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By Kenneth S. Johnson

Iodine, a grayish-black nonmetallic element, with a density of 4.9 g/cm3, is a solid at ordinary temperatures. It is a member of the halogen family, along with fluorine, chlorine, bromine, and astatine. Iodine melts at 114°C. and at 184°C it is volatilized to a blue-violet gas that has an irritating odor. It does not occur as an element in nature, but occurs as iodates, iodides, or other combined forms. It is the 47th most abundant element in the earth's crust. Iodine was discovered by Bernard Courtois in 1811. He observed an unknown substance in the crude soda ash that results from the burning of seaweed. Samples of this unknown substance were identified to be a new element, and in 1813 Gay-Lussac named the substance iode, from the Greek word for violet color. The world production during 1989 and 1990 [(Table 1)] is estimated to be about 16 million kg per year (Lyday, 1991), of which about 30% is consumed in the United States. GEOLOGY AND MINERALOGY Compounds of iodine are minor constituents in seawater and brines, in certain marine organisms, and in minerals of the Chilean nitrate deposits. Seawater contains approximately 0.05 ppm iodine, and certain marine organisms, such as seaweed, sponges, fish, and some brown algae, are able to further concentrate iodine (Lyday, 1989a). Some seaweed can extract and accumulate iodine up to 0.45% of their weight, on a dry basis. The northern Chilean nitrate deposits, in the Atacama Desert, contain the following iodine minerals: lautarite, Ca(I03), (calcium iodate); dietzeite, CaJIO,), (CrO,) (calcium iodate-chromate); and bruggenite, Ca(I03), . H20 (Erickson, 1981). Various subsurface brines also contain iodine compounds. Some gas-field brines in the United States and Japan locally contain 30 to 1 300 ppm iodine. Several coals in Germany also contain iodine compounds. Iodine has been recovered from brines mainly in Japan and the United States, but also in Java, Indonesia, Italy, England, and the former USSR. Iodine has also been recovered from seaweed in Ireland, Scotland, France, Japan, Norway, and the USSR. Seaweed was a major source of iodine for the world in the first half of this century, and it remains as a large resource. The reserves and future resources of iodine are large, even excluding the resources in seaweed and seawater, and are shown in [Table 1]. Analysis Iodine as the free element can be detected by the characteristic blue color it gives to a starch solution. Quantitatively it is determined as the free element by titration with standard thiosulfate solutions using starch as an indicator. Colorimetric methods are also applicable. PRINCIPAL PRODUCING COUNTRIES Major iodine-producing nations are Japan, Chile, the USSR, and the United States, with lesser amounts being produced in China and Indonesia ([Fig. 1; Table 1]). Annual world production in 1989 and 1990, respectively, is estimated at 15.6 and 16 million kg. In Japan and Chile, the production of iodine depends on production of other materials, such as natural gas or nitrates, respectively, whereas in US operations (in Oklahoma) iodine is the major product recovered from natural brines. Chile was for a long time the principal world producer of iodine from its nitrate-fertilizer operations, but in recent years Japan has become the world leader with increased production of natural gas and associated iodine-rich brines.

Jan 1, 1994

By Craig Allan

Underground construction environments, especially those with limited airflow such as shafts, cross passages, and stations, necessitate effective dust control. This requires combining existing measures with adapted approaches for more efficient and productive operations, cleaner jobsites, and decreased worker exposure to contaminated air. This paper will discuss new configurations and trends in dust collection on Australasian infrastructure projects including WestConnex, Melbourne Metro Tunnel and City Rail Link, all of which have applied innovative methodologies for mobile at-source dust collection. Mobile dust collectors can be track-mounted dust collectors operate alongside equipment, use hydraulic stepping systems to advance with roadheaders, or compact castor-mounted units are used within cross passage confines.

Dec 1, 2022

By G. Frey, D. Scott, C. Pritchard

Controlled recirculation has been used in the metal/nonmetal mining industry for energy savings when heating and cooling air, in undersea mining and for increasing airflow to mining areas. For safe and effective use of controlled district recirculation, adequate airflow to dilute contaminants must exist prior to implementation, ventilation circuit parameters must be accurately quantified, ventilation network modeling must be up to date, emergency planning scenarios must be performed and effective monitoring and control systems must be installed and used. Safety and health issues that must be considered and may be improved through the use of controlled district recirculation include blasting fumes, dust, diesel emissions, radon and contaminants from mine fires. Controlled recirculation methods are expected to become more widely used as mines reach greater working depths, requiring that these health and safety issues be well understood. The U.S. National Institute for Occupational Safety and Health (NIOSH) conducted two controlled recirculation tests over three days at a Wyoming trona mine, utilizing an inline booster fan to improve airflow to a remote and difficult-to-ventilate development section. Test results were used to determine the effect that recirculation had on air qualities and quantities measured in that section and in other adjacent areas. Pre-test conditions, including ventilation quantities and pressures, were modeled using VnetPC. During each test, ventilation quantities and pressures were measured, as well as levels of total dust. Sulfur hexafluoride (SF6) tracer gas was used to simulate a mine contaminant to monitor recirculation wave cycles. Results showed good correlation between the model results and measured values for airflows, pressure differentials, tracer gas arrival times, mine gasses and dust levels.

Jan 1, 2013

By Otto Schumacher

Shortcut methods are commonly employed for estimating mining costs for prefeasibility studies. Most of these methods, however, are suitable for earliest stage studies or for internal discussion purposes only. The experts at InfoMine?s CostMine division recommend that any cost estimate completed for purposes of significant decisionmaking or for compliance with Canada?s NI 43-101 requirements be completed using a determinative itemized method. The same basic principles apply for an early stage, intermediate stage, or advanced stage estimate. The only difference is in the level of detail and effort employed. ? Based on the results of a completed resource estimate, an itemized cost estimate begins with development of a conceptual mine plan. Using a surface mine as an example, four elements are crucial no matter what level of study is initiated. Basic geometry of the ore deposit and waste material, with a determination of the expected ratio of waste to ore, a reasonable pit slope angle, possibly requiring the completion of geotechnical studies to predict the waste-to-ore ratio with certainty. ? Determination of the assumed ore and waste production rates. ? Locations of all ore stockpiles and waste dumps. ? Segmental haulage distances and gradients for ore and waste.

Oct 1, 2013

By D. F. Doerr, E. Blalock, D. R. Bush, K. D. Cohen

"INTRODUCTION The design, development, fabrication, and test of cryogenic breathing apparatus is part of a much larger effort funded by the National Institute for Occupational Safety and Health (NIOSH) and managed through a Space Act Agreement with the National Aeronautics and Space Administration (NASA) at the Kennedy Space Center (KSC) in Florida. This effort is designed to create cryogenically based life support equipment that is responsive to the needs of miners as required by the Miner Act of 2006. Our goal was to design and build a liquid air based self-contained breathing apparatus (SCBA) that lasted 2 hours and would be used for the egress of miners during a mining accident and be refillable while worn. Therefore, the current report describes tests of an Advanced Cryogenic Breathing Apparatus (termed the ACryoBA) designed to provide miners egressing an emergency situation with a two-hour open-circuit SCBA. The ACryoBA utilizes low pressure cryogenic liquid air instead of high pressure compressed air commonly used in most commercially available SCBA. The ACryoBA can also be self-filled from strategically placed Cryogenic Air Supply and Fill Stations (CryoASFS) initially, and thereafter on the egress route approximately every 1 hour and 30 minutes with a 30 minute air reserve. The ACryoBA evolved originally from a one hour Liquid Air Pack (LAP) developed in the 1980’s for Space Shuttle Rescue forces allowing for longer duration and cool air (Figure 1). It was used successfully for many years, through the end of the Space Shuttle Program. The first attempt at a mine egress pack was the Cryogenic Breathing Apparatus (Figure 2). It was to have a low profile, two hours of breathing, attitude independence, and a simple rapid refill while in use. The CryoBA met the two hour criteria, but with difficulty due to excessive heat leakage caused by the dual 4 liter Dewar design. Much of the stored air was lost as it vaporized faster than it could be used. However, the pack was successful in demonstrating both attitude independence and a simple rapid refill capability. The ACryoBA project was designed to continue the progression and address the deficiencies in the CryoBA. The ACryoBA pack was designed to last 2 hours. It minimizes the heat leakage with a single Dewar and thereby requires less liquid air. The single Dewar design also minimizes weight, making it much more manageable by the user (Figure 3). The ACryoBA complies with 42 CFR part 84 NIOSH certification test requirements. One critical requirement for the ACryoBA is operation in positions other than vertical for periods up to 1/4 (i.e. 30 minutes) of the rated service life of 2 hours; this was accomplished by use of new technology called the “attitude independent pickup” which is abbreviated “AIP.” The AIP, developed by BCS Life Support LLC (patent #8,899,226), has a tube going from the top flange down through the center of the Dewar. At the end it has a flexible bellows and a weighted end. Due to the flexible nature of the bellows, the pickup at the end is free to rotate and follow the liquid level around within +/- 90o of vertical."

Jan 1, 2016

By M. C. Fuerstenau

Collophane, cryptocrystalline fluorapatite, is examined as a substrate for plant water and wastewater remediation. The attenuation of Fe3+, Cr3+, Fe2+, Cd2+, Hg2+ and Pb2+ is presented as a function of metal ion concentration, amount of collophane, initial pH and conditioning time. TCLP results for Pb2+ contaminated collophane are presented. Mechanisms of adsorption for divalent and trivalent species are suggested. Key words: Collophane, Wastewater remediation, Heavy metal removal

Jan 1, 2003

By Mokhinabonu Mardonova, Yosoon Choi

Open-source technology to support Industry 4.0 has become the target of academic research in many sectors. This study reviews the trends of open-source technology, its forms, and some industrial applications. As a case study of the use of open-source hardware and software in the mining industry, this study proposed a low-cost environmental monitoring system for nonmetallic underground mines to support mine safety and occupational health. The system was developed using open-source hardware, Arduino and 3D printer, to design the monitoring device, and open-source software, MIT App Inventor, to develop an Android application for smartphones to enable remote communication with the system. Field experiments were conducted at an underground tunnel and a nonmetallic underground mining site to assess the performance of the system in mobile and static modes, respectively. Although a few limitations related to the precision of the low-cost dust and gas sensors exist, the findings of the experiments show that the mining industry can benefit from open-source technology deployment when considering cost factors.

By A. Tordoir, S. S. Kanchibotla, W. Rogers, E. Engmann, B. Bisiaux, S. Ako

Blast-induced rock mass displacement can have a significant impact on ore loss and dilution. The mischaracterization of the grade boundaries both prior to, as well as a result of, blasting can lead to significant financial losses due to ore loss and dilution. Ore dilution occurs when waste material is miscategorized as ore and sent for processing or stockpiling, diluting the run-of-mine head grade and recovery. Ore loss takes place when valuable mineral is miscategorized as waste and sent to the waste dumps, thus never being processed and recovered. Extensive research has been conducted at the University of Queensland over the last fifteen years to understand the impact of blast movement on ore loss and dilution. Recent outcomes of this research have led to the development of innovative tools and techniques to measure and model blast movement. These techniques have been implemented at the Ahafo gold mine in Ghana to understand blast movement dynamics and to implement solutions to reduce blast-induced ore loss and dilution. These solutions are validated through controlled trials and have been incorporated into site standard operating procedures.

Jan 1, 2012

By Yerkezhan Madenova, Kairat Kalmurzayev

This study intends to demonstrate the engineering application of ground penetrating radar (GPR) that would enable site engineers to prevent the high cost of blind drilling. At the tailing dump located in Zhairem Mining and Processing Plant, the challenge of sheet pile driving is encountered due to the indefinite watertight clay layer deposition depth that serves as a protective layer against groundwater contamination. A numerical model of the soil underlying the tailing dump is built using the existing hole data to compare and confirm the existing geological cross sections for three profile lines along the south and southeast parts of the tailing dump. GPR is employed to investigate the subsoil geological structure and detect the watertight clay layer deposition. On the basis of radargrams tied to the existing borehole data in the numerical model, 21 drill hole locations are suggested to assess and confirm the clay layer depth along profile lines at the tailing dump. The drilling results of the suggested holes confirmed the expected depth of the clay layer. It is concluded that GPR is a practical and economic subsurface mapping method that can prevent the high cost of blind digging of the ground and orient the drilling operations effectively.

Jan 12, 2023

By John Murray, Ryan Smith, Daniel Ebin, Robert Gould, Thomas Hennings

The Atlanta Plane Train Tunnel West Extension was excavated at Hartsfield-Jackson Atlanta International Airport using Sequential Excavation Methods (SEM). At its shallowest point, tunnel cover to bottom of Domestic Terminal footings was limited to 6 feet in soft ground. To mitigate risk of excessive building movement due to tunneling-related activities, the columns near the alignment were directly underpinned. Underpinning was accomplished using a combination of grouted mini-piles, installed under low headroom conditions, that supported steel framing spanning over the tunnel excavations. This paper focuses on design and construction of the underpinning system used to mitigate risk from tunneling.

Jun 13, 2023

By Peter Amelunxen, Kain Nugent, Brandon Akerstrom, Willem Duyvesteyn, Todd Harvey

In 2024, Capstone Copper Corp commissioned a new sulfide flotation plant at Mantoverde in the Atacama region of Chile to process copper ore at a design rate of 32,000tpd. The pyrite associated with the copper ore body contains cobalt in solid solution, with Co replacing Fe in the pyrite matrix. As per the existing sulfide flotation flowsheet most of the pyrite is depressed and sent to tailings via the cleaner scavenger tail stream. A new project considers the recovery of the pyrite from the cleaner-scavenger tails via froth flotation to produce a cobaltiferous pyrite concentrate, which is then leached via the existing dynamic copper leach pad to oxidize the pyrite and dissolve the cobalt. The cobalt is recovered from the solution by treating a bleed stream of copper SX raffinate through a continuous, counter-current ion exchange (CCIX) facility. This approach to by-production of cobalt confers numerous benefits, including reduced costs compared with alternative cobalt recovery processes, reduced acid consumption in the heap leach, increased copper production, and reduced acid mine drainage potential due to the removal of pyrite from the mill tailings.

Feb 1, 2025

By B. A. Slaker, T. Miller, M. M. Murphy

An underground limestone mine in eastern Ohio was experiencing significant floor heave and roof falls, attributed to high horizontal stresses. Areas of the mine showing floor heave were monitored with roof-to-floor extensometers and photogrammetry surveys to determine the rate and magnitude of heave. Extensometer data were recorded hourly at four locations across adjacent entries while photogrammetry surveys of the floor were performed at the same locations every two to five weeks. A final survey was performed using an I-Site 8200 laser scanner. Following instrumentation, floor heave up to 10.1 cm (4 in.) was measured by the extensometers, photogrammetric reconstructions and laser scanner over a six-month period. The extensometers were biased by the location where they were placed, failing to consistently capture the location and extent of floor heave and cracking. The photogrammetry surveys were not precise enough to capture small magnitude movements. Mining in the area was halted and within several months the floor movement and incidence of roof falls were significantly lessened.

Jan 1, 2018

By G. D. Hood, B. E. Davis

A problem that has continued to plague the Florida phosphate industry is loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µm) in a separate circuit have resulted in limited success, but recovery is still not optimum. A fundamental examination of the mechanisms involved in the conditioning of the coarse phosphate has led to results that seem to supersede common paradigms. The Bureau of Mines investigated conditioning parameters such as fatty acid/fuel oil dosage, residual clay content in the feed, conditioning time, mixing intensity, and conditioner solids content. The study revealed that the effect of all these parameters was important. However, it was discovered that contrary to common beliefs, the conditioning time affected the grade of the rougher concentrate much more than the recovery. Specifically, the longer the conditioning time, the less quartz that was floated. It was also discovered that high mixing intensity conditioners could lower the conditioning time required for good grade. Many phosphate operators use low intensity drum type conditioners. Optimizing the conditioning time, mixing intensity, and other conditioning parameters resulted in a rougher concentrate grading 30 pct P.2O5, with an attendant recovery of 95 pct.

Jan 1, 1993

By Harry Asche

Tunnels are frequently specified by owners to be designed to a structural code, often a bridge code. In the USA, AASHTO have created a tunnel code, based on structural principles, the AASHTO LRFD Tunnel Design Specification. The Load Resistance Factor Design method (LRFD) described in the AASHTO title is an approximation to the probabilistic design of structures, based on the independence of load and resistance. This methodology is well known to be problematic in geotechnical design, but it is widely used. The paper considers the difficulties of this approach and describes alternative approaches that would result in more appropriate designs for tunnels.

Jun 13, 2021

By Akram Marseet, Andrew J. Petruska, Rik Banerjee

Event cameras are used for their performance in high dynamic-range lighting conditions which are canonical to active mining environments. Direct labeling of event-based image data to train a model to perform semantic segmentation using traditional methods is slow and error-prone. This study proposes a framework to use roughly hand-labeled color images from a mine as an input to an intermediary probabilistic algorithm called alphamatting to generate a ground-truth data set. These high-fidelity labels can be used to train a semantic segmentation model to differentiate the support strap from the roof. This model can then be leveraged to segment an event-based scene to enable autonomous roof bolting. This pipeline has been shown to achieve an accuracy of 88% with a false positive rate of 3%.

Feb 1, 2024

By Z. T. Bieniawsk, C. A. F. F. Santos

The effects of artificial weathering on the mechanical properties of the Loyalhanna sandstone have been investigated. Weathering was simulated in the laboratory by subjecting cylin- drical specimens of rock to alternate cycles of wetting and drying (in distilled water at 2O0C 2 5OC and in an electric oven at 105OC t 1°C, respectively). The total number of cycles was 100 and the geomechanical characteristics of the altered material were determined through uniaxial compressive and indirect tensile ("Brazilian") tests, with the determination of axial and trans- verse strains and monitoring of acoustic emission activity (rate and total event count). Moisture content and weight loss data were collected after each cycle and the mechanical parameters (unconfined strength, indirect tensile strength, young's modulus, Poisson's ratio, permanent set and AE/MS activity) were determined for unweathered specimens and after 10, 20, 50 and 100 cycles of wetting and drying. Hypotheses for the effect of weathering on the geomechanical properties of the Loyalhanna sandstone are proposed as reinforced by petrographic analyses carried out for the different stages of artificial weathering. A methodology for assessing the degree of physical weathering of rocks is proposed based on the number of wetting and drying cycles.

Jan 1, 1986

By Lynn I. Kelley

Industrial-mineral production contributes on the order of CDN$1.5 billion per year to the economy of Saskatchewan, Canada. Potash is the primary industrial mineral produced in the province, followed by aggregate, sodium sulphate, salt, potassium sulphate, peat, clays, silica sand, calcium-chloride brine, and "clinker." Potentially economic deposits of kaolin, diamond, and building stone are under evaluation. All of the major deposits of commodities discussed here are located south of lat 56°30'N. Most of the locations are presented on Figure 1 POTASH Saskatchewan supplies approximately 30% of the world's demand for potash. Eight conventional underground mines and two solution mines produced an all-time high of more than 13 million metric tonnes of potash (KC1) (8 million tonnes K2O equivalent) in 1997, valued at over CDN$1.4 billion. All of the mines exploit the middle Devonian Prairie Evaporite. The four potash-bearing members of the Prairie Evaporite underlie much of southern Saskatchewan and extend southward into North Dakota and Montana and east- ward into Manitoba (Fig. 2). Halite and anhydrite separate the potassic members. The evaporite beds locally are interrupted by solution structures (anomalous ground). Some of the structures may be related to deep-seated tectonic features.

Jan 1, 1999

By Doandy Yonathan Wibisono

Shotcrete is a versatile and widely utilized rock support material in mining and civil engineering projects due to its adaptability, strength, and efficient application. It immediately stabilizes rock surfaces, effectively controlling loose materials and preventing rockfalls in underground excavations. This paper focuses on assessing and analyzing data from observations of nozzlemen (shotcrete sprayers) during primary ground support activities in an underground mine. The study highlights the importance of nozzlemen’s skills in ensuring the quality of shotcrete application, which is critical for underground mining operations’ structural integrity and safety. A comprehensive training program and field support were implemented to enhance the nozzlemen’s proficiency. The training set covered theoretical knowledge and practical techniques to improve shotcrete application daily. Proficiency improvement was assessed using quantitative metrics, with rebound percentages decreasing by 5–14% as nozzleman competency increased. The results of this initiative showed significant improvements in shotcrete quality, including increased efficiency, reduced waste, and fewer reworks or rehabilitations. The findings aim to contribute to a broader understanding of best practices in shotcrete application and nozzlemen training, ultimately enhancing ground support application measures in the mining industry.

Feb 1, 2025

"A commercially available Through-the-Earth (TTE) communications system was evaluated at an active underground longwall mine in West Virginia. This TTE system uses electric field (E-field) sensing to send text based communications using two separate antenna arrays connected in parallel. Each antenna array is composed of interconnected, grounded metallic rods or other such structures. Two-way communication between subsurface locations was investigated in this study using various antenna configurations. This field study was conducted as a part of a larger multi-site evaluation of available TTE systems in an effort to determine their operational sensitivity. INTRODUCTION Wireless, Through-the-Earth (TTE) communication technology is designed to achieve point to point communication through solid strata using very low frequency (VLF) and ultra-low frequency (ULF) electromagnetic waves. This ability allows TTE communication to function without the need for intermediary communications infrastructure, such as repeaters. As a result, such communication systems have the potential to provide reliable, robust communications between surface and underground personnel. Exploration into the use of TTE technology for this purpose dates back to the 1920s (Jakosky and Zellers 1924; Pittman, Church and McLendon 1985), but U.S. permissibility requirements slowed the development of TTE equipment for widespread implementation (Durkin 1980; Pittman, Church and McLendon 1985). One of the primary challenges in producing wireless TTE communications is the counteraction of signal attenuation when propagating through solid strata (Barkand, Damiano and Shumaker 2006; Wadley 1949). The long wavelengths of TTE transmissions make them well-suited for reducing the rate of attenuation. However, even when operating within the VLF to ULF range, the performance of TTE systems is still affected by geologic and anthropogenic factors (Geyer 1973; Geyer and Keller 1976; Geyer, Keller and Ohya 1974; Jakosky and Zellers 1924; Large, Ball and Farstad 1973). Although commercially developed TTE systems have demonstrated the ability to communicate through a variety of conditions, their range and performance have been highly varied (Barkand, Damiano and Shumaker 2006; Geyer and Keller 1976; Geyer, Keller and Ohya 1974; Ilsley, Freeman and Zellers 1928; Jakosky and Zellers 1924; Yenchek et al. 2012)."

Jan 1, 2016

By Mehmet Mesutoglu, Ihsan Ozkan

This study investigates the feasibility of rock bolting support in an underground coal mine gallery with a thick coal seam. The Ömerler underground coal mine working area, owned by West Lignite Enterprise of Turkish Coal Enterprises, was selected for this purpose. Longwall top coal caving is implemented as the production method in the Ömerler underground coal mine. Field and laboratory studies were conducted to determine rock mass and rock material properties, followed by experimental, empirical and numerical analyses based on the acquired data. The obtained design results were evaluated using a resin-grouted rebar rock bolting (RBR) system and steel arch support (SAS) pilot application areas. The numerical modeling results conducted using the fast Lagrangian analysis of the Continua 3D (FLAC 3D v6.0) program indicated less displacement and secondary stress change in the RBR-supported zone compared to the SAS-supported zone. In situ measurements also demonstrated that RBR provided more successful support to the roof during coal production activities. The findings suggest that RBR is a more effective solution when evaluating the feasibility of rock bolting support systems in underground galleries with thick coal seams at the Ömerler Mine. This study emphasizes the importance of more sustainable and safe support systems to enhance operational efficiency in the coal mining industry.

Mar 1, 2025