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By Maurice C. Fuerstenau

INTRODUCTION The term, chelate, from the Greek for 'claw,' has its origin in the pincer-like representation of more than one atom of a single ligand bonded to the same metal atom, forming a ring-like structure. Depending on how many attachments exist on the sphere of coordination around the metal ion, ligands are referred to as bidentate, tridentate, tetradentate, pentadentate and hexadentate According to Calvin and Martell (1952) and Somasundaran and Nagaraj (1984), chelating agents must contain suitable functional groups, and their location within the ligand molecule must enable ring formation that is sterically possible. Typical structures that meet these requirements have been given by Fuerstenau and Herrera-Urbina (1988) and are listed in Figure 1. As noted, the functional groups of these reagents contain electron donor atoms such as oxygen, nitrogen and sulfur. Basic groups, such as amino (-NH,), are those that contain an atom with a lone pair of electrons. Acid groups are those, such as carboxylic (-COOH) which lose a hydrogen ion and coordinate with the metal atom. Examples of each of these types chelating reagents are given in Tables 1-4. The specificity of chelating agents for various metal ions has long been known and was utilized early in the search for new flotation collectors. In 1927, Vivian used ammonium nitrosophenylhydroxylamine as a collector for cassiterite. Holman (1929) tested dimethylglyoxime as a collector for nickel oxide. He also suggested taurin as a collector for oxidized lead ores. DeWitt and von Batchelder (1939) suggested the use of oximes as flotation collectors. Gutzeit (1946) conducted an extensive investigation on the use of chelating agents as collectors and as depressants for gangue minerals. The depressants are those reagents that form soluble chelates with metal ions that could function as

Jan 1, 2005

By Gary L. Simmons

Over the past several years, Newmont Gold Company (previously Santa Fe Pacific Gold Corporation) developed a new technology for the flotation of refractory auriferous sulfide minerals which is referred to as the N2TEC flotation process. Starting in April 1997, the first commercial flotation plant utilizing N2TEC technology was successfully commissioned at the Lone Tree Mine near Valmy, Nevada. The Lone Tree flotation plant was designed to process 4,085 mt/d of ore producing 494 mt/d of sulfide concentrate. A flotation tails leach CIP circuit was added to recover cyanide-soluble gold from the flotation tails. A portion of the flotation concentrate is blended with whole ore feed to the Lone Tree autoclave, up to the limit imposed by the current oxygen plant capacity. The remainder of the concentrate is shipped to either the Twin Creeks autoclaves or the Carlin roaster for subsequent oxidation and gold extraction. This paper discusses the results achieved in the commercial flotation plant compared to pilot plant testing and engineering design flotation modeling. Capital and operating cost information are also presented.

Jan 1, 1999

By Emily Wortman-Wunder

As the 2011 president of the Society for Mining, Metallurgy, and Exploration, Inc., I am pleased to present the 2011 issue of the Transactions of the Society for Mining, Metallurgy, and Exploration, Vol. 330. A significant portion of the contribution that we as a professional society make is the publication of professional and technical papers that accelerate the advancement of scientific knowledge and enable the transfer of technology. Communication within the mining community is the key to a successful society. This technology exchange continues a tradition that dates back to the 1871 meeting of 22 mining engineers in Wilkes-Barre, PA, that resulted in the founding of AIME; those individuals envisioned that these transaction volumes “would form a most valuable and greatly needed addition to our professional literature.” This volume fulfills that pledge. The 2011 Transactions is the second Transactions to take advantage of new publication technologies. It appears solely in electronic format. The decision to go to an all-digital format for this longstanding publication was a difficult one, but one which will better serve the mining community. Based on the feedback from the 2010 Transactions in e-book format, I believe that the transition to the all-digital format was the proper decision. The 2011 Transactions contain some of the most interesting research from the past year, including a 10-year profile of roof and rib fall trends from the National Institute of Occupational Safety and Health (NIOSH) and a new cross-disciplinary application of the tools of epidemiology to assess and mitigate risk in coal mines . This 2011 Transactions comprise of a total of 82 technical papers (626 pages including index), including all 19 papers published in 2011 in the Technical Papers Section of Mining Engineering magazine (Vol. 63) and all 32 papers published in 2011 in Minerals & Metallurgical Processing (Vol. 28). Additionally, this volume contains 31 papers that are being published for the first time in this issue. The papers presented in this volume were written by some of the most distinguished professionals in the industry worldwide. All 82 technical papers were peer-reviewed. The process of review and publication requires much hard work by authors, reviewers and our publications staff. As the 2011 president of SME and on behalf of all our members, I would like to extend our gratitude to all whose volunteer efforts contributed to the publication of this volume.

Jan 1, 2011

By Yoginder P. Chugh

The Department of Energy is presently sponsoring the development of automated miner-bolter machines in an effort to increase production and productivity in the continuous room-and-pillar mining sections. This study is concerned with the production potential of these machines in three different mine layouts. The Underground Material Handling Simulation (UGMHS) computer model was utilized in the study. The effect of variables such as bolt installation delay, shuttle car capacity, and equipment availability on production are analyzed.

Jan 1, 1979

By R. P. Plasket, G. M. Dunn

The cobalt plant was successfully commissioned in mid-1983. It is located within the company's nickel - copper re finery situated in Springs, South Africa. Plant design, which began in 1981, made provision for the corrosive process environment, stringent environmental standards, and the latest noise abatement requirements. In addition, the process flowsheet for the primary recovery of the cobalt byproduct and the purging of six impurity metals (nickel, iron, copper, manganese, lead, and arsenic) was designed with simplicity as a primary objective. High purity cobalt powder has been produced since commissioning.

Jan 1, 1987

By R. W. Guill

For the past five years, Small Mine Development has been involved in the development of small grade underground projects. These projects have been in tough environments where solutions have been found by placing emphasis on creative collaborations by small work forces and selected specialists. This has created an environment where constant innovation and change have become standard operating practice. The cornerstones of these efficient operations have been formed using pneumatic backfill, creative shotcreting, specialized equipment, and highly motivated people. The results realized have served to turn interesting properties into productive operations.

Jan 1, 1988

By Terry Quinlan

The financial evaluation of an orebody uses estimates for the grade of ore produced during each year for the life of the mine. Assay data from the Dolphin Scheelite Mine is used to estimate grades by the Polygonal, Ellipsoidal and Disjunctive Kriging Methods. The results are compared with simulated production data, to show the existence of a bias associated with each method. The affect of bias on the financial evaluation of a theoretical model ia assessed.

Jan 1, 1979

By Allan D. Fernie

Many long conveyors, 2 - 20 km plus, have been installed over the past 10 years. Conveyor belt life, depending on the conveyor length and material handled, will generally range from 10 - 15 years. To replace long conveyors splicing one or two rolls into a conveyor run on an intermittent basis can be prolonged in an operating system involving considerable downtime and scheduling problems. This paper presents some of the methods used to- date and highlights forward planning for such an event. Special belt handling equipment required and the execution of a belt change operation are described in detail. Wright Engineers Limited have worked in collaboration with Canada Conveyor to design and implement the methods described herein.

Jan 1, 1993

By R. Debkowski

Mining methods used to protect the workings in underground salt mines against the destructive activity of natural factors are presented in this paper. Major hazards and methods of elimination of their impact on the stability of workings, were determined. Old and modern technical means and technologies used for protection and preservation of the selected most interesting sites were characterized. The results of surveys and studies allowed proposing the change of mine structure i.e. dividing it into monumental and not-monumental part, which should improve execution of necessary protective works.

Jan 1, 2006

By David R. Zuchelli, Elio L. . Checca

Two case studies of methane gas explosions and their effect on the operation of underground coal mines are presented. The studies detail the recovery operations and investigations at each mine site. These include the circumstances prior to the explosions and the effects on the surface and underground ventilation control systems. Various ignition sources such as surface and underground electrical power systems, degasification sites, ventilation shafts, test well casings, and lightning activity were investigated. In each case, a lightning report from the National Lightning Detection Network1 was used in conjunction with the physical evidence and eyewitness accounts to confirm lightning strikes as the ignition source for the explosions.

Jan 1, 1995

By George E. Niewiadomski

The exposure of miners to radon gas and its airborne daughter products is a serious health problem which has long been recognized in the uranium mining industry. The association of high exposure to alpha particle emitters with incidence of lung cancer is well established. There continues to be a pressing need to reduce and eventually eliminate the high incidence of occupational lung cancer among uranium miners through the development of new and improved measurement and control technologies. This paper highlights the current efforts of the Bureau of Mines radiation hazards research program. It is aimed at obtaining a fundamental understanding of the behavior and transport of radon and radon daughters, developing more accurate and reliable instruments and measurement methods and developing cost-effective control techniques. Also discussed are the most recent accomplishments and the future research plans of the program.

Jan 1, 1981

By C. Tsatsanifos

Following closure of an old asbestos mine in Zidani, Kozani Prefecture, Greece, the geotechnical and environmental restoration of the tailings slopes was required. The geotechnical aspects of the restoration included the formation of gentler slopes to increase stability, in combination with drainage works for the same purpose. The environmental aspects of the restoration included covering the slopes with successive layers of soil in order to minimize infiltration of rainwater, and hence the potential for further transport of asbestos fibers, and to provide a suitable layer for revegetation of the slope. The paper presents results of slope stability evaluation using both limit equilibrium and finite element analyses and raises some issues related to reducing impacts to the geoenvironment when designing such restoration projects.

Jan 1, 2006

By Ethan Steward, Kyle Perry

The study investigates the effects of high-velocity impacts of common mine materials on a reinforced mine seal rated to 120 psi. It found that materials propelled during an underground explosion could generate enough stress to crack or damage seals, even with little visible damage. This highlights the need for careful evaluation of mine seals after any impact or high-pressure event.

Aug 1, 2023

By Kenneth N. Han, Yuhong Chen

The removal of carbonaceous material from Carlin gold ore has been investigated via froth flotation. The effect of type and concentration of various oils as flotation collectors and of sodium silicate as the dispersion agent on the overall recovery of carbonaceous material has been studied. Other variables affecting froth flotation efficiency were also examined closely. These included particle size, pH of the solution, and temperature. The effect of reduction and oxidation of carbonaceous material on froth flotation efficiency has also been investigated. This investigation showed that aromatic type oil was the most effective collector. Also found in this investigation was that oxidized carbonaceous material was difficult to float unless the oxidized portion was subject to reduction before flotation. More than fifty percent of the carbonaceous material was able to be removed via froth flotation. It can be concluded from this study that the effect of pH and temperature during the rougher flotation state is of little significance to the overall recovery of carbonaceous material. Since pyrite is responsible for the high consumption of chlorine, removal of pyrite is very important in order to reduce the overall consumption of chlorine.

Jan 1, 1990

By F. N. Kissell

The Bureau of Mines used sulfur hexafluoride (SF6) tracer gas to evaluate the effectiveness of gob ventilation and/or sealing practices at three coal mines, each having different problems associated with their mined-out areas. The purpose of these ventilation studies was to better understand whether current techniques employed for ventilation or sealing are successful at minimizing the potential for gob fires and explosions. The work performed at each mine is discussed: One is a longwall operation that uses ventilation to carry off hazardous gases, and two are room-and-pillar operations, each with far different concerns, that seal off the gobs to isolate them from the main mine ventilation. In all cases, employment of the Bureau's SF6 tracer gas technique resulted in answers to questions raised by the mine operators concerning the effectiveness of their gob ventilation or sealing practices in preventing mine fires.

Jan 1, 1987

By Robin B. Steven

Rio Tinto's Kennecott Bingham Canyon Mine is one of the largest open pit copper mines in the world. In 1988 they completed a $400 million project using a conveying system to transfer the ore from an in-pit crusher to the concentrator. The longest conveyor, C-6, was 17,352ft long and ran in a tunnel through the mountain-side to the concentrator. The belt was removed after 14+ years after carrying 700 million tons of 10 minus ore. The paper discusses the original G6 belt's performance and new splicing methods used to achieve a 60% dynamic splice efficiency on the replacement belt.

Jan 1, 2004

By A. I. A. Salama

A computationally efficient technique for generating a balanced set of density or size separation data is developed. The technique proposed utilized minimization of a modified form of error squares to generate the optimum estimates of outputs mass yields (splits) and balanced direct mass distributions of feed and outputs. The estimated separation data set satisfies mass balance conditions of the streams mass distributions around the separator. The technique proposed avoids the generation of small negative values for the estimated feed and outputs direct mass distributions. Actual data are used to demonstrate the technique proposed.

Jan 1, 1996

By G. Meiers, M. O’Kane

Dry cover systems as a closure option for management and decommissioning of waste rock and tailings is a common prevention and control technique used at numerous sites around the world. Numerous site-specific factors control the long-term performance of dry cover systems. Site-specific climate conditions are one of the key factors to consider when determining the objectives of a dry cover system because these conditions will significantly influence long-term performance. There are advantages and disadvantages of characterizing the site on an annual basis as generally a “dry” site (annual potential evaporation greatly exceeds annual precipitation), or generally a “wet” site (annual precipitation meets or exceeds annual potential evaporation). The field performance monitoring data and discussion presented herein illustrates the caution that is required when using these “annual” criteria for characterizing site climate conditions. Numerous sites exist where precipitation exceeds potential evaporation on an annual basis; however, the site typically experiences hot, dry summer months where evaporation greatly exceeds rainfall. These dry summer conditions have a strong influence on long-term performance. In contrast, sites where potential evaporation exceeds precipitation on annual basis, typically experience periods of the year when a moisture surplus occurs, which also impacts on long-term performance. This paper uses soil-atmosphere cover design modelling and field performance monitoring from sites in Canada, Australia, and the United States to demonstrate the importance of considering site-specific climate conditions when predicting long-term cover system performance.

Jan 1, 2003

By A. LaPlante, A. Cauchon

This gravity circuit at Les Mines Camchib Inc. consists of two pinched sluices to bleed a feed to one of two 76 cm (30") Knelson concentrator. The Knelson concentrate is upgraded to smeltable grade with a smaller Knelson (18130 cm) and a riffleless table. Their tails are column cyanided and washed prior to recycle to the grinding circuit. This paper details size- by-size circuit performance. The Knelsons recover around 90% of free gold (as determined by Mozley Laboratory Separator), even below 37 pm. The sluices are ineffective, with upgrading ratios around 2, but approaching unity in the fine sizes. Much of the effectiveness of the circuit lies in the high gold circulating loads in the grinding circuit, which partly atone for the poor sluice performance, and the ability of the Knelsons to recover free gold. Secondary upgrading recovers slightly above 99% of the primary concentrate gold, 90% of it in a 65% Au concentrate and the balance in a heavily loaded (10 to 20 oz/st) pregnant solution, generated by intensive column cyanidation.

Jan 1, 1990

By R. L. Grayson, Y. J. Wang

An integrated approach to the management of underground coal mine production and cost is presented. A conceptual model for objectively analyzing an underground mine to obtain lower cost and higher productivity from operations is outlined. The model is designed to provide mine managers with a quantitative, decision-assisting methodology that can be used in formulating timely responses to fluctuations in operations. It consists of a productivity fore- cast component, routine use of current resource consumption factors, a linear programming scheduling component, a manpower loading analysis, and an inventory control component. The model is applied to an underground coal mine.

Jan 1, 1990