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By J. D. Miller, P. L. Sibrell

The nature of surface sites for the adsorption of gold from alkaline cyanide solutions has been investigated using samples of synthetic, highly-oriented pyrolytic graphite (HOPG). This HOPG material offers an idealized graphite structure enabling the independent study of the graphitic basal-plane sites and the edges, or defect sites, of the graphitic planes. Radiochemical and X-ray photoelectron spectroscopic experiments independently demonstrated that gold adsorption was much higher on the edges (defects) of the graphite planes than on the planes themselves. These results suggest that site-specific adsorption is prevalent in the adsorption of gold by graphitic carbons (including activated carbon, carbon black and graphite) and that most of the favored sites are at edge defects in the graphite crystal structure.

Jan 1, 1993

By W. R. Reed, W. J. Archer, A. B. Cecala, J. D. Potts

The U.S. National Institute for Occupational Safety and Health (NIOSH) uses light-scattering real-time dust monitors (nephelometers) in its research to develop dust controls to reduce respirable silica dust overexposures in miners. Recently, the model 1500-pDR, an active nephelometer (i.e., with cyclone and pump configuration), was introduced by Thermo Scientific. Testing was completed to ensure compatibility with the metal/nonmetal mine dust personal sampling unit (M/NMDPSU). Results of testing demonstrated that gravimetric concentrations measured from the 1500-pDR are comparable to the gravimetric concentrations measured using the M/NMDPSU, without need for correction, under commonly observed dust loading conditions.

Jan 1, 2012

By M. Li, J. D. Miller

It has been discovered that water insoluble alcoholic solutions of alkyl hydroxamic acids serve as selective collectors for the flotation of phosphate mineral resources (Miller et al., 2000). The effectiveness of the new collector chemistry has been demonstrated by the results from single stage bench scale flotation experiments for feed material from plants in Florida, North Carolina, and Utah. In the best case, from experiments with low grade (5% P20,) coarse feed (16 x 35 mesh), a single stage phosphate recovery of 95% was achieved with a concentrate grade of 31% P20,. Such a separation efficiency could not be achieved using the traditional fatty acid/fuel oil collectors as is evident from a comparison of the respective grade/recovery curves.

Jan 1, 2002

By A. Cecala, J. Noll, J. Organiscak

Many underground metal/nonmetal mines are using enclosed cabs on mining equipment to reduce the exposure of miners to diesel particulate matter (DPM). However, some enclosed cab systems may not be meeting their expected efficiency in capturing DPM, which could be a result of inappropriate filter use, cab leaks or insufficient pressurization. NIOSH investigated several types of filters for reducing DPM to determine which type had the best capture efficiency. The laboratory results indicated that a MERV 8 (minimum efficiency reporting value, as defined by the American Society of Heating, Refrigerating and Air- Conditioning Engineers) filter captured about 50% of the DPM, a MERV 16 filter collected 96-98% of the DPM and two HEPA (high efficiency particulate air) grade filters captured over 99% of the DPM. NIOSH also performed a field study to measure the efficiency of two cabs at a limestone mine. The cab filtration systems of a loader and haul truck were found to be over 90% effective in removing DPM, except under certain operating conditions when the efficiency was as low as 41%. A possible reason for the low efficiencies is an open window in the cab, but more studies need performed to obtain a better understanding of the cause and solution of the problem.

Jan 1, 2011

By T. Dombrowski

Acid-activated montmorillonite is used worldwide as a catalyst and as a sorbent for the enhancement and purification of petroleum products as well as vegetable and animal-based fats. The solid-acid character of the activated montmorillonite is imparted by the manufacturing process, giving it unique properties that are exploited in these industries. Several international companies and a multitude of local clay producers are focusing on improving the efficiency of their standard and specialized products. This paper will describe the use of acid-activated montmorillonite in traditional sorbent applications, as a solid acid catalyst, and other new uses.

Jan 1, 1997

By Albert L. St. Peter

The "Old Reliable" four million pound blast in March of 1972 marked the opening, as far as is known, of serious efforts to commercialize the In Situ concept. That was a coyote shot, and it was followed by three blasts at McAlester Fuel's "Zonia" operation which were surface hole shots. As the only individual who had a principal part in all four shots, it seems to be appropriate to present experiences in the developments and evolutions of the in Situ method of ore extraction. Some of the problems will be described, along with proposals for management of such projects in the future.

Jan 1, 1976

By Fred L. Stanley, Ricky Q. Honaker, Michael J. Mankosa

Spiral concentration has gained a great deal of popularity as a cheap, effective method for recovering fine coal (8x100 mesh). Typically, 6-turn, wide-profile spirals are used in either a single pass, open- circuit configuration or in combination with a middlings retreat circuit. Recent work conducted at Carpco, however, has indicated that a split feed scenario and/or hydraulic classification in advance of spiral concentration offers significant advantages in both capacity and metallurgical performance. In addition, it has also been shown that the apparent density separation which naturally occurs in a hydraulic classifier provides significant up-grading in terms of pyrite and ash rejection. The results from this study will be presented in comparison with those obtained from open-circuit spiral testing.

Jan 1, 1995

By D. Kidd, T. Tucker, L. M. Indergard, S. Davis

"INTRODUCTION The Lisbon Valley Mining Co LLC (LVMC) operates the Lisbon Valley Mine located in SE Utah. The mine includes 3 open pits, 150-acre heap leach pad, and solvent extraction electro winning plant (SX/EW). Approximately 25MM tons of ore has been mined since 2005. The ore is stacked on the leach pad to an average height of 55 feet and occurs as a blend of crushed material (minus 2”) and run-of-mine (minus 24”). The host rocks include Dakota and Burro Canyon Sandstones. Copper occurs finely disseminated in this material at an average grade of 0.46%. Minerology is 63% sulfide, 27% oxide, and 10% insoluble. Total inventory mined through 2016 is approximately 230 MM lbs. METALLURGICAL CONSTRAINTS Copper production is constrained by areas of low permeability ore and geochemical issues, including acid consumption. The intrinsic permeability the ore ranges from 10-2 to 1 Darcy. This permeability does not permit sufficient aeration by natural convection, therefore oxygen transport is largely limited to the mass of oxygen that can remain dissolved in leachates. As a result, greater than 50MM lbs of copper remains in inventory and occurs secondary sulfides, including chalcocite, covellite, and bornite. BIOLEACHING FUNDAMENTALS Due to the higher activation energies of secondary sulfides, notably covellite and bornite, a strong oxidant is needed to remove an electron from the metal-sulfide lattice and release the copper cation into the sulfate solution. This process occurs most efficiently using the strong oxidant ferric iron (Fe3+). Ferrous iron can be oxidized to ferric iron by oxygen via chemical oxidation or biologically; which was measured to occur 500,000 times faster when using microbes versus oxygen.1 The microbes that oxidize ferrous iron (Fe2+) to ferric iron are naturally abundant and will develop biomass when appropriate conditions and nutrients present themselves. Most nutrients are provided by the ore/irrigation (P,N,Mg, Ca & Fe2+) while the others (O2 and CO2) are provided by air. In most cases, oxygen transfer is the rate limiting step during copper sulfide leaching. 1 Lacey & Lawson 1970 FORCED AERATION SYSTEM DESIGN This paper describes LVMC’s efforts to bioleach the remaining inventory by forced aeration. Two basic aeration systems were installed and tested including vertical wells and horizontal piping. Vertical System The vertical system was installed using the mine’s blast hole drilling rig. Wells were constructed using 4” high-density polyethylene (HDPE) connected to 4” polyvinyl chloride (PVC) screens similar to conventional bioventing wells. Ore samples were collected at each well location to characterize the spatial distribution of the remaining inventory along with fines (minus 200 sieve), pH (acid consumption), and iron. A block model of each analyte was developed and mapped in 3D."

Jan 1, 2017

By D. A. Barr

The Galore Creek copper deposits lie in the Stikine River district of northwest British Columbia, a largely undeveloped region which possesses rugged mountain terrain with deeply incised valleys which support dense undergrowth. Timberline is normally at about 1300 m (4265 ft) and the higher levels contain glacial systems and large ice fields with peaks rising to 3500 m (I 1,483 ft). A location map of the Galore Creek area is given in Fig. 1. In the late 1920s, field parties under the direction of F.A. Kerr (1948) of the Geological Survey of Canada completed geological surveys of the district. Primary access for this work was provided by riverboats on the Stikine and Iskut Rivers. Kerr's party had to contend with extremely difficult travel conditions that required considerable backpacking, augmented by pack dogs in certain cases. Absence of ground control led Kerr to establish his own topographic maps. Among the geological data established was the recognition [ ] that small bodies of orthoclase porphyry in the district are often well mineralized with base metal sulfides. Copper mineralization in the upper Galore Creek valley, a tributary of Scud River which flows into the Stikine River some 80 km (50 miles) south of the small settlement of Telegraph Creek, was originally discovered during aerial reconnaissance by M. Morrison and W. Buckholz while prospecting for Hudson Bay Exploration and Development Co. Ltd. in 1955. Malachite- and azurite-stained out- crops in several parts of the Galore Creek watershed are clearly visible from distances of 500 m ( 1640 ft) or more. Claims were staked in 1956 and the copper showings were partly mapped, trenched, and investigated by shallow diamond drilling. Because of the remoteness of the area and higher priorities for expenditures elsewhere, no further work was undertaken and most of the claims were allowed to expire.

Jan 1, 1991

By Robert E. Carver

Opaline clays from central and eastern Georgia are widely used as industrial and domestic absorbants, principally as insecticide carrier and animal litter. The clays are classified as fuller's earth, although they &e somewhat atypical of the group, since opal (cristobolite) is commonly the dominant clay-sized mineral. A preliminary investigation of absorption characteristics indicated that water vapor absorption (264 days) is' related to opal content as determined by x-ray diffraction peak height ratios. Ethylene glycol vapor absorption is related to montmorillonite content. Contact absorption of water is complexly related to surface absorption, porosity, opal content and montmorillonite content, and may be as great as 112% of the original sample weight. The most absorbent clays are highly porous (to 65%) and contain both montmorillonite and opal.

Jan 1, 1972

By Peter Zhang, Mark Van Dyke, Ted Klemetti, Morgan Sears

Room-and-pillar mining is a mining method used in the United States to extract coal from underground, and pillar recovery is widely practiced for maximizing coal recovery and mining economics. Under certain conditions, room-and-pillar mining can create high stresses in coal pillars resulting in a coal outburst. These outbursts represent one of the more severe safety hazards in underground coal mines, potentially causing injuries and fatalities. Over the past ten years, coal outbursts have resulted in three fatalities in U.S. room-and-pillar mines. Though coal outbursts generally occur under deep cover, they are more likely to occur during pillar recovery and under multiple-seam mining conditions. Coal outbursts are generally associated with strong roof and floor and heavy loading of coal pillars, but it is difficult to predict whether, where, and when they will occur. In this respect, risk management provides a proactive tool to prevent coal outbursts in room-and-pillar mining by identifying mining areas with high risk of outburst and mitigating the risk accordingly.

Apr 26, 2022

By J. L. González-Chávez, A. Ballester, M. L. Blázquez, F. González

In recent years, the bioleaching of sulfidic raw materials has been of great interest. However, the application of this biotechnology is now very limited for many different complex reasons. The mechanism of the chemical and electrochemical reactions taking part in the process is not well understood. The application of electrochemical techniques is useful in its elucidation. Among the common sulfides, galena has been studied very little with respect to its behavior during bioleaching. Therefore, the electrochemical evolution of massive electrodes of lead sulfide in the presence and absence of' a mixed culture of mesophilic microorganisms was investi¬gated by the application of potentiometry, anodic and ca¬thodic polarization and cyclic voltammetry. The agitation rate, the use of pH control and the composition of the nutrient mediums did not have any significant affects on the oxidation of galena. However, the temperature (25 'to 45 °C), the scan rate (4 to 100 mV/s) and the acid used to adjust the pH were significant variables that influenced sulfide oxidation. There¬fore, the peak (600 to 1,000 mV) corresponding to the oxida¬tion of sulfide ions from the mineral was only detected in the presence of a complexing anion of lead. In the presence of bacteria, the peaks corresponding to galena oxidation de¬creased and, at the same time, new peaks appeared both during the oxidation at -300 mV and during the reduction of the mineral surface at 150 and -300 mV. These signals were more important when the attack time increased. The rest potential of bioleached mineral increased with an increase in leaching time, which was related to the electrochemical transformation of the galena surface.

Jan 1, 2000

By Shail J. Butani

This paper analyzes the 1982 coal mine accident data collected by the Mine Safety and Health Administration (MSHA) for key equipment types, by mine type, and by geographic region. The differences in hazards associated with the various equipment types are studied both in absolute (i.e., total number of incidences) and relative (i.e., incidence rate or the number of incidences per 200,000 employee or exposure hours) terms. The paper compares and contrasts the total number of incidents as well as incidence rates classified by several types of severity measures such as lost workdays cases, mean number of lost workdays per lost workdays case, fatal cases, non- fatal cases without lost workdays, total number of cases, and total number of lost workdays This statistical analysis shows that significant differences in hazards exist not only due to equipment type but also due to mine type and geographic region.

Jan 1, 1986

By Joe Hachey, Jerry Dorn, Jeff Schutt, Derek Penrice

"Sound Transit’s East Link Project, a $3.7 billion (2015 $), 14-mile light rail extension, will connect downtown Seattle with the rapidly developing east side cities of Bellevue and Redmond. Among the most technically challenging aspects of the Project is the 2,435 foot long Downtown Bellevue Tunnel (DBT), which will be constructed through the central core of Bellevue underneath 110th Avenue NE using a combination of Sequential Excavation Methods (SEM) and cut and cover tunneling. The 1,980 foot long central SEM component of the DBT will be mined at shallow depth through challenging and complex geology, comprised of glacially overconsolidated soils, containing both regional and perched groundwater conditions and in close proximity to existing high rise buildings. The paper shares lessons learned from the planning decisions and risk based approach to the investigation, design and procurement processes which shaped the DBT configuration and enabled a successful transition to the project’s construction stage. INTRODUCTION The East Link Project is a voter-approved $3.7 billion (2015 $), 14-mile extension of the existing Sound Transit (ST) light rail transit (LRT) system from downtown Seattle, across Lake Washington via I-90, to the cities of Bellevue and Redmond on the east side of Lake Washington. With targeted completion in 2023, East Link will provide riders with an efficient and reliable connection between the largest population and employment centers on the east side and downtown Seattle. The project alignment is indicated in Figure 1 below.ST completed the Preliminary Engineering (PE) phase of the East Link project in late 2011. Subsequently the final design contract for the easternmost seven miles of the project was awarded to the H-J-H Team, a joint venture comprised of HNTB, Jacobs Engineering and Hatch Mott MacDonald in February 2012. H-J-H’s final design scope includes approximately 7 miles of double-track LRT between the east end of the I-90 East Channel Bridge and the Overlake Transit Center Station. While the project scope is extensive and diverse, the focus of this paper is the DBT. The DBT is located immediately north of the East Main Station, and travels approximately one half mile through downtown Bellevue under 110th Avenue NE between Main Street and NE 6th Street; terminating at the Downtown Bellevue Transit Center (BTC) Station. The location and extent of the DBT is indicated in Figure 2."

Jan 1, 2016

By Wieda Azani, Alexander Tarigan, Willem de Beer

In block caving, the rates and sequencing of undercut production blasting, drawbell blasting, and mucking are the key levers for attempting to manage cave performance. Cave performance encompasses a range of factors, which include growth, shape and the effect of the cave on the abutments, excavations, geological structures and lithology. We compare production data in several panels in the Grasberg DMLZ and GBC block caves with the seismic response in work areas, around geological structures, and in geotechnical domains. These comparisons enable evidence-based conceptualising of the effect of production rates and mining layouts. By also considering the correlation of seismic release rates in different parts of the rock mass, the wider influence of a cave can be gauged through considering possible stress and / or deformation transfer. This concept is not novel, but it is rarely implemented in a routine fashion, principally because production data rarely are easily available. Previously, it has also been used to retrospectively compare seismic hazard between different mines. This paper discusses practical, day-to-day tools to manage seismic response to mining. Therefore, the paper presents a methodology for presenting seismic release and production rates on integrated plots at any time to facilitate quick identification of correlated spatial regions. This methodology explores the production data collection and geolocation at Grasberg, which will be described in some detail.

Apr 26, 2022

By Robert E. Mclvor

Classification system efficiency (CSE) is a simple metric that can be used to measure and increase ball milling circuit efficiency. It is defined as the percentage of the ball mill energy being used to grind target (oversize) particles. This paper describes CSE analysis conducted for a variety of operations with related improvements in circuit efficiency ranging from 3 to 30 percent. The achievable CSE for any given ball milling circuit is described, providing the means to determine the extent to which every plant can benefit from increasing grinding circuit CSE.

By H. Kimura

A new technology for ironmaking based on direct gaseous reduction of iron ore concentrate is under development. The process is based on the flash reduction of the concentrate particles in a gaseous reducing agent, such as hydrogen, natural gas, a reducing gas generated by partial combustion of coal, or a combination thereof. This technology is expected to drastically lower CO2 emission and reduce energy consumption by about 38% of the blast furnace requirements. The energy savings are possible largely due to the elimination of pelletization and cokemaking. Process design and simulation using hydrogen as the reductant for iron ore concentrate have been performed. A process flow sheet composed of a flash reactor, heat recovery system, water removal system for purifying recycled hydrogen, and all connecting streams was evaluated using the METSIM software. Ironmaking using two reactors was also designed and simulated, which could reduce the total required amount of hydrogen although it would increase the complexity of the flow sheet and operation.

Jan 1, 2010

By Richard Newcomb, Michael Rieber, William A. Vogely

INTRODUCTION The solid fossil and nuclear fuels, but especially uranium, are given prominent, indeed leading, roles by energy experts in most long range estimates of world energy futures. Optimistic forecasts are inspired partly by the disproportionately large solid fuels resource base compared to present rates of consumption or to oil and gas resources, and partly by the vision of inexpensive high technology applications. Such a view overlooks the fact that while resource- use disparities and new technologies give allure to the promise of the solid fuels, they do not guarantee cheap solutions to the basic problems of solid fuel uses: viz., their relatively difficult conditions for efficient ignition and control, including the management of environmentally acceptable residuals disposal. Contrary to the varied versions of this optimistic hypothesis, this paper shows that a great many persistent economic and technical problems interfere with such a simple inference. These act as constraints which qualify or dispute much of the national energy policy based on existing modeling of solid fuel requirements and optimistic engineering evaluations. The assumptions and techniques of such exercises are sometimes at fault. As often as not, however, the distortions created in open market fuel com- petition due to misdirected national energy policies themselves are to blame for misdirected efforts. A number of interesting implications result. Among them are the distinct possibility that the low technology applications will dominate, so that more direct coal and less synfuel or nuclear use will occur; that, accordingly, exhaustion rates for uranium will be low, that the most extensive growth of solid fuel through 2000 will be in conventional pulverized coal cumbustors, and that the traded share of the world coal bum will be much larger than predicted. These trends will place much more pressure on oil and gas prices than forecast by most experts. On the way to these findings the paper demonstrates that solid fuel resource adequacy in situ, balanced against the projections of demands as capacity requirements, mean little as conventionally measured by years to exhaustion or potential supply schedules. Indeed, all stock concepts of demand requirements or of fuel re- sources must be tied to the paths of the unit costs and the deliverable prices of all substitute fuels and systems over time. This requires a dynamic analysis of supply and demand, integrated with geological and engineering constraints, to provide insights into the multiple modes of market and product substitution. Market forces rather than technical promise will determine the allocation of the solid fuels. Moreover, the equilibrium paths of individual fuel prices and market shares are not easily simulated by general or network models, and decision makers will continue to rely on the partial, local comparison of alternatives in their choices of fuel systems at any time. 'The economics of the solid fuels differs from that of other energy sources in important ways relating to their form in use, conversion efficiency, (dis)economies and externalities. Petroleum and gas are in a more convenient form for

Jan 1, 1985

By K. J. Hartman

The term kaolin is derived from "kauling". a Chinese word meaning high ridge, which was the name of a hill in China where kaolin was first mined several hundred years ago.(1) Other common names used today for kaolin include "clay" and "China Clay". The former word technically has a broader meaning and could refer to various types of clays such as bentonite and ball clay as well as kaolin. China clay, as a descriptive term, apparently results from kaolin's origin as described above but could also be due to a significant historical use in ceramic applications. The terms "kaolin" and "clay" will be used interchangeably in this analysis because of the common practice of using these terms in the paper industry. Major reasons for kaolin's widespread industrial usages center on the mineral's (kaolinite) physical features of good color, low viscosity and inertness. Kaolin is described as a hydrous aluminum silicate with approximate composition Of 2H20.A1203.2Si02. As will be shown later, a new version of the product, calcined clay with modified hydration content, is gaining widespread usages. Components of any particular kaolin in addition to alumina and silica are viewed as impurities. The more valued deposits and, hence, higher priced kaolin products are those of highest purity.

Jan 1, 1986

By J. A. Organiscak

Enclosed cab filtration systems are typically used on mobile mining equipment to reduce miners? exposure to airborne dusts and diesel particulates generated during mining operations. Various filter configurationscan be used within the heating, ventilation and air conditioning (HVAC) systems of cabs to remove the airborne contaminants. The air cleaning performance of cab filtration systems is highly dependent on the efficiency of the air filters, the number of filters used and their placement within the HVAC system. This paper shows how to mathematically model cab filtration systems and illustrates a methodology for developing other cab filtration system design models. Node diagrams of several filtration system circuits are illustrated with their mathematical models at steady state airflow and concentration conditions. Laboratory and field data are presented to demonstrate the validity and utility of modeling enclosed cab air cleaning performance. The paper concludes that incorporating multiple filters throughout the HVAC system improves the air cleaning performance and robustness of the cab filtration system design