pelletizer and early granulation systems are compared with the new continuous .granulation, dewatering and handling systems developed in the past decade.

Jan 1, 1992

By Lv Guozhi, Niu Liping, Liu Yan, Zhang Zhiqi, He Jicheng, Zhang Ting’an, Dou Zhihe

"CuCr alloy can be extensively used as contact materials in integrated circuit, electrodes, electric contact and high strength conductor. We proposed thermit reduction-electroslag remelting method of preparing the large scale CuCr alloy. But there are pores and oxide inclusions in CuCr alloy prepared by thermit reduction process. This paper studied mainly the effects of ratio of reactant and additive on the inclusion type and their occurrences in CuCr alloy. The slags and CuCr alloy were characterized respectively by XRD and SEM. The results show that when the additive is Na3AlF6, the slag consist of Al2O3 and Cr. When the additive is CaF2, the slag consist of Al2O3, Cr, CaF2 and CaAl4O7. The inclusions in CuCr alloy are mainly Al2O3 and pores which disperse in Cu-rich zone and Cu-Cr phase interface. When 5% CaF2 and 5% KClO3 are added, there are fewer pores and inclusions, and the more better microstructure.1 IntroduceCuCr alloy is the contact terminal material with an eximious properties[1,2], which gradually replaces CuBi alloy becoming the first choice for contact terminal material in the medium and high power vacuum switch after the 1970s. The traditional preparation methods of CuCr alloy mainly contain powder metallurgy, infiltration process and vacuum electric arc melting methods. But the above methods exist some shortcomings, such as poor product quality, high cost of production, processes complex ect[3-9]. CuCr alloy is made by the thermit reduction self-propagating method, which uses CuO, Cr2O3 and Al as raw material to get the high-temperature melt, and then casts to manufacture CuCr alloy ingot, which response equation follows as:"

Jan 1, 2012

By J. S. Becker

Technology developed and first implemented in the United Kingdom enables very low grade aluminum scraps containing oils, organics, plastics and ferrous metals to be directly charged, without pretreatment, into a unique melting furnace. The system has been in full scale production for four years. The oxy-fuel-based furnace design incorporates internal afterburning in the furnace's hot zone, producing excellent thermal efficiency and very low emissions. The furnace is inherently low in NOx. This paper will provide both theoretical background and extensive operating results for this new melting concept. Applications describing both purpose built new furnaces and retrofits of existing reverberatory furnaces will be presented. Extensive operating emissions data will be presented.

Jan 1, 1997

By Hemraj Dangi, S. Murali, Bhisham Yadav, Mohini Saxena, P. Asokan

"Demonstration studies were carried on the use of fly ash as soil modifier and supplier of micronutrients to improve the agricultural productivity based on the process optimised at lab scale at Advanced Materials & Processes Research Institute, Bhopal. The field trials were conducted in Uttar Pradesh (North India) Orissa (South Eastern India) and Madhya Pradesh (Central India) under different soil and crop conditions. 100-650 tonnes of fly ash per hectare were applied depending upon the soil and fly ash characteristics. Both short and long term studies on impact of fly ash on soil and food quality were conducted. With the fly ash application, the edible yield of tomato, cabbage, potato, wheat, pea, onion, paddy, sunflower, maize etc., were increased from 12 - 46% as compared to the control soil where no fly ash was used. The crop response to various elements mainly heavy metals grown in soil and fly ash applied soil was found comparable to that of control, which are within the permissible limits and meet the food quality standards. The results of impact of fly ash on biotic and abiotic properties of soil, along with the quantity and quality of agricultural produces generated under pilot scale demonstrations in three different parts of India are discussed in this paper. The outcome of this work could act as guiding force for confidence building and to maximise the use of fly ash, generated from thermal power plants worldwide as one of the major mineral waste for agriculture purposes.IntroductionThe advantages of application of fly ash in terms of improvement of soil properties and crop yields have been published by various researchers in India and abroad. Attention is also given about the possible negative and beneficial impact of pond ash in agriculture due to presence of heavy elements, radioactive nuclides and plant nutrients in fly ash. It is evident from the analysis of Indian fly ash that the presence of heavy elements and radionuclides levels are comparable with normal soil. The positive impact that has been reported is with regard to germination, yield and crop growth. The significant impacts are: long term effect of heavy and toxic elements content of fly ash on soil and up take of these elements by plant. Pilot scale demonstration studies have been completed with varying soil crop-combination under different agro-climatic conditions showed considerable improvement in the productivity of cereals, oil seeds and vegetables."

Jan 1, 2008

By André Laplante

The mineralogy of the Joe Mann mine differs from that of other deposits of the Chibougamau area that are exploited by Les Mines Camchib Inc.. It is characterized by very fine first generation gold and very coarse second generation electrurn. Successful milling required adjustments of the processing flowsheet, which includes gravity, flotation, and cyanidation. A study of coarse gold liberation in the gravity/grinding circuit is described. Modifications to the flotation circuit and the reconditioning of a small capacity cyanidation circuit are presented. As a result of the circuit modifications, gold recovery increased from 65 to 81% in flotation and cyanidation. Overall gold recovery increased from 77% to 88-89%. These improvements are mostly attibutable to the recovery of -10 urn gold, whose presence in the Joe Mann ore and original circuit tails had been identified by process mineralogy.

Jan 1, 1989

By Junji Shibata

Waste solution from the Ni non-electric plating process contains 4.0 kg/m3 Ni, 0.1 kglm3 Fe, 0.0 I kg/m3 Zn, 48 kg/m3 S042-, 98 kg/m3 HP032-and 31 kg/m3 laetic acid as a typical composition. Solvent extraction, cementation, ion exchange resin and precipitation methods are possible to use for the treatment of this kind of solution. In this study, solvent extraction of Ni was investigated using two kinds of extractants to clarify the relation between extraction percent and pH for various extractant mixtures. As Ni ion has an octahedral structure with ligands, the synergistic effect for Ni extraction is considered to take place in solvent extraction using two types of extractants. The investigation of the synergistic effect for Ni extraction was carried out in case of various extractant systems.

Jan 1, 2003

By Kimio Itagaki

The distribution ratios of Ag, Pb, As, Sb and Bi for the Cu2S-FeS or Ni3S2-FeS matte / FeOx SiO2, FeOx-SiO2-CaO or FeOx-CaO slag equilibration in a MgO crucible were determined experimentally at 1523~1573K under controlled partial pressures of S2 and O2 at given PSO2 of 10.1, 50.7 and 101.3 kPa (0.1, 0.5 and 1 atm) and be observed dependency of distribution ratio on the matte grade, SO2 pressure and slag basicity were analyzed on the basis of thermodynamics,

Jan 1, 2003

By Xin Li, Hai-Xing Fang, Bing Xie, Hong-Yi Li

Chromium-containing vanadium slag (V-Cr slag) was obtained by an industrial smelting process of Hongge Ore, which is valuable vanadium-titanium magnetite to extract V and Cr in China. Sodium roasting thermodynamics of V-Cr slag in presence of oxygen were calculated to evaluate the reactivity of chemical compounds. Results showed that the oxidation of FeV2O4 was intensified in presence of Na2CO3 while the oxidation tendency of FeCr2O4 was far lower than that of FeV2O4. It was probably that reactions of impurities including Al2O3, SiO2 and Fe2O3 with Na2CO3 happened and the products can promote the oxidation of vanadium or chromium compounds in lower valence. Based on thermodynamic analysis, a two-step selective extraction process of vanadium and chromium was proposed. Extraction rate of vanadium was 88.6% while 7.0% for chromium in the first extraction step; extraction rate of 90.7% and 95.4% for vanadium and chromium, respectively, were obtained in the second step.

Jan 1, 2014

By Natasa Mitevska

In order to ensure the minimal copper concentration in the reverb furnace slag, the graphical optimization method is used and the optimal slag composition of the reverberatory furnaces No.1 and No.2 in the RTB BOR, Copper Smelter and Refinery (Serbia) is obtained: (Si02) .. 38.0%; (FeO) .. 40.0%; (Fe3O4) = 5.0%; (CaO) = 5.0%; (Al2O3) .. 6.0%. Keywords: Optimization, Reverb Furnace Slag, Graphical Method

Jan 1, 2003

By Zhi-yong Liu

A novel process, which includes hydrochloric acid leaching, iron powder cementation, sulphide precipitation and spray pyrolysis, was proposed to treat iron concentrate recovered from zinc kiln slag for comprehensive utilization. Treated by two-stage hydrochloric acid leaching, the leaching extents of Ag, Pb, Cu, Fe and Zn are 96.78%, 95.14%, 97.72%, 94.51% and 87.74%, respectively. More than 99% Cu and Ag are recovered from the leach liquor when iron powder is 25% higher than the stoichiometric requirement. More than 96% Pb and Zn is removed with three times of theoretical consumption of FeS, and the concentration of impurities of the final solution is less than 500 mg/L. Fe2O3 powder, which is spherical with a mean size of 12 μm and purity of 99%, is prepared with final solution at 700 °C. In this process, not only the metal values can be recovered effectively, but also the iron resources of zinc kiln slag can be converted into high purity Fe2O3, thus, the comprehensive utilization of iron concentrate recovered from zinc kiln slag can be realized.

By R. S. Tahautdinov, A. N. Posazhennikov, V. V. Bastrygin

"The Bakal (South Ural, Russia) deposit of iron ore bearing iron carbonate (siderite) with the capacity of more than 1 billion tones belongs to the MMK. This ore cannot be fully processed via blast furnace technology because of high content of MgO. According to the investigations carried out in the USA and Japan in 1999-2004 the ITmk3 (Ironmaking Technology mark three) RHF technology is a breakthrough in Ironmaking. Four iron ore types (hematite, magnetite, high and low Al2O3/SiO2) were tested. Reduction, melting and slag removal can be achieved in just 10 min. The main objective of the investigation is to establish optimum operation conditions for the production of iron nuggets from iron carbonate bearing ore via the ITmk3 by means of the lab scale testing. Samples of iron ore and carbon reductant were chemically and physically analyzed. Green pellets were processed via a lab tube furnace to simulate RHF conditions. The nuggets and slag were chemically analyzed. This preliminary test work provides valuable information which may be used for large-scale testing in a commercially sized RHF.IntroductionThe ITmk3 process upon which this paper focuses was developed by Kobe Steel in its research facilities in 1996 [1]. After pilot testing at Kobe Steel’s Kakogava Works in 1999-2004 the pilot demonstration plant was built and operations were successfully carried out by Mesabi Nugget joint venture in 2002-2004. Steel Dynamics has committed to building the commercial plant at the Mesabi Nugget site in Hoyt Lakes (Minnesota). Only 4 iron ore types (hematite, magnetite, high Al2O3/SiO2 and low Al2O3/SiO2), as well as 4 coal types with range of volatility, ash and fixed carbon were tested. Results were consistent with nugget characteristics confirming ITmk3’s flexibility with respect to raw material inputs. At the same time, no research in the field of nugget from iron carbonate bearing ore with high content of MgO has been done. Such kind of iron ore is restricted for charging into the blast furnace due to contamination of MgO. The reason for restriction is the limitation of load of MgO in the blast furnace. If a lot of MgO enters the blast furnace, slag becomes viscous. The viscous slag is obstacle for stable operation of the blast furnace."

Jan 1, 2011

By E. V. Redin

"The Bakal (South Ural, Russia) deposit of iron ore bearing iron carbonate (siderite) with the capacity of more than 1 billion tones belongs to the MMK. This ore cannot be fully processed via blast furnace technology because of high content of MgO. According to the investigations carried out in the USA and Japan in 1999-2004 the ITmk3 (Ironmaking Technology mark three) RHF technology is a breakthrough in Ironmaking. Four iron ore types (hematite, magnetite, high and low Al2O3/SiO2) were tested. Reduction, melting and slag removal can be achieved in just 10 min. The main objective of the investigation is to establish optimum operation conditions for the production of iron nuggets from iron carbonate bearing ore via the ITmk3 by means of the lab scale testing. Green pellets were processed via a lab tube (chamber) furnace to simulate RHF conditions. This preliminary test work provides valuable information which may be used for large-scale testing in a commercially sized RHF.IntroductionThe ITmk3 process upon which this paper focuses was developed by Kobe Steel in its research facilities in 1996 [1]. After pilot testing at Kobe Steel’s Kakogava Works in 1999-2004 the pilot demonstration plant was built and operations were successfully carried out by Mesabi Nugget joint venture in 2002-2004. Steel Dynamics has committed to building the commercial plant at the Mesabi Nugget site in Hoyt Lakes (Minnesota). Only 4 iron ore types (hematite, magnetite, high Al2O3/SiO2 and low Al2O3/SiO2), as well as 4 coal types with range of volatility, ash and fixed carbon were tested. Results were consistent with nugget characteristics confirming ITmk3’s flexibility with respect to raw material inputs. At the same time, no research in the field of nugget from iron carbonate bearing ore with high content of MgO has been done. Such kind of iron ore is restricted for charging into the blast furnace due to contamination of MgO. The reason for restriction is the limitation of load of MgO in the blast furnace. If a lot of MgO enters the blast furnace, slag becomes viscous. The viscous slag is obstacle for stable operation of the blast furnace."

Jan 1, 2012

By Richard A. Heckman

Destructive Thermal Technology (DTT) is used in the management of various waste streams. DTT includes Destructive Distillation, Pyrolysis and Classical Incineration. Recent work has more clearly defined the differences in these technologies based upon a more rigorous thermochemical approach. The U.S. Environmental Protection Agency (EPA) has chosen Classical Incineration as the Best Developed Available Technology (BDAT) for the management of hazardous organic wastes. Municipal Solid Wastes (MSW) and Sewage Sludges (SS) are also managed using Classical Incineration. Three environmental problems plague the use of Classical Incineration. Destructive Distillation, on the other hand, avoids these problems. It is an environmentally benign DTT for managing a wide variety of organic waste streams, including hazardous wastes. Thermochemical analysis of the available data on the performance of three types of DTT will be discussed.

Jan 1, 1994

By Jared Ball, Darren Snashall, Paul Telford, Pengfu Tan, Ben Hogg

"The foamed converter charges were up to 3 8 per month in Xstrata Copper Smelter at Mount Isa. The issue of high converter foamover frequency had remained unsolved for many decades in Mount Isa. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow, in order to understand the mechanism of converter foamover. The model predicts the chemistry and viscosity of slag during slag blow and copper blow. The effects of oxygen potential, charge of dirty reverts, slag carryover, under-blowing, over-blowing, and temperature on the foamover and viscosity of slag in copper blow have been discussed. A theory has been developed to understand the mechanism of converter foamover. The practical solutions have also been developed and implemented in Mount Isa Copper Smelter. Some improvements of the industrial operations have been presented. After a series of improvements, the number of foamed charges per month in the converter operations has been decreased significantly from 35 in Aug 2008 to only one per month in 2009/2010.1. IntroductionThe Copper Smelter in Mount Isa receives the concentrate containing about 25% copper and produces anode copper that contains about 99% copper. There are several stages in the process. The first stage carries out in the ISASMELT™ furnace. The ISASMELT™ process produces a molten copper matte containing about 60% copper. An iron-silica slag and a sulfur dioxidebearing off-gas are the by-products of the process. The slag is taken to the slag dams for cooling before it is recycled through the Mount Isa Copper Concentrator.The matte is sent to Peirce-Smith converters. The converters further remove iron and sulphur to produce blister copper which contains about 97% copper. The anode furnaces remove any remaining sulphur and oxygen to produce anode copper that is about 99. 7% pure. This is cast into anodes and sent to the Xstrata Copper Refinery in Townsville for final refining.In the copper pyrometallurgical industrials, slag foaming is an important phenomena which occurs when the gas bubbles have stability and not rupture. Foaming greatly increases the interfacial area between matte, slag and gas and is essential for the operation of high intensity smelting processes. However, foaming or foamover is undesirable in P-S converter since it can damage the equipment and injure the operators. Figure 1 shows that the whole process of a foamover development in a converter."

Jan 1, 2011

By Isabela Leao Amaral da Silva, Felipe Perisse Duarte Lopes, Alice Barreto Bevitori, Sergio Neves Monteiro

"Jute fibers have in the past decades being investigated as possible reinforcement of polymer composites. However, information is still needed on the fiber interaction with a polymeric matrix for a complete evaluation of the capacity of load transference inside the composite. The present work investigated the interaction of jute fibers with polyester matrix by means of the critical length assessment through pullout tests. Tensile tests of polyester sockets embedded with different fiber lengths allowed the critical length to be determined and then the interface shear stress to be calculated. A relatively low interfacial strength was found, which indicates a weak adhesion between the ramie fiber and the polyester matrix. The SEM analysis of pulled out fibers corroborates this result.Introduction Natural fiber, mainly those lignocellulosic extracted from plants, have, in the past few decades, attracted the attention not only of scientists but also of industrial technologists of our society interested in their engineering applications. As it is well known, uses of natural fiber in clothes carpets, baskets, ropes and low cost construction roofing has existed from the beginning of our civilization. Today environmental and energy saving issues are motivating research works on new uses of lignocellulosic fibers in polymer composites [1-6]. Moreover, industrial application of lignocellulosic fiber composites are already in technological sectors such the automobile industry, packing and civil construction [7-9].In addition to environmental, economical and social benefits, some lignocellulosic fibers present specific properties that are comparable to those of other synthetic fiber used for polymer composite reinforcement. For instance, the specific strength (GPa.cm3/g) of curaua (1.31), sisal (0.92) and ramie (0.93) fibers, from results obtained with very thin diameters [10] are relatively closer to that of glass fiber E (1.33). Therefore, in principle, it would be technically justified to replace glass fiber, which is more expensive, toxic and represents a problem to the environment [ll], by a strong lignocellulosic fiber. However, serious drawbacks such non-uniform dimensions and heterogeneous properties [6] as well as the tendency to form aggregates during processing and incompatibility with a hydrophobic polymer matrix, reduce the potential of lignocellulosic fiber to be used as composite reinforcement [1-6]. In particular, a low interfacial strength causes a weak adhesion between the hydrophilic fiber and the polymer matrix."

Jan 1, 2011

By D. R. Kreuzer

The sulfide smelting industry is striving for up-scaling their operations by increasing the throughput and efficiencies of the furnaces. The physical phenomena related to refractory materials prevailing in smelters and furnaces are highly complex. The refractory materials are exposed to fairly high temperatures, thermo-mechanical stresses, penetration of pores, erosion and chemical corrosion. The application of numerical simulation tools is needed for the refractory engineering task to consider those phenomena and to evaluate the impact of operational regimes on the refractory design and finally on the integrity of the furnaces. The work discusses case studies of simulations addressing problems and questions related to the refractory design process. Practical simulation approaches which employ simplified models are introduced as the engineering process demands results in a reasonable time.

By Feng Liu

A thermal upgrading process by which nickel value can be concentrated in a ferronickel alloy is a possible alternative to treat Sudbury pyrrhotite (Po) tailings with nickel content of 0.5–1.5 wt%. The basis of this process is precipitation of Ni from Po at high temperature once Fe/S ratio in the iron-deficient Po is shifted towards stoichiometric or near stoichiometric FeS (troilite) either by the addition of iron and/or the removal of sulfur. For the iron addition route, the reaction between elemental iron and nickeliferous pyrrhotite to produce ferronickel alloy and Ni-depleted iron sulfide phase plays a critical rule. In this paper, the formation mechanism of ferronickel alloy was investigated using the diffusion couple technique to better understand the nickel diffusion behavior in the iron and sulfide phases.

By Jun Zhu, Jilai Xuel, Tao Li

"Coal gangue is industrial waste containing Al2O3 and SiO2 with great recycling and reuse values. This work is aimed at extracting Al2O3 content in the coal gangue by a process of carbonthermal reduction - alkaline leaching. The Al2O3 and SiO2 contents first became a mixture of SiC and Al2O3 in the process of carbonthermal reduction, and then Al2O3 was separated by leaching in NaOH solution, thus producing the sodium aluminate solution for Al(OH)3 precipitation. The products generated at various stages in the process were inspected using XRD and chemical analysis. The effects of parameters such as reduction temperature, carbon ratio, NaOH concentration, leaching time, leaching temperature, stirring speed, etc were investigated in details.IntroductionCoal gangue is an industrial residue resulted from the process of coal mining and washing, accounting for 100 - 150 kg with 1 ton raw coal mined. The existence of coal gangue in large quantities has become a serious problem for environment pollution. On the other hand, the chemical compositions of coal gangue are Si02 and Ah03 primarily. In China, the accumulation storage capacity of Ah03 in coal gangue is not less than 600 million ton at a rough estimate, which should be considered as an abundant second resource [1]. If the alumina can be recycling and reused effectively from coal gangue, it will not only reduce the imperilments caused by coal gangue, but also yield good economic returns.Generally, the processes of extracting Al2O3 from coal gangue can be divided into acid leaching (vitriol or hydrochloric acid) and alkaline leaching (mostly NaOH) [2]. The acid leaching processes have many problems, such as lower leaching ratio, corroding the equipments, recycling the spent acid hardly, etc. The primary matter of alkaline leaching process is silica dissolving with alumina, which brings perplexing desilication process, alumina loss seriously and higher energy consumption."

Jan 1, 2011

By Augusto Viana Leandro Teixeira

Rare Earth Elements (REE) are fundamental for modern life products and green technologies. Supply constraints and the price peak of 2011 boosted intensive research for alternatives for processing and separation. Complex monazite- type, rare earth ores usually contain high acid consumption impurities, such as iron and aluminum, and radioactive thorium in their composition. These impurities are not removed by conventional concentration processes due to fine, micro-level association between the REE carrying minerals and the gangue minerals. This work presents a selective process route for REE extraction from iron-rich, monazite ores. The process involves sulfation by addition of concentrated sulfuric acid and pyrohydrolysis at temperatures of approximately 700–750 °C. Experimental results show REE extraction higher than 70% and low iron (below 5%) and thorium extraction (below 10%). A method based on thermogravimetric analyses was shown to be adequate to predict the behavior of a given ore sample in the sulfationselective pyrolysis-leaching process.