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By K. Najim, D. Hodouin

"The raw ores which are processed in mineral processing plants exhibit very strong variations of their physical and chemical properties. As a consequence, the performances of the comminution and separation processes vary greatly from time to time. Model-based control strategies improve the performance of the plant; however, they require some form of adaptation to cope with the variations of the are properties.This paper deals with the use of adaptive techniques for the control of mineral processes. It begins with a survey on adaptive control algorithms including parameters estimation aspects. Then several examples dealing with crushing, rod, ball, autogenous and semi-autogenous grinding, flotation , drying and calcination processes are reviewed.IntroductionThe operation of the various processes of mineral processing plants (crushing, grinding, flotation, dewatering, etc.) is generally controlled using empirically tuned regulators of constant structure, such as PID controllers. To improve the operation performance, mineral processors try to implement specifically designed controllers, i.e. controllers based on plant dynamic models. Most of the time, these techniques improve the control of the mineral processing installations. However, modelling is a complex procedure because of the problems of measurement and data management, specific to this industry, and because of the variations of the model parameters. In this context model-based control strategies do not always bring the expected improvements or are sometimes discarded and replaced by more conventional techniques .The sources of variation of the dynamic behaviour of mineral processing systems can be classified into three categories: (I) the inherent changes of the raw ore properties (composition, grindability, mineralogical texture, etc.); (2) the process tuning modifications (grinding media loads, number of hydrocyclones, slurry level in flotation cells, agitation speeds, etc.); (3) the feedrate variation of the ore, water, chemical reagents, etc. All these factors change the fundamental properties of the process dynamics such as the grinding or flotation rates and the residence time in the equipment. The simplified linear models which are used to describe the process dynamics are not able to track the complex behaviour of the mineral processing systems when the amplitude of the sources of variation are too large. The mismatch between the model and the plant behaviour is then frequently a cause of model-based controller failures."

Jan 1, 1992

By Joe Shoemaker

Automated Spot Generation ? No Operators below the Highwall ? No Operator Wear and Tear ? Reduced Swing Time ? Single and Double Sided Loading ? Minimized Bench Width

Aug 1, 2013

By J. Coffin, R. Multani, C. Deredin

Glencore’s Strathcona Mill has recently evaluated a pyrrhotite depressant combination of diethylenetriamine (DETA) and sodium metabisulfite (SMBS) to improve its overall plant pyrrhotite- pentlandite (Po-Pn) selectivity, with the aim of producing a higher quality nickel concentrate. In a previous paper, key findings from a comprehensive lab-scale program (completed at the XPS Centre) were summarized where, of the depressants tested, DETA/SMBS combination was found to be the most effective in improving the Po-Pn selectivity. The present paper describes the metallurgical program recently completed at Strathcona Mill; DETA/SMBS evaluation on select plant “grab” samples as well as the major results of three DETA/SMBS plant trials conducted on several plant ore feeds (long-term testing). Interestingly, it was found that there was variable success in using DETA/SMBS depressants on the different plant ore feeds; DETA/SMBS (dosage: 25/50 g/t milled feed) on lower Cu feeds demonstrated a ~2% Ni recovery increase at the same Ni grade. On the other hand, higher Cu feeds demonstrated virtually no benefit from DETA/SMBS at the same plant dosage, suggesting that higher DETA/SMBS dosage (at specific locations) than that tested is required to overcome the increased Cu-DETA complexation for these particular feeds. Glencore Nickel – Sudbury Integrated Nickel Operations owns and operates Strathcona Mill which has been processing Ni-Cu ores from the Sudbury Basin since 1968. The valuable sulfides are pentlandite (Pn) – (Ni,Fe)9S8 and chalcopyrite (Cp) – CuFeS2, majority of the sulfide gangue is pyrrhotite (Po) – Fe(1-x)S [0 < x ≤ 0.125] which is present in two forms: hexagonal Po (Fe9S10) and monoclinic Po (Fe7S8) (Multani & Waters, 2017; Lawson et al., 2014). Currently Strathcona Mill processes ore mined from two primary sources from the Sudbury area and produces two concentrate streams: (1) nickel-copper concentrate that is sent to the Sudbury Smelter; and (2) copper concentrate that is shipped to the Fonderie Horne (Glencore Copper, Rouyn-Noranda).

Jan 1, 2019

By R. Haecker, S. Bajic, R. Thorpe, A. Palko, M. Kalstrom

"Historically, mineral processors have used inferential data like plant instrumentation, assays, and grind sizes to monitor the performance of their plants. The ability to monitor the minerals themselves on a daily basis has eluded all but the very largest and richest of operations. The advent of a new generation of compact, robust, and user-friendly SEM-based automated mineralogy systems looks set to accomplish this, aiming to bring daily mineral monitoring of plant performance within the reach of all mills from mid-size upwards. This paper describes the use of this machine at Greens Creek Mine, a 2.5 ktpd Ag-Au-Pb-Zn operation with a complex flotation flowsheet. During the trial, the machine provided turnaround from sample collection to reporting averaging 24-36 h for key daily samples. All equipment was located within the compact mill, and proved highly reliable despite the challenging environment. Turnaround time was fast enough for metallurgists to understand, and, where possible, respond to ore and process changes while they were still happening. The plethora of data generated was filtered to a simple report whereby mill management could quickly absorb key daily mineral-based performance indicators. This paper will describe how the data was used to understand the key drivers behind metallurgical efficiency at Greens Creek, and how metallurgists began using the information to enhance daily mill performance."

Jan 1, 2014

By L. W. Vigrass

Porous and permeable rocks deeply buried in sedimentary basins contain immense volumes of hot water with the potential to supply low-grade heat energy. A part of Canada with sizeable potential for low-grade geothermal energy is the northern Williston Basin of southern Saskatchewan. In this region, the University of Regina has conducted a geological study investigating the feasibility of producing large quantities of warm water suitable for space heating in the Regina - Moose Jaw area. The study has shown that the most favourable geothermal reservoirs are in the Basal Clastic Unit (Cambrian Ordovician), which, at an approximate depth of 2,000 metres has predicted temperatures of 71°C to 74°C. We anticipate sustainable flow rates from these reservoirs of 100 to 300 ms/hr. The water contains about 150,000ppm of total dissolved solids, mostly sodium chloride. It is anticipated that the sulphate content will be 3,000 to 6,000 ppm, that the dissolved oxygen and hydrogen sulphide content will be small, and that the waters will be neutral to slightly alkaline. It is anticipated that the piezometric level will be 46 m below the ground surface for reservoirs in the upper part of the Basal Clastic Unit and 141m below the ground surface for the lower reservoirs of the unit. Plans are to build a low-grade geothermal research, testing and demonstration facility at the University of Regina. To be a practical demonstration, the facility will have to handle very large volumes of water. Because of high salinity, the water will be re injected into a subsurface reservoir. We do not anticipate insurmountable problems because of salinities or as a result of corrosion provided that the waters are not aerated during handling

Jan 1, 1979

By L. J. Heaslip, J. M. Toguri, T. R. Meadowcroft, R. L. Addinall

"""Pilot Plant Operations"" is a final-year core course given to the Metallurgy and Materials Science students at the University of Toronto. This course involves a laboratory study of an industrial project at an industrial site. Details of this program are discussed and reviewed after eight years of experience. IntroductionEducators in the field of Metallurgy and Materials Science have long agreed that ""hands-on"" experience is an important component in the education of metallurgical engineers. This philosophy is reflected in the undergraduate curricula of most metallurgical schools. The major problems encountered with laboratory-associated courses are the requirements for equipment, space and funds for both purchase and maintenance of equipment. For example, consider an exercise in crushing and grinding treatment in a mineral processing laboratory. Such operations require the handling of tons of material and often equipment of large size. The problems of storage of ore, methods of handling and maintenance of equipment are a few of the concerns facing the department. Considering that metallurgical departments at universities are, in general, relatively small, the support to purchase and maintain largescale equipment becomes an annual budgetary concern. In reality, universities today are not geared to operate mini-pilot plant equipment, either in terms of space or personnel.For the above reasons, in 1972an undergraduate core course called ""Pilot Plant Operations"" was introduced to the fourth year curriculum in Metallurgy and Materials Science at the University of Toronto. This course consists of I to 2 full weeks (8 hrs per day) of pilot plant laboratory study at an industrial site on a project of mutual interest with the industrial organization whose facility is being used. The first 5 years of the program were carried out at the pilot plant facility at the Ontario Research Foundation; Stelco&apos;s Research Centre in Burlington, Ontario, was used for the last 3 years. The nature of the projects undertaken during the 8-year period is shown in Table 1."

Jan 1, 1980

By Kevan Ford, Getulio Junior, Rob Henderson, Wayne Philips, Chris Martin, Rob Thorpe

"Plant 2 at the Kinross Paracatu gold operation in Minas Gerais State, Brazil, was commissioned in late 2008. Designed to be the largest tonnage, lowest grade gold milling operation in the world, Plant 2’s throughput has steadily increased towards its design capacity of 5087 tons per hour.The plant employs a gold-specific flotation scheme to recover the majority of gold, which is present as discrete free gold particles. Additional gold is recovered by jigs in the grinding circuit, and the jig concentrates are reground, upgraded and subjected to intensive cyanide leaching. The flotation cleaner concentrate is reground and leached using a conventional CIL circuit.One year after start-up, with the plant stabilizing operationally, plant circuit surveys were completed by a joint team from Kinross Paracatu and Blue Coast Metallurgy Ltd. The surveys audited the flotation and concentrate treatment circuits to investigate the metallurgical performance.This paper describes the Plant 2 operation and how the surveys were designed and executed. Some of the quality control systems that were employed to provide meaningful data from such a low grade gold ore are described and findings and actions taken to improve metallurgy as a consequence of the surveys are discussed.INTRODUCTIONThe Paracatu mine is located two kilometres north of the city of Paracatu, in the north western portion of the state of Minas Gerais, Brazil, 230 km southeast of the national capital Brasília (shown in Figure 1). The present day Paracatu mining operation, fully owned by Kinross Gold, through its Brazilian subsidiary Rio Paracatu Mineração (RPM) is designed to be the largest tonnage, lowest grade free milling gold operation in the world.The deposit currently hosts some 1.2 billion tonnes of ore at a grade of ~0.41 g/t gold, hence contains a total gold reserve of over 20 million ounces. At a designed plant throughput rate of 61 Mt/year the mine life goes beyond 2030."

Jan 1, 2011

By Kosuke Hosoda, Shuji Owada, Hiroyuki Tokuichi, Hirobumi Ohta, Chiharu Tokoro, Moto-o Sato, Katsushi Okumura, Hiroto Ogawa, Hideaki Umezawa

The Japanese government enforced the "Small Domestic Appliances (SDAs) Recycling Law" in 2013. The law targets metals such as Ta, Nd, Dy, Co, and W to be recycled. Considerable amounts of these minor rare metals are mounted on printed circuit boards (PCBs) of the SDAs and/or e-scrap (electric and electronic scraps). Although precious metals and copper can be recovered from the e-scrap in non-ferrous metals smelters, most of the minor rare metals report to the slag in these smelters in non-recoverable forms. These metals are often used in particular types of devices, and therefore it is possible to concentrate them by separating such devices before feeding to the smelters. In previous work we developed technology for "Device Separation" to concentrate several minor rare metals, but some problems remained, such as how to remove the PCBs from e-scrap bodies, and how to detach devices from PCBs after their removal from escrap bodies. This paper proposes a two-stage crushing process in which, firstly, PCBs are removed from the e-scrap body with various crushers, and secondly, devices are detached from the PCBs involving the application of elevated temperatures. It was found that in the first stage, crushers with physically flexible rotating media such as chains, which provide high collision probability with the sample and consume relatively low energy, can quite effectively separate the PCBs from the e-scrap bodies non-destructively. In the second stage, heating was found to be remarkably effective in helping to detach mounted devices from PCBs, also non-destructively. This paper will also discuss the detailed mechanism of the heating effect on the detachment of devices from PCBs.

Jan 1, 2014

By Margarete Kalin

"Biotechnological approaches to decommissioning of mine waste management areas are presented in the context of sustainable environmental management. Improved design of waste sites and environmental management paves the way for the application of new technological approaches. Mining wastes are better confined, effluent quantity is reduced and the quality is expected to improve in the future. The biologically mediated treatments focus on the creation of conditions inside the waste management area which lead to the confinement of the contaminants in the inactive tailings ponds and seepage collection ponds, as well as pits or other disturbed areas which were part of the operating conditions.Biogeochemical reactions lead to three fundamental water treatment steps mediated biogeochemically , alterations in chemistry which lead to formation of particles, which then have to flocculate and be assisted to collect in the bottom of the ponds. Microbially active sediments are installed to assist particulate formation and serve as sinks for metals. In deeper sediment strata, stable forms of metals are created. Biological polishing is used to collect the particulates and relegate them to the sediment. Examples will be given of the application of these processes, to waste rock piles, open pits and tailings ponds. This paper attempts to show that, through the integration of applied biotechnological advances and the application of new approaches to decommissioning, reductions of environmental impacts by mining are possible. * Note: this paper has been presented at the 13th Annual Meeting of BIOMINETIntroductionThe role of biotechnology in decommissioning of mining waste management areas should be placed in the context of sustainable development. The concept of sustainable development as defined by the Brundtland Commission (1987) for the restoration/ reclamation of mining operations could be translated as follows: The increasing demand for the resources by the world population must be met in a manner which does not compromise the earth's environment over the long term (Brooks et al., 1995)."

Jan 1, 1998

By John A. Herbst, Xiangjun Qiu

"Prediction of wear on a microscale level in mineral processing equipment turns out to be a challenging undertaking. This is particularly true for cases in which the objective is to use such predictions for wear parts design. The key to obtaining such predictions has turned out to be the use of physics based models along with phenomenological constitutive equations. In this paper, two components of the HFS tool set, one for particles (DEM) and one for slurry (MPF), are used for modeling. These tools are applied to the simulation of wear of SAG/AG shell lifters/plates and wear in slurry pumps. In each case wear predictions are validated with plant measurements.INTRODUCTIONHigh Fidelity Simulation (HFS) has emerged as an important tool set for mineral processing plant equipment design and optimization (Herbst and Potapov, 2003; Herbst and Nordell, 2002; Herbst and Lichter, 2006). This tool set consists of Discrete Element Modeling (DEM) of particle motion, Multi-Phase Flow (MPF) for liquid motion, discrete grain breakage (DGB) for particle fragmentation and discrete grain liberation (DGL) for mineral liberation (Campbell, Potapov and Tsuji, 1997; Ferzinger and Peric, 1997; Potapov and Campbell, 1996; Herbst and Potapov, 2005).Three sample snapshots of basic HFS illustrating the use of each of the various types of mineral processing equipment are shown below.Figure 1 shows a snapshot of a DEM simulation of ball charge motion in a commercial scale Vertimill. DEM simulation involves simultaneous solution of Newton’s Laws of Motion for 400,000 balls."

Jan 1, 2007

By Paul R. Clark

Outline of Presentation ? Brief review of gasification and IGCC ? Polygenerationand its potential ? Why gasification today ? Major technology providers and their activities ? US initiatives ? Alberta Energy Resources and application of gasification ? CO2 management ? Advantages and barriers to gasification ? Conclusions

May 1, 2006

By Andrew Chapman

The scope of the SA (Situational Awareness) working group is to analyze the effectiveness of information delivery systems in mining equipment and develop a unified display design, to mitigate against the proliferation of screens within equipment cabs. This working group comprises a variety of stakeholders representing a cross-section of relevant mining and mining-related organizations. This stakeholder network will help guide the direction of the working group towards a common, mutually beneficial end. For now, the focus is on shovel displays; however it should be noted that this work is expected to form the foundation for similar work with other equipment in the future.

Aug 1, 2013

By Luis Castelli, Aldo Bonomelli, Giselle Schifferli, Claudio Zamora

"This paper introduces the operational concept and the description of a multi-site Remote Support Center for knowledge management and long-term process performance improvement.This centralized Support Center provides real-time monitoring of open-platform process automation systems, and on-line access to process data and control applications information for multiple sites.Considering that process automation is a key enabler to business performance improvement, sustaining effective performance benefits over time becomes essential. Unfortunately, changes in manufacturing process dynamics, technology obsolescence and in plant operational practices cause the control strategies to lose their effectiveness over time unless their performance is periodically evaluated, and if required, tuned to the new process conditions.A new concept in process automation is proposed through the addition of a new control loop based on performance analysis methodology which is intended to feedback process and automation operation information to system and process specialists, allowing for continuous manufacturing process improvement and sustainable production benefits through effectual control strategies.A remote support center can play a key role in the delivery of such services, by providing the base platform from which a comprehensive process overview and a centralized knowledge database can be executed and additionally, as an enabler for plant operational practices change.INTRODUCTIONA Benchmark on Automation Level in Copper Concentrators conducted by AMIRA in 2004, reported that the Codelco divisions scored below their peers in several categories.Codelco had thereafter been looking for a new automation concept, and had focused on process automation as a key enabler for process manufacturing and business performance improvement. The final decision was to create a strategic alliance with a world-class automation technology provider.The traditional approach based on isolated automation solutions/projects, showed that the control strategies benefits were decreasing progressively over time, because of the on-going need to adapt the control models to the ever-changing process conditions and different plant operational practices. Another consequence of this traditional approach was the wide variety of technologies and automation systems deployed in the different plant sites, with no common automation standards, and with low opportunities to transfer knowledge or practices."

Jan 1, 2010

In this paper, geostatistical techniques are applied to forecast the annual copper price in the short and medium terms (from one to five years ahead). These techniques allow the incorporation of monthly and multivariate information in the analysis and provide more accurate results than traditional approaches, especially as far as the one-year forecast is concerned. A second advantage of geostatistics stems from its ability to assess the uncertainty associated with the unknown future prices, thanks to estimation variances or confidence intervals, depending on the technique used. Such an assessment has a crucial importance in decision-making, from both macroeconomic and microeconomic points of view

Sep 1, 2004

By A. Cabañas

"In this paper, geostatistical techniques are applied to forecast the annual copper price in the short and medium terms (from one to five years ahead). These techniques allow the incorporation of monthly and multivariate information in the analysis and provide more accurate results than traditional approaches, especially as far as the one-year forecast is concerned.A second advantage of geostatistics stems from its ability to assess the uncertainty associated with the unknown future prices, thanks to estimation variances or confidence intervals, depending on the technique used. Such an assessment has a crucial importance in decision-making, from both macroeconomic and microeconomic points of view. IntroductionThe copper price traded in the London Metal Exchange is a relevant parameter for defining macroeconomic policies of producing countries like Chile. It is also a key factor for the mining companies, since fluctuations in the sell price affect the expected financial flows. Due to the amount of money involved in decision-making, it is necessary to have accurate forecasts of the future copper prices and to quantify the uncertainty associated with such prices.This paper focuses on the annual copper price estimation in the short and medium terms, i.e., from one to five years into the future. Henceforth, the word “estimation” will be used as a synonym of “forecast,” according to the geostatistical jargon (Matheron, 1989).Two main approaches, based either on statistics or econometrics, are currently used to forecast commodity prices, but both of them are not very accurate when applied to copper. First, the main methods are briefly reviewed, then the geostatistical formalism will be presented. So far, the latter approach hardly has been used to estimate commodity prices, although it may reconcile both statistics and econometrics via (1) the use of a stochastic approach and (2) the handling of ancillary variables related to the copper market. Another advantage of geostatistical techniques is the ability not only to forecast the copper price, but also to measure the uncertainty associated with it."

Jan 1, 2004

By K. Duckworth

"Comparative tests of the conventional Turam survey configuration and an alternative configuration called the Tx-parallel configuration were conducted at the McClean uranium deposit in northern Saskatchewan. Both configurations detected the known conductors at the site but the alternative configuration demonstrated its particular effectiveness in the reconnaissance role. This effectiveness results from the fact that the length of Tx-parallel traversesis controlled only by the length ofthe transmitter and not by its power. In addition, the field strength along a Tx-parallel traverse is uniform unless the traverse approaches the end of the transmitter. This freedom from a strong gradient of the primary field along a Tx-parallel traverse eliminates the gradient-induced anomaly shifts which are common in conventional Turam operations. The locations of each of the McClean conductors, that were obtained from the Tx-parallel profiles, werein better agreement with the locations known from drilling than were the locations obtained from the conventional profiles. However, the conventional profiles gave better estimates of the conductance of the targets.The results obtained over the McClean conductors indicate that current gathering has a strong influence on Tx-parallel results with consequent unpredictable influence on depth and conductance estimates. However, the depth estimates obtained from the Tx-parallel data appear to be in good agreement with the known depth of the McClean south conductor. The Txparallel results provide shallow estimates of the depth of the McClean north conductor which suggest that the fracture zone above the graphitic conductor is a significant conductor as was also suggested by earlier VLF surveys.Comparison with the wide range of published geophysical test surveys for the McClean site showed that apart from the work required to lay the transmitter, the Tx-parallel mode of operation of a Turam exploration system is operationally very similar to a moving source Slingram type of survey. At the McClean test site, it provided the same depth of exploration as a conventionally deployed fixed loop transmitter."

Jan 1, 1988

By C. Larsen, E. Goodwin, E. Konigsmann

"This paper describes the development of an innovative effluent treatment process for cyanide and heavy metal removal from tailings wastewaters at Hemlo Gold Mines Inc. Golden Giant operation.The importance of minimizing dissolution of contaminants in the gold leaching circuit is discussed, as well as using recycled water in milling circuits to the fullest extent possible. Finally, a brief description of the role of natural cyanide degradation in the tailings pond is provided.Emphasis is placed on the need for overall water quality management to ensure minimum effluent treatment process costs and complexity while producing excellent quality effluents.1.0 INTRODUCTIONHemlo Gold Mines Inc. owns and operates its Golden Giant Mine located forty kilometres east of Marathon, Ontario. The Golden Giant mine is one of three gold operations exploiting the large gold orebody located in the Hemlo area. The milling facilities include two stage secondary crushing, three stage, closed circuit ball mill grinding with no reagents, thickening, cyanide leaching and carbon in pulp gold recovery unit operations. The average throughput is 3000 tonnes per day of 10 grammes per tonne gold ore. Figure 1.1 shows a schematic flowsheet of the operation."

Jan 1, 1989

By F. E. du Plessis

"The distinction between data suitable for process control and data subject to aliasing only becomes quantifiable with the availability of rapid real-time measurements. Expecting the dynamics of flotation to vary for different ore types, process flows and equipment types; a study was conducted to compare the dynamics of different flotation processes. The results shed light on the critical sampling intervals required for process control which in turn allows process stabilization and optimization. The technology used for the in-line measurements is based on diffuse reflective spectroscopy and has been introduced into the mineral processing industry over the past ten years. It has been widely implemented in the sulphide flotation industry in South Africa for the real-time measurement of grade.BACKGROUND AND OBJECTIVE A study was conducted by Du Plessis and Keet (2010) to quantify the minimum sample frequency required for grade and/or impurity control. The study was based on chromite data collected at 15 second intervals from the concentrate line of a flash float cell in the Platinum industry. The data captured the natural process variation of the entrained chromite through water recovery due to changes in feed parameters and flotation performance. It was found that the minimum rate of sampling required from the studied flash float concentrate was 2 minutes. This sampling interval time accounted for 90% of the variance in the process data. It was further found that a sampling interval time of longer than 4 minutes produced data with no significant correlation to reality. The dynamics of the flotation process has been misjudged in the past but can be quantified with the availability of real-time grade measurement based on diffuse reflective spectroscopy. The objective of the study was to compare the dynamics of different sulphide flotation processes through the comparison of maximum sampling interval times required to combat aliasing. All data were collected from single stream analyzers that are currently installed at mineral concentrators. The technology used is based on diffuse reflective spectroscopy."

Jan 1, 2012

By Mario Gerards, Axel Wellendorf, Arulnesan Rajesh

"In times of increasing energy cost and global demand for improved machine technology, the optimization of industrial mineral processes in terms of efficiency and production cost is an important factor when choosing industrial equipment suppliers. Of course this applies for screening machines, feeders and distributers as well!Besides of the ability of a screening machine for being adjustable to changing requirements during the production process itself, it becomes more and more important to choose the correct screening machine type, peripheral equipment for arising screening tasks and to optimize the overall design of the screening machine starting at a very early stage.The different types of screening machines bring many advantages and disadvantages with them. The selection of the correct type of screening machine can improve the flow rate, energy, efficiency, yield, quality, output, availability and decrease the maintenance costs and structural steel work.The machine optimization has to be a consecutive process in which at any time results of simulation and “real-life measurement” are compared and the findings are implemented in machine development and design. As an example, it is possible to reduce machine weight and reinforce the steel structure of a screening machine at the same time, which enables the manufacturer to use smaller drives for the screen.This paper will present the methods ANSYS and 3D Solid Works used at RHEWUM GmbH for this way of optimizing machine design and construction and examples for results gained from this continuous improvement process."

Jan 1, 2016

By K. Yamaguchi, Sekimoto. H.

"Platinum Group Metals (PGMs) used as catalyst which reduces toxic substances in emission gas exhausted from an automobile should extensively be recycled because they are rare metals produced only at the limited regions. The recycling process is to smelt an alumina honeycomb, in which PGM is built, in molten iron with flux such as lime and silica to separate them. PGMs are concentrated in molten iron while alumina in slag.The objective of this study is to understand the factor to concentrate PGMs in liquid iron as much as possible. Fundamental research of the distribution of the PGMs between the slag and liquid iron was carried out to recover the value metals of platinum, palladium and rhodium from the three-way auto catalyst. The distribution ratios of platinum, palladium and rhodium between the Al2O3-CaO-SiO2 slag and liquid iron are from 10-6 to 10-5, and these are concentrated in comparison with slag phase by about 1 million times to the liquid iron at 1873 K. The distribution ratios of platinum between the FexO-CaO-SiO2 slag and liquid iron decrease from 0.1 to 2?10-4 with increasing the CaO content in the slag. The CaO addition to the FexO unary slag is effective in concentrating platinum in molten iron.Based on the distribution ratios obtained in this work, recovery of PGMs was determined. The recovery of platinum, palladium and rhodium increase with increasing the mass ratio, Mmetal/Mslag. In the case of the conditions of Mmetal/Mslag = 0.04, the recoveries of PGMs showed more than 99.97%. The use of liquid iron and carbon saturated liquid iron as the collector metal is advantageous for the PGM recycling of the three-way auto catalyst. We found that PGMs are enriched to the molten iron or the carbon saturated iron and the slag loss of PGMs is negligible small."

Jan 1, 2014