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By L. L. Godirilwe, and A. Shibayama, G. Danha, K. Haga, Y. Takasaki

Selective extraction through leaching of an amorphous slag obtained from a base metal smelter plant in Botswana is investigated in this paper, where the main objective is to optimise the experimental variables that would result in the maximum selective extraction of the three base metals (Ni, Cu and Co) from the slag waste. Mineralogical tests showed that the sample is composed mainly of fayalite (Fe2SiO4), with a total entrapped metal sulphides content of about 1.0 wt.% occurring as fine occlusions in the fayalite phase. In our experimental program, we compare the effectiveness of two common leaching techniques. In the first method, we use sulphuric acid to carry out atmospheric beaker leaching tests, and in the second method we use high pressure oxidative leaching. The effects of acid concentration, oxidant addition/oxygen partial pressure and pulp density on metal dissolution rate are examined. The optimal Ni, Cu, Co extractions of 80.5%, 81.9 and 98% respectively were obtained under high pressure oxidative leaching conditions (150 oC, 0.6 M H2SO4, 0.5 MPa O2), with substantially low dissolved Fe of 9.6%, the majority of which was removed as jarosite in the residue. Atmospheric beaker leaching yielded poor extractions of Ni below 40% when sulphuric acid combined with hydrogen peroxide (1.0 M and 0.6 M respectively, 65 oC) were used for leaching, while Fe, Cu and Co dissolutions were each about 80%. Therefore, using high pressure oxidative leaching provides a possibility to effectively extract Ni, Cu and Co while producing an environmentally benign residue, thus alleviating the current adverse environmental issues associated with the abandoned smelter slag. Keywords: Slag, amorphous, fayalite, atmospheric beaker leaching, high-pressure oxidative leaching, extraction

Jan 1, 2020

By D. Stone, M. Le Roux, Q. P. Campbell, M. Fofana

Float-and-sink analysis is widely used in the coal industry to obtain washability data, yielding important information about beneficiation potential and performance. This method is associated with health and environmental problems, and research into alternative densimetric methods is important. The RhoVol is a new technology developed by De Beers Group Technology South Africa (DebTech) for the image-based generation of densimetric data from ores. The analysis is done on a per-particle basis, within a size range of +3 mm –8 mm. In this paper we compare the established methods used for the float-and-sink analysis of coal with a new method using RhoVol. The aim of the study was to determine the validity of the information obtained from the RhoVol analyser by performing comparative densimetric analysis on three different coal samples. The results showed that the RhoVol method was more rapid, safe, and precise, but tended to consistently underestimate the density of the coal sample, probably due to varying coal porosity.

Oct 3, 2023

By I. Ince, S. Kahraman

Preparation of suitable core specimens for physico-mechanical testing s not always possible, particularly for soft and clay-bearing rocks. Although several indirect test methods have been proposed to predict the properties of rocks, specimen preparation from soft rocks for some indirect tests is still difficult. For such cases, the needle penetration test has been developed. In this paper we present a study on the predictability of the physico-mechanical properties of pyroclastic rocks from the needle penetration index (NPI). The NPI, uniaxial compressive strength (UCS), Brazilian tensile strength (BTS), density, and porosity tests were performed in the laboratory on specimens from ten different locations in Turkey. Correlations were established between the NPI values and the physico-mechanical properties. Strong correlations were observed between NPI and both UCS and BTS. General correlations were found between NPI and both density and porosity.

Sep 6, 2023

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached to remove base metals from a concentrate containing platinum group metals (PGMs). We investigated the atmospheric leaching process to develop a better understanding of the leaching behaviour of the base metals (Cu, Fe, and Ni) and the PGMs, in particular Ru, Ir, and Rh with respect to key process variables, acid concentration, and Cu concentration under oxidative and non-oxidative conditions. With oxidative leaching, a higher initial acid concentration resulted in higher Cu, Ni, and Fe extractions, as well as faster leaching reaction rates. A higher initial acid concentration also resulted in faster precipitation of Cu, Ru, and Ir under oxidizing conditions. Under non-oxidative conditions, Ni and Fe extraction was much slower, and the effect of initial acid concentration on Cu precipitation was less pronounced. The initial Cu concentration had a slightly smaller effect on the leaching behaviour of Fe and Ni, as well as precipitation of Ru, Ir and Rh. Moreover, a higher initial Cu concentration suppressed both Ni and Fe leaching and had a slight inhibiting effect on the precipitation behaviour of Cu, Ru, and Ir.

Nov 1, 2021

By R. Minnitt, C. Morgan, D. Fourie

The problems associated with outliers and their adverse effects on resource estimation in deep level South African gold mines are presented, and solutions suggested in available literature are reviewed. Traditional Witwatersrand type outlier capping uses the 99th percentile grade as the upper limit, a somewhat blunt approach. The occurrence of high and low grade areas in mining operations and the estimation of resources using geostatistical techniques require that the assumption of stationarity be upheld. Honouring the stationarity of data requires that mining areas be subdivided into appropriately sized and spaced domains. In order to overcome high-grade conditionally biased block estimates, the overly strong influence of extreme grades is mitigated by using naturally occurring grade sub-domains, by identifying outliers within the grade sub-domains, allocating relevant capping limits, and weighting them in a post-estimation process to. Rather than applying a capping value across a domain it applies a maximum cap based on the extreme value and its range of influence; the method also ensures that relevant capping occurs even in lower grade sub-domains. The proposed method for capping outliers recognises that metal contained in high grade chip samples should not be over-capped, and based on the grade of surrounding samples. The post-processing method of capping outliers does not interfere with the kriging equations. The method is simple, elegant, and can be easily applied. An advantage is that the output from the kriging process is not overwritten, allowing for comparison between original kriging results and post-processing results.

Sep 1, 2021

By S. Chai

Waste dumps are widely used to discharge stripped mine wastes in open pit mining methods. As mining progresses, the height of the waste dumps will increase gradually, which may induce sliding failure once the height exceeds a critical value. Therefore, estimation of the maximum dumping height is crucial to the life-cycle use of a waste dump. However, published information about the maximum height of mine waste dumps are extremely rare. In this study, the maximum dumping height is estimated based on the strength-reduction technique by numerical simulations. The influences of dump geometry and properties on the maximum height are investigated. The results show that the maximum dump height decreases as the dump slope inclination angle α or the unit weight of dump materials γ increases, but decreases when the shear parameters of dump materials (cohesion c and internal friction angle ϕ) increase. The maximum height starts to increase with the ground inclination β when shear failure occurs at the interface between the dump and the base. Furthermore the effects of the dump width B, Young’s modulus E, and Poisson’s ratio μ of dump materials on the maximum height are almost insignificant. Good agreement was found between numerical results available in the literature and those obtained in this study.

Oct 1, 2022

By A. E. Lewis, J. Du Plessis, J. Chivavava

Current metallurgical processes lack selective and efficient REE recovery from aqueous leach liquors. Antisolvent crystallisation is used to selectively recover pure inorganic salts from aqueous solutions without excessive chemical use in ambient conditions. Yttrium sulfate octahydrate (Y2(SO4)3.8H2O) was used as a representative rare earth salt to investigate the effect of antisolvent selection on the crystal morphology and size distribution of the final crystalline product produced through antisolvent crystallisation. The antisolvents of choice were short length alcohols that are water miscible i.e. methanol, ethanol, 2-propanol and t-butanol. All experimental parameters except the type of antisolvent were kept constant under isothermal conditions. The large reduction in solubility of the salt by the antisolvent creates high supersaturations. This leads to high product yields as observed in this study at > 91%. In general, a variety of morphologies were successfully formed in each individual alcohol including; rods, plates, prismatic cubes and starburst clusters. The powder X-ray diffraction (XRD) analysis indicated that Y2(SO4)3.8H2O was the only species present for all final products. There was a change observed from the starburst and rod structures for the shorter alcohols towards prismatic cubes for the longer alcohols due to different strengths in the solute-antisolvent interaction at the crystal growth faces. The crystal sizes increased with an increase in the alcohol chain length because of the lower supersaturation conditions due to a limit in the mass transfer induced by the bulkier alcohol structure. In conclusion, it has been shown that the particle morphology and size can be greatly affected by the selection of antisolvent even under high supersaturation conditions, contributing to understanding the effect of different antisolvents on the final particle characteristics. The engineering of favoured product characteristics can therefore be achieved by antisolvent crystallisation, presenting a viable alternative process for the recovery of REE. Keywords: Antisolvent crystallisation, rare earth elements, morphology, particle size

Jan 1, 2020

By G. L. Smith, B. Genc, V. Morar, U. Govender

This paper presents a novel holistic healthy human framework for C-suite executives and senior leaders in the minerals industry. The value-add of the framework centres around the integration of inner holistic health and interpersonal holistic health to support and enhance environment, social, and governance transformation, with a focus on the social enterprise. The framework unpacks key components of holistic health and their interlinkages to environment, social, governance, and stakeholder engagement. Insights were gleaned from interviews with 10 C-suite executives, each with over twenty years of experience in mining or business leadership. By applying the holistic healthy human framework, industry leaders can strengthen the social licence to operate and positively transform the industry's public image. Broader application to other sectors is underway.

Oct 2, 2025

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

By E. Matinde

Poor phase separation and fine dissemination of the desired components within congruous slag phases are key challenges limiting the recoverability of values from slags by conventional beneficiation methods. Slag microstructure conditioning is a pragmatic approach to increasing themvalue-in-use of discard slags, especially when integrated with the broader smelter infrastructure. Although not yet tested on oxide slag systems, this paper explores the potential application of magnetohydrodynamic principles to the crystallization behaviour of bulk slags. Integrating the slag microstructure conditioning infrastructure to the existing smelter infrastructure is key to unlocking the economic value of slags because it is most economic to condition the properties of molten slag directly after tapping. A new business model that integrates smelting units to transversalmeconomic activities, such as cement production and suppliers of construction aggregates, canmsignificantly increase the circularity of metallurgical slags.

Oct 9, 2024

By Y. R. Murthy, S. Angadi, A. K. Bhatnagar, S. K. Tripathy, L. O. Filippov

Dolomite is an essential raw material for the refractory industry, a flux in the iron and steel industry and also for the extraction of magnesium metal. Generally, particle size reduction, screening and classification are used for the preparation of the high-grade sized material for different applications, whereas low-grade fine fractions are not utilised. These fines or low-grade overburdens are dumped at the mine site for future utilisation, which creates environmental issues along with inadequate space management. In the present investigation, a detailed study was carried out to decrease the silica content of the low-grade dolomite fines from Gomardih , India, containing 28.6% CaO and 20.1% MgO along with 8.3% silica. Different process flow sheet options were evaluated with a combination of dry classifier, wet classifier, gravity concentrators as well as flotation. Different process variables were assessed along with mineralogical characterisation to optimise the process for efficient rejection of siliceous gangue minerals. Results indicated that dolomite, calcite and quartz are the major mineral phases present in the ore along with other minor minerals. It was concluded that two-stage flotation was an effective process for the reduction of silica up to below 1% after grinding to a particle size below 212 μm. A process flow sheet with a combination of gravitation air classifier and flotation can produce a concentrate with silica content below 4.5%. Keywords: Dolomite, flux, dry classification, flotation, characterisation, beneficiation

Jan 1, 2020

By Wei Sun, Ruolin Wang, Wenjuan Sun, Junhao Fu, Haisheng Han, Zhao Wei

Pb–benzohydroxamic acid (BHA) (lead complexes of benzohydroxamic acid) exhibits high selectivity but low collecting efficiency in scheelite flotation. This paper reports the manner in which BHA and sodium dodecyl sulfate (SDS) were employed as ligands to coordinate with the lead ions to obtain a colloidal lead-group multiple ligand complex, i.e., the Pb–BHA–SDS, for improving the collecting efficiency of Pb–BHA. The flotation mechanism of Pb–BHA–SDS with respect to scheelite was investigated from the viewpoint of interface science based on the pure mineral flotation, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The results showed that the BHA and SDS coordinated with Pb2+ to form novel leadgroup multiple ligand complexes, which are different from the traditional understanding associated with the mixed collectors. Pb–BHA–SDS was a better collector with stronger collecting ability and excellent selectivity in regard to a scheelite flotation than Pb–BHA. The addition of SDS to Pb–BHA enhanced the latter’s adsorption ability on the scheelite surface and improved the hydrophobicity of the collector’s nonpolar groups, rendering Pb–BHA–SDS as a more efficient collector at a low dosage. Keywords: Scheelite; Pb-BHA complexes; sodium dodecyl sulfate; multiple ligands; Pb–BHA–SDS

Jan 1, 2020

By R. Uwaoma, A. Goosen, R. Matjie, K. Mphahlele, J. Bunt

Coal properties that are associated with wear and damage of grinding equipment during pulverization prior to combustion were investigated. A South African Highveld feed coal and its beneficiated fractions were crushed to <1 >0.25 mm particles for the grindability tests. These particles were milled and screened into <75 μm and >75 μm fractions, which were analysed by different techniques to establish a correlation with the conventional Hardgrove Grindability Index (HGI). The <1.5 g.cm-3 float fraction, which contained 93 vol.% (mineral matter free) total -macerals,9% kaolinite, and had the lowest HGI (57) (hardest to grind) was pulverized for 15, 30, 60, and 120 minutes for particle size distribution analysis. This analysis indicated that the content of <75 μm particles increases with increased grinding time. The >1.9 g.cm-3 sink fraction, with the highest HGI (76), 44% kaolinite, and 20 vol.% total macerals, was ground easily to generate the highest proportion of <75 μm particles. Based on higher correlation coefficients (R2 = 0.77–0.91), the ash yield, mineral matter, petrographic composition, and fixed-carbon have significant effects on the HGI. Conversely, the inherent moisture and total sulphur (R2 = 0.48–0.62) have only minor effects on the HGI. Results from this investigation could be implemented in the preparation of a suitable pulverized fuel with little equipment wear, as well as utilizing mineralogical and petrographic compositions. Finally, the effect of microlithotypes and maceral types in South African feed coals on the HGI should be investigated in further pulverization and grindability studies.

Jul 5, 2023

The industrial relations handbook, by A. Pons. Juta (P.O. Box 14373, Kenwyn 7790). 1989. "&apos;"250 pp. Looseleaf binder. R180 + GST. Industrial laser materials processing. World Business Publications Ltd (4th Floor, Britannia House, 960 High Road, London N12 9RY, England). 1989. 180 pp. £310. Mining 1990. Longmans, Financial Times International Year Books, 1989. 592 pp. £90.00. Innovations in materials processing using aqueous, co/oid and surface chemistry, by F.M. Doyle, S. Raghavan, P. Somasundaran, and G.W. Waren (eds.). 300 pp. $125. Light metals 1989, by P.G. Camp bel (ed.). No. of pp. not available. $150. Process control and automation in extractive metalurgy, by R. Partelpoeg and D.C. Himmesoete. 225 $98. Process mineralogy VIl, by D.J. Carson and A.H. Vassiliou (eds.). 4oopp. $150. Super plasticity and super plastic forming, by C.H. Hamilton and N.E. Paton (eds.). 700 pp. $140. Supera/oys 1988, by S. Reichman, D. Duhl, G. Maurer, S. Antolovich, and C. Lund (eds.). 880pp. $99. Surface modification technologies, by T.S. Sudarshan and D.G. Bhat (eds.). 305 pp. $49. World survey of nonferous smelters, by J .C. Taylor and H.R. Traulsen (eds.). 365 pp. $90. Second Parsons International Turbine Conference. London, The Institute of Metals, 1989.270pp. £40. Mineral processing in the United Kingdom. London, Institution of Mining and Metalurgy, 1989. £25. Today&apos;s technology for the mining and metalurgical industries. London, Institution of Mining and Metalurgy, 1989. 623 pp. £60. 1989/1990 E&MJ international directory of mining. Chicago, Mining Information Services (P .0. Box 6500, Chicago, IL 60680, USA). 620 pp. US$95. Advances in project scheduling, edited by R. Stowinski and J. Weglarz. Amsterdam, Elsevier, 1989. 540 pp. Dfl. 270. Proceedings of the 3rd International Conference on Molten Slags and Fluxes. London, Institute of Metals, 1989. 335 pp. £38. Brochure on industrial screens. Obtainable from Philippe Lavernhe, Johnson Filtration Systems S.A., Z.I. Availes-en-Chatelerault, 86538 Naintre, France. 16 pp. Free. Numerical techniques, edited by P. Spiling. London, The Institute of Metals, 1989. 226 pp. £25. Phase diagrams of ternary iron aloys, Part 2, by V. Raghavan. New Delhi, Indian Institute of Metals, 1988. 360 pp. £95 (from the Institute of Metals, London). cas publications These publications are available from the Centre for Resource Studies, Queen&apos;s University, Kingston, Ontario K7L 3N6, Canada. Economic aspects of gold exploration: How much is too much, by B.W. Mackenzie and M. Dogget. 30 pp. $10.00. Mineral exploration and mine development potential in Ontario: Economic guidelines for government policy, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 180 pp. $25.00. Economic potential of base metal and gold mining in Newfoundland: Assessing the impact of regional developmentpolicy options, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 188 pp. $25.00. Publications of the AusIMM The folowing publications are available from The Australasian Institute of Mining and Metalurgy, P. O. Box 122, Parkvile, Vic 3052, Australia. Prepayment is required with al orders. The AusIMM 1989 Annual Conference 1989. $A 50. Mineral fuel alternatives and the greenhouse efect. July 1989. A$ 35. NQ gold &apos;89. Apr. 1989. $A 50. Second Large Open Pit Mining Conference. Apr. 1989. $A 50. Explo &apos;88. Nov. 1988. $A45. Mineral deposits of New Zealand, edited by Dr D. Kear. Monograph 13. 244 pp. $A 60. Field geologists&apos; manual, compiled by D.A. Berkman. 3rd edition. 1989. : 350pp. $A45. The rocks speak. Essays in geology-some personal responses of a wiling listener, by Haddon F. King. 300pp. $A45.

Jan 1, 1990

By I. Ngo, L. Q. Ma, J. S. Guo

Deformation of gob-side entries has always been a critical concern for ensuring stability in longwall coal mines. This paper addresses the significant deformation and support challenges that arise in thick and hard roof longwall faces (THRLF) due to dynamic pressure. The study aims to elucidate the characteristics and mechanisms of deformation during the retreat of the longwall face. The research findings indicated that the primary cause of deformation was the combination of advanced abutment stress resulting from longwall face mining and the movement of the lateral roof over the chain pillar. To mitigate this issue, we propose a deformation control method known as cutting off the lateral roof (COLR) over the chain pillar. Simulation results demonstrate a significant reduction in roof stress and deformation of the gob-side entry after implementing the lateral roof-cutting technique. These findings provide valuable guidance for effectively managing deformation in gob-side entries, particularly when dealing with thick and hard roof strata.

Aug 3, 2023

By R. Jacobs, R. E. L. Pobe

The Moab Khotsong Metallurgical Complex comprises a gold recovery circuit (Noligwa Gold Plant) and a uranium recovery circuit (South Uranium Plant). The metallurgical complex employs the reverse leach technology for the recovery of uranium; specifically, uranium extraction prior to gold using acid leaching processing. The inherent uranium species in the ore are uraninite, coffinite and brannerite. The slurry that has been subjected to the uranium leach is further subjected to solid-liquid separation to separate the uranium in a solution through counter-current decantation and the solids (solids carrying all the gold), which are repulped and returned to the gold plant for gold processing. The uranium leaching process is critical to the uranium playing a pivotal role as a value adding by-product to the gold operation. The benefit of adopting this reverse leach process, for improved gold recovery, is that it exposes gold particles occluded within the uranium matrices and avails them for cyanidation. However, the drive for operational efficiency in uranium extraction must be weighed against the incremental operating cost against the backdrop of depressed spot uranium market prices. Over the years, efforts were directed at maintaining the benefit of extracting uranium to enhance gold recovery and simultaneously, optimising the operating cost model for the uranium operation to remain relevant to the gold operation. The aim of this paper and the corresponding presentation is to give an account of the uranium processing optimisation journey embarked on over the years; namely, the operational tradeoffs made in the process of ensuring that uranium continues to add value to the gold operation. These challenges were faced while striking a fine balance between processing cost and operational efficiencies against the prevailing depressed uranium spot market prices. Mineralogical- and laboratory tests conducted form the support basis for the results and observations articulated in the paper. Keywords: By-products, gold extraction, reverse leach benefit, uranium extraction

Jan 1, 2020

By M. Kerr

Background- History The most significant change in mining since the late 1970?s has been the emergence of very large scale mining operations , which have been developed to ensure profitability with relatively low grade ores. These large tonnage operations have resulted in the development of larger unit sized machines in all operations of beneficiation, solid-liquid separation and dewatering. Often only a few flotation lines are installed and tonnages up to 25 ktpd and beyond are not uncommon. The increased throughputs have led to the development of circular, reactor type tank designs. The reactor cell system is the most up to date flotation cell design to utilise the principles of circular cell design. The Svedala DV mechanism was specially developed to suit the RCS machine giving good solids handling characteristics and excellent metallurgical performance. Development of UG2 ore type flotation equipment The equipment was developed and optimised by Svedala process from 1995. A higher energy specification was requested by industry. This amounted to 3kW/m3 for installed volume. Existing designs were at 1.5kW/m3. Hence various modifications were required to achieve the required power input. The first 50m3 machines were installed and developed at Impala Platinum?s UG2 circuit over a one year period. Once reliability and performance was achieved, over 300 large volume flotation cells were installed at Anglo Platinum and Lonmin operations as well. Pilot Plant Development The Impala Platinum High Energy pilot plant was commissioned in 2002 and had an installed power exceeding 5kW/m3. It was operated for over a year at the tailings dam booster station and was fundamental to the large scale scavenging plant design. All experience in overcoming mechanical and operational problems was applied in scale up design principles. A very robust mechanism was designed to accommodate the additional power input from installed motors, as well as the high SG (>1.5) of the feed source. The pilot plant flowsheet is shown in the figure below.

Jan 1, 2007

By R. C. A. Minnitt, A. Akpabio

This study presents a rigorous comparison between ordinary kriging and commonly used machine learning algorithms, those being, linear regression, support vector regression, decision trees, random forests (RF), and k-nearest neighbours for spatial interpolation of platinum grade estimates in a complex ore body within the Bushveld Igneous Complex. Using only X and Y coordinates as predictors, both ordinary kriging and machine learning models were evaluated at point and block supports under traditional and spatial block cross validation frameworks. While naive validation results suggested superior performance for k-nearest neighbour and random forest (R² = 0.92 and 0.86, respectively), these were revealed to be overly optimistic under spatial dependence. Spatial block cross validation results demonstrated substantial declines in model performance, with R² often falling below zero, particularly for decision trees and k-nearest neighbour, indicating strong overfitting and limited generalisability. Ordinary kriging exhibited more stable, albeit modest, performance under spatial validation, reflecting its strength in geostatistical interpolation when contextual geological variables are unavailable. The study underscores the critical importance of spatially aware validation in resource estimation and highlights that machine learning models constrained to spatial coordinates behave as interpolators rather than true learners of geological variability. Recommendations are provided for future work incorporating geological information to enhance predictive robustness.

Mar 30, 2026

COUNCIL The following served on Council during the year under review Office Bearers Dr J. P. Hugo (President), P. W. J. van Rensburg and Professor R. P. Plewman (Vice-Presidents), Professor D. D. Howat (Immediate Past-President), and D. G. Maxwell (Honorary Treasurer). Ordinary Members of Council H. P. Carlisle (until February), R. C. Espley-Jones, G. H. Grange, Dr D. I. Legge, W. W. Malan, J. B. Mudd, Dr R. E. Robinson, Dr M. D. G. Salamon, L. W. P. van den Bosch, D. A. Viljoen (co-opted May 1973), and P. A. von Wielligh. Branch Chairmen A. Bain (Witbank-Middelburg Branch), C. J. Isaac (O.F.S. Branch). Past Presidents Serving on Council R. J. Adamson, M. Barcza, H. Britten, J. K. E. Douglas, R. C. J. Goode, P. Lambooy, Professor J. de V. Lambrechts, Dr J. T. McIntyre, J. F. Reid, and V. C. Robinson. Ten Council meetings were held during the year, with an average attendance of 18, and the standing committees held 29 meetings. MEMBERSHIP Twelve Fellows, ten Members, twenty-one Graduates, eleven Associates, thirty-one Students, and forty-two Company Affiliates were elected during the year. One Member was reinstated. Eight Fellows, two Members, and two Associates were admitted to retired membership. Four Graduates were transferred to Members, one Associate to Member, three Students to Members, one Graduate to Associate, two Students to Graduates, and one Student to Associate. Your Council records with deep regret the death during the year of the following : D. R. Campbell, J. Daniel, M. J. Dennehy, and F. S. C. Rogers (Life Fellows) ; W. T. balling and T. Pryor (Life Members); C. Boocock, W. Drake R. J. Moore, M. P. Pearse, J. M Pike, W. A. Schwezoff, A. I. Suss man, and L. G. S. Wright (Fellows) ; A. F. Chalmers (Member) ; and W. R. Gerry and G. T. Rimmer(Associates). A comparative statement of membership as at 30th June, 1973, and the end of the previous year it shown in the following tabulation: 30th - 30th June, - June, 1972 - 1973 Honorary Life Fellows 5 - 4 Honorary Fellows 13 - 9 Life Fellows 181 - 177 Fellows 541 - 536 Members 479 - 487 Graduates 115 - 128 Associates 182 - 186 Students 162 - 183 Company Affiliates 24 - 64 1 702 - 1 774 JOURNAL The papers that were published in the Journal during the year are listed below: August, 1972 The effects of chromium oxide, iron oxide, and calcium oxide on the liquidus temperatures, viscosities, and electrical conductivities of slags in the system MgO-Al2O3-SiO2, by M. S. Rennie, D. D. Howat, and P. R. Jochens A study of the dust exposure of South African white gold miners, by R. J. Page-Shipp and Elizabeth Harris A forecast of the coal and uranium requirements for electric power generation in South Africa, by E. J. Maunders September, 1972 Mine management by objectives, by A. A. Hazell Some aspects of the deformation behaviour and temperature rise during instantaneous compression loading of high purity aluminium, by H. J. E. Hamel Computer control of flotation at the Ecstall concentrator, by M. P. Amsden, C. Chapman, and M. G. Reading Optimizing the public gains from the exploitation of mineral resources, by A. Azis and J. Zwartendyk October, 1972 Presidential Address: Nuclear energy: its interactions with mining and metallurgy, by J. P. Hugo Presidentsrede: Kernenergie: sy wissel-werkinge met mynbou en metallurgic, deur J. P. Hugo Raise-boring experiences in the gold mines of the Anglo American Corporation Group, by J. W. Wilson and P. C. Graham November, 1972 Materials for winding plant components, by G. T. van Rooyen An analytical solution to the batch-comminution equation, by R. P. King A new approach to the study of human factors in stope productivity, by A. C. Lawrence Fundamental studies of the flotation process: the work of the National Institute for Metallurgy, by N. P. Finkelstein and V. M. Lovell Growing use of deionised water in surface coating techniques, by W. F. Lorch December, 1972 The development and application of a computer system to aid in the planning of production in mines, by F. H. Deist, L. F. Duvel, J. D. Austin, and H. D. Small PERT, and how PERT techniques can be used in modern mine management, by E. J. Boome and A. C. Schmidt A critical comparison of specific cooling power and the wet kata thermometer in hot mining environments, by J. de V. Lambrechts January, 1973 Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-silicide produced in South Africa, by J. C. M. Wethmar, D. D. Howat, P. R. Jochens, and O. A. W. Strydom Platinoids in the Witwatersrand System, by C. A. Cousins The development of a continuous recording scintillation counter mounted on a cyclometer, by P. D. Teens and D. Visser February, 1973 Computer analysis, modelling, and optimisation of gold recovery plants of the Anglo American Group, by M. I. Brittan and E. J. J. van Vuuren The significance of the mineralogical and surface characteristics of gold grains in the recovery process, by C. E. Feather and G. M. Keen Statistical valuation of diamondiferous deposits, by H. S. Sichel March, 1973 The effect of the reactivity of lime on desulphurisation efficiency in the basic oxygen furnace, by A. A. Hejja, D. D. Howat, and P. R. Jochens A review of real-time particle size analysers, by A. L. Hinde In situ measurements of the surface heat transfer coefficient in underground airways, by K. R. Vest April, 1973 An investigation into the kinetics and mechanisms of the oxidation of iron (II) by oxygen in aqueous chloride solutions, by R. P. Colborn and M. J. Nicol Electric smelting at Rustenburg Platinum Mines Limited of nickel-copper concentrates containing platinum-group metals, by J. C. Mostert and P. N. Roberts Metallurgical considerations in the

Jan 10, 1973

By F. Dinter, S. A. C. Hockaday, Q. G. Reynolds

The thermal decomposition of carbonate minerals as pre-treatment before smelting reduces the energy requirement for smelting. It can also make the combustion of fossil fuels for heating unnecassary. Thermal decomposition may become important in reducing greenhouse gas emissions when producing ferromanganese alloys while simultaneously reducing electrical energy demand during smelting. A kinetic reaction rate model for the thermal decomposition of manganese ores is presented, based on published reaction rate kinetics for the decomposition of manganese oxides and calcium carbonate. The model was validated against thermogravimetric data for two carbonaceous manganese ore samples and one ferruginous manganese ore sample. The reaction rate model shows that carbonate minerals in the manganese ores are decomposed at temperatures above 900 °C while pyrolusite is decomposed at temperatures from 450 °C to 500 °C. Mn2O3 decomposes rapidly at 550 °C. Braunite decomposition at temperatures below 1000 °C was negligible. The presence of organic carbon in the samples led to further reduction of the samples during thermal treatment.

Aug 3, 2023