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By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018

By B. Suresh

Iron ore in Bellary-Hospet region is friable in nature and generates a significant amount of micro-fines (-150 µm) during mechanized mining, handling and processing. Present beneficiation practice generally employs spiral classification followed by hydrocycloning to remove slimes (-15 µm). The iron ore fines, beneficiated at JSW Steel Ltd., Karnataka generates tailing having 48-52% iron content in the form of slimes, which accounts for 50 to 55% by weight with respect to classifier overflow. The loss of iron as slime is considerably high. In this context, laboratory studies were carried out with different combination of beneficiation techniques with an objective to develop an efficient flow sheet to achieve better product grade and recovery from classifier overflow. The results revealed that de-sliming process by hydrocycloning in combination with either magnetic separation or froth flotation leads to increased iron loss in tailing. Based on investigation it is observed that forward flotation is beneficial over the reverse flotation. The experimental approach of forward flotation on classifier overflow followed by magnetic separation on flotation tailing resulted in overall product grade of 62.9% Fetotal and 70.3% yield. The tailing contains 34.6% iron, which accounts for 29.7% by weight with respect to classifier overflow.

Sep 1, 2012

By Robert Snow, Shibo Zheng, Wenyi Song, Xiaoqing Ma, Patrick Zhang

Numerous phosphate mineral depressants have been reported in the literature for use during anionic flotation of dolomite from carbonate fluorapatite in slightly acid circuits. In one part of this research, laboratory flotation experiments were conducted to compare the effectiveness of phosphate depressants to process ground, deslimed high-MgO Florida phosphate pebbles. Ten potential phosphate depressants were evaluated during laboratory anionic flotation of dolomite from phosphate in a slightly acid circuit using a sulfonated oleic acid soap plus oil as the dolomite collector. Eight of the depressants have been used by various investigators with foreign and domestic carbonate-phosphate ores. Four of the depressants were found to be reasonably effective during the current flotation study, namely: sodium tripolyphosphate (STPP), sodium hexametaphosphate (SHMP), tetrasodium pyrophosphate (TSPP) and diphosphonic acid (DPA). Without depressants, the sulfonate collector required to produce cell underflow phosphate products containing <0.80% MgO and MgO/ P2O5 ratio <.033 was 1.13 kg/ton of flotation feed at a flotation pH range = 5.5-6.0. Using this collector level with 0.91 - 1.36 kg/ton of feed of STPP, SHMP or TSPP yielded phosphate products analyzing 0.73-0.92% MgO and MgO/ P2O5 ratios = .027-.034 at 90.0-96.8% P2O5 recovery. Similar grade phosphate products were obtained using DPA as the phosphate depressant at 84.1-87.5% P2O5 recovery. When no depressant was used, a similar grade phosphate product was obtained at only 65.9% P2O5 recovery. Another part of the research aimed at reducing MgO content in the final concentrate from Florida phosphate plants by conducting dolomite flotation on the final concentrate. Numerous phosphate depressants were tested for this purpose, including acidic, neutral and alkaline reagents. The most effective phosphate depressant was found to be phosphoric acid, giving both high grade and recovery.

Jan 1, 2014

By S. K. Chaurasiya

o meet the ever increasing demand of iron oxide feed stock for rapidly growing domestic steel industries and to effectively manage the depleting reserve of high grade lumpy iron ore, Pelletization of iron ore fines/slimes are expected to play a dominant role in the near future. Use of pellets will also enable the blast furnace operator to achieve higher levels of productivity with lowering of operating cost. The effective utilization of Iron Ore Slimes is important not only from the point of view of optimum utilization of Iron values in the mined ore but also for preventing environmental pollution. A significant amount of slime is being accumulated at the tailing dam of one of the iron ore mines and with the present scale of operation the tailing dam will be filled in another 10 years. Hence to increase the life of tailing dam and for better utilization of the iron values a study has been carried out for the suitability of pellet manufacturing with slimes and fines at our laboratory. The pelletization studies are aimed for optimization of various parameters for production of Blast furnace/ DR grade pellets from beneficiated slimes and Fines. This paper attempts to describe the production of blast furnace grade pellets from beneficiated slime and fines and its characterizations.

Sep 1, 2012

By Yury V. Kulikov, Rakan Rahbani, Arkady Y. Senchenko

"The relevancy of complex minerals treatment is constantly increasing taking into account mineral resources depletion. Different refractory ores and concentrates, oxidized and polymetallic ores, as well as metallurgical products (slags) can be assigned to such mineral type. The treatment of such products via conventional flowsheets requires considerable capital and operational costs and does not always provide high recovery level of valuable components into a saleable product. Therefore, considerable amount of ores and metallurgical products are not treated, or treated inefficiently. One of the most promising approaches that allows economic treatment of refractory products is their ultrafine grinding down to 5-20 µm with subsequent processing or hydrometallurgy. Horizontal bead mills - the IsaMillTM, developed by Xstrata Technology, received their wide application in mining industry. Standard testing is performed under laboratory conditions in an M4 IsaMillTM (volume - 4 liters) to define the parameters of fine grinding. This mill completely simulates the operation of full scale industrial mills up to 50 m3 in volume (up to 8000 kW motor). The paper describes fine grinding technology performed in bead mills, and the importance of testing according to a certified method for industrial equipment selection. The paper contains description of promising directions of fine grinding technology application for several projects in Russia and Kazakhstan."

Jan 1, 2014

"Wet low intensity magnetic separation has been used for the recovery of magnetite for decades. As high-grade reserves continue to decline, low grade magnetite ores are being targeted for iron production. Low grade magnetite mineralisation is typically fine grained and requires fine to ultrafine grinding (P80 40 - 30 µm) to liberate it from, predominantly, silica/silicate gangue matrices. Grinding to such particle sizes requires high power consumption and produces excessive fines which impact negatively on wet magnetic separation and tailings dewatering. In addition, the dearth of fresh water for mineral processing in arid areas impacts negatively on the economic viability of low grade magnetite projects. These challenges have motivated innovation in dry magnetic separation technologies for the beneficiation of magnetite that can be economically applied on a large-scale. Such technology has been developed in the Cyclomag Planar magnetic separator (PMS) invented by South Australia-based Christopher Kelsey of IMPTEC P/L. The significant gangue mineralisation associated with magnetite ores in South Australia is quartz. In this study, the performance of the Cyclomag PMS on the recovery of magnetite mineral from magnetite-quartz blends was investigated. Magnetite-quartz blend were subjected to the PMS at varying control parameters - magnet discs rotation speed, inlet airflow and feeder speed. The study showed a successful dry separation of magnetic mineral from non-magnetics using the Cyclomag PMS. The PMS has potential to effectively recover magnetite mineral."

Jan 1, 2018

By V. A. Zhilina, I. V. Shadrunova, O. E. Gorlova

"The aim of the study is to develop and scientifically justify a new adaptive approach to the separating processes of deep and complex processing technogenic mineral raw materials. Technogenic mineral resources as a waste of mining and processing industry are mostly complex objects that have specific features of material composition and technological properties and make it processing ineffective with traditional schemes of mineral raw materials enrichment. Mineral wastes are regarded in this study as a complex object with a large number of signs in conditions of uncertain environment and object. However, adaptation is regarded as the process management system’ adaptation to the specific the properties of the object and the environment that has several hierarchical levels corresponding to different stages in the management of complex object. An adaptive approach is considered as a methodological basis of multivariate schemes for opening the mineral resources and creating mechanisms that could transfer these potential technogenic resources to the actual that significantly expand the mineral resource base of the country's black, coloured, rare, noble metals and construction materials. In this case, potentially the solution to the most pressing social and environmental problems associated with the adverse effects of past economic activity simultaneously with the commercial objectives. This approach to the wastes mining and related processing manufacturers meets the core idea of sustainable development as the balance of interests of State, society, business, private enterprise and each person in the areas of rational use of resources, economic efficiency and environmental safety. On the example of metal-containing raw materials in the form of slags of ferrous and nonferrous metallurgy, ferrous metallurgy sludge, mature fine tailings, the application of adaptive approach illustrates to the development of technologies of its deep and complex processing as phased, thoughtful movement from a comprehensive study of technogenic raw materials to build optimal topologies of technological schemes for processing the mineral wastes. INTRODUCTION Involving the Russian economy in the system of global economic relations significantly changes the nature of the country's competitiveness in the development of the world market and urgently requires competent management of its own natural and mineral resources. The latter at the present time in real economic processes cease to be a passive material foundation and become the producing basis in the production processes in the status of so-called natural capital. Introduced in the field of economic theory at the end of the 20th century, this term means both the flow of natural services and real natural resources. Consequently, natural objects, which act as natural resources of a certain production, today must necessarily be evaluated in a strategic sense. Modern standards of sustainable development presuppose that the economy should equally be oriented to balance the interests of the state, society, business, individual enterprise and each person in the spheres of rational use of resources, preservation of healthy ecosystems, ensuring well-being, high quality of life and environmental safety of not only the current generation, but also respect for the rights of future generations, that is, intergenerational equality. Most types of minerals are classified as non-renewable resources, therefore resource-saving in the sphere of mineral and raw materials complexes is one of the most important factors-indicators characterizing the degree of approximation to the model of rational subsoil use, and, consequently, sustainable development (State Report, 2017)."

Jan 1, 2018

By Wei Zhang, Jinhong Zhang

"In froth flotation, the adsorption of collector on mineral surface is critical for a successful flotation process. In present work, an atomic force microscopy (AFM) has been applied to study the adsorption of potassium amyl xanthate (PAX) on copper sulfides, i.e., chalcopyrite, chalcocite and bornite. The in-situ collected AFM images show that PAX adsorbs on chalcopyrite mainly in the form of oily dixanthogen; while it strongly adsorbs on chalcocite and bornite in the form of insoluble metal xanthate, which binds strongly with the mineral surface. The information obtained from the AFM study shed lights on the collectivity and therefore the selection of specific collector for different copper sulfide minerals in industrial practice.INTRODUCTIONFroth flotation, which treats the highest throughput in mining industry and produces the maximum economic outcome of any surface chemistry process, has been widely applied for the concentration of copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineral-bubble attachment and thus a high flotation recovery. Therefore, the adsorption of collector on mineral surface is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2018

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Lj. D. Andric

Development of modern devices for mechanical and mechanochemical materials activation has been dated since the beginning of last century. Rapid development of high-energy mills that are different in type, size, design and performances, has been occurred during the last four decades. Because of complete understanding of mechanical processing, entire knowledge of theoretical principles of high-energy mills is necessary. These principles are main causales of process that are happened in materials during the mechanical activation. This paper is occupied by theoretical principles of operation of high-energy mills. Conventional high energy mills with balls, high-energy planetary mills and high-energy vibrational mills are particularly considered in the paper.

Jan 1, 2014

By H. J. Schulze

From a colloidal science point of view (Schulze 1984, Nguyen & Schulze, 2004) five micro-processes are responsible for successful particle-bubble formation: the approaching of the particle to the liquid-air interface, the thinning and rupture of the intervening liquid film, the expansion of the three phase contact perimeter, the generation of sufficient large capillary force to stabilise the aggregates and the transport process of particles into and within the froth layer. Flotation reagents influence mainly the thinning and rupture of the intervening liquid film between particles and air bubbles, the expansion of the three phase contact after the rupture of the liquid film and the stability of the aggregates against external destruction forces in the flow field. But it exist also a non-negligible influence on the approaching of particles to the bubble surface during the encounter process and on their passing over into the froth layer and the froth stability.

Jan 1, 2003

By A. V. Nguye, P. A. Harvey

Previous studies have reported that inorganic electrolytes can enhance floatability of coal. The research has shown that the enhancement, if any, is highly dependent on changes in solution pH, type of electrolyte, and electrolyte concentration. The reasons for this are still not clear. In this study the floatability of coal particles in mono and divalent salt solutions was investigated. The zeta potential and hydrophobicity of the coal was measured experimentally, and a modified Hallimond tube was used to determine the floatability of coal particles by single bubbles, where the collision efficiency was equal to unity. The experimental information was used in conjunction with the Hogg-Healy-Fuerstenau equation to quantify the electrical double layer interaction. It was found that for low electrolyte concentration (less than 0.1 M) solutions the flotation recovery of coal particles was less than that for distilled water, and decreased with increase in concentration. Conversely, at electrolyte concentrations above 0.1 M, flotation recovery increased with increasing concentration. Both of these results are consistent with previous observations, but are inconsistent with expectations when considering the possible influence of electrical double layer interaction. A possible mechanism, based on the existence of the pre-existing submicron-sized gas bubbles, known as bubstons (i.e. bubbles stabilized by ions), present in water in close proximity to the hydrophobic coal surfaces is discussed in line with the early observation of flotation improvements by microbubbles “nucleating” on hydrophobic surfaces. In particular, the dependence of the bubble-particle attachment efficiency on electrolyte concentrations supports hypothesis on the salt-dependent and ion-specific existence of bubstons. However, a theoretical explanation of the transition salt concentration (at about 0.1M) is deficient at present. The existence of these submicrobubbles in close proximity to hydrophobic surfaces is not trivial. They can (as can individual gas molecules or other solutes) mediate and extend the range and magnitude of the attraction between hydrophobic macroscopic surfaces. These bubbstons may explain the curious phenomena of the socalled long-ranged hydrophobic attraction measured with the Surface Force Apparatus and Atomic Force Microscopy, and the slippage at hydrophobic surfaces. Finally, the coalescence of bubbstons affects the rupture of liquid films at a very large thickness (over 100 nm), observed, but unexpected, by flotation chemists.

Jan 1, 2003

By Lawrence Bbosa, Aubrey Mainza, Indresan Govender

"Positron Emission Particle Tracking (PEPT) and the Discrete Element Method (DEM) are used to develop a probability based model for the power draw of a tumbling mill. Experiments are conducted using dry spherical glass bead charge in a laboratory scale tumbling mill, which is mounted with a torque transducer and tachometer to measure mill power. Particle tracking information from PEPT is used to reconstruct the motion of glass beads and infer the overall charge behavior, while DEM is employed to simulate particle motion and interaction, with collision mechanics calculated using the Hertz-Mindlin contact model. For both sets of data, the product of torque and average angular velocities in discrete cells are accumulated to obtain mill power. This method is found to be within statistical agreement with measured power for all tests. The information from both techniques is then used to develop a model for the power draw as a function of particle size, mill speed and volumetric filling. Predictions of the model match well with measured and calculated values. The model is found to predict mill power within close agreement with measurement and follows trends consistent with existing work on tumbling mill modelling."

Jan 1, 2014

By Jia Muxin

The adsorption behaviors of metal ions on a silicate mineral and the flotability of a metalized silicate mineral with sodium oleate as collector are closely related to the structure of the silicate mineral. The adsorption isothermals of the metal ions on different silicate minerals are studied, the parameters of the isothermal give the information how many surface oxygen anions a metal ions is attached to, from this information and the structure of the mineral the site where a metal ion is attached can be guessed (The adsorption isothermals and adsorption behaviors with pH are fitted with Temkin, Frenudlich and Kurbatov equations respectively). Metal ions as Cu2+, Ni2+, Zn2+ are attached to the oxygen anions of surface species –Si-O– on the quartz surface, most of them coordinate to only one surface oxygen, their adsorption ability on quartz is low, but this metal ions on quartz surface protrude out of the surface perfectly, so their ability to combine with oleate acid radical is excellent. Quartz can be activated well by such metal ions. The isothermal of Fe3+ on quartz indicates these cations coordinates with more than two surface oxygen anions. This means the Fe3+ nucleates on quartz surface in the form of Fe(OH)3 colloid particles. The isothermals of Cu2+, Ni2+, Zn2+ Fe3+ on spodumene shows such ions coordinate with more than two surface oxygen anions, it indicate these ions may attach to the position where Li+ is formerly exists, such metal ions stay in a cave on the mineral surface, their adsorption abilities on spodumene are quite well, but they are affect by the oxygen anions of the two Si tetrahedron chains, the can almost not activate this mineral. These cations may attach on the site where Al3+ exists on the muscovite surface, just like spodumene, muscovite can not be activated well by such cations. Pt2+ has a large ion radius, as Pauling’s rules depicts polyhedron can not attach to Si tetrahedron well, the adsorption ability of Pt2+ on quartz is low and quartz is activated badly by Pt2+. On the other Pt2+ can adsorb well on spodumene and muscovite well and activated them well because it is not affected so bad by the tetrahedron oxygen anions of the minerals for their its large radius. The isothermal of Ca2+ on quartz indicates a Ca2+ coordinates with less than one surface oxygen anion, this means Ca2+ attaches on quartz mainly by physical adsorption. The adsorption abilities on mineral surface and the interaction abilities with oleate acid radical of the transition metal ions with the same valence are guessed to be determined by their d electron number, the rules should be d1<d2<d3<d4>d5<d6<d7<d8<d9>d10. Hydrogen bond may play an important rule in the activation of the mineral by HF and the interaction of the HF activated silicate mineral with collectors. The general rule is high bond valence and small metal ion radius surface species –Me-O can be activated well by HF with sodium oleate as collector. For example – SiIV-OH is neutral while –SiIV-FH+ and –SiVI-FH+0.33 are positively charged, the positively charged surface species are more likely to connect oleate acid radical via hydrogen bonds.

Jan 1, 2003

By Qingming Feng, Dongbo An, Jinhong Zhang

The application of the geopolymerization of mine tailings as construction materials is hindered by the fact that conventional geopolymerization of mine tailings usually involves a large consumption of alkali, i.e., sodium hydroxide (NaOH), and a long curing time, because of the relatively low reactivity and the high Si/Al ratio of mine tailings when compared to other active resources such as fly ash and clay minerals. The present study is focused on efficiently activating mine tailings, reducing alkali consumption, decreasing curing time and improving compressive strength. We firstly investigate the temperature effect on the alkali activation of mine tailings during geopolymerization. Secondly, the impact of additives, i.e., calcium hydroxide and aluminium oxide, on the compressive strength of samples is studied. Thirdly, different forming pressures have been applied to remove excessive alkali and its impact on samples&apos; strength has been investigated. The results show that a 40 MPa unconfined compressive strength (UCS) can be achieved with the geopolymerization samples after mine tailings are activated by sodium hydroxide at 170°C for 1 hour with the addition of calcium hydroxide and alkali dissolved aluminium oxide, further compressed with a 10 MPa forming pressure and finally cured at 90°C for 3 days. The findings of the present work provide a novel method for the geopolymerization of mine tailings as construction materials.

Jan 1, 2014

By Juan Estrada, Mirtha Frómeta, Rubén Alcalá, Emilio Montejo, José Castellanos, Juan Berto, María Rivas

"The oxidized nickel ores from San Felipe deposit are composed mainly Smectites which gives to the pulps very unfavorable rheological .properties (cinematic viscosity and high shearing strength) for transportation processes (pumping), very low settling velocities and very low thickened pulps. These properties do not allow the preparation of high % solids, which affects the economic efficiency if a high pressure acid leach (HPAL) process is used. Pulps of close to 30% solids have very high BYS making pumping impossible. CIPIMM developed three technologies to solve these problems and to substantially increase the % solids in the pulps to be leached without a thickening step. These technologies are: • CIPIMM 2. At Preparation of pulps using additives. This method is based on the effect of some additives (inorganic salts) to improve the pulp’s properties. The use of this method allows increasing the % solids in the pulp up to 40% with good rheological properties • CIPIMM 2B. Preparation of pulps by thermal treatment of the ore previous to the preparation of the pulps. This method is based on the thermal destruction of the clays structure. Its use allows to obtain pulps with 50 - 60 % solids with excellent rheological characteristics. As a collateral effect, the Ni and Co grades increases by 10 - 15%. • CIPIMM 2C. Pulp preparation by chemical treatment. This method is based on the chemical transformation of clays, to obtain without thickening, pulps with 43- 45% solids and excellent rheological properties. The use of one of the three technologies depends on the chemical and mineralogical composition of the ores and the results of technical-economical evaluations to determine which one is the best alternative before running higher scale tests."

Jan 1, 2014

By Güven Önal, Gülay Bulut, Mustafa Özer, Yunus Emre Benkli, Olgaç Kangal, Mustafa Tarkan

There are various types of natural zeolite deposits in Turkey. Naturally occurring zeolites are excluded from many important commercial applications where uniformity and purity are essential. In this paper, the beneficiation of natural zeolite, taken from western part of Turkey, was investigated. According to X-Ray Diffraction (XRD) and mineralogical studies carried out on the representative ore sample, the natural zeolite was found to be in the forms of clinoptilolite and heulandite. Clinoptilolite forms as a devitrification product of volcanic glass in tuffs. Quartz, clay minerals, orthoclase, plagioclase, biotite, seruzite-muskovite and epidote were observed as impurities. Several types of mineral processing methods were performed in order to remove impurities from the natural zeolite sample to produce high purity zeolite. Gravity separation methods such as shaking table and superpanner were carried out for separating heavy minerals, while high intensity dry magnetic separation was used for discarding magnetic minerals.

Jan 1, 2003

By J. K. Afidenyo

Microbial pretreatment of a double refractory gold ore was investigated using a white rot fungus, Coriolus versicolor (ATTC 20869) to improve gold extraction. A series of preliminary tests were conducted to determine the amenability of the ore to fungus degradation. Pulp density, temperature, pH and retention times were the process variables considered. Both a single. Stage and two-step processes were studied to establish process conditions. During the single stage process, the ore was contacted with the fungus culture (biotic) for 3weeks at 30°C and pH 10.0. For the two-step process, the first step involves ore contact with the culture medium (abiotic) at 45°C and pH 10.0 followed by fungal contact (biotic) at 30°C. Results indicated that carbonaceous matter is not degraded but passivated by the fungus; as preg-robbing activities dropped significantly from 18.1% to below 1.0%. The single stage process resulted in higher gold recovery than the two-step process Gold ex-traction by cyanidation of the pretreated ore was 78.9% for the single stage compared with 15.0% for the untreated ore. In the two-step process, only 73.3% gold extraction was achieved. Application of the two step process conditions to a high grade flotation concentrate, resulted in 93.3% gold ex-traction as against untreated concentrate of 30.5%. The results show that the microbial pretreatment process degraded sulfide sulfur, passivated carbonaceous matter and enhanced gold extraction from double refractory gold ore and concentrate.

Jan 1, 2014

By A. V. Zimin

It is a well-known fact that usage of reverse cationic flotation in magnetite ores processing enables to improve the quality of magnetite concentrates. We designed an iron ore concentrate technology (with 70 -71 % of iron) including reverse cationic flotation in pneumo-mechanical flotators RIF (developed by RIVS Corporation, Russia) with good biodegradable etheramines as collectors for flotation of quartz. Practical application of high biodegradable flotation reagents decreases environmental impact risk of objects and enterprises of mining industrial complex. This work presents results of development of flotation technology for production of high quality ferruginous concentrates from magnetite ores of Russia and Ukraine deposits. Keywords: magnetite ores, reverse cationic flotation, ferruginous concentrates, pneumatic-mechanical flotation machines, environmental impact

Sep 1, 2012

By P. Fawell, C. Castillo, C. Ihle

"The need to reduce fresh water consumption has pushed many Chilean mining companies to utilize seawater obtained from distant locations. At the same time, increasing amounts of fine particles in copper tailings raise new operational challenges, in particular, the thickening and transport of tailings featuring significant fine fractions, which are predominantly clays. In the present paper, we study the role of salinity – using seawater and NaCl – on the flocculation efficiency of copper sulphide tailings to which kaolinite was added. To mimic the water recovery stage in thickeners, flocculation has been induced in jar tests and the corresponding aggregate size distribution has been estimated from chord length distribution data obtained using a focused beam reflectance measurement (FBRM) probe, at various mean turbulence intensities. Results show that for constant flocculant dosing, a measurable influence of the salt on the resulting aggregation exists. For each case, resulting optimal turbulence levels are also reported, a particularly interesting feature when comparing flocculation efficiency of the coarse and fine fraction. INTRODUCTION The concentration of copper minerals through comminution and flotation is intensive in the use of fresh water. The need to reduce the consumption of fresh water and the environmental standards associated with increasingly demanding mining operations have driven improvements in the techniques of recovering water from tailings. The challenges are even greater when required to treat minerals with high clay contents. In Chile, kaolinite is one of the most important clays to consider due to its abundance in the tailings from many operations. The most common and highest throughput unit operation in the mining industry for the recovery of water from tailings is gravity thickening, with sedimentation of fine particles assisted by flocculation. Flocculation is the process of forming aggregates by contacting the suspended particles with a flocculant. The flocculant is typically a water-soluble synthetic long-chain polymer, where copolymers of acrylamide and sodium acrylate are the most common types used in the Chilean mining industry. The aggregation mechanism includes the following key steps: (1) flocculant distribution through the suspended particles, (2) flocculant adsorption onto particle surfaces, and (3) collisions between particles leading to polymer bridging to form aggregates, but concurrently (4) breakage of aggregates becomes a factor under prolonged shear (Gregory, 1988)."

Jan 1, 2018