Search Documents

By D. Djokic

One of the most attractive features of electron beam curing as a process for manufacturing composite structures is the potential for attaining very low levels of residual stress as compared to thermal curing. This residual stress reduction is important both for the potential to reduce composite failure strains at low operating temperatures and the associated reduction in process-induced deformation. Previous work has demonstrated that it is possible in some cases to significantly reduce residual stress development during irradiation and also avoid development of additional residual stress during post cure. In this paper, simple L-shaped composite laminates were used to study the development of residual stress and deformation during thermal post-cure of specimens that were already partially cured using different radiation doses. Following post-cure, these specimens were also subjected to high-temperature loads to study creep behaviour under service conditions. Aerospace

Jan 1, 2006

By Yusuke Yamamoto, Mineo Asano

"The present study investigated the texture transition during secondary recrystallization in the AA5182 sheet. During the initial stage of annealing, the texture showed a weak Cube orientation as the primary recrystallization texture. During the secondary recrystallization with abnormal grain growth, the area ratio of the {hkl} <011> orientations increased by consuming the other orientations. The texture transition was calculated by the 2-D Monte Carlo simulation with the misorientation dependency. When the higher grain boundary mobility was set in the specific range of the high angle misorientation, the orientation preferential growth of the RW {100} <011> orientation was reproduced. However, other {hkl} <110> orientations could not be well reproduced by the misorientation dependency.INTRODUCTION Crystal orientation and texture are important factors for aluminum sheet products from the standpoint of mechanical property, formability and isotropy. The recrystallization texture results from the orientation preferential growth from the rolling deformation microstructure and the texture (Alvi, Cheong, Suni, Weiland, & Rollett, 2008). Texture development has been a topic of intense research for decades with advances in analysis methods, e.g., orientation mapping (OIM) and computer simulations (Fjeldberg & Marthinsen, 2010; Ivasishin, Shevchenko, Vasiliev, & Semiatin, 2006). The grain boundary characteristic is considered to be a key for the orientation preferential growth. In the case of the recrystallization from the deformed microstructure, not only the grain boundary characteristic, but also the dislocation density and the subgrain size affect the nucleation and the grain growth (Engler, Löchte, & Hirsch, 2007). On the other hand, in the case of secondary recrystallization, the dislocation density and the subgrain size can be ignored and the effect of the grain boundary characteristic can play a significant role in the grain growth. There is intense research about the texture development during secondary recrystallization in aluminum alloys and it was reported that coarse {hkl} <011> grains were formed during the secondary recrystallization (Suk, Shin, & Huh, 2006; Rios, & Gottstein, 2001). However, the mechanism of forming the {hkl} <011> grains has not been fully clarified. In the present study, the effect of the grain boundary characteristic on the orientation preferential growth was investigated by EBSD analysis and Monte-Carlo (MC) simulation."

Jan 1, 2018

By S. I. Saif

The Key Anacon deposit lies about 6 miles northeast of the Brunswick NO.6 mine of Brunswick Mining and Smelting Corporation. Geological mapping, especially in the well-exposed Nepisiguit River section, geophysical data, and information from extensive underground and some surface drilling show that the rocks at Key Anacon are similar in many aspects of stratigraphy and structure to those of the Brunswick Mine area. They include narrow beds of fine acid volcanic material interpreted to be metatuff and volcanogenic metasediments. The massive sulphide ore body at Key Anacon lies immediately above these acidic rocks, in association with other chloritic, sideritic or magnetic iron-rich metasediments. The iron formation, which is similar to that associated with other orebodies in the district, is overlain by massive andesitic material. Four phases of structural deformation have been recognized in the Key Anacon area; they are similar in intensity and style to those of the Brunswick No. 6 mine area. The orebody lies in a zone of complex isoclinal folding along the flank of a major F2 fold (Key Anacon Syncline) and in general appears to be stratiform. The ore occurs in probable F2 parasitic folds, and this suggests a complicated structural geometry superimposed on the original beds. The general similarity of the mineralization at Key Anacon, together with its occurrence with other iron-rich metasediments between a footwall of acid volcanic material and overlying andesitic rocks, is suggestive of stratigraphic time-equivalence with the Brunswick zone . If so, the metavolcanics at Key Anacon might have been derived either from a center within the main volcanic pile to the west or from a smaller local center active at the same time. Alternatively, the Key Anacon ore could have been formed during a much older volcanic cycle. The solution to this aspect of the problem is the subject of a continuing study.

Jan 1, 1978

By F. H. Samuel, P. Burke, F. Mucciardi, J. Gruzleski, S. A. Musmar

A new thermal analysis technique has been developed and tested. It utilizes the enhancement in heat transfer characteristics associated with a recent advancement in heat pipe technology. Heat is extracted from a liquid sample of a melt taken in-situ within a vessel or furnace. The rate of heat extraction is such as to cause the sample to solidify. The technique was tested in both laboratory scale and industrial scale (Grenville Castings, Perth, Ontario). A 356 Al Alloy, subjected to various melt treatments was used to perform the tests. Classical thermal analysis was also performed simultaneously using a preheated graphite cup and at the same melt conditions. The comparison showed the potential of the new technique over classical thermal analysis. The major advantages of the new method are that it conducts the analysis inside the melt (i.e. a physical sample is not removed from the melt), it consumes less time and the cooling rate can be precisely controlled during the solidification process. Moreover, the resolution of the results is better than that of conventional techniques. Aluminium

Jan 1, 2006

By J. Bouchard, M. Levesque, D. Georges-Filteau, P. Radziszewski, G. LeBlanc

"Grinding mills are infamous for their extremely low energy efficiency. This paper reports the results of an investigation that characterized energy outputs in industrial grinding mill circuits. It identifies and discusses the potential for recovering energy from grinding circuits. Agnico-Eagle Goldex Division, Mine Canadian Malartic, and New Gold New Afton Mine participated in the study by providing operating data for three semi-autogenous grinding mills and four ball mills. Results showed that on average, 79% of the supplied electrical energy was converted to heat absorbed by the slurry, 8% was lost through the drive system, and approximately 2% was transmitted to the ambient air. Only 9% of the input energy was actually used for grinding. The remaining 91%—wasted as heat—could potentially be recovered using suitable technologies or integrated energy management systems. This topic remains to be further investigated. ¦ KEYWORDS Comminution processes, Energy recovery potential, Grinding mills RÉSUMÉ Les broyeurs sont tristement célèbres pour leur rendement énergétique médiocre. Cet article présente les résultats d’une étude qui caractérise les rendements énergétiques des circuits industriels de broyage et examine les possibilités de récupération d’énergie dans les circuits de broyage. La mine Goldex d’Agnico Eagle, Mine Canadian Malartic et la mine New Afton de New Gold ont participé à l’étude en fournissant des données de fonctionnement pour trois broyeurs semi-autogènes et quatre broyeurs à boulets. Les résultats montrent qu’en moyenne 79 % de l’énergie électrique fournie sont convertis en chaleur absorbée par la pulpe, 8 % sont perdus dans le système d’entraînement et environ 2 % sont dispersés dans l’air ambiant. Seuls 9 % de l’énergie primaire sont, de fait, utilisés pour le broyage ; les 91 % restants (perdus sous forme de chaleur) peuvent potentiellement être récupérés à l’aide de technologies adaptées ou intégrées dans des systèmes de gestion de l’énergie. Cette question demeure toutefois ouverte. ¦ MOTS CLÉS broyeurs, potentiel de récupération de l’énergie, procédés de comminution INTRODUCTION Grinding is largely recognized as a very inefficient process; energy efficiency estimates range from < 1 to 2% (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002, 2004) when comparing the input energy to that required for generating new mineral surfaces. Criticizing an “ill definition of the reference for the output energy,” Fuerstenau and Abouzeid (2002) proposed a “more meaningful baseline” would be “the energy for producing new surface area by the ¬mens.” Based on this reference, they concluded that “the ball mill is reasonably efficient energetically,” exhibiting an efficiency of approximately 15% for quartz."

Jan 1, 2019

By Burrows. A.

Temperature profiles in the lead smelter sinter bed at Xstrata Zinc Mount Isa sinter plant have been measured using a wireless temperature probe. Corresponding sinter samples have been collected for characterization. The sinter peak bed temperatures were found to be in the range of 1000 - 1200 °C. Microstructures and softening temperatures of these sinters have been characterised. Strong correlations have been observed between peak bed temperature and peak hood temperature, and between mean sinter softening temperature and peak bed temperature. It was found that higher peak bed temperature results in higher sinter softening temperature. For the feed material used in the trials, to obtain sinters with mean softening temperatures above 1050 °C, peak bed temperatures above 1130 °C are required. There appears to be a direct correlation between granule size distribution in the feed and peak bed temperature attained. High peak bed temperatures are observed in sinters with narrow granule size distribution.

Jan 1, 2008

By D. B. Johnson

Acidic, metal-rich waters generated at working metal mines and abandoned mine sites are generally considered to be major pollutants of the environment. However, the metals they contain often have significant value of their own, or as sources of useful mineral products. We have developed novel bioreactor systems that facilitate the selective recovery of various transition metals (e.g. copper, zinc and iron) as defined minerals that can be recovered and recycled. The bioreactors use novel species of acidophilic bacteria. Ferrous iron is oxidised by Ferrovum myxofaciens, a specialist bacterium that forms large amounts of exopolymers and grows as filamentous streamers in flowing mine waters, and the ferric iron generated is precipitated as the mineral schwertmannite, a small proportion of which is used to remove any arsenic present in mine water. Copper and zinc are precipitated as sulphides using H2S generated by consortia of acidophilic and acid-tolerant sulphate-reducing bacteria in a continuous flow, on-line low pH bioreactor. Transition metal sulfides can be segregated by precipitating them, either on-line or off-line, at different pH values. The modular units that have been developed can be configured to treat mine waters of different chemistries. A hypothetical acidic (pH 2.5) mine water stream containing 500 mg/L iron, 100 mg/L of copper and zinc, 50 mg/L of aluminum and manganese, 2 mg/L of arsenate, and discharged at a rate of 10 L/s, is used as an example of the potential application of the mineral-generating bioreactors. The environmental benefits and economic implications of considering mine waters as resources rather than wastes are discussed.

Aug 1, 2013

By Marc C. Bétoumay

Workplace safety, health, climatic conditions and rising oil prices are aspects that are important to the mining industry. The need for cleaner energy for underground mine vehicles is requiring serious consideration. A number of alternate energy systems offer clean solutions to diesel emissions while maintaining the current liberty of vehicle movement. This watershed article provides a broad comparison of cleaner diesel and alternative energies for underground production vehicles. Most alternate energies and clean diesel have already been tested in underground production vehicles. There are no technology gaps that would prevent the development of commercial alternative energy power plants, but in the case of alternate energies, second and third generation versions will be required to fully test for safety and operation viability. Full regulatory development is also required and could be done in parallel to power plant testing. Vehicle operation and maintenance manpower would be the same for alternate energy application as for clean diesel. Capital cost for alternate energy power plants will remain higher until the medium term. Owing to significant ventilation savings possible with alternate technologies, operating costs would be reduced.

May 1, 2011

By P. Turcotte, E. Karampinos

"Construction of underground excavations in squeezing ground conditions faces several technical challenges that can result in delays in production and high costs due to rehabilitation. A review of the behaviour of drifts under squeezing ground conditions was undertaken at the LaRonde mine. In particular it focused on implemented strategies to control the observed large deformations. The mine experiences a large range of squeezing ground conditions, mostly driven by the presence of foliation and high stresses. This results in large deformations over one meter in radius. A comprehensive ground control strategy has been implemented with the aim to manage, rather than arresting drift closure. The evolution and effectiveness of the employed support strategy are discussed based on documented field observations. In complement to the field implementation numerical models are used to provide further insight on the observed squeezing conditions.INTRODUCTIONThe development of underground excavations under squeezing ground conditions is usually associated with excessive rehabilitation and significant failure of ground support due to large deformations. Cost research case studies have concentrated on squeezing ground conditions in tunnelling. An overview of the methods used for the identification and quantification of squeezing and the numerical methods for the simulation of these conditions in tunnelling has been provided by Barla (2002). Numerous support systems that can manage ground deformation are available for civil engineering tunnelling. Nevertheless, the use of these systems in mining would result in high support cost and production delays. Mining operations have higher development rates and shorter service life. This study focuses on the behaviour of underground excavations under squeezing ground conditions in hard rock mining.In a mining context, the magnitude of deformation is usually higher than in civil engineering tunnelling as there is a higher tolerance for operation purposes. Potvin and Hadjigeorgiou (2008) noted that in mining, squeezing is encountered when the total displacement of an excavation reaches at least tens of centimeters over the life expectancy of a supported drive and is associated with considerable damage to the ground support."

Jan 1, 2015

By Xiaolin Cheng, A. J. Sinclair

"Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeo chemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:<equation>where all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemico-mineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By Xiaolin Cheng, A. J. Sinclair

"Abstract - Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeochemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:SMineralparent rock ± e + SConstituentgained from solution ± e= SMineralaltered rock ± e + SConstituentlost from wall-rock ± ewhere all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemicomineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By E. L. Jones

THE concentration of tin in the tailing from Sullivan ore has been de-scribed by H. R. Banks, superintendent of the Sullivan concentrator, in a paper presented at the annual meeting of the B.C. Division of the Institute in October, 1941(1). The reduction of the concentrate EARLY EXPERIMENTAL WORK Experimental work on the smelting of Sullivan tin concentrate was done in Trail. Preliminary tests in the laboratory indicated that the concentrate could be successfully treated in an electric furnace. A small electro-thermic pilot plant was built and, at the same time, reduction tests were made in an oil-fired reverberatory furnace. Both types of treatment gave satisfactory results. It developed that no fluxes, other than those already in the ore and in the ash of the reducing agent (either coke or coal), were needed. By using an excess of iron, a complete recovery of the tin in the slag was obtained, but with 20 to 30 per cent iron in the tin. A counter-current treatment was thus indicated, viz., the primary slag was first treated with hard-head (iron-tin alloy) from the refining and final slag smelting, producing tin with 2 to 4 per cent Fe. This secondary slag was subsequently treated with scrap iron to produce tin-iron alloy, and a final slag low enough in tin to waste. By following this line of endeavour, a tentative flow-sheet was drawn up and a successful operation was established. Without resorting to electrolytic refining, a metal comparable in purity to standard tin was produced. Metallurgical results and operating costs were found to be very similar with an electric furnace or a fuel-fired furnace. &apos;However, electric furnace smelting was chosen because the furnace required was smaller, and because some doubt existed as to the cleaning of the final slag in the reverberatory furnace reduction.

Jan 1, 1944

By F. E. Lee

The following outline gives a brief account of some of the ways in which microscopy is applied to the problems arising from the various operations of the Tadanac reduction works, at Trail, B. C. The Sullivan ore is a very fine-grained mixture of galena, marmatite, pyrite and pyrrhotite. The separation of minerals associated so intimately is a difficult task and requires careful control. Various oils and reagents are used in the process as developed, and it is essential that the operators have a means of control which shall be rapid, and at the same time, approximately correct. This result is obtained by microscopic analysis in the following manner: The operator places a quantity of the material upon a slide, a drop of water is added, and it is covered with a cover glass. Upon examination with transmitted light, the zinc mineral particles appear reddish, the ordinary gangue colorless, the lead and iron sulphides opaque. This method has proved of great assistance both in the development and in the operation of the present method for concentrating Sullivan ore. The miscroscope has thus become as much a part of the metallurgical equipment as the balance and burette. The microscope used in the laboratory is a Fuess "petrographic" with a specially-made vertical "illuminator" by Bausch & Lomb, with the usual accessories.

Jan 1, 1924

By Kan Xing

This paper introduces common detrimental consequences to the environment from mining in the Beijing West Mining Area. For example, ongoing mining operations can cause the following environmental deterioration: rock burst, roof rises, roof falls and inrush (Pit dash for ward water). Post-closure, after minerals resources are exhausted, the following environmental issues may remain: landslides (collapse, and mud-rock flow), dropping or exhausted water tables, water pollution, desertification and soil erosion, water accumulation, Slay endanger, ground subsidence, and causal factors in seismic activity. This paper analyzes this wide range of environmental consequences of mining, and offers a theoretical foundation to underpin a corresponding management scheme.

Aug 1, 2013

By S. Sundararajan, J. Brousseau, P. Bocher, M. Galopin, N. Barka

This research is committed to the prediction of the hardness profile produced by induction heating, using a computer-modeling software. The paper presents the simulation of the induction hardening process to analyse the sensitivity of the induction parameters on the hardness profile of a low alloy steel specimen. The developed numerical model includes the coupling effect between electromagnetic and thermal fields, and takes into account the non linear behaviour of the material properties. The study applies an enlightened experimentation method to build the feasible domain of the process and to achieve predictive empirical modeling. The ultimate goal is to replace the trial and error method that is usually used for the development of new parts, by costless experiments with the numerical model. Further development of this approach will lead to the computation of the residual stresses and finally to the assessment of the mechanical properties of the part. The end result will be the ability to shorten the development time and to improve the quality of the hardened part.

Jan 1, 2006

By E. Pallumbo, N. Szwedska, R. Asselin

"This paper highlights the results of collaboration between geology, mining and mineral processing teams during the restart of the North American Lithium Project, located near La Corne, Quebec, Canada. This collaboration was central in ensuring a cross discipline harmonization of design parameters and key inputs, all of which allowed for the development of an optimized life of mine plan suited to the particular needs of the operation.INTRODUCTION In July 2016, North American Lithium Inc. (NAL) began the process of restarting operations at the former Quebec Lithium Mine, located in the municipality of La Corne, Quebec, Canada. The North American Lithium Project (the Project) as it is known today, is the latest chapter in the history of this property. In order to provide a robust foundation for the project, multidisciplinary collaboration was instituted between the geology, mining and metallurgy teams. Despite the intrinsic link between these departments, in many instances their work is completed separate from one another; in silos. This collaboration highlighted specific drivers in the mining value chain that could be exploited to ensure that a saleable product could be produced effectively. This paper explores some of the concepts and strategies that were developed during the feasibility study that supported the project restart (excerpts from the study technical report have been used throughout this paper). PROJECT HISTORY In 1942, prospectors identified the presence of numerous spodumene-bearing pegmatite dykes on the Property. This led to additional interest and exploration drilling campaigns. In 1955, Quebec Lithium Corp. (QLC), who had acquired the property, began construction of an underground mine with mill facilities located on the surface. Operations began the following year at a production rate of 1,100 tonnes per day. A historical cross-section view of the underground mine is shown in Figure 1. In 1959, QLC began the construction of an on-site lithium refinery to produce lithium hydroxide. The refinery was finally operational by 1963. Mining and processing operations continued until 1966 when activities were halted due to a labour dispute. The property was sold and a few years later attempts to resume production were unsuccessful. Property ownership changed several times again until being acquired by Cambior in 1987. In the early 1990’s the existing mine and mill facilities were sold and the mine site rehabilitated"

Jan 1, 2019

By K. G. Wheeland, K. G. Byberg

The occurrence of a secondary, dust-fuelled explosion following blasting of sulphide ores has been reported in mines in many countries, including canada, the USA, Australia and South Africa. However there has been little effort to document the events and develop effective control technology. Following a detailed investigation of an incident at the Geco Di vision of Noranda Minerals Inc. , the company held a conference of interested parties in October 1986 to review the state-of-the-art and to agree on action. '!his paper outlines the causes and effects of such explosions, the key conference points and conclusions, and subsequent information-exchange and teclmology-developrnent activities.

May 11, 1988

By M. Mirnezami, J. A. Finch

The McGill component of the consortium contributed detailed examination of the electrokinetic properties of the constituent minerals, primarily pentlandite and serpentine. Mineral specimens were derived from an ore sample; mineralogical examination showed the serpentine was predominantly clinochrysotile, a fibrous mineral responsible for much of the flotation separation problem. The study included design of a novel sedimentation potential measuring device to classify the surface charge of the ore and electrophoresis measurements on single and mixed minerals which progressively approached flotation conditions. The sedimentation potential measurements provided a general association between surface charge and the visual state of aggregation as a function of pH. The electrophoresis experiments started with single minerals in a background of indifferent electrolyte and progressed to mixed minerals in a background of supernatant derived from an ore sample. The single mineral tests supported the suspected electrostatic interaction, i.e., hetero-coagulation, at flotation pH 9-10. The mixed mineral tests demonstrated this interaction and also revealed hetero-coagulation with Mg(OH)2 precipitates, derived from the supernatant. This interpretation was confirmed by optical and electron beam imaging. A series of agents, CMC, polyphosphate, soda ash, EDTA, were examined to disperse the system. To accommodate the small mass of single mineral available a novel turbidity measurement using a UV/Vis spectrophotometer was introduced. Selected conditions were used in contact angle and small-scale flotation tests.

Jan 1, 2011

By Nigel Saunders, Zhanli Guo

"Quench sensitivity of heat-treatable aluminium alloys is closely related to the precipitation process taking place during quenching. Faster cooling results in less precipitation of coarse phases during cooling, leaving more solutes in the solution before ageing. An alloy in such state would be of greater hardening potential as larger amounts of hardening phases may precipitate out during ageing. Hence, to understand the quench sensitivity of an alloy, it is essential to understand its precipitation process. Precipitation is a diffusion-controlled process and the diffusion is made complicated by the so-called quenched-in vacancies. These vacancies form during solution treatment, become “excess” when temperature goes down, and annihilate during the following cooling and ageing treatments, making diffusion now a function of both temperature and time. This paper first investigates the formation and annihilation of quenched-in vacancies and their effect on diffusion. The diffusion affected by quenched-in vacancies is considered in the kinetic models to realise the calculation of TTT/CCT diagrams for aluminium alloys. The calculated CCT diagrams have been used to explain the observed quench sensitivity and age hardening behaviour of various commercial alloys. The transformation from GP zones to other hardening phases during ageing is also discussed.INTRODUCTION The heat treatment of aluminium alloys mainly consists of three stages: a solution treatment at an elevated temperature, quenching from this solution treatment temperature to room temperature, followed by an ageing treatment to allow the precipitation of strengthening phases(Davis, 1993).The following statements generally describes how quench sensitivity is observed in heat-treatable Al-alloys: faster cooling results in,(i) less precipitation of coarse phases formed at high temperature during cooling, (ii) more solutes kept in solution before ageing, and (iii) larger amounts of hardening phases being formed, i.e. a greater hardening potential. Thus, the quench sensitivity of an alloy is closely related to its precipitation kinetics."

Jan 1, 2018

By Bergh. L. C.

On line monitoring and diagnosis systems of process operating performance are becoming an important part of industrial programs, leading to improve process operation and therefore product quality over time. In processes, such as the contact section of a sulphuric acid plant, a large number of input variables, highly correlated, are presented. These characteristics usually pose more difficulties in modelling the process for monitoring and diagnosis purposes. Multivariate statistical projection methods, such as Main Component Analysis, have been proposed to effectively deal with these situations. The application of these ideas to a section of a 2350 MTD sulphuric acid plant, located at the Caletones Smelter, including dry tower, gas blowers, catalytic reactor and S03 absorber processes, is discussed here. A PCA model with eight main components is used for monitoring and diagnosis of more than seventy operating variables. Hottelling&apos;s T2 and Q residuals test were used for detecting measurement problems in relevant variables, and for identifying which set of variables were responsible for driving the process outside its normal operating region. Furthermore, considerable information for the correction of the tested operating problems was given by the use of these techniques.

Jan 1, 2007