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By W. W. Weller

Low-temperature heat capacity measurements were conducted, and entropies at 298.15° K were evaluated for sodium monomolybdate (Na2Mo04), magnesium monomolybdate (MgMo04), and calcium monomolybdate (CaMo04). The 298.15° K entropy values were sodium monomolybdate, 38.1±0.3 cal/deg mole, magnesium monomolybdate, 28.4±0.2 cal/deg mole, and calcium monomolybdate, 29.3±0.2 cal/deg mole.

Jan 1, 1963

By C. Pritchard

John Marks said in his acceptance of the Hartman Award in 2008, "I guess that without the occasional complaint, your mine is probably over-ventilated" (Marks, 2008). Miners are seldom in this situation and spend much of the time trying to find enough air to keep an operation running. With examination, there are usually changes that can be made to increase the efficiency of ventilation systems. Mine ventilation air is a costly commodity, especially by the time it has been heated or cooled and moved to the bottom of the shaft and through the mine airways. Modifications that result in surplus mine ventilation air could bring financial and environmental benefits. Some issues mine operators have needed to address recently are increased airflow requirements to dilute diesel particulates in metal and nonmetal mines, to ventilate reserves that are deeper, hotter, and further away from fans and shafts, and to meet demands from increased production. This paper discusses successful methods to find additional usable air when there is no extra ventilation capacity. Most of the options presented in this paper are useful for metal/ nonmetal operations but some may be applicable to coal as well.

Jan 1, 2010

By A. L. Johnson

In this Bureau of Mines report, time-resolved infrared emission spectra and corresponding pressure and temperature histories are reported for large-scale propagations of CH4-air, CH4-air-N2, and CH4-air-CF3Br ignitions in a 12-ft-diam sphere. Absolute spectral radiances were obtained throughout combustion over the 1.6- to 4.8-gym range, and the radiance growth patterns for the H20 (2.5-µm) bands are presented as a function of methane stoichiometry and diluent concentration. Flame temperatures were determined from the C02-band emissions, which approximated unit emissivity shortly after ignition. Burning velocities are also given for some of the test-mixture compositions. Measured flame temperatures were in excellent to fair agreement with theoretical adiabatic values for the CH.-air and CH4-air-N2 mixtures; the best agreement was for the stoichiometric CH4-air mixture. The CH4-air-CF3Br mixtures with =2 pct CF3Br gave poor agreement with theory. The measured temperatures were significantly lower during the early stage of combustion; furthermore, the later stage of combustion was uninhibited and yielded unexpectedly high pressures. Supplemental data from a 2-ft-diam sphere at various initial pressures confirmed that the CF3Br inhibition effectiveness decreases with increased pressure. The possible effects of buoyancy, turbulence, and changing kinetics are discussed.

Jan 1, 1977

By David C. Oyler, Paul W. Jeran, William P. Diamond

The Bureau of Mines is cooperating with the U.S. Department of Energy in a directional degasification project at the Emerald mine near Waynesburg, Pa. This project is designed to combine the highly successful underground horizontal degasification technology with surface drilling methods. The objective of this program is to demonstrate that directional drilling can be used as a technique for degasifying coalbeds ahead of mining to reduce the hazards of methane-air explosions in coal mines. The directional hole at the Emerald mine is designed to start vertically and enter the Pittsburgh coalbed horizontally. A 3-inch-pilot hole entered the Pittsburgh coalbecl at a vertical depth of 999 feet, The hole will be reamed to 8-3/4 inches in diameter, and 5-1/2-inch casing will be cemented in place. Three individual 3-inch-diameter, 3,000-foot horizontal gas collection holes will be drilled into the coalbed in a “bird foot” pattern. A corehole and vertical dewatering hole have been completed at the anticipated coalbed intercept. The dewatering hole was drilled to130 feet below the Pittsburgh coalbed, a depth of 900 feet, and 880 feet of 7-inch-OD casing was cemented in place. Seven vertical holes for monitoring the extent and progress of degasification have been drilled within the horizontal drilling area.

Jan 1, 1979

By D. A. Paice, A. B. Shimp

Illegitimate loads on a mine dc power distribution system can be detected by measuring a superimposed ac current. To implement such a scheme, a 10-volt, 3-kHz voltage is applied at each dc power substation. By this means, the mine dc power distribution network, consisting of a feeder and trolley wires with a grounded rail return, is caused to serve also as a 3-kHz ac distribution network.

Jan 1, 1975

By Susan M. Moore

According to the Mine Safety and Health Administration (MSHA) injury database, 227 knee injuries were reported in underground coal mining in 2007 [ 1]. Low-seam coal mines are those with extremely low working heights (<42?). Gallagher et. al [2] found that the average cost per knee injury in low-seam coal operations was $13,121.29. Thus, it can be estimated that the financial burden of knee injuries was nearly three million dollars in 2007. Pressure applied to the knee while kneeling and crawling is likely a risk factor. Typically, mine workers utilize kneepads to better distribute the pressures at the knee; however, their ability to reduce the stresses at the knee is unknown. The objective of this study was to determine the pressure applied to the knee during static postures used in low-seam mining while not wearing kneepads and while wearing two kneepads commonly used in the industry (one articulated and one non-articulated).

Jan 1, 2009

In this U.S. Bureau of Mines report, proposed narrow-vein and longwall mining concepts using drill-split technology (described in part 1 of this series) and in situ liner concepts (described in part 2 of the series) are combined and applied conceptually to environmental problems. Proposed applications deal with (1) acid mine drainage (AMD), (2) solid waste disposal, (3) site remediation, and (4) pollution prevention through innovative industrial design. For control of AMD from abandoned hillside mine workings, it is proposed that source veins be re-mined, processed for residual values, then backfilled using an impermeable compound backfill mix. For solid waste disposal, "vertical landfills" are proposed, consisting of trash-backfilled underground rock quarries. Vertical landfill activities take place in in situ lined containments that geohydrologically isolate the mining-backfilling activities. Site remediation through the creation of in situ underliners, for the capture of toxic leachates, and pollution prevention through the underground storage of toxic, flammable, and explosive materials in in situ containments, are proposed.

Jan 1, 1995

By Fred N. Kissell

A parachute-type stopping intended for changing the course of mine ventilation air during mine emergencies has been designed and tested. Some production uses are also visualized for metal mines. Preliminary tests in the laboratory and underground indicate that the parachute stopping is a workable concept, but further developmental research is required.

Jan 1, 1975

By R. V. Ramani

"The importance of adequate mine ventilation for good health and safety conditions has been recognized since miners first ventured underground. All over the world, governmental actions on mine health and safety arc directly connected with mine atmospheric environments their assessment and control. These governmental actions have been, and continue to be, motivated by the repeated experience that potential threats from inadequate control can evolve, either suddenly or in the long-term, into unpleasant reality, with catastrophic health and safety consequences. These governmental actions arc also an indication of the remarkable professional progress being made in the field of mine ventilation.Surely, no developed country allows underground mines to operate without strong measures for the control of ventilation under legislation specific to the mining industry. In the United States, the federal government's responsibility for mine safety has evolved over the years through a series of legislative actions beginning in 1865 and continuing through 1910, 1941, 1947 and 1952.The passage of the Federal Metal and Nonmetallic Mine Safety Act of 1966 (the 1966 Metal Act), the Federal Coal Mine Health and Safety Act of 1969 (the 1969 Coal Act) and the Federal Mine Safety and Health Amendments Act of 1977 (the 1977 Mine Act) arc the most important milestones in this long legislative history. The 1977 Mine Act adopted many of the stronger features of the Occupational Health and Safety Act of 1970, perhaps the most significant piece of legislation on workers' occupational health and safety in US history.It is worthwhile to ask, ""How far has the United States come in mine ventilation since the enactment of the 1969 Coal Mine Health and Safety Act?"" This Act and its associated regulations defined in great specificity many standards for healthful and safe operation of a mine and. in some cases, what constitutes good ventilation practice."

Nov 1, 1995

By Suzann C. Ambrosio

The mineral industry in Burundi continued to be a minor contributor to the 1980 gross domestic product (GDP) estimated at $293 million in constant 1970 prices.2 Mineral export revenues, primarily from cassiterite, increased by a factor of 15 between 1979-80, reaching approximately $434,000 by yearend 1980. Gold, bastnasite, colombite-tantalite, and wolfremite continued to be exploited on a small scale, using manual and semimechanical methods. Despite a sharp decline in mining activities during 1979, attributed to a lack o? profitability and shortage of construction materials, the mining sector exhibited signs of recovery during 1980. The mineral exploration budget grew 32% over 1979 levels and was equivalent to approximately $42,000 in 1980. In addition, the Burundi Geographical Institute (IGE BU) was created in September 1980 and given responsibilities to collect cartographic, topographic, hydrogeologic, and other geomorphological data., SONIBUROM, the Burundian and Romanian Government joint mineral corporation, conducted mineral deposit inventories during 1979-80 and has been charged with exploiting some of these as yet unspecified resource areas. Another Burundian-Romanian effort, called Mabaya-Butahana, was initiated to search for gold deposits. Meanwhile on the Ruzizi plain, alluvial gold prospecting, with an estimated grade between 0.2 to 1.0 gram per ton, was carried out on a small scale.

Jan 1, 1982

Provide a low-cost, low-maintenance method for im¬proving mine water quality on abandoned mine land (AML) sites. Approach A model (figure 1) is presented for selecting, designing, and sizing one or several passive mine drainage treatment systems that can be used in remediation of AML. The three principal types of passive mine drainage technologies for the treatment of coal mine drainage are an aerobic system, a compost wetland, and an anoxic limestone drain. The multistep approach presented here provides a simplified method to characterize the type and magnitude of the water quality problem and then to select either a single treatment system or a combination of treatment systems to address the specific site situation. How It Works Step 1. Discharge Characterization. Characterization of the discharge consists of measuring the discharge flow rate and collecting water samples at the point of discharge for chemical analysis. Both the flow rate and chemistry of a discharge can vary seasonally and in response to storm events. It is important to account for this variability by determining flow rates and water chemistry under various conditions. Water should be analyzed for pH, dissolved iron (Fe), alkalinity, and hot acidity (using the H2O2 method).

Jan 1, 1994

By R. A. Friedel

Data on compositions of natural substances are important in the study of possible interrelationships. The similarity of the low molecular weight alkane isomers from crude oil and Fischer-Tropsch catalytic synthesis product has been reported (8).3 A similar composition for the alkane isomers from high-temperature coal carbonization has been found. The composition of the C4 to C 7 alkane isomers from these three sources can be calculated quantitatively with the equations previously developed to calculate alkane isomers in Fischer-Tropsch product. An KM sting reversal of the concentrations of the monomethyl isomers from C6(2 Me > 3 Me) to C7 (3 Me > 2 Me) occurs in all three products; fragmentary comparisons at higher carbon numbers indicate some dissimilarities. Naphthene isomers in the C6 to C7 range for crude oil and high-temperature coal carbonization also have similar compositions. Aliphatic hydrocarbons from low-temperature coal carbonization processes are considerably different, consisting mainly of normal alkanes.

Jan 1, 1968

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

3. Application of Proposed Revised Standards 57.11-50 to Mines Surveyed 3.1 Subparagraph (a) 1 "Each mine shall have at least two separate and properly maintained escapeways from each working place to the surface which are so positioned that physical or environmental damage to one will not lessen the effective¬ness of the other, and which meet the requirements of travelways and man hoisting standards These escape¬ways shall reach to within 1000 feet horizontally or 300 feet vertically of each working place " 3. 1. 1 Discussion This section will deal with the 1000 and 300 feet distance requirements, Section 3. 5 will deal with the "environmental damage" provisions. During the course of the mine surveys, it became obvious that one mine&apos;s 1000 foot distance was nowhere near equal to another&apos; s --not in the actual distance but in the time required to traverse that distance. This -Ls true for the 300-foot requirement as well. The most obvious example is that one could traverse down a 300-foot raise much faster than climbing up the same distance. The temptation is strong to recommend that the distance requirement be changed to travel times instead. However, this approach would unfortunately lead to a lot of subjective evaluations. Having a time requirement for an entire mine evacuation (Subparagraph 6) is one thing, time requirements and the requisite inspection proce¬dures for each working place are quite another.

Jan 1, 1976

By C. B. Manula, R. L. Sanford, R. A. Rivell

A generalized flow diagram is presented in Figure 1, which shows the relationship of major model functions. This chart does not necessarily represent the anatomy of the computer program, but is designed to illustrate the informational interchange between major model functions. The related flow-charts-and computer program are listed in Parts I and II, Appendix A, respectively. Mine Car Stations The mine car stations are the activity centers for the model. The locomotive logic structure is designed to provide these stations with adequate cars and to clear them of car buildup. The model is designed to simulate a three stage haulage situation which suggests the need to differentiate station levels by type numbers. These are: a) TYPE 1 stations - mine cars are loaded here; b) TYPE 2 stations - intermediate stop and storage for mine cars; c) TYPE 3 stations - all mine cars that are stored here leave mine; and d) TYPE 4 stations - mine portal. TYPES 1, 2, and 3 have all loaded cars assigned to an ascending TYPE as their next destination. In input, if single stage haulage is designated, TYPES 1 and 3 do not exist, and if two stage haulage is called for, TYPES 2 and 3 are absent. A motor is not permitted to exchange cars between stations of the same type. Station Status Update. One major model function is to continuously evaluate the status of each mine car station. The major evaluations

Jan 1, 1974

By V. A. Marple, K. L. Rubow, B. A. Olson

"A virtual impactor personal aerosol sampler (VIPAS) bas been developed for use in diesel-equipped mines to collect size-separated samples or diesel exhaust and mine dust particles in the respirable size range. This sampler consists or three stages: a 10-mm cyclone, a 0.8- µm cutpoint virtual impactor and two filter cassettes. The large non-respirable particles are removed in a 10-mm cyclone. The respirable particles from the cyclone pass through a 0.8- µm cutpoint virtual impactor with the particles larger than and smaller than 0.8 JI.ID (mine dust and diesel exhaust particles, respectively) collected on two 37-mm filter cassettes. The sampling How rate is 2 L/min so as to be compatible with the standard respirable dust sampler and personal sampling pumps. INTRODUCTIONThe mining industry has been increasing its use of diesel-powered equipment in underground mines, especially in coal mines. With this increased usage has come an increased concern regarding the health effects associated with inhaling diesel exhaust particles since they are in the respirable particulate size range. A Mine Safety and Health Administration (MSHA) advisory committee directed MSHA to develop a sampling protocol for diesel exhaust particles to assess worker exposure (MSHA, 1988). In addition, the National Institute for Occupational Safety and Health (NIOSH) has recommended that ""whole diesel exhaust be regarded as a potential occupational carcinogen as defined in the Cancer Policy of Occupational Safety and Health Administration"" (NIOSH, 1988).Past work, with cascade impactors in both the laboratory and in underground coal mine studies, has shown that the diesel exhaust particles are primarily in the less than 0.8 µm aerodynamic diameter size range whereas the coal dust particles are primarily greater than 0.8 µm (Marple et al., 1986; Cantrell, 1987; Rubow and Marple, 1988; Rubow et al., 1990a, b; Cantrell and Rubow, 1991). This work has been jointly performed by the University of Minnesota and Bureau of Mines researchers over the last 8 years. Typical particle size distributions for a diesel-equipped coal mine and an all electric coal mine are shown in Figure l. Note that the particles in the < 0.8-µ.m mode are the diesel exhaust particles (seen only in diesel-powered mines) and the particles in the > 0.8-µ.m mode are coal particles (seen in both the electric-powered and diesel-powered coal mines). Chemical mass balance analysis was also performed on these two size fractions to determine the degree of particle cross-contamination in the two modes. This analysis showed less than 10% cross-contamination, i.e., in coal mines Jess than 10% of the diesel exhaust particulate was collected in the coarse fraction and Jess than 10% of the mine dust was collected in the fine fraction (Cantrell, 1987; Rubow et al., 1990a)."

Dec 1, 1996

By S. P. Kinney, P. H. Royster, T. L. Joseph

An investigation of the production of iron in the blast furnace is obviously not an easy subject for research . Enough is known of the mechanical , thermal and chemical conditions existing inside the furnace to say certainly that they are complicated. Furnace operators have found that the process is sensitive to a number of known and to many unknown operating conditions . In order to form any conclusions of value , it seems necessary to collect a large amount of data taken with considerable care and accuracy. These facts make a blast furnace research difficult but not impossible . The most serious obstacle in attacking the problem comes from the fact that it is useless in the design and operation of the blast furnace to use the method of " trial and error , which has proved valuable in so many other industrial problems . The variables are so interrelated and are so dependent one on the other that the number of experimental combinations to be tried is enormous . There are certainly not less than twenty factors in furnace operation and design that are known to influence the results . This is apparent if it is remembered that a phrase like " size and shape of the furnace" includes height of the furnace , height , diameter and angle of the bosh , inwall batter , stockline diameter , and furnace volume ; and that a phrase like " chemical and physical properties of the fuels charged " includes size and shape of the lumps , density, porosity and strength of the coke , in addition to its chemical analysis . Let us suppose that we need choose for each of twenty factors one of two values , for example , suppose we must say only that the furnace shall be " tall " or " short , " that the bosh angle shall be " flat " OF "steep , that the ore shall be " coarse " or " fine , " or that the blast has to be "hot" or " cold , " the number of resulting combinations is more than one million . In putting twenty pennies on the table , either heads up or tails up, the number of permutations possible is the twentieth power of two , slightly more than one million. It is obvious , therefore , that some sort of mathematical relationship , a set of rules of thumb , laws , curves or the like , are needed . Whether the relationships , curves or formulas are derived from experiment , from theory, or from mere guess -work, makes no difference provided they agree with the known facts . If they do not agree with known facts , they are worthless no matter what their origin or how weighty the " authority" vouching for them. Few such relationships have appeared in blast- furnace literature , and it may be doubted whether such formulas can be discovered .

Sep 1, 1923

By J. M. Mutamansky

"Coal mine dust research throughout the world has been stimulated by the recognition of its importance in the development of coal miners' diseases, particularly coal workers' pneumoconiosis (CWP). A historical look at the problem and the present state of knowledge in this area of importance to the worldwide coal industry is presented. A summary of progress made in this area is provided and some research ideas for the future are discussed.1. INTRODUCTIONI thank Dr. Yong Won John, President of the Korean Institute of Mineral and Mining Engineers, for his invitation to address the International Symposium on Coal Mining and Safety. This presents me with an interesting opportunity to take a broad look at the research in coal mine dust and where we are going. From this broad perspective, we can all view the progress and problems that are apparent in the present state of knowledge of coal mine dust. One important element in the review of coal mine dust research and its role in miners' diseases is that of its history. The existence of diseases attributed to the mine atmosphere is often traced back to Pliny the younger in the first century A.D. His work on natural history mentioned observed human effects attributed to mine fumes and vapors. However, the subject of the effects of dust in the mine was not mentioned in published literature until 1556 when Agricola discussed the ailments of miners in his day (Seaton 1975).For many centuries, many medical ailments of the lungs were often categorized together and distinct diseases were often not recognized until more modern times. The ability to distinguish different lung diseases was limited until the discovery of X-rays in 1986. Nonetheless, Zenker in 1866 applied the term pneumonokoniosis to any disease where dust gathers in the lymphatic depots of the lungs. This term was changed to pneumoconiosis in 1932. While pneumoconiosis was defined in the 1800s, scant attention was paid to control of miners' diseases until recent decades. The first attempt to control disease through control of the mine atmosphere has been attributed to the South Africans who instituted a silica control in 1910 (Drinker and Hatch 1954)."

Jan 1, 1989

By Andrew Cecala

Miner?s exposure to dust remains a top concern among regulatory agencies, particularly at production facilities with high levels of silica. This respirable dust is present in almost all operations and is a direct cause of the deadly disease silicosis. Silica is one of the most abundant minerals on Earth and is a threat at all operations, especial-ly granite and sand and gravel facilities. The National Institute for Occupational Safety and Health continues to analyze silica?s threat. The institute?s research indicates that heavy-equipment operators have an increased risk to dust exposure, especially when drilling or breaking rock, even when working from an enclosed cab. However, there are methods to reduce an operator?s exposure further, according to recent NIOSH research, which is detailed in its report, Improving Air Quality in Enclosed Caps with Uni-Directional Filtration/ Pressurization System. NIOSH indicates that when surface mining equipment is new, the operator?s dust exposure is normally at accept-able levels. As the equipment ages and components such as gaskets and seals deteriorate, the level of protection can degrade to a point where it is no longer acceptable. However, the institute indicates that at least two critical factors necessary for an effective system.

Jan 1, 2009

By L. J. Prosser, G. Esterhuizen, A. T. Iannacchione

The potential for roof fails in underground mines remains a clear and present danger for mine workers An investigation of ground conditions in nearly 50 percent of the nation’s underground stone mines fold that the slate of roof stability is primarily determined in a limited and subjective manner. These large-opening mines with roof heights typically 7 m (23 ft) or more, make physical observation difficult. Although some mines use monitoring techniques to gain additional information an roof stability, this practice is usually short term and localized to address ground conditions in a particular section or part of the mine. A roof-fall hazard-assessment techniques was development based on engineering judgment acquired from extensive underground stone mine experience and on exanimation of the related literature. This technique utilizes observational processes to determine roof fall likelihood Case-study scenarios offer a realistic picture of model implementation. Providing the mine level decision-maker with an accurate assessment tool to ascertain the level of ground fall hazards is expected to reduce mint worker injuries and fatalities Moreover; the presences of danger can be overcome with a clear picture of quantified ground conditions.

By Nicholas Kyriazi, John P. Shubilla

The National Institute for Occupational Safety and Health, National Personal Protective Technology Laboratory, has undertaken a study to determine how well self-contained self-rescuers (SCSRs), deployed in accordance with Federal regulations (30 CFR 75.1714), hold up in the underground environment with regard to both physical damage and aging. This report presents findings regarding laboratory-tested SCSRs in the seventh phase of testing from May 1999 to August 2000. The SCSRs were tested on human subjects and on a breathing and metabolic simulator. The results indicate that most of the apparatus, if they pass their approved inspection criteria, perform satisfactorily. The deployed CSE SR-100s, however, exhibited significantly higher inhaled carbon dioxide (CO2) levels than new units, as they did in the previous two phases. Several Draeger OXY K-Pluses that rattled when shaken were found to have potassium superoxide (KO2) particles throughout the breathing circuit, including the mouthpiece. Draeger investigated the problem and developed a shake test to detect damaged units. The durations of new Ocenco M-20s were statistically significantly longer than those of deployed units, although only by 2 min.

Jan 3, 2002