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By H. R. Manouchehri, A. Weh

"High voltage electric pulse comminution (SELFRAG) relies on inducing electrical breakdown that occurs when the resistivity of a dielectric is insufficient to completely block all transfer of electricity while the conductivity is not high enough to fully accommodate the flow of electricity without considerable changes to the crystal lattice. The technology is based on introducing the electrical discharges into solids immersed in water and placed between two electrodes. The technology has received significant attention since investigations have revealed the potential for fully fragmenting particles or pre-weakening rocks in order to reduce the energy consumption in comminution practices, improve liberation and potentially increase the recovery in mineral processing. Mineralogical analysis of samples showed possible liberation at coarser sizes by high voltage breakage in comparison with conventional mechanical comminution.This study explored the potential of implementing SELFRAG to treat the Sandvik’s Mittersill mine tungsten ore (scheelite) for recovery improvement. Accordingly, standard SELFRAG tests were conducted on four samples from the tungsten process plant to evaluate the energy-breakage relation and potential to liberate the value minerals at coarser size fraction for recovery improvement. The size reduction of the ore after processing with SELFRAG revealed that size deportment occurs at 0.4, 0.2, and 0.1 mm, which indicated potential liberation of gangue and target minerals at respective sizes. In comparison with conventional milling, the difference is the deportment of values into 0.4 mm sizes, which was, to some extent, confirmed by SEM liberation analysis. However, more tests are needed to proof the concept. The study has indicated that, despite consuming more energy in comparison with conventional mechanical comminution, there are promising prospects in liberating the values at coarser fraction and improve recovery by making use of SELFRAG. The energy consumption can be reduced through customized generator and equipment setup, which must be further investigated."

Jan 1, 2016

By S. Kaushik

The control room in a mineral processing plant has become increasingly complicated with complex unit operations coupled with rapidly evolving systems of sensors and control. Even with significant automation, human intervention is required to counter various scenarios that play out every day. A typical control room operator must monitor over 300 individual points of data in order to ensure the safe and efficient operation of the plant. At the same time, the experience of the workforce is decreasing as operators retire and the new generation enters the concentrators. Global competition for skilled operators continues to be strong and the opportunity to apprentice has diminished. The challenge is to provide a skill foundation for the operators so that they can be effective in the concentrator in a timely and safe manner. Progressively, the industry is turning to dynamic simulation tied into the control system. The simulator environment operates behind the control system to emulate the plant operation, reacting as the plant would when a change is made. The operator drives the process, with realistic feedback, which enables learning in a safe environment. This paper will take the reader through a green-field case study and discuss the effectiveness of integrating an operator training simulator (OTS) on the operator’s learning curve.

Jan 1, 2014

By R. S. James, D. C. Peck, P. T. Chubb

"The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered mafic intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendriticpegmatitic mafic pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and magmatic breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to 100/0 within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that affected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd:Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Several factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic interaction with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion.The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril'sk-Talnakh region, Siberia; Duluth Complex, U.S.A.) in terms of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economic concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginaltype POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993

"The main purpose of geometallurgy is to develop a model to predict the variability in the mineral processing performance within the ore body. Geometallurgical tests used for developing such a model need to be fast, practical and inexpensive and include as an input data relevant and measureable geological parameters like elemental grades, mineral grades and grain size. Important in each geometallurgical program is to define the number of samples needed to be sent for geometallurgical testing to enable reliable metallurgical forecast. This is, however, a complicated question that does not have a generic answer.To study the question on sampling a simulation environment was built including a synthetic ore body and sampling & assaying module. A synthetic Kiruna type iron oxide - apatite deposit was established based on case studies of Malmberget ore. The synthetic ore body includes alike variability in rock types, modal mineralogy, chemical composition, density and mineral textures as its real life counterpart. The synthetic ore body was virtually sampled with different sampling densities for a Davis tube testing, a geometallurgical test characterising response in magnetic separation. Based on the test results a forecast for the processing of the whole ore body was created. The forecasted parameters included concentrate tonnages, iron recovery and concentrate quality in terms of iron, phosphorous and silica contents.The study shows that the number of samples required for forecasting different geometallurgical parameters varies. Reliable estimates on iron recovery and concentrate mass pull can be made with about 5-10 representative samples by geometallurgical ore type. However, when the concentrate quality in terms of impurities needs to be forecasted, the sample number is more than 20 times higher. This is due to variation in mineral liberation and shows the importance of developing techniques to collect qualitative information on mineral and ore textures in geometallurgy."

Jan 1, 2016

By John Loop, W. A. Gibbins, Donald D. Hogarth

"Introduction Background The Frobisher voyages of 1577 and 1578 were organized by the Cathay Company for the express purpose of finding and mining gold ore. Since publication of the Baffm expedition of Charles Francis Hallill, the location of Kodlunarn or Countess of Warwick Island, the headquarters of Frobisher's third (1578) voyage, and focal point of the largest Arctic voyage of all time, has been known to the world. Through Hall we also know the location of the Countess of Warwick Mine on Kodlunarn Island. However, the exact locations of the other mines are not known. Of the ""ore"" we know little. Pieces of the original ""black stone"", once as large as ""a half-penny loaf' have now disappeared altogether. Specimens collected at random from the repository of shipments in England and from loose rock on Kodlunarn Island were termed, respectively, ""hornblende pyroxenite"" and ""amphibolite"" and from a locale about 200 yards from Kodlunarn as (hornblende) ""pyroxenite""121. However, it is uncertain whether these specimens are representative of Kodlunarn or of the other mines, although Blackadar131 notes that, in the northern trench of Kodlunarn, biotite gneiss contains lenses and bands of amphibolite. The ""gold"" itself is even less well defined. It has long been accepted that gold was virtually absent in Frobisher's ore. The ""gold"" has been termed pyrite, biotite and both biotite and pyrite together. Even t h e word "" marquesset"" , which appears and reappears in contemporary descriptions, is nebulous and is defined as ""a stone participating in the nature of some metal, yet in so small quantity, that the metal cannot be melted from it"" (0.E.D., definition of 1616)."

Jan 1, 1999

By Tetsuya Yumoto, Toshikazu Shiratori

Information on the elements contained in E-Waste is important from the viewpoint of recycling. We analyzed several components of waste electrical and electronic equipment (WEEE) collected from citizens. The distributions of the minor metals in WEEE were determined with elemental mapping and chemical analyses. The annual change in elemental composition was investigated by analyzing equipment manufactured in different years. The information will be of use for separation techniques required for future advanced recycling.

Jan 1, 2011

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations for the smelting and refining of non-ferrous metals, and it is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate. It is also the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y zinc. Since then, production capacity has increased, and at present, it stands at 240,000 t/y zinc. In this paper, the leaching process and particularly the operation of the jarosite circuit is reviewed, specifying process improvements to treat high iron calcines.INTRODUCTIONTwenty years ago the Electrolytic Zinc Plant in Peñoles was treating high quality zinc concentrates with low concentrations of iron (~7.5 wt.%) and silica (1.8 wt.%). Nowadays the quality of zinc concentrates is poor with a typical iron content of around 11 wt.% and silica at 2.0 wt.%. This has created numerous processing problems in our roast-leach-purification- electrolysis sections. In order to meet customer requirements it is necessary to find processing solutions to assure the operational continuity of the plant. These processing solutions are the focal point of this paper.REVIEW OF THE LEACHING PROCESSThe purpose of the leaching process is to recover the metals, mainly zinc, through a series of extraction stages with sulphuric acid solutions, which progressively increases the zinc dissolution. After the series of acidification stages, the solution, which is rich in iron, is sent to the jarosite circuit to separate zinc from iron (Garcia & Valdez, 1996). The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper. Then this solution is sent to the tank house to feed the electrolytic cells."

Jan 1, 2016

By P. R. Warner

This paper reviews the development of certain aspects of the electrical specifications of Anglo American?s suite of specifications for gearless mill drives (?GMDs?). These specifications are based on experiences in both Anglo American?s and others? operations, benchmarking against large hydro generators, the advice of industry and university experts, and continuous close co-operation with OEMs. To achieve a step change in availability additional final testing and electrical protection have been implemented, insulation requirements have been specified for machines to be operated at high altitude and clean area and access control systems have been developed.

Nov 1, 2011

By P. R. Warner

This paper reviews the development of certain aspects of the electrical specifications of Anglo American’s suite of specifications for gearless mill drives (“GMDs”). These specifications are based on experiences in both Anglo American’s and others’ operations, benchmarking against large hydro generators, the advice of industry and university experts, and continuous close co-operation with OEMs. To achieve a step change in availability additional final testing and electrical protection have been implemented, insulation requirements have been specified for machines to be operated at high altitude and clean area and access control systems have been developed.

Jan 1, 2012

By David Morrison

Our present longwall problems in Cape Breton can be grouped under five main classifications. These are: (1) Roof control on the face and on the main roadways leading thereto. (2) Transportation of coal along face and levels. (3) Mechanical loading at the face. (4) Safe method of conducting and applying power at the working faces. (5) Dust nuisance. The usual layout for longwall operation in Cape Breton is to have three, and sometimes four, faces in line with each other, the length of face being from 400 feet to 500 feet (see Figure 1), and producing between 425 and 500 tons per face. Each wall is serviced by a well constructed roadway for transportation of coal, men, and materials, and is operated as an independent unit. Each wall works under a regular cycle of operations: first, cutting and boring; second, drawing hardwood chocks, building midwalls, and shifting panlines; and third, loading. The present method of roof control and operation of longwall faces has developed through trial and error since the commencement of longwall miring in Cape Breton. The basic method of roof control in all longwalls in Cape Breton is: rigid support of the roof in the immediate vicinity of the working faces by hardwood blocks, as shown in Figure 2, accompanied by a cushion support furnished by continuous midwalls, 12 feet wide, constructed of stone obtained from the waste and spaced at 50-foot centres. These midwalls are kept forward to within 4 feet to 10 feet of the working face and allow a gradual subsidence of overhead strata, thus preventing any sudden break at the working face.

Jan 1, 1947

By R. Thierbach, W. Kahnt, Oberthür. T., D. Eisenburger, V. Gundelach

ABSTRACT: The ground penetrating radar (GPR) method was used in a platinum mine in Zimbabwe by members of the Federal Institute for Geosciences and Mineral Resources (BGR). The measurements were carried out in boreholes and drifts. Electromagnetic re?ections from a fault that consistently trends parallel to the mineralization zone permitted the mapping of the economically minable parts of the deposit. An introduction is given to the geology of the studied area and the application of the GPR method. The electrical parametres of the rocks are measured in situ, the GPR measurements are displayed with radargrams, and the visible structures are explained in illustrations.

Jan 1, 2010

By G. J. Desroches, E. Ozberk, M. J. Collins, B. D. Krysa, I. M. Masters

The zinc refinery of Hudson Bay Mining and Smelting Co., Ltd. went through a major modernization in 1993, when the roaster and the calcine and fume leach circuits were replaced by a new Sherritt zinc pressure leach plant. The HBMS plant, in Flin Ron, Manitoba, represents the first commercial application of the Sherritt two-stage zinc pressure leach process, with /00% of the zinc concentrate feed processed in autoclaves. The process design of the new plant required definition of the deportments of elements such as antimony, arsenic, chlorine, cobalt, fluorine, germanium, magnesium, manganese, selenium, tellurium and thallium. This paper describes the deportment of these elements in the commercial zinc plant during the first nine months of pressure leach operation, and compares these results with operations prior to the introduction of pressure leaching, and with the results of tests carried out in the She"itt laboratory during the process development phase.

Jan 1, 1995

By Alan L. Sangster

Auriferous, bedding-parallel veins occur in zones of carbonaceous, argillaceous and sulfidic turbidites in the Lower to Middle Cambrian sandy flysch of the Goldenville Formation. The 0348 values for vein and wall-rock arsenopyrite and pyrrhotite, and for regional pyrite and pyrrhotite, are highly positive. The values are similar to those from Cambro-Ordovician sediment-hosted deposits of other types, and display trends that increase upward in the stratigraphic sequence. The similarity in composition of vein and wallrock sulfides indicates a seawater-sulfate sourCe for sulfur, derived from the enclosing rocks at the time of vein formation. The upward increase in ?34S values is consistent with closed system sulfate reduction in the anoxic portion of a stratified water-colurnn. Published ? 13C and ? 18() values for Meguma Group vein carbonates are unlike those of other gold-vein carbonates, but are similar to those of diagenetic-metamorphic carbonates from the Meguma Group and elsewhere. These data indicate that the source for the vein-related sulfides and carbonates may be the host strata; possibly the arsenic and gold were derived from the same source.

Jan 1, 1992

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By R. Druffel, P. Wittke-Gattermann, M. Wittke

"The two tubes of tunnel Hirschhagen along the highway A44 in Germany, underpass the federal road B7, a railway line and the valley of the river Losse close to the city of Hessisch Lichtenau. The ground in the area consists of Triassic sand- and siltstones (""Buntsandstein"") as well as tertiary clays. Prior to tunneling, the groundwater in the area is planned to be lowered by means of a gallery of deep wells. As a basis for the design of this dewatering gallery, two large pumping tests have been carried out. The results of these tests have been evaluated by means of 3D-Finite Element analyses. By means of the large-scale model, the influence of the anisotropy resulting from jointing and bedding and the influence of fault zones in the area have been taken into account, which lead to a thorough basis for the design of the dewatering gallery.INTRODUCTIONThe 4.2 km long Tunnel Hirschhagen of the highway A 44 crosses below the federal road B7, a railway line and the river Losse close to the city of Hessisch-Lichtenau in central Germany. Both tunnel tubes are located in a subrosion depression in which Triassic sandstone and tertiary clay prevail. It is planned to lower the groundwater table in the area of the meadow of the Losse prior to tunnel heading [1]. Groundwater lowering is planned to be achieved by means of a series of large pumping wells. The bottom of the river Losse will be sealed in order to avoid direct inflow of water from the river into the ground (Fig. 1 and 2)."

Jan 1, 2015

By Siavash Zamiran, Abdolreza Osouli

"One of the most concerns of room and pillar mining system is subsidence of the ground surface due to coal mining particularly in room and pillar mines. Subsidence of ground surface is a result of floor, pillar, or roof failure of the mine. At the same, due to many difficulties associated with surface disposal facilities of coal refuse, some mining companies are trying to use underground space as a disposal storage place. In this study, stability and subsidence analyses of an underground coal mine located in the Illinois Basin are conducted. This room and pillar mine was abandoned and later on was used as a storage place to accommodate the coal fine refuse with slurry backfilling method. The geological stratigrophy and geomechanical properties of the mine floor and roof were collected. Floor and pillar stability analyses were conducted for areas with various extraction ratios. The stability of the mine was evaluated both prior and after slurry backfilling. The floor and pillar stability analyses results of the mine due to moisture exposure after slurry backfilling are discussed. The subsidence potential due to mine failure is also evaluated.INTRODUCTIONA typical lithology of coal seams in the Illinois Basin consists of weak underclay stratum. The immediate weak underclay causes frequent floor instability problems in Illinois underground coal mines. There are two different stages in assessing floor stability of the mines where slurry backfilling is planned. The first stage is during the mining operation when weak underclay layer squeezes under pillar stress and results in punching or bearing capacity failure. The second stage is after slurry backfilling. During this stage, the slurry material soaks non-durable floor layers and causes strength reduction in floor material. Pillar stability conditions should also be taken into account during both the operational period and after the slurry backfilling."

Jan 1, 2015

By D. Laguitton, D. Cimon

"BILMAT is one of the most powerful algorithms in existence for material balance computation in mineral processing flowsheets. It is based on a hierarchical decomposition coupled with the Lagrange multipliers method widely reported in the literature. Flowrates can be calculated optionally for pulp, solid or water. Assays are adjusted for a variety of subnetworks, such as assays of the solid as well as assays of fractions of the solid called level 4 data (l: pulp, 2:solid and water, 3:assays of solid, 4:assays of classes of solid).BILMAT4 is a new implementation of BIU1AT that operates in a new microcomputer environment and makes the method more accessible than ever. Its main features are a full-screen colour editor allowing graphic flowsheet drawing and data entry with automatic error checking. Mass balance equations are automatically generated by analysis of the graphics and corresponding data, thus relieving users from the error-prone definition of networks. Sensitivity analysis is performed to assess confidence intervals of computed flowrates and adjusted assays.BILMAT4 incorporates an option for gold leaching circuits where the element to be balanced appears in both the solid and liquid phases with negligible effect on the mass flows of solids. Recoveries are computed in all streams. This program is currently released by CANMET as part of the CAMP collection for Computer Aided Mineral Processing. A complete sample run of the program is discussed."

Jan 1, 1989

By Q. Ricoux, F. Goettmann, A. Maihatchi

"Electrodeposition processes are widely used in the metallurgical industry to produce, extract and refine metals from various feed materials. However, raw materials used to provide non-ferrous metals often contain high amounts of iron. In the presence of iron, while metals are plated at the cathode, electrowinning processes produce corrosive and highly oxidative ferric ions at the anode that are harmful for the process sustainability. In fact, these ferric ions cause dramatic current efficiency loss, induce high maintenance expenditures to limit the corrosion of devices and it results in the formation of impure and dendritic deposits on the cathode. Consequently, the management of iron in electrodeposition process became a major issue in non-ferrous metals production. Actually, numerous methods have been developed to limit the ferric ion concentration in the electrolyte or, at least, to limit its harmful effect. Many methods aim to limit the iron(III) concentration in the electrolyte, generally by coupling electrowinning to extraction process such as solvent extraction (SX) (Bender & Emmerich, 2015), ion exchange (IX) (Gula, Dreisinger, & Horwitz, 1996) or cementation (Kust, 1979) processes to remove ferric ions. Other routes consist of (i) using the ferric ions oxidant properties to leach raw materials, either directly in the electrolytic cell (Fanta & Tributsch, 1975) or through a secondary circuit (Cain, 1950), or (ii) reducing ferric ions through periodic reversal of direct current to enhance the formation of Fe2+ (Loutfy & Bharucha, 1980). On the other side of the spectrum, papers discuss methods to valorize the iron from by-products of the non-ferrous metal industry, that generates vast quantities of iron containing wastes (A. Agrawal, Sahu, & Pandey, 2004). Many studies on iron electroplating and electrolytic iron production from ores have been carried out (Cain, 1950; Mostad, Rolseth, & Thonstad, 2008), but very few have been conducted on waste or by-products. Therefore, we propose to build on the previous literature review to develop a process for the production of electrolytic iron from by-products.INTRODUCTIONNon-ferrous metals and their alloys are used in a large variety of applications. Aluminum and titanium are used for their strength, light weight and corrosion resistant properties in structural applications. Copper has been used in various applications requiring high thermal and electrical conductivity, as kitchen products and electrical wires. Nickel and zinc are commonly used as plating materials; nickel offers a wide range of working temperature and zinc is used for steel plating. Gold, silver, and platinum group metals are used in electrical/electronic applications, jewelry and chemistry as catalysts."

Jan 1, 2016

By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019

By R. T. Seaman

There are several hydrometallurgical alternative processing options under development for high enargite and arsenic containing copper concentrates ranging from biological, atmospheric, medium temperature oxidation to total oxidative leaching. The most developed of these options is the CESL process boasting pilot campaigns totaling more than 8760 hours of fully integrated continuous operation, as well as, over two thousand batch scale oxidation tests performed on dozens of concentrates for flowsheet development. This paper reports the observed deportment of arsenic under varying arsenic, iron and acid oxidation conditions; it also describes the impact of iron to arsenic ratios and residue recycle on overall arsenic behavior and its stability in residue. INTRODUCTION The CESL Hydrometallurgical Process (CESL) was originally developed to compete with smelting of clean chalcopyrite concentrates. High Treatment Charges and Refining Charges (TC/RCs) combined with premiums on London Metal Exchange (LME) grade copper from onsite refining made treatment of copper concentrates using CESL a viable option at the time. As world demand for copper increased and a subsidized Chinese refining market developed, smelting contracts became more favourable for the miner and focus was placed on modifying the CESL Hydrometallurgical Process to handle concentrates with elevated deleterious elements. Dozens of pilot campaigns processing concentrates containing elevated concentrations of uranium, fluoride, mercury and nickel all led to further developments of the CESL Hydrometallurgical Process. In 2016 a United States patent was granted for a novel modification of the CESL Hydrometallurgical Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates, Henry Salomon de Friedberg (2016). To date, over 2000 bench scale tests along with five fully integrated closed loop pilot campaigns, totaling over a year of online operation time, have been conducted processing arsenic bearing copper concentrates. This paper summarizes the observed behavior of arsenic under varying autoclave and process conditions.

Jan 1, 2019