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By E. Salinas R.

This work is related with a whole characterization of cantera stone, to establish its characteristics that can give it an additional value for the reuse and reutilization of dust, slurries and small pieces of stone which can be treated as wastes. The obtained results reflects that the residues studied can be used as substitutes of feldspars in the production of pieces of ceramic, and also in the elaboration of paints for the same pieces according to the mixes that can be made with the variation of Na2O, CaO and K2O. According to the humidity proofs and specific gravity done, this material can be proposed as a soil improver into hydroponics systems, leading so an important alternative for food production in zones leaking of water. In the same way, it was found the possibility of use this material as a seal 3A in processes of asphalting of roads, highways and streets.

Jan 1, 2009

By Yanping Xiao

In submerged-arc furnace (SAF) for smelting chromite ores into ferrochrome, there exist large temperature gradients and wide distributions of mineralogy and compositions in the furnace, due to the complexity of feed structure and electrical-thermal-chemical interactions. This leads to various zones in the furnace and thus different reaction mechanisms. In the present paper, the behaviour of chromium in the submerged arc furnace is discussed in various reaction zones, including solid state chromite reduction in the packed bed zone, chromite dissolution and reactions in the smelting and coke bed zone, and recovering chromium from slag to metal. In the gas-solid reaction zone, the reaction mechanism is discussed based on the experimental observations and analysis. In the smelting zone, the behaviour of partially reduced chromite and slag formation are analyzed based on the information in literature. The slag in FeCr process contains mainly Al2O3, MgO, SiO2, CaO and CrOx, featured by chromium with both divalent and trivalent oxidation state, which plays an important role for chromium recovery into metal. The factors influencing the slag and metal interfacial reactions and the chromium recovery are addressed.

Jan 1, 2006

By Maurizio Marezio Bertini

Successful treatment of contaminated sediments was achieved by sparging either 0.5 M NaOH solutions or distilled water with an SO2/O2 gas mixture. Metals such as Cu, Pb, Cr and Cd were successfully removed in a relatively short time. The effect of temperature and pH was investigated. Higher temperatures produced faster and higher recoveries with Pb and Cr more affected to temperature increase than Cu and Cd. The removal of copper, up to 50% percent, was achieved in alkaline solutions through the formation of copper sulfite complexes. The complete removal of metals such as Cu, Pb, Cr and Cd required that part of the treatment be carried out in acidic solutions. A preliminary cost analysis was carried out.

Jan 1, 2003

By Jozef Zmik, Sergey Dobatkin, Martin Fujda, George Raab, Libor Kraus

"The present work, likewise, deals with grain refinement of medium carbon steel AISI 1045 having different initial microstructure resulting from thermal and/or thermomechanical treatment (TM) applied prior severe plastic deformation. In case of TM treated steel, structure refinement was conducted in two steps. Preliminary structure refinement has been achieved due to multistep open die forging process which provided total strain Eef ~ 3. Uniform and fine recrystallized ferrite structure with grain size of the order of 2-5 µm and with nest-like pearlite colonies was obtained. The further grain refinement of steel samples having different initial structure was accomplished during warm Equal Channel Angular Pressing (ECAP) at 400°C. The microstructure development was analyzed in dependence of effective strain introduced ( Eef ~ 2.5 - 4). Employment of this processing route resulted in extensive deformation of ferrite grains where mixture of subgrains and ultrafine grain was found regardless the preliminary treatment of steel. As straining increases the dynamic polygonization and recrystallization became active to form mixture of polygonized subgrains and submicrocrystalline grains having high angle boundaries. The intensive straining and moderate ECAP temperature caused the partial cementite lamellae fragmentation and spheroidization as straining increased. The lamellae cementite spheroidization was more extensive in TM treated steel samples. The deformation behavior of for both steel structural state confirm the strength increase; however the work hardening behavior was modified with respect to initial structure of steel prior SPD processing.IntroductionIn the last years, ultrafine grained materials have attracted considerable research interest because they tend to possess high strength without sacrificing toughness and ductility. Microstructural refinement of steel is usually achieved by alloying and/or by thermomechanical treatment process, which modifies phase transformation. Recently, advancement of severe plastic deformation (SPD) techniques provides another efficient access for grain refinement of metals and alloys. The fabrication of bulk materials with ultrafine grain sizes has attracted a great deal of attention over the past two decades because of the materials' enhanced properties [ 1, 2]. In last decade a worldwide effort in manufacturing process to obtain ultrafine grain structures in steels is persisting."

Jan 1, 2011

By R. G. Reddy

The Margules .equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of 'a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules. equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.

Jan 1, 1996

By M. H. Erten

Most of the fourteen workable coal seams in the State of Missouri have high ash and sulfur levels and need beneficiation in order to meet customer and Environmental Protection Agency requirements. If proper ash and sulfur removal methods can be designed, more Missouri coals will be mined and used within the state. One of the main objectives of this research is to investigate the possibility of removal of sulfur of Missouri coals by conventional beneficiation methods.

Jan 1, 1982

By KNona C. Liddell

The time and spatial dependence of component and species concentrations during in situ uraninite leaching have been modeled using a reactive transport model based on partial equilibrium between reactive minerals and the solution. The flow field is represented by mixing cells in series. The effects of the H2O2, (NH4)2CO3, and NH4HCO3 component concentrations have been simulated, and results are presented for a one-dimensional flow field.

Jan 1, 1995

By H. Y. Sohn, S. PalDey

"A new chemical synthesis process for the preparation of intermetallic compounds has been developed. It involves the vapor-phase reduction of mixtures of constituent metal chlorides by magnesium vapor to produce intermetallic compounds in the form of fine powder. The advantages of the process include (a) the use of inexpensive raw materials, (b) low reaction temperatures, and (c) products in the form of fine particles. Titanium and nickel aluminides were prepared by this method. The effect of AlCl/TiCl3 partial pressure ratio on the formation of different titanium aluminides was studied. A two-phase mixture containing 80 mol % of TiAl and 20 mol % of TiA13 formed at an AlC13/TiC13 ratio of 10. The amount of TiA13 was maximized to 72 mol% at an AlC13/TiC13 ratio of 16. The maximum conversion of the limiting chloride TiCl3 was 94 % . In the case of nickel aluminides, NiAI, NiAl3, and Ni2Al3 were formed by reducing mixtures of NiC12 and A1Cl3 vapors. The effect of the partial pressure ratios AlCl3/NiC12 and Mg/NiC12 on the formation of nickel aluminides was studied. The maximum content of NiAl obtained was 98 mol % . At the AlC13/NiC12 ratio of 19, a two-phase mixture of 17 mol% of NiAl and 83 mol% of NiA13 was produced. The product particles were very fine in the size range of 0.05 to 0.2 µm.A. IntroductionIntermetallic compounds are attracting much attention [1]. Titanium and nickel aluminides have attracted a great deal of attention from the aerospace as well as automobile industries because of their potential for high-temperature application (e.g., low density, good oxidation resistance, and high-temperature strength retention [2, 3]). Gamma TiAl and two-phase (TiAl and Ti3Al) alloys [4] are used for gas turbine engine rotational components as well as automobile exhaust valves. TiAl3 is one of the most extensively investigated aluminum-rich intermetallics. Nickel aluminides are attractive because of their low densities, relatively high melting point and good high-temperature strength properties. For example, Ni3Al shows increasing rather than decreasing yield strength with increasing temperature [5]."

Jan 1, 1998

By Songsong Wang

Recently, replacing Pierce-Smith converting process with the oxygen bottom-blowing continuous converting technology has become a new research focus. Based on the principle of Gibbs free energy minimization, the thermodynamic model of oxygen bottom-blowing continuous converting multiphase equilibrium system has been established. The elements distribution behavior is calculated at the same burden composition and operation parameters as the industrial production. The results show that the absolute errors of the mass fraction (wt%) of Cu, Fe, S, Pb, Zn, As, Sb, Bi in crude copper are 0.06, 0.0030, 0.070, 0.38, 0.39, 0.020, 0.017, 0.034, 0.010, respectively, and the absolute errors of the mass fraction (wt%) of Cu, Fe, S, Pb, Zn, As, Sb, Bi in slag are 0.53, 0.81, 0.020, 0.23, 2.5, 0.0048, 0.0010, 0.0030, 1.49, respectively. The calculated results agree well with the actual industrial production data, indicating that the model can be well applied in the oxygen bottom-blowing continuous converting practice.

By S. R. Reddy, R. G. Reddy

"The Margules equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.1 IntroductionIn most of the pyrometallurgical high temperatures processes, interactions of solutes such as oxygen, nitrogen and sulfur, with the solvent atoms are most important during refining processes. There are numerous theories are developed [1-25] to interpret the thermodynamics of solutes in multicomponent alloy systems. Which are mainly developed using statistical or Quasichemical equations.Wagner [4] developed one energy parameter ideal solvent model based on activity coefficient of solutes compositional dependency. He used one energy interaction term which is not able to account for interaction energy parameters for the same solute concentration at different solvent compositions and also it is ineffective model to predict for strong interacting systems."

Jan 1, 1996

By John Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbonate gangue from sedimentary apatites (francolite) in the pH range of 4-6, without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to beneficiate a high MgO siliceous phosphate matrix from South Florida. The modified process includes two flotation stages, one for carbonate removal, as mentioned above, and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the MgO was rejected in the froth, and the phosphate flotation stage produced concentrates analyzing about 31% P20S' 0.7% MgO and 4% acid insolubles. The overall P20S recovery in the two stages is about 85%.

Jan 1, 1989

By Kumar Ganesan

Elevated mercury levels are expected in aged gold mine tailings due to residual mercury from the amalgamation process, The fate of mercury in tailings is not well understood, Its potential health risk depends mainly on the degree to which mercury is mobile in soil. Mercury is re-moved from soil by evaporation, plant uptake, microbial activities, leaching, and other physico-chemical processes. In this research the amount of mercury lost by evaporation was evaluated. Several aged gold mine tailings in Montana were sampled for total mercury and its flux into the atmosphere. Mercury levels in tailings were higher than the general background levels in most sites. The mercury levels in some cases were as high as 10,000 ug/g. The field measurements using flux chambers indicated a wide range of mercury flux from aged gold mine tailings. The mercury flux ranged from 0-11,000 ng/m2/hr. The mercury loss by evaporation helps rid the soil of mercury but the mercury vapor then will participate in the atmospheric mercury cycle, The low solubility of elemental mercury in water helps to minimize mercury leaching from tailings, however, conversion of elemental mercury to more soluble forms by bio-geo-chemical processes can enhance its mobility posing increased health risk.

Jan 1, 2003

By L. Evrard, S. Brouwer, E. Bosly, E. Boydens

"A partial desulfurization roasting process has been tested on a typical copper-zinc sulfide concentrate in a Nichols Herreshoff monohearth pilot furnace whereby the su!fµr is partially removed and iron is to a certain degree preferentially oxidized. The phase changes that occur in the particles during selective roasting at 650°C and 800°C over a range of residence times were investigated by the use of chemical analysis, optical microscopy, X-ray diffraction and electron microprobe analyses. The purpose of this work was to get an insight into the mineral assemblages formed by controlled oxidation roasting and to evaluate if this non traditional approach could be afterwards used to recover zinc, copper and iron by a physical separation method. IntroductionThere has been considerable interest over the years in improving extraction and processing procedures for recovering non ferrous metals especially from polymetallic ores containing copper, lead, zinc and iron sulfides with very fine intergrown phases. Complex sulfide ores, which represent considerable reserves and resources in copper, lead and zinc, as well as precious metals and sulfur, are difficult to treat by conventional physical processes, leading to impure concentrates at low metal recovery. Some methods that can be used to treat such ores were described by G. Barbery (1). Various metallurgical routes generally combining pyro- and hydrometallurgical methods have been explored to develop new processes to recover the metals from zinc-bearing sulfidic ores and concentrates (2, 3, 4). The feasibility of partitioning complex sulfide minerals to simpler phases in order to improve selective extraction of mineral constituents has also been investigated (5)."

Jan 1, 1999

By Duan Xin-hui, Wang Xin, Peng Jin-hui, C. Srinivasakannan, Zhang Li-bo

The work attempts to optimize the process of preparation of modified semi-coke from semi-coke using phosphoric acid (H3P04) as the activating agent using the response surface methodology (RSM). The influences of three major dependent variables, the impregnation ratio, activation time, and activation temperature were assessed on the independent variables yield and the iodine number. The empirical relationship between the dependent and the independent variables were established using the quadratic response surface models, which were utilized to optimize the process parameters. The significance of each of the parameters and interaction among the parameters on the independent variable was assessed based on analysis of variance (ANOVA). The process variables were varied within the range of impregnation ratio (IR) from 1.5 to 4, activation time from 30 to 90 min and activation temperature from 550 'C to 650 'C. The optimized process conditions were estimated to be an IR of 2.29, activation time of 32 min, and an activation temperature of 605°C respectively using the process optimization tool. The BET surface area of modified semi-coke of the optimized sample was estimated to be 915m2/g, with the pore volume of0.71cm3/g, with an average pore diameter of 3.09 nm, with micropore volume fraction being 52.36%. The scanning electron microscope (SEM) images were utilized to visualize the surface pore structure.

Jan 1, 2013

By T. T. Chen

Gold in the Twin Creeks ore is primarily associated with arsenian pyrite. During pressure oxidation, the sulphides are solubilized, but part of the dissolved iron reprecipitates as jarosite and as an iron sulphate-arsenate-phosphate phase. The pressure oxidation products are subjected to cyanide leaching. The cyanide leach residues consist of quartz, gypsum, bassanite, anhydrite, small amounts of jarosite, an iron-sulphate-arsenate-phosphate phase, as well as trace amounts of orthoclase, rutile, pyrite, hematite and monazite; all these particles are dispersed in a fine grained matrix of illite-muscovite. The autoclave leach residues contain a small amount of carbonaceous matter. Many gold grains are detected on the surfaces of the carbon particles, and these gold particles are not leached during cyanidation. The gold particles are typically 0.1-0.2/Lm in size and commonly are embedded in the carbon surface or are coated with a K-AI-Si-S-O phase on the surface of the carbon. The gold grains are consistently associated with elevated CI contents (50-300 ppm Cl). The poor gold cyanide leach recoveries, which initially occurred in the Twin Creek developmental circuit under certain operating conditions, are attributed to the presence of chloride in the feed. This results in the formation of soluble gold chlorocomplexes in the autolcave and the subsequent sequestering of the gold on the surfaces of the carbon particles.

Jan 1, 2000

By H. Bai, B. G. Thomas

"A three-dimensional finite difference model has been developed to study the liquid steel-argon bubble two-phase turbulent flow in continuous casting tundish nozzles. Experiments have been performed on a 0.4-scale water model to verify the computational model by comparing its prediction with velocity measurements using PIV (Particle Image Velocimetry) technology. The computational model was developed using CFX and then employed to investigate the effects of various casting process variables. A fast, simple inverse model to quantify relationships between those process variables was developed, based on interpolation of the numerical model results, using Bernoulli's Equation and advanced multivariable curve fitting methods. Predictions using this model compare well with plant measurements. The model has been applied to present trends and observations on the relationship between casting speed, tundish depth, slide gate opening, and argon gas injection rate. The results can also be used to predict .the theoretical steel flow rate through the nozzle, so that clogging conditions can be identified in the plant.IntroductionTundish nozzle geometry is one of the few variables that are both very influential on the casting process and relatively inexpensive to change. Designing an effective nozzle requires quantitative knowledge of the relationship between nozzle geometry and other process variables on the influential characteristics of the flow exiting the nozzle. This relationship depends on the flow pattern within the nozzle components. Most previous modeling studies of flow in the nozzle have focused on single-phase flow [1-4]. Argon injection into nozzle is an efficient and widely employed method to reduce nozzle clogging, even though the real working mechanism(s) are still not fully understood [5]. Argon injection may greatly affect the flow pattern in the nozzle, and subsequently in the mold. Therefore, two-phase flow modeling is needed to improve understanding of fluid flow in the nozzle."

Jan 1, 2000

By Christina Viklund-White

Life Cycle Assessment has been used to compare the environmental performance of landfilling versus recycling of the zinc used for galvanizing steel. Hypothetical process routes were com-posed involving four different EAF dust treatment processes; Waelz kiln, DC-furnace, EZINEX and slag fuming, as well as scrap dezincing. The study shows that recycling of zinc used for galvanizing steel has environmental benefits in that it saves zinc resources. However, zinc recovery does not necessarily decrease the potential impact on global warming and acidification. The magnitude of these two impact categories is tightly correlated with the amount and type of primary energy consumed in a process. Due to the high electricity consumption in the dezincing process, this route has the highest impact on Global Warming Potential as well as Acidification Potential. The major part of the energy requirement for the production of zinc from primary and secondary sources is consumed in the reduction of ZnO to Zn. The consequence is that the theoretically possible savings in primary energy by recycling zinc-containing materials are relatively minor. The impact categories "land use" and "waste generation" are not considered in this study, but most likely the evaluation of such impacts would further increase the potential environmental impact of the landfill alternative. The results also show that the location of an electricity-intensive process highly affects the potential environmental impact. Comparing process and material alternatives in LCA studies where branch average data is used, is considerably more complex than when LCA is used within a company.

Jan 1, 2000

By J. G. Eacott

This paper reviews the role of oxygen potential and the advances that have been made in the application of tonnage oxygen in copper smelting. Brief reference is made to reaction kinetics before attention is turned to the thermodynamic considerations in copper melting to illustrate the importance of oxygen and. oxygen potential in the component parts of the overall smelting process. The chemical potential diagram for the Cu-Fe-S-O-Si02 system is used to elucidate the difference b etween the conventional matte smelting process and the modern continuous processes. A progressive oxidation scale' is constructed to show the common elements which exist, and the matte grades produced, during the smelting of concentrates to blister copper in commercially available copper smelting processes and those under development. The common route in producing blister copper from molten mattes, regardless of process, is illustrated on the Cu-Fe-S equilibrium phase diagram. The essential features of oxygen enrichment, in terms of its effect on combustion conditions (i.e. oxidation of fuel and sulphide minerals) and the heat balance are outlined. The benefits of oxygen enrichment are listed. The influence of tonnage oxygen and its effect on productivity, fuel savings, gas volume and strength in various copper melting processes are examined as a state-of-the-art review. Reference is made to the economics of tonnage oxygen utilization.

Jan 1, 1983

By Musa Karakus

The sedimentary iron ores of Alsace-Lorraine, France have very high phosphorous contents that average 0.7% and are as much as 2.19% P. Ores from the Tucquegnieux and Joeuf mines have been studied by cathodoluminescence microscopy, X-ray diffraction, scanning electron microscopy, and electron microprobe analysis in order to fully characterize the mineralogy, size, shape, and distribution of the deleterious phosphate grains. The phosphorous occurs as collophane, a carbonate fluorapatite, in ten morphological forms, most abundantly as microcoprolites, but also as intraclasts, concentric layers, and cortices in ooids, phosphate replaced ooids and bioclasts, phosphatiC shells, fossil infillings and internal molds, fish teeth, phosphatiC laminae, and cements between the goethite ooids. About 95% of the phosphate grains are sufficiently large that relatively fine grinding fol'lowed by reverse flotation would be expected to be effective in significantly diminishing the phosphorous content of the concentrates.

Jan 1, 1989

By Agnes Y. Lee

he U.S. Bureau of Mines developed a method to treat lead-contaminated soil and ebonite battery casing wastes to produce a nonhazardous material. The cleanup procedure involves wet screening to separate a minus 18-mesh soil fraction; removal of metal1ic lead, rocks, wood, etc. ; carbonation to change lead sulfate to acid-soluble lead carbonate; size reduction; acid leaching; and rinsing. The casing wastes undergo size reduction and washing to remove the lead sulfate sludge before carbonation. Similarly, the minus 18-mesh soil is carbonated, then acid leached and rinsed. In leaching, fluosilicic acid (H SiF,) and hydrogen peroxide (H20,) are used to dissolve lead compounds. An electrowinning method is employed to strip lead from the lead-rich leachate. The acid content in the leachate is replenished with fresh H,SiF, acid prior to recycling. Treated casing wastes and soils pass the Toxicity Characteristic Leaching Procedure (TCLP) test and can be reclassified as nonhazardous materia1s. Based on this process, a conceptual pilot plant has been designed which will be demonstrated on wastes from two Superfund sites.

Jan 1, 1993